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A method to calculate the Stokes parameters Q, U, as well as angle of polarization (AoP) from the new generation CIMEL Dual-Polar sun/sky radiometer CE318-DP polarized skylight measurements is developed in this thesis. Besides the degree of linear polarization (DoLP) and the total radiance I, the parameters Q, U, and AoP have much potential to improve retrievals of aerosol microphysical and chemical properties. However, they have not been derived based on the CE318-DP so far because they change with the reference plane that is hard to know due to an uncontrolled initial angle related to installation of the optical sensor head to the automated mount of this type of instrument. In this work, the polarization pattern of skylight with the direction of polarization perpendicular to the scattering plane (i.e., the principal plane in the solar principal plane geometry) is applied to correct the initial angle and then to obtained Q, U, and AoP. The perpendicular and parallel polarized radiances Ir and Il, as well as the linear depolarization ratio ρ are further derived after Q is known. A new polarized almucantar geometry based on CE318-DP is measured to illustrate abundant variation features of these parameters. These new polarization parameters in conjunction with DoLP and I are analyzed based on some typical long-term sites within the Sun/sky-radiometer Observation NETwork (SONET) and a joint site of the AErosol RObotic NETwork (AERONET) in China. Results calculated in this work are consistent with previous results, and generally comparable with the vector radiative transfer simulations and the measurements by other polarimetric instrument. Considering a 1°discrepancy of AoP, 3% fractional uncertainty in I and 0.005 uncertainty in DoLP propagated to Q and U, the uncertainties of Q in both of solar principal and almucantar planes and that of U in the almucantar geometry are acceptable.

The degree to which the normal eye can adapt to the dark is related to or dependent upon the eye's ability to regenerate visual purple. The relationship of vitamin A to the visual cycle has caused much development in improved methods of detecting vitamin A deficiency. For the most part these methods have been applied to adults and school age children. This study seeks to analyze this method as applied to pre-school age children.

Techn. Universiẗat, Diss., 2001--Berlin.

Because of the paucity of evidence with regard to dark adaptation and the vitamin A status of pre-school children, this study is made. The purpose, therefore, is to add to the available data on this subject through an investigation of the bio-photometer as a means of detecting vitamin A deficiency in pre-school children.

A groundbased instrument to measure the Atmospheric airglow of the molecular oxygen infrared atmospheric band emission was designed, built, tested and operated. The two channel photometer constructed was based on the original design by Evans (1967) that had been used in balloon experiments. The two channel photometer system specifications are presented. The major difference between the presented design and the earlier two channel photometers is the detector. An Indium Gallium Arsenide (InGaAs) photodiode provided better signal to noise in the conversion of the infrared light signal to an electronic signal than the previously used Lead Sulphide (PbS) detectors. The completed instrument was tested to determine its performance characteristics. Through these tests it was found that the photometer output offset is sensitive to ambient temperature fluctuations. An analysis of the instrument noise was done in an attempt to explain this sensitivity. The output noise performance was characterized and is presented together with the absolute brightness and wavelength calibrations. Data was collected with the instrument in Saskatoon, SK and Eureka, NU. After an initial observation campaign in the high arctic (Eureka, NU) modifications were made to the environmental housing of the instrument in order to improve the scientific value of the data collected. The collected data was processed and a simple analysis performed to demonstrate the capability of the photometer to measure the infrared atmospheric airglow. The collected data can be used to determine the mesospheric ozone height profile. The required data analysis to do so is beyond the scope of this presentation. However, the presented data does demonstrate that the designed and constructed two channel photometer can make the necessary measurements.

A groundbased instrument to measure the Atmospheric airglow of the molecular oxygen infrared atmospheric band emission was designed, built, tested and operated. The two channel photometer constructed was based on the original design by Evans (1967) that had been used in balloon experiments. The two channel photometer system specifications are presented. The major difference between the presented design and the earlier two channel photometers is the detector. An Indium Gallium Arsenide (InGaAs) photodiode provided better signal to noise in the conversion of the infrared light signal to an electronic signal than the previously used Lead Sulphide (PbS) detectors. The completed instrument was tested to determine its performance characteristics. Through these tests it was found that the photometer output offset is sensitive to ambient temperature fluctuations. An analysis of the instrument noise was done in an attempt to explain this sensitivity. The output noise performance was characterized and is presented together with the absolute brightness and wavelength calibrations. Data was collected with the instrument in Saskatoon, SK and Eureka, NU. After an initial observation campaign in the high arctic (Eureka, NU) modifications were made to the environmental housing of the instrument in order to improve the scientific value of the data collected. The collected data was processed and a simple analysis performed to demonstrate the capability of the photometer to measure the infrared atmospheric airglow. The collected data can be used to determine the mesospheric ozone height profile. The required data analysis to do so is beyond the scope of this presentation. However, the presented data does demonstrate that the designed and constructed two channel photometer can make the necessary measurements.

Le carbone-suie, ou “black carbon” (BC), contribue au réchauffement climatique avec un forçage positif de l’ordre de +1.1 W m-2 dont l’incertitude reste haute (de l’ordre de 90%). Ce forçage s’effectue à travers l’interaction aérosol-radiation et l’interaction aérosols-nuage. Ces deux mécanismes sont affectés par le degré de mélange des particules du BC avec divers matériaux non-réfractaires et non-absorbants. Cependant, les estimations du forçage radiatif considèrent rarement les effets du mélange interne. Par ailleurs le rôle du BC comme noyau glaçogène qui influence l’interaction aérosol-nuage est largement inconnu. L’objectif de cette thèse est de mieux comprendre les mécanismes par lesquels le degré de mélange interne du BC influence la variabilité des propriétés optiques du BC et les propriétés d’activation des noyaux glaçogènes contenant du BC.Dans le premier chapitre de cette thèse, nous avons exploré la variabilité spatiale et saisonnière du coefficient d’absorption massique -mass absorption cross-section (MAC)- dans l’atmosphère en Europe. Les valeurs de MAC sont déterminées à partir de concentrations de carbone élémentaire et de coefficients d’absorption observée à différentes stations d’observation européenne du réseau ACTRIS (Aerosol, Cloud and Trace gases Research InfraStructure). Les résultats montrent une faible variabilité spatiale du MAC avec une moyenne de 10 ± 2.5 m2 g-1 à 637 nm de longueur d’onde qui peut être considérée comme représentative du BC en Europe. Le cycle saisonnier du MAC est probablement lié à la composition chimique de l’aérosol et son état de mélange, qui provoque une augmentation du MAC.Dans le second chapitre on s’est intéressé au lien entre l’absorption du BC et son état de mélange après transport sur longue-distance. Ce travail se base sur des mesures effectuées dans le cadre du projet CLIMSLIP (CLimate IMpact of Short-Lived Pollutants and methane in the Arctic). Une campagne de mesure a été conduite sur la station de recherche Zeppelin au Svalbard, Norvège en Avril 2012. Les données acquises avec un Single Particle Soot Photometer (SP2) révélaient que le BC est généralement présent en mélange interne dont l’épaisseur moyenne de la couche superficielle de matériel non-absorbant est de 47 nm pour des particules de BC de diamètre compris entre 170 et 280 nm. Ce mélange interne conduit à une augmentation d’absorption de 46%. Elle entraîne cependant une diminution relativement faible de l’albédo de simple diffusion, de l’ordre de 1%.Enfin, la capacité du BC à agir comme noyaux glaçogène pour la formation de cristaux de glace a été étudiée sur le site de haute altitude du Jungfraujoch (Suisse) dans le cadre du “cloud and aerosol characterization experiment” (CLACE) en 2013. Les différents éléments du nuage étaient séparé à partir d’une prise d’entrée type ice-CVI connectée au SP2. Ce dispositif permet de sélectionner uniquement les cristaux de glace et quantifier la fraction de BC activée. Une réduction de la présence de BC dans les résidus de glace a été observée. Des mesures de l’épaisseur de la couche de mélange interne des particules contentant du BC ont montré que les résidus de cristaux de glace présentaient des enrobages bien plus épais comparée à l’aérosol total.Les résultats obtenus au cours de ce travail ont permis de mieux comprendre l’impact du degré de mélange interne sur les propriétés optiques du BC et sur son rôle dans la formation de cristaux de glace. Les propriétés optiques du BC évoluent en fonction de la saison, tandis que la formation d’une couche superficielle amplifie sa capacité d’absorption du rayonnement solaire. De plus, cette étude souligne l’importance du vieillissement atmosphérique du BC sur sa capacité à servir de noyau de nucléation de la glace. Enfin, il fournit une avancée au sujet des propriétés sensibles mesurées dans l’atmosphère avec des techniques innovantes qui permettront la simulation plus précise du forçage radiatif. / Black carbon (BC) induces a warming effect (RFBC = +1.1 W m-2 ± 90%) through two main pathways: aerosol-radiation interaction (RFari) and aerosol-cloud interaction (RFaci). Both BC-radiation and BC-cloud interaction are affected by the mixing of black carbon with other non-refractory and non-absorbing matter present in the atmosphere. An estimation of the global radiative forcing of BC rarely accounts for internal mixing of BC while the net global cloud radiative forcing is sensitive to assumptions in the initiation of cloud glaciation, which is mostly unknown for black carbon particles. Within this thesis we investigated the variability of the light absorbing properties of black carbon, the mixing of black carbon, and the impact on light absorption and ice activation.In the first part of this thesis we investigated the spatial and seasonal variability of the mass absorption cross section (MAC) over Europe. MAC values were determined from ambient observations of elemental carbon mass concentrations (mEC) and absorption coefficients (σap). The data had been acquired during several years at different background ACTRIS supersites spread over Europe. Site specific MAC values were found to be spatially homogeneous, suggesting that the overall MAC average 9.5 ± 1.9 m2 g-1 at a wavelength of 637 nm might be representative of BC at European background locations. The MAC values showed a distinct seasonal cycle at every station. This seasonality might be related to chemical composition and aging. We observed that the MAC value has a linear and positive proportionality with the non-absorbing matter mass fraction.The second part of the work focuses on the coating acquisition of BC and the induced absorption enhancement after long-range transport. Within the CLIMSLIP (climate impact of short-lived pollutants and methane in the Arctic) project field experiments were conducted at the Zeppelin research site in Svalbard, Norway, during the Arctic spring. SP2 data were used to characterize the BC size distribution and mixing. BC containing particles having a core diameter between 170 and 280 nm were found to have a median coating thickness of 47 nm. The relationship between coating thickness and BC absorption was simulated. The observed coating thickness enhanced the mass absorption cross section by 46%, which led to a decrease of less than 1% in the single scattering albedo.In the final part of this work, the role of black carbon as ice nuclei in mixed phase clouds was investigated at the high elevation measuring site Jungfraujoch (Switzerland) during the cloud and aerosol characterization experiment (CLACE) held in 2013. The ice-CVI inlet and a single particle soot photometer were used to select and quantify the ice activated BC particles. According to the observations, BC containing particles were depleted in the ice residuals. The activation efficiency showed a size dependency, with larger BC containing particles being activated more efficiently compared to smaller ones. Activated BC cores having a diameter between 170 and 240 nm showed a larger coating thickness (median = 53 nm) compared to the total aerosol (median = 16 nm).The results obtained in this thesis shed new light on the effect of the mixing state on the optical properties and cloud activation of black carbon particles. Absorbing properties of BC showed a distinct seasonal pattern, while aging was found to consistently increase its absorption behavior. However, black carbon was found not to act as ice nuclei in low tropospheric mixed-phase clouds, where the coating thickness might play a role in the activation efficiency. This work provides freshly determined physical properties derived from ambient observations that will improve the accuracy of future aerosol and cloud radiative forcing estimations.

The Highveld region of South Africa contributes substantially to the aerosol loading over southern Africa because of its importance as an industrial, mining and farming base. Aerosols affect climate by absorbing or reflecting incoming solar radiation, and by affecting cloud microphysics, cloud albedo and precipitation. The physical and optical properties of industrial/urban aerosols over the Highveld region of South Africa were analysed during a 32-day winter sampling period (21 May to 21 June) in 2002; a 32-day summer sampling period (21 October to 21 November) in 2002, and a second 32-day winter sampling period (19 May to 19 June) in 2003. Synoptic circulation systems were examined in as far as they affect the horizontal transport of aerosols over the Highveld region. Measurements of aerosol optical thickness (AOT) from the ground to the top of the atmosphere and aerosol size distribution characteristics over the Highveld region were taken using hand-held hazemeters and a CIMEL sun photometer. The AOT observed over the region during the winter 2002 and 2003 sampling periods and during the summer 2002 sampling period indicated high turbidity. In the 2002 winter sampling period, the AOT530nm ranged between 0.05 to 0.7 with an average of 0.14. In the 2002 summer sampling period, the AOT530nm ranged between 0.05 to 0.6, with an average of 0.24. In the 2003 winter sampling period, the AOT500nm ranged between 0.06 to 0.6, with an average of 0.21. The Ångström exponent value had a wide range, 0.8 to 2.4 in the 2002 winter and summer sampling periods and also in the 2003 winter sampling period, indicating that a range of particle sizes was present over the Highveld region. The Ångström exponent values obtained were derived from the influences of Aeolian dust, coarse-mode industrial particles and, to a small extent, fine-mode biomassburning aerosols. Case studies, based on trajectory analysis and meteorology of the sampling area, were made of the aerosols emanating from the township sites during each of the three sampling periods to observe the build-up and dispersion of aerosols at that time.

Made available in DSpace on 2015-04-22T22:02:00Z (GMT). No. of bitstreams: 1 Capa da Dissertacao Fabio.pdf: 72495 bytes, checksum: eb902f0def752f5d58493cc98419e657 (MD5) Previous issue date: 2010-02-26 / Fundação de Amparo à Pesquisa do Estado do Amazonas / In this work was developed a photometer for didactic purposes for use in the context of social themes chemicals, such as environmental chemistry and classes of analytical instrumentation, with total determination of total orthophosphate in water. The instrument was developed using cheap materials and easy disposal. The instrument consists of a yellow LED and LDR; the first is the source and the former the detector. The signal of the photometer is available by values in resistivity, within is measured with assistance of the digital multimeter. For the determination of the orthophosphate was used the Molybdenum Blue Colorimetric Method, using river waters as test samples. Procedures for analytical validation tests were for the most suitable configuration, choosing a bucket acrylic, range from 200 kW resistivity and use of cover to the apparatus, as well as checking the stability of the source. Accuracy, precision, recovery and linearity of the photometer were checked. The repeatability and intermediate precision had coefficients of variation average 3.0 and 2.8, respectively. Accuracy was examined with statistical comparison based upon test F and t for p < 0.05, with same measures evaluated in the photometer and spectrophotometer UV-Vis, for comparison. With 95% confidence level was revealed that there are significant differences between the values of concentration, and the results were satisfactory with the use of a correction factor The recovery tests were satisfactory, with variations between 97.6 and 107.3%. The linearity is satisfactory in the range 8-48 μmol l-1, with r2 values above 0.99. / Foi desenvolvido um fotômetro para fins didáticos para uso na contextualização de temas químicos sociais, como química ambiental, e em aulas de instrumentação analítica, com determinação de ortofosfato total em águas. Para sua construção foram usados materiais de baixo custo e de fácil aquisição. O aparelho consiste basicamente de um LED (Diodo Emissor de Luz) amarelo como fonte e LDR (Resistor Dependente de Luz) como detector. O sinal do fotômetro é dado em valores de resistividade, medida com uso de multímetro digital. Para a determinação do ortofosfato foi usado o método do azul de molibdênio, sendo águas de um igarapé poluído usados como amostras teste. Para procedimentos de validação analítica, foram feitos testes para configuração mais adequada, optando-se por cubeta de acrílico, escala de 200kW de resistividade e uso de cobertura no aparelho, assim como verificação da estabilidade da fonte. O aparelho foi validado usando critérios de precisão, exatidão, recuperação e linearidade. A precisão intermediária e repetibilidade apresentaram coeficientes de variação médios de 3,0 e 2,8, respectivamente. A exatidão do fotômetro foi verificada com comparação estatística baseadas nos testes F e t para p < 0,05, sendo as mesmas medidas feitas no fotômetro e espectrofotômetro UV-Vis, para fins de comparação. Com 95% de nível de confiança foi revelado que há diferenças significativas entre os valores de concentração, sendo que os resultados foram considerados satisfatórios com o uso de um fator de correção. Os testes de recuperação foram satisfatórios com variações entre 97,6 e 107,3%. A linearidade foi considerada satisfatória no intervalo de 8 a 48 μmol l-1, apresentando valores de r2 acima de 0,99.