• Refine Query
  • Source
  • Publication year
  • to
  • Language
  • 163
  • 27
  • 5
  • 5
  • 4
  • 3
  • 2
  • 2
  • 1
  • 1
  • 1
  • 1
  • 1
  • 1
  • Tagged with
  • 281
  • 74
  • 72
  • 58
  • 57
  • 50
  • 50
  • 49
  • 48
  • 46
  • 39
  • 36
  • 34
  • 30
  • 30
  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
211

Quels indicateurs pour évaluer la qualité de sols forestiers soumis à des contraintes environnementales fortes ?

Cécillon, Lauric 31 October 2008 (has links) (PDF)
Les sols des régions de montagne sont confrontés à de fortes modifications climatiques et d'usages qui les rendent particulièrement sensibles à trois menaces : l'érosion, la perte de matière organique et de biodiversité. Cette thèse aborde la question de la qualité des sols sous l'angle de processus clés (décomposition et agrégation de la matière organique) au sein de différents compartiments de la partie superficielle du sol vivant (épipédon). Ces processus clés interviennent dans l'intensité des services rendus par les sols comme la séquestration de carbone, la fertilité des sols et le maintien de leur activité biologique. Parmi les indicateurs utilisés dans l'évaluation de la qualité des sols, nous avons choisi de tester des indicateurs simples et composites reliés aux processus clés de deux types d'écosystèmes subissant de fortes contraintes environnementales. Deux sites d'étude situés dans les massifs du Dévoluy (Isère) et des Maures (Var) ont été utilisés. Tous deux sont marqués par un fort gradient de végétation induit par des contraintes naturelles (sols à permafrost pour le site du Dévoluy) ou anthropiques (incendies pour le site des Maures). Dans ce travail, nous formulons trois hypothèses : (i) il existe au niveau des sols une signature originale des modifications environnementales influençant le fonctionnement des écosystèmes forestiers ; (ii) cette signature est liée à la qualité des sols et recouvre une partie biologique largement sous estimée ; (iii) la réflectance du sol résume cette signature et permet sa caractérisation dans des conditions contrastées. Les résultats de la thèse démontrent que les contraintes liées au pédoclimat et aux incendies induisent de fortes modifications des variables décrivant les processus de décomposition et d'agrégation dans les sols. Le compartiment biologique du sol (microflore ou microfaune) est particulièrement affecté par ces contraintes, révélant des modifications dans les processus liés aux chaînes trophiques des sols (voies préférentielles de décomposition et d'agrégation biologique, nitrification et dénitrification potentielles). La spectroscopie proche infrarouge se révèle être un outil pertinent pour rendre compte des modifications de qualité physico-chimiques mais aussi biologiques des sols soumis à de fortes contraintes.
212

Microbial perspectives of the methane cycle in permafrost ecosystems in the Eastern Siberian Arctic : implications for the global methane budget

Wagner, Dirk January 2007 (has links)
The Arctic plays a key role in Earth’s climate system as global warming is predicted to be most pronounced at high latitudes and because one third of the global carbon pool is stored in ecosystems of the northern latitudes. In order to improve our understanding of the present and future carbon dynamics in climate sensitive permafrost ecosystems, the present study concentrates on investigations of microbial controls of methane fluxes, on the activity and structure of the involved microbial communities, and on their response to changing environmental conditions. For this purpose an integrated research strategy was applied, which connects trace gas flux measurements to soil ecological characterisation of permafrost habitats and molecular ecological analyses of microbial populations. Furthermore, methanogenic archaea isolated from Siberian permafrost have been used as potential keystone organisms for studying and assessing life under extreme living conditions. Long-term studies on methane fluxes were carried out since 1998. These studies revealed considerable seasonal and spatial variations of methane emissions for the different landscape units ranging from 0 to 362 mg m-2 d-1. For the overall balance of methane emissions from the entire delta, the first land cover classification based on Landsat images was performed and applied for an upscaling of the methane flux data sets. The regionally weighted mean daily methane emissions of the Lena Delta (10 mg m-2 d-1) are only one fifth of the values calculated for other Arctic tundra environments. The calculated annual methane emission of the Lena Delta amounts to about 0.03 Tg. The low methane emission rates obtained in this study are the result of the used remotely sensed high-resolution data basis, which provides a more realistic estimation of the real methane emissions on a regional scale. Soil temperature and near soil surface atmospheric turbulence were identified as the driving parameters of methane emissions. A flux model based on these variables explained variations of the methane budget corresponding to continuous processes of microbial methane production and oxidation, and gas diffusion through soil and plants reasonably well. The results show that the Lena Delta contributes significantly to the global methane balance because of its extensive wetland areas. The microbiological investigations showed that permafrost soils are colonized by high numbers of microorganisms. The total biomass is comparable to temperate soil ecosystems. Activities of methanogens and methanotrophs differed significantly in their rates and distribution patterns along both the vertical profiles and the different investigated soils. The methane production rates varied between 0.3 and 38.9 nmol h-1 g-1, while the methane oxidation ranged from 0.2 to 7.0 nmol h-1 g-1. Phylogenetic analyses of methanogenic communities revealed a distinct diversity of methanogens affiliated to Methanomicrobiaceae, Methanosarcinaceae and Methanosaetaceae, which partly form four specific permafrost clusters. The results demonstrate the close relationship between methane fluxes and the fundamental microbiological processes in permafrost soils. The microorganisms do not only survive in their extreme habitat but also can be metabolic active under in situ conditions. It was shown that a slight increase of the temperature can lead to a substantial increase in methanogenic activity within perennially frozen deposits. In case of degradation, this would lead to an extensive expansion of the methane deposits with their subsequent impacts on total methane budget. Further studies on the stress response of methanogenic archaea, especially Methanosarcina SMA-21, isolated from Siberian permafrost, revealed an unexpected resistance of the microorganisms against unfavourable living conditions. A better adaptation to environmental stress was observed at 4 °C compared to 28 °C. For the first time it could be demonstrated that methanogenic archaea from terrestrial permafrost even survived simulated Martian conditions. The results show that permafrost methanogens are more resistant than methanogens from non-permafrost environments under Mars-like climate conditions. Microorganisms comparable to methanogens from terrestrial permafrost can be seen as one of the most likely candidates for life on Mars due to their physiological potential and metabolic specificity. / Die Arktis spielt eine Schlüsselrolle im Klimasystem unserer Erde aus zweierlei Gründen. Zum einen wird vorausgesagt, dass die globale Erwärmung in den hohen Breiten am ausgeprägtesten sein wird. Zum anderen ist ein Drittel des globalen Kohlenstoffs in Ökosystemen der nördlichen Breiten gespeichert. Um ein besseres Verständnis der gegenwärtigen und zukünftigen Entwicklung der Kohlenstoffdynamik in klimaempfindlichen Permafrostökosystemen zu erlangen, konzentriert sich die vorliegende Arbeit auf Untersuchungen zur Kontrolle der Methanflüsse durch Mikroorganismen, auf die Aktivität und Struktur der beteiligten Mikroorganismen-gemeinschaften und auf ihre Reaktion auf sich ändernde Umweltbedingungen. Zu diesem Zweck wurde eine integrierte Forschungsstrategie entwickelt, die Spurengasmessungen mit boden- und molekularökologischen Untersuchungen der Mikroorganismengemeinschaften verknüpft. Langzeitmessungen zu den Methanflüssen werden seit 1998 durchgeführt. Diese Untersuchungen zeigten beträchtliche saisonale und räumliche Schwankungen der Methanemissionen auf, die zwischen 0 und 362 mg m-2 d-1 für die untersuchten Landschaftseinheiten schwankten. Für die Bilanzierung der Methanemissionen für das gesamte Delta wurde erstmals eine Klassifikation der unterschiedlichen Landschaftseinheiten anhand von Landsat-Aufnahmen durchgeführt und für eine Hochrechnung der Methandaten genutzt. Die Mittelwerte der regional gewichteten täglichen Methanemissionen des Lenadeltas (10 mg m-2 d-1) sind nur ein Fünftel so hoch wie die berechneten Werte für andere arktische Tundren. Die errechnete jährliche Methanemission des Lenadeltas beträgt demnach ungefähr 0,03 Tg. Die geringen Methanemissionsraten dieser Studie können durch den bisher noch nicht realisierten integrativen Ansatz, der Langzeitmessungen und Landschafts-klassifizierungen beinhaltet, erklärt werden. Bodentemperatur und oberflächennahe atmosphärische Turbulenzen wurden als die antreibenden Größen der Methanfreisetzung identifiziert. Ein Modell, das auf diesen Variablen basiert, erklärt die Veränderungen der Methanflüsse gemäß der dynamischen mikrobiellen Prozesse und der Diffusion von Methan durch den Boden und die Pflanzen zutreffend. Die Ergebnisse zeigen, dass das Lenadelta erheblich zur globalen Methanemission aufgrund seiner weitreichenden Feuchtgebiete beiträgt. Die mikrobiologischen Untersuchungen zeigten, dass Permafrostböden durch eine hohe Anzahl von Mikroorganismen besiedelt wird. Die Gesamtbiomasse ist dabei mit Bodenökosystemen gemäßigter Klimate vergleichbar. Die Stoffwechselaktivitäten von methanogenen Archaeen und methanotrophen Bakterien unterschieden sich erheblich in ihrer Rate und Verteilung im Tiefenprofil sowie zwischen den verschiedenen untersuchten Böden. Die Methanbildungsrate schwankte dabei zwischen 0,3 und 38,9 nmol h-1 g-1, während die Methanoxidation eine Rate von 0,2 bis 7,0 nmol h-1 g-1 aufwies. Phylogenetische Analysen der methanogenen Mikro-organismengemeinschaften zeigten eine ausgeprägte Diversität der methanogenen Archaeen auf. Die Umweltsequenzen bildeten vier spezifische Permafrostcluster aus, die den Gruppen Methanomicrobiaceae, Methanosarcinaceae und Methano-saetaceae zugeordnet werden konnten. Die Ergebnisse zeigen, dass die Methanfreisetzung durch die zugrunde liegenden mikrobiologischen Prozesse im Permafrostboden gesteuert wird. Die beteiligten Mikroorganismen überleben nicht nur in ihrem extremen Habitat, sondern zeigten auch Stoffwechselaktivität unter in-situ-Bedingungen. Ferner konnte gezeigt werden, dass eine geringfügige Zunahme der Temperatur zu einer erheblichen Zunahme der Methanbildungsaktivität in den ständig gefrorenen Permafrostablagerungen führen kann. Im Falle der Permafrostdegradation würde dieses zu einer gesteigerten Freisetzung von Methan führen mit bisher unbekannten Auswirkungen auf das Gesamtbudget der Methanfreistzung aus arktischen Gebieten. Weitere Untersuchungen zur Stresstoleranz von methanogenen Archaeen – insbesondere des neuen Permafrostisolates Methanosarcina SMA-21 - weisen eine unerwartete Widerstandsfähigkeit der Mikroorganismen gegenüber ungünstigen Lebensbedingungen auf. Eine bessere Anpassung an Umweltstress wurde bei 4°C im Vergleich zu 28°C beobachtet. Zum ersten Mal konnte gezeigt werden, dass methanogene Archaeen aus terrestrischem Permafrost unter simulierten Marsbedingungen unbeschadet überleben. Die Ergebnisse zeigen, dass methanogene Archaeen aus Permafrostböden resistenter gegenüber Umweltstress und Marsbedingungen sind als entsprechende Mikroorganismen aus Habitaten, die nicht durch Permafrost gekennzeichnet sind. Mikroorganismen, die den Archaeen aus terrestrischen Permafrosthabitaten ähneln, können als die wahrscheinlichsten Kandidaten für mögliches Leben auf dem Mars angesehen werden.
213

Geochemistry and Noble Gases of Permafrost Groundwater and Ground Ice in Yukon and the Northwest Territories, Canada

Utting, Nicholas C. 11 January 2012 (has links)
In Canada’s western Arctic, perennial discharge from permafrost watersheds is the surface manifestation of active groundwater flow systems, yet understanding the mechanisms of groundwater recharge and flow in periglacial environments remains enigmatic. This thesis addresses questions on how and where groundwater recharge occurs. Watersheds were selected in Yukon (Fishing Branch River at Bear Cave Mountain) and the Northwest Territories at latitudes spanning from continuous to discontinuous permafrost (five tributary rivers to the Mackenzie River from Wrigley to Aklavik). All are characterized by perennial flow with open water in the winter, and discharge from sedimentary formations of karstic carbonates and evaporate rocks. Determinations of groundwater contributions to discharge, mixing, recharge conditions and circulation times were made on the basis of a suite of analytical approaches involving measurements of major dissolved ions, δ18O, δD, δ13CDIC, 3H, noble gases and flow gauging was conducted at some sites. The application of these tracers show that hydrogeological conditions and flow paths in permafrost terrains are surprisingly similar to those of temperate regions. Groundwater recharge was determined to be a mix of annual precipitation with contributions from snowmelt and precipitation. All systems investigated show that groundwaters have recharged through organic soils with elevated PCO2, which suggests that recharge occurs largely during summer when biological activity is high. Noble gas concentrations show that the recharge temperature was between 0 and 6 °C, which, when considered in the context of discharge temperatures, suggests that there is no significant imbalance of energy flux into the subsurface. Groundwater ages were found using the 3H-3He method and were dependent on flow path. By characterizing groundwater and surface water chemistry, the proportion of groundwater was found in numerous water courses. The possible impact of ground ice formation and melting on noble gas concentrations in groundwater was considered. To assess this link, a new method to measure the noble gas composition of ground ice bodies was developed. The method can be used to determine the origin of ice, based on changes in noble gas ratios between ice originating from compaction of snow (e.g. glacier ice) vs. ice originating from freezing of water. No significant fractionation of noble gases during groundwater freezing and ground ice formation was identified. Applied to determination of the origin of ground ice bodies, the method was shown to be both diagnostic of ice origin and un-encumbered by reactivity in the subsurface, which compromises the use of the dominant atmospheric gases (O2 and N2).   Résumé Dans l’Ouest de l'Arctique canadien, la décharge pérenne dans certaines rivières en région de pergélisol est la manifestation en surface d’une circulation d’eau souterraine; cependant la compréhension des mécanismes d’écoulement et de recharge des eaux souterraines en région de pergélisol demeure énigmatique. Cette thèse s’intéresse à la question de savoir comment et où la recharge des eaux souterraines se produit. Des bassins versants ont été choisis au Yukon (Rivière Fishing Branch à Bear Cave Mountain) et dans les Territoire du Nord-Ouest à des latitudes s’étendant du pergélisol discontinu au pergélisol continu (cinq tributaires du Mackenzie entre Wrigley et Aklavik). Toutes ces rivières ont un écoulement d’eau pérenne avec des zones non gelées et une décharge dans des formations sédimentaires de roches carbonatées et d‘évaporites. L’identification des contributions des eaux à la décharge, les mélanges, les conditions de recharge, et les temps de circulation ont été faits à partir d’analyses qui ont inclus les concentrations en éléments majeurs, leur valeur isotopique (δ18O, δD, δ13C, 3H), ainsi que leur teneur en gaz rares. A certain des sites analysés des mesures d’écoulement ont été prises. L’application de ces traceurs montre que les conditions hydrauliques et le chemin des écoulements en région de pergélisol sont similaires à ceux des régions tempérées. La recharge en eau souterraine a été identifiée comme étant un mélange de précipitations annuelles, avec des contributions de neige et de pluies. Tous les systèmes étudiés montrent que les eaux souterraines se sont rechargées en traversant des sols organiques avec une PCO2 élevée, ce qui suggère que la recharge se produire largement durant l’été quand l’activité biologique est élevée. Cependant, les concentrations en gaz nobles montre que la température de recharge des eaux souterraines était entre 0 et 6 °C ce qui indique qu’il n’y a pas de déséquilibre de flux d’énergie à l’intérieur de la zone proche de la surface. L’âge des eaux a été déterminé par la méthode 3H-3He et cet âge est dépendant du chemin d'écoulement. En caractérisant les paramètres chimiques des eaux de surface et des eaux souterraines, il a été possible de trouver la contribution des eaux souterraines aux eaux surface. Le possible impact de la formation et de la fonte de la glace souterraine sur les concentrations des gaz nobles a été considéré. Pour déterminer s’il y a un lien entre ceux-ci, une nouvelle méthode pour mesurer la concentration en gaz nobles dans les glaces souterraines a été développée. La méthode peut être utilisée pour déterminer l’origine de la glace; elle est basée sur les changements dans les rapports des gaz nobles entre la glace issue de la compaction de la neige (c’est-à-dire la glace de glacier) par opposition à la glace issue du gel de l’eau. Aucun fractionnement significatif des gaz nobles durant l’engel des eaux souterraines et la formation de glaces souterraines n’a été identifié. Appliquée à l’identification de l’origine des masses de glace enfouies, on a montré que la méthode pouvait permettre d’identifier l’origine des glaces souterraines sans qu’elle soit affectée par des réactions biologiques de sub-surface, lesquelles rendent inutilisables les gaz atmosphériques (O2, and N2).
214

Assessment of Mercury and Organic Matter in Thermokarst Affected Lakes of the Mackenzie Delta Uplands, NT, Canada

Deison, Ramin 26 January 2012 (has links)
The Mackenzie Delta region of the Northwest Territories, Canada, has experienced rapid climate warming in the past century resulting in rapidly thawing permafrost in this region. This thesis examines spatial and temporal changes to sediment organic carbon and mercury flux in lakes from thermokarst regions by comparing sediment cores from lakes with and without retrogressive thaw slumps on their shorelines. We show that sediments from lakes with permafrost thaw slump development on their shorelines (slump lakes) had higher sedimentation rates as well as lower total Hg, methyl mercury (MeHg), and labile OC fractions when compared to lakes where thaw slumps were absent. Total Hg and MeHg concentrations in sediments were correlated with total organic carbon (TOC), S2 (labile algal-derived OC), and inferred chlorophyll a content, indicating an association between autochthonous organic carbon and Hg in these sediments. Correlations between mercury and S2 in these study lakes generally support the hypothesis that algal-derived materials correlate with Hg concentration in sediments. We observed higher S2 concentrations in reference lakes than in slump lakes, likely due to uninterrupted algal production, lower dilution by flux of inorganic matter, and possibly better anoxic preservation in reference lakes compared to slump lakes. It is evident that thaw slump development in this thermokarst region increases inorganic sedimentation in lakes, while decreasing concentrations of organic carbon and associated Hg and MeHg in sediments.
215

Geochemistry and Noble Gases of Permafrost Groundwater and Ground Ice in Yukon and the Northwest Territories, Canada

Utting, Nicholas C. 11 January 2012 (has links)
In Canada’s western Arctic, perennial discharge from permafrost watersheds is the surface manifestation of active groundwater flow systems, yet understanding the mechanisms of groundwater recharge and flow in periglacial environments remains enigmatic. This thesis addresses questions on how and where groundwater recharge occurs. Watersheds were selected in Yukon (Fishing Branch River at Bear Cave Mountain) and the Northwest Territories at latitudes spanning from continuous to discontinuous permafrost (five tributary rivers to the Mackenzie River from Wrigley to Aklavik). All are characterized by perennial flow with open water in the winter, and discharge from sedimentary formations of karstic carbonates and evaporate rocks. Determinations of groundwater contributions to discharge, mixing, recharge conditions and circulation times were made on the basis of a suite of analytical approaches involving measurements of major dissolved ions, δ18O, δD, δ13CDIC, 3H, noble gases and flow gauging was conducted at some sites. The application of these tracers show that hydrogeological conditions and flow paths in permafrost terrains are surprisingly similar to those of temperate regions. Groundwater recharge was determined to be a mix of annual precipitation with contributions from snowmelt and precipitation. All systems investigated show that groundwaters have recharged through organic soils with elevated PCO2, which suggests that recharge occurs largely during summer when biological activity is high. Noble gas concentrations show that the recharge temperature was between 0 and 6 °C, which, when considered in the context of discharge temperatures, suggests that there is no significant imbalance of energy flux into the subsurface. Groundwater ages were found using the 3H-3He method and were dependent on flow path. By characterizing groundwater and surface water chemistry, the proportion of groundwater was found in numerous water courses. The possible impact of ground ice formation and melting on noble gas concentrations in groundwater was considered. To assess this link, a new method to measure the noble gas composition of ground ice bodies was developed. The method can be used to determine the origin of ice, based on changes in noble gas ratios between ice originating from compaction of snow (e.g. glacier ice) vs. ice originating from freezing of water. No significant fractionation of noble gases during groundwater freezing and ground ice formation was identified. Applied to determination of the origin of ground ice bodies, the method was shown to be both diagnostic of ice origin and un-encumbered by reactivity in the subsurface, which compromises the use of the dominant atmospheric gases (O2 and N2).   Résumé Dans l’Ouest de l'Arctique canadien, la décharge pérenne dans certaines rivières en région de pergélisol est la manifestation en surface d’une circulation d’eau souterraine; cependant la compréhension des mécanismes d’écoulement et de recharge des eaux souterraines en région de pergélisol demeure énigmatique. Cette thèse s’intéresse à la question de savoir comment et où la recharge des eaux souterraines se produit. Des bassins versants ont été choisis au Yukon (Rivière Fishing Branch à Bear Cave Mountain) et dans les Territoire du Nord-Ouest à des latitudes s’étendant du pergélisol discontinu au pergélisol continu (cinq tributaires du Mackenzie entre Wrigley et Aklavik). Toutes ces rivières ont un écoulement d’eau pérenne avec des zones non gelées et une décharge dans des formations sédimentaires de roches carbonatées et d‘évaporites. L’identification des contributions des eaux à la décharge, les mélanges, les conditions de recharge, et les temps de circulation ont été faits à partir d’analyses qui ont inclus les concentrations en éléments majeurs, leur valeur isotopique (δ18O, δD, δ13C, 3H), ainsi que leur teneur en gaz rares. A certain des sites analysés des mesures d’écoulement ont été prises. L’application de ces traceurs montre que les conditions hydrauliques et le chemin des écoulements en région de pergélisol sont similaires à ceux des régions tempérées. La recharge en eau souterraine a été identifiée comme étant un mélange de précipitations annuelles, avec des contributions de neige et de pluies. Tous les systèmes étudiés montrent que les eaux souterraines se sont rechargées en traversant des sols organiques avec une PCO2 élevée, ce qui suggère que la recharge se produire largement durant l’été quand l’activité biologique est élevée. Cependant, les concentrations en gaz nobles montre que la température de recharge des eaux souterraines était entre 0 et 6 °C ce qui indique qu’il n’y a pas de déséquilibre de flux d’énergie à l’intérieur de la zone proche de la surface. L’âge des eaux a été déterminé par la méthode 3H-3He et cet âge est dépendant du chemin d'écoulement. En caractérisant les paramètres chimiques des eaux de surface et des eaux souterraines, il a été possible de trouver la contribution des eaux souterraines aux eaux surface. Le possible impact de la formation et de la fonte de la glace souterraine sur les concentrations des gaz nobles a été considéré. Pour déterminer s’il y a un lien entre ceux-ci, une nouvelle méthode pour mesurer la concentration en gaz nobles dans les glaces souterraines a été développée. La méthode peut être utilisée pour déterminer l’origine de la glace; elle est basée sur les changements dans les rapports des gaz nobles entre la glace issue de la compaction de la neige (c’est-à-dire la glace de glacier) par opposition à la glace issue du gel de l’eau. Aucun fractionnement significatif des gaz nobles durant l’engel des eaux souterraines et la formation de glaces souterraines n’a été identifié. Appliquée à l’identification de l’origine des masses de glace enfouies, on a montré que la méthode pouvait permettre d’identifier l’origine des glaces souterraines sans qu’elle soit affectée par des réactions biologiques de sub-surface, lesquelles rendent inutilisables les gaz atmosphériques (O2, and N2).
216

Assessment of Mercury and Organic Matter in Thermokarst Affected Lakes of the Mackenzie Delta Uplands, NT, Canada

Deison, Ramin 26 January 2012 (has links)
The Mackenzie Delta region of the Northwest Territories, Canada, has experienced rapid climate warming in the past century resulting in rapidly thawing permafrost in this region. This thesis examines spatial and temporal changes to sediment organic carbon and mercury flux in lakes from thermokarst regions by comparing sediment cores from lakes with and without retrogressive thaw slumps on their shorelines. We show that sediments from lakes with permafrost thaw slump development on their shorelines (slump lakes) had higher sedimentation rates as well as lower total Hg, methyl mercury (MeHg), and labile OC fractions when compared to lakes where thaw slumps were absent. Total Hg and MeHg concentrations in sediments were correlated with total organic carbon (TOC), S2 (labile algal-derived OC), and inferred chlorophyll a content, indicating an association between autochthonous organic carbon and Hg in these sediments. Correlations between mercury and S2 in these study lakes generally support the hypothesis that algal-derived materials correlate with Hg concentration in sediments. We observed higher S2 concentrations in reference lakes than in slump lakes, likely due to uninterrupted algal production, lower dilution by flux of inorganic matter, and possibly better anoxic preservation in reference lakes compared to slump lakes. It is evident that thaw slump development in this thermokarst region increases inorganic sedimentation in lakes, while decreasing concentrations of organic carbon and associated Hg and MeHg in sediments.
217

A numerical study of a highway embankment on degrading permafrost

Gholamzadehabolfazl, Arash 04 December 2015 (has links)
In this research, two comprehensive numerical models were developed using ABAQUS/CAE Finite Element (FE) software: 1) geothermal model, and 2) coupled thermo-hydro-mechanical model. In the first model, a purely heat transfer analysis was performed to reproduce the conditions at the site and investigate the subsurface thermal regime beneath the road embankment. The existence of a frozen section (frost bulb) underneath the embankment and its size and location were investigated by the model. The second model concentrated on the mechanical behaviour of the road embankment. Temperature-dependent thermal and mechanical properties were used for all the materials. Model parameters were calibrated using the results of the triaxial and oedometer tests which have been conducted by previous researchers. A fully-coupled and a sequentially-coupled analysis were conducted. The results of the two analyses were compared to each other and to the field measurements. / February 2016
218

GEOLOGIC AND ENGINEERING CONTROLS ON THE PRODUCTION OF PERMAFROST–ASSOCIATED GAS HYDRATE ACCUMULATIONS

Collett, Timothy S. 07 1900 (has links)
In 1995, the U.S. Geological Survey made the first systematic assessment of the in-place natural gas hydrate resources of the United States. That study suggested that the amount of gas in the gas hydrate accumulations of northern Alaska probably exceeds the volume of known conventional gas resources on the North Slope. Researchers have long speculated that gas hydrates could eventually be a commercial resource yet technical and economic hurdles have historically made gas hydrate development a distant goal rather than a near-term possibility. This view began to change over the past five years with the realization that this unconventional resource could be developed in conjunction with conventional gas fields. The most significant development was gas hydrate production testing conducted at the Mallik site in Canada’s Mackenzie Delta in 2002. The Mallik 2002 Gas Hydrate Production Research Well Program yielded the first modern, fully integrated field study and production test of a natural gas hydrate accumulation. More recently, BP Exploration (Alaska) Inc. with the U.S. Department of Energy and the U.S. Geological Survey have successfully cored, logged, and tested a gas hydrate accumulation on the North Slope of Alaska know as the Mount Elbert Prospect. The Mallik 2002 project along with the Mount Elbert effort has for the first time allowed the rational assessment of the production response of a gas hydrate accumulation.
219

SEISMIC MODELING OF HETEROGENEITY SCALES OF GAS HYDRATE RESERVOIRS

Huang, Jun-Wei, Bellefleur, Gilles, Milkereit, Bernd 07 1900 (has links)
The presence of gas hydrates in permafrost regions has been confirmed by core samples recovered from the Mallik gas hydrate research wells located within Mackenzie Delta in the Northwest Territories of Canada. Strong vertical variations of compressional and shear velocities and weak surface seismic expressions of gas hydrates indicate that lithological heterogeneities control the lateral distribution of gas hydrates. Seismic scattering studies predict that typical horizontal scales and strong velocity contrasts due to gas hydrate concentration will generate strong forward scattering, leaving only weak energy to be captured by surface receivers. In order to understand the distribution of gas hydrates and the scattering effects on seismic waves, heterogeneous petrophysical reservoir models were constructed based on the P-wave and S-wave velocity logs. Random models with pre-determined heterogeneity scales can also be used to simulate permafrost interval as well as sediments without hydrates. Using the established relationship between hydrate concentration and P-wave velocity, we found that gas hydrate volume content can be determined by correlation length and Hurst number. Using the Hurst number obtained from Mallik 2L-38, and the correlation length estimated from acoustic impedance inversion, gas hydrate volume fraction in Mallik area was estimated to be 17%, approximately 7x108 m3 free gas stored in a hydrate bearing interval with 250,000 m2 lateral extension and 100 m depth. Simulations of seismic wave propagation in randomly heterogeneous models demonstrate energy loss due to scattering. With the available modeling algorithm, the impact of heterogeneity scales on seismic scattering and optimum acquisition geometries will be investigated in future studies.
220

GEOLOGIC AND POROUS MEDIA FACTORS AFFECTING THE 2007 PRODUCTION RESPONSE CHARACTERISTICS OF THE JOGMEC/NRCAN/AURORA MALLIK GAS HYDRATE PRODUCTION RESEARCH WELL

Dallimore, Scott R., Wright, J. Frederick, Nixon, F. Mark, Kurihara, Masanori, Yamamoto, Koji, Fujii, Tetsuya, Fujii, Kasumi, Numasawa, Masaaki, Yasuda, Masato, Imasato, Yutaka 07 1900 (has links)
A short-duration production test was undertaken at the Mallik site in Canada’s Mackenzie Delta in April 2007 as part of the JOGMEC/NRCan/Aurora Mallik 2007 Gas Hydrate Production Research Well Program. Reservoir stimulation was achieved by depressurization of a concentrated gas hydrate interval between 1093 and 1105m (RKB). Geologic and porous media conditions of the production interval have been quantified by geophysical studies undertaken in 2007 and geophysical and core studies undertaken by previous international partnerships in 1998 and 2002. These investigations have documented that the production interval consists of a sand-dominated succession with occasional silty sand interbeds. Gas hydrate occurs mainly within the sediment pore spaces, with concentrations ranging between 50-90%. Laboratory experiments conducted on reconstituted core samples have quantified the effects of pore water salinity and porous media conditions on pressure-temperature stability, suggesting that the partition between gas hydrate stability and instability should be considered as a phase boundary envelope or zone, rather than a discrete threshold. Strength testing on natural core samples has documented the dramatic changes in physical properties following gas hydrate dissociation, with sediments containing no hydrate behaving as unconsolidated sands. While operational problems limited the duration of the production test, a vigorous reservoir response to pressure draw down was observed with increasing gas flow during the testing period. We interpret that pressure temperature (P-T) conditions within the test zone were close to the gas hydrate phase equilibrium threshold, with dissociation initiated at 10 MPa bottomhole pressure (BHP), approximately 1 MPa below in situ conditions. The observation of an increase in production rates at approximately 8.2 MPa BHP may be consistent with the notion of an indistinct gas hydrate stability threshold, with rates increasing as P-T conditions traverse the phase boundary envelope. Significant sand inflow to the well during the test is interpreted to result from the loss of sediment strength during gas hydrate dissociation, with the sediment behaving as a gasified slurry. The increase in gas production rates during the final hours of the test may result from non-uniform gas hydrate dissociation and be affected by accelerated dissociation along water filled natural fractures or fine-scale geologic heterogeneities. These may initiate worm hole or high permeability conduits in association with sand production.

Page generated in 0.118 seconds