We study the formation of novel bicontinuous phases in binary mixtures of AB diblock copolymers (DBCP) using the polymeric self-consistent field theory. We predict that the bicontinuous double-diamond (DD) and plumber’s nightmare (P) phases, which are metastable phases of neat diblock copolymers, could be stablized in gyroid-forming A-minority DBCPs via the blending of specifically designed A-majority DBCPs. The mechanisms of stabilizing different bicontinuous phases are revealed by analyzing the spatial distribution of the different DBCPs. It is found that the A-majority DBCPs residing mainly in the nodes of the structure, thus alleviating the packing frustration of the A-blocks. Furthermore, a local segregation of the two DBCPs occurs at the AB interface, thus regulating the local curvature of the interfaces. A synergetic interplay of these two mechanisms results in a larger stable region of the DD and P phases via the addition of tailored A-majority DBCPs. The theoretical study provides an efficient route to obtain novel bicontinuous phases. / Thesis / Master of Science (MSc)

Eating disorders affect an estimated 1 million Canadians per year and have the highest mortality rate of all mental illnesses (Statistics Canada, 2016; Arcelus, Mitchell, & Wales, 2011). Research suggests that those who fall under the transgender umbrella are at a higher risk for developing mental health concerns, and more specifically disordered eating practices (Dhejne, Vlerken, Heylens, & Arcelus, 2016). Despite this the existing literature on this population is lacking, with little research going outside of the gender binary. Majority of the existing literature is limited in looking at individual case studies seeking to prove that transgender folks can struggle with disordered eating, rather than bring attention to the experiences of transgender individuals within eating disorder treatment and recovery. The purpose of this study was to expand on the current literature by bringing in the voices of lived experience. Semi-structured interviews were conducted with individuals, over the age of 18, who identify their gender as falling under the transgender umbrella who have participated in a form of eating disorder recovery for a minimum of one year. Through a thematic analysis, commonalities were uncovered between the participants stories leading to the identification of five themes: the connection between gender identity and eating disorder development, the impact of LGBTQ+ beauty standards, discrimination within the healthcare system, the use of the internet, and the role of community in recovery. The findings suggest there is a strong connection between transgender identity and the development of eating disorder behaviours that create an experience vastly different than the cisgendered reality in which the treatment programs are based. To address these differences the participants provided guidance towards recommendation for practitioners and treatment including: mandated training on both transgender identities and eating disorders, the development of supportive and inclusive environments, the creation of a transgender specific eating disorder treatment program. Further, topics for future research to deepen the understanding of the experiences shared within the study included: impact of online eating disorder support for trans and non-binary individuals, the variance in experience between binary transgender and non-binary identities within treatment, and the impacts of race and ethnicity on the experiences of transgender individuals. / Thesis / Master of Social Work (MSW)

In this paper, a new approach to modelling 3D faces based on 2D images is introduced. Here 3D faces are created using two photographs from which we extract facial features based on image manipulation techniques. Through the image manipulation techniques we extract the crucial feature lines of the face in two views. These are then used in modifying a template base mesh which is created in 3D. This base mesh, which has been designed by keeping facial animation in mind, is then subdivided to provide the level of detail required. The methodology, as it stands, is semi-automatic whereby our goal is to automate this process in order to provide an inexpensive and expedient way of producing realistic face models intended for animation purposes. Thus, we show how image manipulation techniques can be used to create binary images which can in turn be used in manipulating a base mesh that can be adapted to a given facial geometry. In order to explain our approach more clearly we discuss a series of examples where we create 3D facial geometry of individuals given the corresponding image data.

Yes / A comprehensive study of the thermal behavior of the 1:1 and 2:1 benzoic acid/isonicotinamide cocrystals is reported. The 1:1 material shows a simple unit cell expansion followed by melting upon heating. The 2:1 crystal exhibits more complex behavior. Its unit cell first expands upon heating, as a result of C–H···π interactions being lengthened. It then is converted into the 1:1 crystal, as demonstrated by significant changes in its X-ray diffraction pattern. The loss of 1 equiv of benzoic acid is confirmed by thermogravimetric analysis–mass spectrometry. Hot stage microscopy confirms that, as intuitively expected, the transformation begins at the crystal surface. The temperature at which conversion occurs is highly dependent on the sample mass and geometry, being reduced when the sample is under a gas flow or has a greater exposed surface area but increased when the heating rate is elevated.

This thesis paper gives a brief history of the vampire narrative and its role in representing the collective anxieties of an age as well as serving as a metaphor for oppressed peoples. It uses Bram Stoker’s Dracula and J. Sheridan le Fanu’s Carmilla as historical examples of how the vampire adapts to suit issues of the day such as reverse colonization and female sexuality, respectively. The latter part of this paper speculates on the future role of the vampire in literature and proposes that the vampire could be used to discuss transgender issues as well as challenge the gender binary. It addresses the suitability of the vampire narrative in particular for representing gender as a spectrum using the lenses of Foucault’s heterotopias, Kristeva’s abject, and Freud’s uncanny and pulls examples of early evidence of this trend from Anne Rice’s Vampire Chronicles.

Thesis (Ph.D. (Physics)) --University of Limpopo, 2011 / Planewave pseudopotential calculations were conducted to predict the energetics and phase stability of Pt-Cr and Ru-Cr binary alloys. Validation of appropriate number of k-points and planewave energy cut-off was carried out for all studied systems. At the composition of A3B and AB3 (where A = Cr and B = Pt or Ru) phases, the heats of formation determined for five different structures, L12, A15, tP16, DOC and DO′ C are almost of the same magnitude and the relaxed structures show no rotation. We observed that the cubic L12 Pt3Cr is the most stable structure in agreement with the experiments. The results for PtCr3 indicate the negative heat of formation for the A15 phase whereas all the remaining studied phases have positive heats of formation. It is clear that the PtCr3 (A15) is the most stable structure. PtCr (L10) was found to be more stable compared with PtCr (B2) phase. The L12 Pt3Cr, A15 PtCr3 and L10 PtCr phases could be considered as possible coatings to cover the engines which are exposed to aggresive environments. The heats of formation of all studied compositions and phases of Ru-Cr systems are positive, these results suggest that, generally, studied Ru-Cr phases are not stable. The effect of pressure and doping were investigated on A15 RuCr3 structure which was reported to exist at a higher temperature. Elastic constants and moduli were investigated to determine the strength of the PtCr systems. The strength of PtCr L10 is greater than that of B2 phase. The ratio of shear to bulk modulus (G/B) has been used to predict the ductility or the brittleness of the material. It was found that Pt3Cr L12 is the most ductile phase among those considered in this study. The density of states were calculated to further analyze the stability of systems. The magnetic properties of Cr were studied using VASP which predicted an anti-ferromagnetic and a non-magnetic ground state for pure Cr. We have investigated the thermal stability at 0 GPa for different phases of Pt3Cr, PtCr3, PtCr and RuCr3 A15 phase, where we detected the soft modes at X, G, M and R points of the Brillouin zone from the phonon spectra of Pt3Cr A15 phase. Pt3Cr L12 and PtCr3 A15 are predicted as dynamically stable structures. RuCr3 A15 phase was found to be dynamically stable but thermodynamically unstable. Phonon DOS were studied to observe the modes of vibration and atoms that contribute to soft modes. Lastly we investigated the thermal expansion of Pt3Cr L12 and A15 phases. / The National Research Foundation,and the South African Gas Turbine Research Program

No description available.

Shannon showed that the codes with random-like codeword weight distribution are capable of approaching the channel capacity. However, the random-like property can be achieved only in codes with long-length codewords. On the other hand, the decoding complexity for a random-like codeword increases exponentially with its length. Therefore, code designers are combining shorter and simpler codes in a pseudorandom manner to form longer and more powerful codewords. In this research, a method for designing non-binary compound codes with moderate to high coding rate is proposed. Based on this method, non-binary single parity-check (SPC) codes are considered as component codes and different iterative decoding algorithms for decoding the constructed compound codes are proposed. The soft-input soft-output component decoders, which are employed for the iterative decoding algorithms, are constructed from optimal and sub-optimal a posteriori probability (APP) decoders. However, for non-binary codes, implementing an optimal APP decoder requires a large amount of memory. In order to reduce the memory requirement of the APP decoding algorithm, in the first part of this research, a modified form of the APP decoding algorithm is presented. The amount of memory requirement of this proposed algorithm is significantly less than that of the standard APP decoder. Therefore, the proposed algorithm becomes more practical for decoding non-binary block codes. The compound codes that are proposed in this research are constructed from combination of non-binary SPC codes. Therefore, as part of this research, the construction and decoding of the non-binary SPC codes, when SPC codes are defined over a finite ring of order q, are presented. The concept of finite rings is more general and it thus includes non-binary SPC codes defined over finite fields. Thereafter, based on production of non-binary SPC codes, a class of non-binary compound codes is proposed that is efficient for controlling both random-error and burst-error patterns and can be used for applications where high coding rate schemes are required. Simulation results show that the performance of the proposed codes is good. Furthermore, the performance of the compound code improves over larger rings. The analytical performance bounds and the minimum distance properties of these product codes are studied. / Thesis (Ph.D.)-University of KwaZulu-Natal, Durban, 2013.

Machine emulation allows for the simulation of a real or virtual machine, the source machine, on various host computers. A machine emulator interprets programs that are compiled for the emulated machine, but normally at a much reduced speed. Therefore, in order to increase the executions peed of such interpreted programs, a machine emulator may apply different dynamic optimization techniques. In our research we focus on emulators for real machines, i.e. existing computer architectures, and in particular on dynamic binary translation as the optimization technique. With dynamic binary translation, the machine instructions of the interpreted source program are translated in to machine instructions for the host machine during the interpretation of the program. Both, the machine emulator and its dynamic binary translator a resource and host machine specific, respectively, and are therefore traditionally hand-written. In this thesis we introduce the Walkabout/Yirr-Ma framework. Walkabout, initially developed by Sun Micro systems, allows among other things for the generation of instrumented machine emulators from a certain type of machine specification files. We extended Walkabout with our generic dynamic optimization framework ‘Yirr-Ma’ which defines an interface for the implementation of various dynamic optimizers: by instrumenting a Walkabout emulator’s instruction interpretation functions, Yirr-Ma observes and intercepts the interpretation of a source machine program, and applies dynamic optimizations to selected traces of interpreted instructions on demand. One instance of Yirr-Ma’s interface for dynamic optimizers implements our specification-driven dynamic binary translator, the major contribution of this thesis. At first we establish two things: a formal framework that describes the process of machine emulation by abstracting from real machines, and different classes of applicable dynamic optimizations. We define dynamic optimizations by a set of functions over the abstracted machine, and dynamic binary translation as one particular optimization function. Using this formalism, we then derive the upper bound for quality of dynamically translated machine instructions. Yirr-Ma’s dynamic binary translator implements the optimization functions of our formal framework by modules which are either generated from, or parameterized by, machine specification files. They thus allow for the adaptation of the dynamic binary translator to different source and host machines without hand-writing machine dependent code.

abstract: This phenomenological study explores the question: What are the lived experiences of Arizonans who identify their gender identities as ‘non-binary’? (‘non-binary’ defined here as anyone who identifies their gender as something other than ‘always and exclusively male or always and exclusively female’). The study explores the lived realities of four non-binary identified transgender people living in Arizona. Each participant took a short survey and conducted a 45-minute in-person interview, conducted through phenomenological questioning to evoke deep descriptions of experience. After analyzing the results through feminist hermeneutic phenomenology, this study suggests that the experience of non-binary gender identity presents an essential pattern of cultivating self-realization. The essential themes of internal recognition, external presentation, and movement toward wellness fell into this pattern. The United States has conceptualized transgender identity in many ways, from pathologizing to politicizing, to medically affirming views. Although the literature on this topic is quite small, there is no doubt that non-binary transgender people exist in U.S. public life. Ultimately, if non-binary people are to find affirming paths toward self-realization, they must be heard from their own experiences in their own voices. / Dissertation/Thesis / Masters Thesis Social and Cultural Pedagogy 2017