Thesis (Ph. D.)--University of Texas at Austin, 2009. / Title from PDF title page (University of Texas Digital Repository, viewed on Aug. 6, 2009). Vita. Includes bibliographical references.

xiv, 195 p. : ill. (some col.) A print copy of this thesis is available through the UO Libraries. Search the library catalog for the location and call number. / We explore the reconstruction of B-state vibrational wave packets in I 2 from simulated two-color nonlinear wave packet interferometry data. As a simplification of earlier proposals, we make use of different vibrational energy ranges in the B-state--rather than different electronic potential surfaces--for the short-pulse preparation and propagation of both target and reference wave packets. Numerical results from noisy interferograms indicate that experimental reconstruction should be possible with high fidelity (>0.99). Time-resolved coherent nonlinear optical experiments on small molecules in low-temperature host crystals are exposing valuable information on quantum mechanical dynamics in condensed media. We make use of generic features of these systems to frame two simple, comprehensive theories that will enable the efficient calculation of their ultrafast spectroscopic signals and support their interpretation in terms of the underlying chemical dynamics. Both treatments rely on the identification of normal coordinates to unambiguously partition the well-structured guest-host complex into a system and a bath and expand the overall wave function as a sum of product states between fully anharmonic vibrational basis states for the system and approximate Gaussian wave packets for the bath degrees of freedom. The theories exploit the fact that ultrafast experiments typically drive large-amplitude motion in a few intramolecular degrees of freedom of higher frequency than the crystal phonons, while these intramolecular vibrations indirectly induce smaller-amplitude--but still perhaps coherent--motion among the lattice modes. The equations of motion for the time-dependent parameters of the bath wave packets are fairly compact in a fixed vibrational basis/Gaussian bath (FVB/GB) approach. An alternative adiabatic vibrational basis/Gaussian bath (AVB/GB) treatment leads to more complicated equations of motion involving adiabatic and nonadiabatic vector potentials. Numerical tests of the FVB/GB are presented. We consider two bilinearly coupled harmonic oscillators with varying coupling strengths and initial conditions and show that the mixed quantum/semiclassical theory compares favorably with the exact results. Linear absorption spectra and wave-packet interferometry signals calculated using the theory are presented. This dissertation includes previously published coauthored material. / Committee in charge: David Herrick, Chairperson, Chemistry; Jeffrey Cina, Advisor, Chemistry; Thomas Dyke, Member, Chemistry Michael Kellman, Member, Chemistry; Hailin Wang, Outside Member, Physics

The two main causes of packet corruption in wireless sensor network are multipath fading and WiFi interference. Identifying the cause of the corruption can be used to improve the reliability of the transmission. If the corruption is caused by WiFi interference, the network could change the channel to a free one. If it is caused by multipath fading, the network could reroute the traffic away from the obstacles or shorten the distance. This project proposes a new method of corruption-causes-identification for the two causes mentioned. It is an immediate online diagnostic tool for IEEE 802.15.4 packets with a retransmission mechanism. It provides a statistical boundary with a processed deviation of RSSI value and the frame symbol error rate, and also a rechecking mechanism to check the decisions. In this model, the deviation of RSSI value is measured by the estimated RSSI value of correct packets and the current detected RSSI value. The benefit of the deviation design is that the statistical model hardly needs to retrain and correct the parameters in different transmission environments. The project also discusses two rechecking mechanism methods, one employs an individual secondary classification with its own characters; the other combines the neighbor packets' features to smooththe probable errors. To investigate the performance of the "frame symbol errorrate and deviation of RSSI values"-based diagnostic tool, the evaluation parts provide a comparison of different length packets. The conclusion is that this diagnostic tool provides a correct judgment of the accuracy of packet corruption caused by multipath fading up to 98.70%, and an accuracy of up to 92.99% for the WiFi-interferenced packet corruption.

In this thesis, we present a theoretical investigation of reactive processes involving the HeH$^+$ molecular ion, with applications in laboratory and astrophysical plasma physics. We consider in particular two processes, which are the charge transfer in H + He$^+$ collisions at low energy from a molecular approach and the photodissociation of HeH$^+$.<p><p>At the molecular level, the cross section is the basic quantity that has to be determined in order to achieve an understanding of reactive processes. Its calculation will be based on the description of the reactions using an emph{ab initio}, quantum mechanical approach. In this work, we will rely on the Born-Oppenheimer approximation, which allows the molecular motion to be separated into an electronic and a nuclear motion. The evaluation of cross sections then follows two steps.<p>The first is the determination of the electronic structure of the molecule. We will calculate the adiabatic potential energy curves of the excited electronic states as well as the dipole matrix elements between these states. The non-adiabatic radial and rotational couplings, which result from the breakdown of the Born-Oppenheimer approximation, are also estimated. The second step is to solve the nuclear motion, which we achieve using a time-dependent method based on the propagation of wave packets on the coupled electronic states. <p><p>A particular emphasis will be put on the importance of the excited states and of the non-adiabatic couplings in the description of reactive processes. <p>In the treatment of the charge transfer reaction between H and He$^+$ in excited states, it is well known that the non-adiabatic radial couplings cannot be neglected. However, we will show that the inclusion of the non-adiabatic rotational couplings is also necessary in order to obtain accurate state-to-state cross sections.<p>In the description of the photodissociation of HeH$^+$ from its ground state, we will show the influence of the excited states on the rate constant and the role of the non-adiabatic radial couplings in the determination of partial cross sections.<p>We will also consider the possible astrophysical applications of the first triplet state of HeH$^+$. We will show that this state is metastable by evaluating its lifetime, and calculate the cross sections and rate constants for the photodissociation and radiative association of HeH$^+$ in this state.<p> / Doctorat en Sciences / info:eu-repo/semantics/nonPublished

This study investigated the efficacy of bibiliotherapy in a correctional setting. Bibliotherapy (the utilization of books, pamphlets, or other literature) has been recommended as an adjunct to psychotherapy when professional time was at a premium or when the motivational level of the clientele was marginal. The experimental problem of this present study was to assess the usefulness of bibliotherapy in coping with psychological problems found within the correctional setting. This investigation was designed to explore the effects of two self-help packets on two diverse prison populations.

Tato práce je zaměřena na zpracování a analýzu USB komunikačního protokolu a implementace jeho jednotlivých částí do FPGA obvodu s využitím programovacího jazyka VHDL. Ve finální podobě by měla práce představovat souhrnný a ucelený dokument popisující principy USB rozhraní a jeho komunikace doplněných praktickým návrhem v jazyce VHDL, který by byl schopen převést data do USB.

Die Ausbreitungspfade und die strukturelle Veränderung von quasi geostrophischen Rossby-Wellenpaketen werden mittels der WKB-Methode untersucht. Es wird angenommen, daß die Wellenpakete an einem in Ost-West-Richtung verlaufenden festen Rand reflektiert werden können. Die Dynamik der Rossby-Wellenpakete wird auf der ß-Ebene aber auch auf der sogenannten d-Oberfiäche - wo auch die zweite Ableitung des Coriolis-Parameters eine Rolle spielt - studiert. Es wird gezeigt, daß die Wellenpakete unter bestimmten Umständen große Entfernungen in zonaler Richtung entlang der Küste zurücklegen können und damit die Strömung weit stromab beeinflussen. Die Wellenpakete sind dabei zwischen dem reflektierenden Rand und einer Umkehrbreite gefangen im Unterschied zu freien Rossbywellen in der Atmosphäre, die zwischen zwei Umkehrbreiten gefangen werden können. Es zeigt sich, daß der d-Term keine besonders wichtige Rolle für die Ausbreitung der Rossby-Wellenpakete spielt, am wichtigsten ist er noch bei der Dynamik von Wellen mit negativer Phasengeschwindigkeit. Es wird vorgeschlagen, daß ein selektiver Rossby-Wellenleiter wie er hier diskutiert wird eine Rolle in der Dynamik des Antarktik-Zirkumpolarstromes spielt. / We study the propagation and the structural change of quasi geostrophic Rossby wave packets by means of a WKB-method. Our approach involves the introduction of a rigid boundary, where the wave packets can be refiected elastically. We study Rossby wave packet dynamics at high latitudes on a modified ß-plane, where the second derivative of the Coriolis parameter with respect to latitude is taken into account (d-term). We show that under certain conditions synoptic-scale wave packets can propagate far distances along an east-west oriented \'coast\' and may affect the fiow far downstream of the source region. In contrast to free propagating Rossby wave packets ( e.g. in the atmosphere), which can be trapped between two turning latitudes, the wave packets considered here are trapped between a turning latitude and the reflecting boundary. lt turns out that the 6-term is most important for wave packets with negative phase speeds. Finally, we suggest that such a selective Rossby waveguide may play a role in the dynamics of the Antarctic Circumpolar Current.

The master Thesis deals with an overview of issues necessary for design of custom network analyzer. Describes the existing solutions, provides the theoretical background needed for design of custom analyzer and describes the structure of implemented system. A separate part of the work is devoted to the specification of Metamodel used to modeling of communication protocols and compiler of models modeled with the Metamodel.

This thesis investigates the network performance of DPDK, io_uring, and the standard Linux network stack in terms of latency, packet loss, throughput, and packet rate. DPDK is widely adopted in the telecommunication industry and has been for several years. io_uringis a new Linux system call interface, as of this writing, used for asynchronous I/O operations and could potentially offer better network performance than the standard Linux network stack. The analysis involves benchmarking of DPDK, io_uring and Linux network stack both with a continuous flow of data traffic and bursty traffic to see how the applications are able to handle different kinds of data traffic conditions. The Linux kernel network parameters were tuned in order to investigate what kind of performance increase can be achieved for an application using io_uring to gain a better understanding of howio_uring compares to DPDK. From the analysis, it was concluded that DPDK had the best overall performance when considering packet loss, throughput, latency, and packet rate.io_uring performed better than the Linux network stack in terms of throughput, packet loss, and packet rate but was not considerably better in terms of latency. When comparing the latency of bursty traffic for DPDK, io_uring, and the standard Linux network stack, it was shown that the kernel-based alternatives were better able at handling traffic over their maximum performance than DPDK, thus it may offer better scalability. After tuning the Linux kernel network parameters it was concluded that tuning may impact the performance network metrics of an application using io_uring. We conclude that io_uring shows some promising results compared to the standard Linux network stack, but is not yet able to compare with DPDK in network performance. The development of io_uring is ongoing and it may improve further in the future.

We study the unique phenomena which occur in certain systems characterized by the crossing or avoided crossing of two electronic eigenvalues. First, an example problem will be investigated for a given Hamiltonian resulting in a codimension 1 crossing by implementing results by Hagedorn from 1994. Then we perturb the Hamiltonian to study the system for the corresponding avoided crossing by implementing results by Hagedorn and Joye from 1998. The results from these demonstrate the behavior which occurs at a codimension 1 crossing and avoided crossing and illustrates the differences. These solutions may also be used in further studies with Herman-Kluk propagation and more. Secondly, we study codimension 2 crossings by considering a more general type of wave packet. We focus on the case of Schrödinger equation but our methods are general enough to be adapted to other systems with the geometric conditions therein. The motivation comes from the construction of surface hopping algorithms giving an approximation of the solution of a system of Schrödinger equations coupled by a potential admitting a conical intersection, in the spirit of Herman-Kluk approximation (in close relation with frozen/thawed approximations). Our main Theorem gives explicit transition formulas for the profiles when passing through a conical crossing point, including precise computation of the transformation of the phase and its proof is based on a normal form approach. / Doctor of Philosophy / We study energies of molecular systems in which special circumstances occur. In particular, when these energies intersect, or come close to intersecting. These phenomena give rise to unique physics which allows special reactions to occur and are thus of interest to study. We study one example of a more specific type of energy level crossing and avoided crossing, and then consider another type of crossing in a more general setting. We find solutions for these systems to draw our results from.