Electrical engineers have responded to the increasing demand for circuit speed and functionality by reducing transistor feature size and increasing on-chip transistor density. Consequently, interconnect density, both on-chip and the system level is also increasing. Increasing circuit speed translates into shorter clock cycles and signals with faster edge rates, which have multi-GHz bandwidth. Densely packed parallel interconnects will cause signal integrity problems not only due to the increase in crosstalk noise but also due to the intrinsic low pass filter characteristics of the interconnects. The lossy nature of the interconnects is also going to increase due to metal surface roughness at higher frequencies, which will further degrade the signal quality at the receiver input. Embedded Patterned Layer (EPL), which is a patterned floating metal layer between a signal trace and its return path shows promise in reducing far-end crosstalk (FEXT). EPL also allows designers to modify the characteristic impedance of interconnects by varying the different physical parameters of the EPL. This dissertation analyzes the effect of EPL on conductor backed coplanar waveguides (CB-CPW). CB-CPWs excite higher order modes at high frequencies, so work was done to understand the effect of different ground via fence parameters in suppressing the higher modes which helps increase the interconnect bandwidth. A CB-CPW with ground via fence is called a grounded coplanar waveguide (GCPW). A very basic lumped element model transmission line model was developed to account for the effect of floating metals near a transmission line. This model was then used to explain the effect of EPL on a GCPW with large bandwidth. EPL reduces the characteristic impedance of the transmission line. Engineers can then design narrow high impedance transmission lines and use EPL to reduce the impedance to a desired value. This also allows reduction in crosstalk by increasing the spacing between the transmission lines. The EPL also reduced the differential impedance of a grounded conductor backed edge coupled coplanar waveguide, when it was used for differential signaling. Care must be taken to make sure that the EPL is symmetric to both the legs of the differential pair to avoid differential to common mode energy conversion, which can cause electromagnetic interference (EMI) problems. EPL reduced FEXT while increasing near-end crosstalk (NEXT), when the coupled transmission line system was used for single ended signaling. Finally, a statistical method for modeling transmission line metal surface roughness in three dimensional (3D) full wave electromagnetic solvers was developed to account for increased attenuation in transmission lines, at high frequencies, due to metal surface roughness.

Highly ordered magnetic materials with high perpendicular magnetic anisotropy (PMA), such as the L10 ordered FePt, and new recording technologies, such as bit patterned media (BPM), have been proposed as solutions to the media trilemma problem and provide promising strategies towards future high-density magnetic data storage media. L10 ordered FePt thin films can provide the necessary high PMA. However, the ordering of this material perpendicular to the plane of the films remains challenging since high-temperature and time-consuming processes are required. In this work, a remote plasma sputtering system has been used for the investigation of FePt thin films in order to understand if the greater control of process parameters offered by this system can lead to enhanced ordering in L10 FePt thin films at low temperatures compared with conventional dc magnetron approaches. More specifically, the effect of the different substrate temperatures and the target bias voltages on the ordering, the microstructure and the magnetic properties of FePt thin films was investigated. Highly ordered FePt thin films were successfully fabricated after post-annealing processes and were patterned into arrays of FePt islands. This patterning process was carried out with e-beam lithography and ion milling. Initial MFM measurements of these islands showed their single-domain structure for all the island sizes, which indicated the high PMA of the FePt. Magnetometry measurements were also carried out with a novel polar magneto-optical Kerr effect (MOKE) system which was designed and built during this project. This system has unique capabilities which are: a) the application of uniform magnetic field up to 2 Tesla, b) the rotation of the field to an arbitrary angle and c) the use of lasers of four different wavelengths. The combination of these abilities enabled measurements on ordered FePt thin films and patterned media which can pave the way for further highly sensitive measurements on magnetic thin films and nanostructures.

Cryoturbation is a fundamental soil forming process with large importance for ecosystem functioning in the Arctic. Recent investigations have emphasized the effect of climate change on cryoturbation, but contrast in their predictions on cryoturbation under future climate warming. This study analyzed to what extent conclusions on the response of cryoturbation to environmental conditions depend on: 1) the proxy of cryogenic activity used; 2) the spatial scale of environmental predictor variables; and 3) the mesoclimatic regime of the study site. As an example of cryoturbated soil, 48 non-sorted patterned-ground features were sampled at eight sites along an elevational and a precipitation gradient and vegetation gradients nested within each site in the Abisko area, northernmost Sweden. To quantify cryogenic activity, eight proxies of cryogenic activity were used. In addition, environmental data were obtained at two spatial scales from field surveys and existing geodata. The results suggest a significant correlation between most activity proxies. Cryogenic activity increased along the precipitation gradient and peaked at intermediate elevations, while within-site variation was similar to between-site variation. The response of cryogenic activity to environmental factors was largly independent of the proxy used but varied with the spatial scale of predictor variables and across mesoclimatic regimes, with precipitation and vegetation cover being the most important predictors. The study indicates that spatial scale and mesoclimate should be considered when assessing the sensitivity of cryoturbation to climate changes. The results therefore provide possible explanations for contrasting previous predictions on the fate of cryoturbated patterned-ground ecosystems under future climate warming.

Bit-Patterned Media (BPM) has been recognised as one of the candidate technologies to achieve an areal density beyond 1Tb/in2 by fabricating single-domain islands out of continuous magnetic media. Though much attention has been focused on the fabrication of BPM, existing lithography techniques demonstrate difficulties in producing uniform islands over large areas cost effectively; the resulting fabricated islands often vary in position and size. The primary purpose of the research documented in this thesis is to investigate the issue of island geometry variations on the data recovery process from a perpendicular patterned media with head and media configurations optimised to achieve an areal density of 1Tb/in2. In order to achieve the research aim, a read channel model has been implemented as a platform to evaluate the read channel performance numerically. It can be also altered to investigate new read channel designs. The simulated results demonstrate that island geometry variations have a detrimental effect on read channel performance. It has shown that a BPM system can be tolerant to island position variations, but more effort needs to be paid to the effect that island size variations have on the read channel performance. A new read channel design revolving around the design of a modified trellis has been proposed for use in the Viterbi detector in order to combat the effect of island geometry variations. The modified trellis for island position variations results in extra states and branches compared to the standard trellis, while the modified trellis for island size variations results in only extra branches. The novel read channel designs demonstrate an improved read channel performance in the presence of island geometry variations even with increasing amounts of island position and size variations. There are two ways to obtain the read channel performance in terms of the bit-error-rate (BER): a) by running a numerical Monte-Carlo simulation to count the number of bits in error at the output of the read channel model and b) using an analytical approach to calculate the BER by approximating the noise into a known distribution. It is shown that both ways demonstrate very similar results, which indicates as long as the distribution of the noise present in read channel model is predictable, the analytical approach can evaluate the BER performance more efficiently, especially when the BER is low. However, the Monte-Carlo simulation is still useful for understanding of the correlation of the errors. Novel trellis proposed in this work will contribute to the commercial development of BPM in two ways: a) to improve the data recovery process in BPM systems, b) to allow a tolerance of 10% size variations for the existing fabrication techniques.

For the past 50 years, the magnetic storage industry has been the ultimate provider, covering the ever-expanding needs of digital mass storage. Up to now, scaling to smaller dimensions has been the core approach for achieving higher areal densities in conventional media. However, recent studies have shown that further miniaturisation is physically bound by superparamagnetic effects. Bit patterned media (BPM) is one of the most promising solutions for extending the areal densities beyond 1Tbit/in². The ability to magnetically characterise novel BPM is a key requirement for its future commercialisation. The work presented in this thesis describes the investigation of the Magneto-Optic Kerr Effect (MOKE) and the Anomalous Hall Effect (AHE) techniques, used in the characterisation of BPM samples. These samples were produced as part of this work using a customised subtractive fabrication process. Continuous thin magnetic films with Ptseed(10nm)/[Co(0.4nm)/Pt(1nm)]x15 composition and perpendicular anisotropy, were deposited using electron-beam (e-beam) evaporation, and subsequently patterned into magnetic nano-islands through means of e-beam lithography and Ar⁺ ion milling. In terms of the MOKE technique, a fully customised polar MOKE system has been developed and successfully used to observe the hysteretic behaviour of magnetic nano-island arrays with varying dimensions. An expected reduction in the MOKE signal due to pattering has been observed, as well as an additional signal reduction due to the scattering effect arising from the non-vertical sidewalls of the dome-shaped islands. In the case of islands with improved shape profile, the magnetic reversal of BPM arrays with islands sizes down to 35nm has been successfully detected, demonstrating a sensitivity of approximately 6x10⁻¹³emu for the MOKE system. In terms of the AHE technique, Au Hall crosses were deposited on top of the BPM arrays that had been previously characterised by MOKE, allowing the direct comparison and cross-verification of the results obtained by the two techniques. A revised Hall cross design, where the Hall crosses were generated by direct patterning of the Pt seed layer, has provided a significant improvement in AHE signal. This has allowed the detection of the magnetic reversal of individual sub-50nm magnetic islands, demonstrating a sensitivity of approximately 6.6x10⁻¹⁵emu for the AHE technique. The spatial sensitivity of these Hall cross structures has been experimentally determined, indicating a decrease in sensitivity with increasing distance from the cross centre and with decreasing island diameter. In conclusion, the sensitivity profile of Hall cross structures must be taken into account for the accurate interpretation of BPM characterisation results obtained by the AHE technique. Finally, some suggestions are outlined with regard to the future improvement of the developed characterisation techniques and the further continuation of the work presented in this thesis.

The work in this PhD thesis covers two strands of x-ray experiments: firstly, the characterisation of large arrays of dense structures by means of x-ray scattering, and, secondly, the investigation of hybrid anisotropy square structures with x-ray microscopy. The ability to accurately characterise large arrays of nanoscale magnetic structures is a key requirement for both scientific understanding and technological advance such as bit patterned recording media (BPM). In this work small angle x-ray scattering (SAXS) was investigated as a characterisation technique for large arrays of patterned structures. Dense arrays of magnetic nanostructures were prepared on x-ray transparent membranes and measured. The SAXS data was then modelled to obtain structure parameters such as the mean structure diameter, the diameter distribution and the mean position variance with statistical significance. Arrays (500 x 500 μm2) of nominally uniform nanostructures with centre-to-centre distances between 250 nm-50 nm were structurally characterised and compared to structure diameters obtained by optical scanning electron microscopy measurements. The mean structure diameter was found to be between 39 nm-15nm and agree within the errors with the diameter obtained from SEM measurements. This work provides accurate data on the distribution (variance) of nanostructure sizes which is key for modelling these arrays for applicationin BPM. In the second part of the work, the static and dynamic properties of patterned hybrid anisotropy square structures ([Co/Pd]-Py) were investigated by using time-resolved scanning transmission X-ray microscopy (STXM). In these patterned structures the magnetisation in the layers change both in magnitude and direction and gives rise to interesting new domain configurations. The reciprocal interaction between magnetic vortices in the Py layer and locally circular stripe domains in the Co/Pd was investigated and a mutual domain imprint between the layer was observed. In dynamic excitation experiments the precession of the vortex core is studied and showed good agreement with micromagnetic simulations made by Hrkac and Bryan. As demonstrated patterned hybrid anisotropy square structures have promising magnetic properties with potential applications in data storage (vortex switching) or spintronics (vortex oscillators).

Forensic anthropologists and taphonomists are often tasked with interpreting the sequence of events from death through decomposition to skeletonisation. Discovery of burnt bone often evokes questions as to the condition of the body prior to the burn event. The purpose of this study was to evaluate features of thermal damage on bones in relationship to the condition of the bone (dry/wet) and progression of decomposition. Twenty-five pigs in various stages of decomposition (fresh, early, advanced, early & late skeletonisation) were exposed to fire for 30 minutes. The skeletal elements were scored and features included: colour change (unaltered, charred, calcined), brown and heat borders, heat lines, delineation, greasy bone, joint shielding, predictable and minimal cracking, delamination and heatinduced fractures. Colour changes were scored according to a ranked percentage scale (0 – 3) and the remaining traits as absent or present (0/1). Cohen’s Kappa statistics evaluated intraand interobserver error. Density plots and frequency distributions were constructed and multiple regression (categorical variables) and transition analysis were employed. The majority (8) of the 13 traits displayed potential to predict decomposition stage from burned remains. An increase in calcined and charred bone occurred synchronously with an advancement in decomposition. The organic composition of bone and presence of flesh affect the characteristics features of burned bone. Greasy bone occurred most often in the early/fresh stages (fleshed bone). Heat borders, heat lines, delineation, joint shielding, predictable and minimal cracking were associated with wet tissue/bone; whereas brown burn/borders, delamination and other heat-induced fractures were associated with early and late skeletonisation. No statistically significant differences were noted among observers for the majority of the traits except for predictable and minimal cracking and heat-induced fractures in the cranium. Heat-induced changes may assist in estimating decomposition stage from unknown, burnt remains and thereby aid in a providing an indication as to the condition of the bone prior to the burn event. / Thesis (PhD)--University of Pretoria, 2013. / gm2014 / Anatomy / unrestricted

In the thesis at hand, different concepts of magnetic recording were investigated both from an experimental and theoretical point of view. On the one hand, micromagnetic simulations of bit patterned media were performed examining the influence of magnetic and geometrical parameters on the magnetization reversal mechanism of the bit array. In this regard, the recording concept called exchange coupled composite (ECC) media was applied in combination with bit patterned media (BPM). It was demonstrated that ECC/BPM is superior in terms of narrowing the SFD which is vital for the implementation of BPM as a recording scheme in magnetic data storage deviced. Moreover, the stability of the magnetic state was calculated for single nanomagnets using the nudged elastic band algorithm. It was found out that the magnetic and geometrical properties have a severe influence on both, the energy barrier for magnetization reversal and the magnetization reversal process of the single nanomagnets. On the other hand, experimental studies of granular CoCrPt:SiO2 films deposited on self-assembled arrays of SiO2 nanoparticles with a size from 10 nm to 330 nm have been carried out, showing a distinct size-dependence of the coercive field and remanent magnetization with changing nanoparticle size. Moreover, these films have been irradiated with Co+ ions with different fluences, resulting in a change of the magnetic properties of the films due to both a change of the intergranular exchange coupling of the film and a degredation of the magnetic layers at higher irradiation fluences.

Nowadays, Carbon Fiber-Reinforced Polymers (CFRPs) have been widely applied in the aerospace and automotive industries. Secondary adhesive bonding, instead of using rivets or bolts in conventional mechanical fastenings, is promising in joining CFRPs because it is simple and applicable for cured parts, widely applied for repairing structures, and of light weight. However, the mechanical performance of secondary bonding is very sensitive to the treatment of CFRP parts. Besides, another concern arises from the fact that secondary bonded specimen often prematurely fails due to delamination and leads to a catastrophic structural collapse. While enhancing the joint strength and toughness is important, limiting the progression of damage is crucial, to ensure confidence in the design and allow enough time for maintenance and repair. Therefore, it is significant to introduce a crack arrest feature into the joints, to slow down (or even stop) the crack growth and achieve progressive failure. In this thesis, we employ advanced surface preparation strategies to enhance the strength, toughness, and safety of adhesively bonded CFRP joints. Globally uniform surface pretreatments, using conventional mechanical abrasion, peel-ply, and pulsed CO2 laser irradiation, are employed at first to improve the mechanical responses of adhesively bonded CFRP joints. Then, to better understand damage mechanisms and guide the joint design, characterizations of surface chemistry, surface energy, and surface morphology are correlated with obtained strength and toughness. Next, trench patterns, ablated by pulsed CO2 laser irradiation, are applied to CFRP substrate to further analyze the role of surface roughness on increased mode I energy release rate. Finally, a novel surface patterning strategy is proposed to achieve superior toughness enhancement in adhesively bonded CFRP joints to improve the joint safety. Such surface preparation strategy is assessed through 2D numerical models and realized experimentally by patterning of pulsed CO2 laser irradiation, illustrating its potential in toughening the joint and successfully delaying the crack propagation.

The histologic distinction of follicular patterned lesions of thyroid, that is follicular adenoma, follicular carcinoma, and the follicular variant of papillary thyroid carcinoma can be extremely difficult. The differential diagnostic criteria regarding nuclear features of papillary thyroid carcinoma are subjective, resulting in high interobserver variability. Although papillary thyroid carcinoma metastasizes mainly via lymphatic vessels, whereas follicular carcinoma spreads mostly hematogenously, there are no data regarding utility of objective quantitative criteria such as lymphatic and general blood vessel density for the differential diagnosis of these lesions. In this study, 35 follicular patterned lesions of thyroid (14 follicular adenomas, 10 follicular carcinomas, and 11 of the follicular variant of papillary thyroid carcinomas) were evaluated immunohistochemically. An assessment of intra- and peritumoral lymphatic vessel density was performed using novel lymphatic endothelium-specific marker D2-40, and the intra- and peritumoral general vessel density was determined by the panendothelial marker CD31. There were no significant differences in the intra- and/or peritumoral general vessel densities, and peritumoral lymphatic vessel densities among follicular adenoma, follicular carcinoma and the follicular variant of papillary thyroid carcinoma. In contrast, the intratumoral lymphatic vessel density was significantly higher in the follicular variant of papillary thyroid carcinoma than in either follicular adenoma or follicular carcinoma (34.63, 15.04, and 0.11 respectively; P<0.0001). The results of the study show that intratumoral lymphatic vessel density may serve as a useful tool in the differential diagnosis of follicular patterned lesions of thyroid. © 2005 USCAP, Inc All rights reserved.