Fractional crystallization, magma mixing, assimilation of continental crust, and how those processes modify volatile budgets, control the evolution of magma. As a consequence, the understanding of these processes, their magnitudes, and timescales is critical for interpreting ancient magma systems, their eruptions, and the potential future volcanic activity. In this dissertation I present the results of three projects. The first explores how magmatic processes affect magma reservoirs and eruption dynamics. The second explores where in the storage system and how often these processes occur. The third explores how volatile budgets are modified by processes such as crystallization, mixing, and assimilation. Volcán Popocatépetl (central México) erupted ~14100 14C yr BP producing the Tutti Frutti Plinian Eruption (TFPE). The eruption tapped two different silicic magmas that mixed just prior and during the eruption. The influx of mass and volatiles generated during the mixing of both magmas overpressured the reservoir, which was weakened at the top. The weakened reservoir relaxed while magma was tapped and collapsed to form a caldera at the surface. Although it is known that fractional crystallization, mixing, and assimilation can greatly modify magmas, the frequency and intensity of these events is not known. I investigated the magmatic processes responsible for the evolution of magmas erupted during five Plinian events of Popocatépetl volcano. Results show that during the last 23 ky magma was stored in two different zones, and was variably modified by replenishments of mafic magma. Interestingly, little evidence for large mafic inputs triggering explosive eruptions was found. Each of these processes alters the abundances of volatiles and introduces different types of volatiles to the system. Hence, the volatile budget of magma can have a rich and complex history. To investigate how volatile budgets evolve in active magma systems, I analyzed the abundances of volatiles (H2O, CO2, F, Cl, and S) in numerous glass inclusions trapped in phenocrysts. Results show that the magmas that produced the last five Plinian eruptions at Popocatépetl volcano evolved by crystallization and magma mixing, assimilation of the local carbonate basement is not chemically appreciable. Mixing with mafic magmas added substantial CO2 and S to the system, dewatered the magma, yet produced little change in the F contents of the magmas. / text

Mafic magma is the most common magma erupted at the surface of the earth. It is generated from partial melting of the mantle, which has been subdivided into end-members based on unique geochemical signatures. One reason these end members, or heterogeneities, exist is subduction of lithospheric plates back into the mantle. The amount of elements, such as Cl and K, removed during subduction and recycled into the deep mantle, is poorly constrained. Additionally, the amount of volatiles, such as Cl, that are recycled into the deep mantle will strongly affect the behavior of the system. I have looked at Cl and K in HIMU source melts to see how it varies. Cl/Nb and K/Nb suggest that elevated Cl/K ratios are the result of depletion of K rather than increased Cl recycled into the deep mantle. After the mantle has partially melted and mafic melt has migrated to the surface, it usually erupts effusively or with low explosivity because of its low viscosity, but it is possible for larger eruptions to occur. These larger, Plinian eruptions, are not well understood in mafic systems. It is generally thought that basalt has a viscosity that is too low to allow for such an eruption to occur. Plinian eruptions require fragmentation to occur, which means the melt must undergo brittle failure. This may occur if the melt ascends rapidly enough to allow pressure to build in bubbles without the bubbles expanding. To test this, I have done decompression experiments to try to bracket the ascent rate for two Plinian eruptions. One eruption has a fast ascent, faster than those seen in more silicic melts, whereas the other eruption is unable to be reproduced in the lab, however it began with a increased viscosity in the partly crystallized magma. After fragmentation and eruption, it is generally thought that tephra do not continue to crystallize. We have found that crystallinity increases from rim to core in two basaltic pumice. Textural data along with a cooling model has allowed us to estimate growth rates in a natural system, which are similar to experimental data. / text

Tephra deposits are one of the possible outcomes of explosive volcanic eruptions and are the result of vertical settling of volcanic particles that have been expelled from the volcanic vent into the atmosphere, following magma fragmentation within the volcanic conduit. Tephra fallout represents the main volcanic hazard to populated areas and critical facilities. Therefore, it is crucial to better understand processes that lead to tephra transport, sedimentation and hazards. In this study, and based on detailed mapping and sampling of the tephra deposit of the 2450 BP Plinian eruption of Pululagua volcano (Ecuador), I investigate tephra deposits through a variety of approaches, including empirical and analytical modeling of tephra thickness and grain size data to infer important eruption source parameters (e.g. column height, total mass ejected, total grain size distribution of the deposit). I also use a statistical approach (smoothed bootstrap with replacement method) to assess the uncertainty in the eruptive parameters. The 2450 BP Pululagua volcanic plume dynamics were also explored through detailed grain size analysis and 1D modeling of tephra accumulation. Finally, I investigate the influence of particle shape on tephra accumulation on the ground through a quantitative and comprehensive study of the shape of volcanic ash. As the global need for energy is expected to grow in the future, many future natural hazard studies will likely involve the assessment of volcanic hazards at critical facilities, including nuclear power plants. I address the potential hazards from tephra fallout, pyroclastic flows and lahars for the Bataan Nuclear Power Plant (Philippines) posed by three nearby volcanoes capable of impacting the site during an explosive eruption. I stress the need for good constraints (stratigraphic analysis and events dating) on past eruptive events to better quantify the probability of future events at potentially active volcanoes, the need for probabilistic approaches in such volcanic hazard assessments to address a broad range of potential eruption scenarios, and the importance of considering coupled volcanic processes (e.g. tephra fallout leading to lahars) in volcanic hazard assessments.

ABSTRACT Medieval xenophobia fostered attitudes that viewed anything foreign or distasteful as monstrous. Accordingly, insular inhabitants of the Middle Ages were constantly striving to distinguish Self from Other. My dissertation argues that sixteenth-century England began to reverse this trend: it began to reconcile difference, not by distinguishing Self from Other, but by blurring those distinctions. Visions of ancient Self and contemporary Other began to fuse as proponents of Imperial Britain sought to assimilate foreign monsters that were once considered barbaric, inferior, or inhuman. This method of assimilation is especially apparent during the Elizabethan Age of conquest in the New World. England's prophetic destiny was inextricably tied to its epic history, its Trojan ancestry, and its most glorified rulers, Brutus and his distant successor, King Arthur. Thus, reestablishing and rewriting Britain's legendary past became an exercise in securing its future. I maintain that John Dee (c. 1527-1608/9) and Edmund Spenser (c. 1552-1599) strategically fused ancient Britain and the New World via the figures of King Arthur and his alleged descendant, Queen Elizabeth. Portions of Dee's Brytanici Imperii Limites are explored to illustrate this connection, as are some of his arcane mystical pursuits. I further examine sections of Spenser's Faerie Queene in relation to Queen Elizabeth and King Arthur, and interpret Arthur in Faery lond as a metaphor for England in the New World. My introduction establishes the key features of the Galfridian tradition and its significance to the Tudor dynasty. It further discusses medieval perceptions of the monstrous that influenced the early-modern era. Subsequent chapters argue that England's assimilation of Other extended to pagan deities and giants, Native Americans, ancient Israelites, and (in Elizabeth's case) to the feminine Other. My final chapter demonstrates how Queen Elizabeth, via her affiliation with King Arthur, became a temporal bridge uniting England's epic past with its future glory.

Made available in DSpace on 2014-06-11T19:26:38Z (GMT). No. of bitstreams: 0 Previous issue date: 2010-08-27Bitstream added on 2014-06-13T19:48:02Z : No. of bitstreams: 1 souza_da_me_assis_parcial.pdf: 54774 bytes, checksum: d766c143bca0c004bcecebbd9cc9a048 (MD5) Bitstreams deleted on 2014-11-14T12:16:57Z: souza_da_me_assis_parcial.pdf,Bitstream added on 2014-11-14T12:17:44Z : No. of bitstreams: 1 000638477.pdf: 729122 bytes, checksum: 3041b976b775470280bae3f35a83a9b9 (MD5) / Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) / Essa dissertação concebe uma breve reconstituição da situação dos estudos plinianos no Brasil e no mundo, apresentando os principais pesquisadores da referida área. Aborda a problemática da representação de homem político de acordo com o discurso apresentado por Plínio, o Jovem em seus livros de I à IX. Por meio desse epistolário faz uma análise da contribuição da fides e da virtus, bem como da imagem que o autor constói de si e do princeps na constituição do modelo de homem político durante o período de 96 a 113 d.C. Para tanto, utilizase dos pressupostos advindo das contribuições metodológicas elaboradas pela Histórica Cultural, em especial pelo conceito de representação adotado por Roger Chartier / This dissertation conceives a brief reconstitution of studies about Pliny, the Younger in Brazil and in the World, showing the majors researchers of this area. Approach problematic of the civil man’s representation according to the discourse presented by Pliny, the Younger in him books I to IX. Through this epistolary, we make a analysis of the contribution of the fides and the virtus, as well as the image created by the autor about himself and about the princeps in the constitution of the civic man’s model while 96 to 113 a. D. For this, we used the assumptions coming of methodological contributions prepared by the Cultural History, in special the representation’s concept adopted by Roger Chartier

La croissance de la phase vésiculée, moteur de l'éruption, est contrôlée par les processus de diffusion qui permettent la migration des gaz (et notamment des gaz rares) dans les bulles. On utilise la haute volatilité des gaz rares comme traceur géochimique de l'évolution d'une phase gazeuse sans interaction chimique. Ainsi, documenter précisément les mécanismes de diffusion des différents gaz rares (He, Ne, Ar) lors de l'éruption (c'est-à-dire en fonction de la chute de température et de pression du système), permet de quantifier les phénomènes de fractionnement de la phase gazeuse. La compréhension des processus de fractionnements cinétiques, permet dès lors de prédire le temps nécessaire pour atteindre une certaine quantité de gaz rares dans une bulle (située au sein d'un système magmatique), lors de l'éjection des laves. Pour cela, la compréhension de l'influence de la température et de la structure du réseau silicaté sur les coefficients de diffusion est nécessaire. Cependant, la compréhension physique des processus de diffusion ainsi que l'évolution des coefficients de diffusion en fonction de la température, n'est pas suffisante pour dériver des temps caractéristiques d'une éruption volcanique de type Plinian. La complexité symptomatique de tels systèmes, nécessite une résolution numérique des équations de diffusion prenant en compte la dépendance des coefficients de diffusion à la température. Plusieurs verres synthétiques et naturels de composition basaltique ont été fabriqués dans le but de déterminer la vitesse de diffusion des gaz rares. Les données de diffusivités expérimentales mesurées sur ces systèmes, depuis l'état vitreux de basse température (T = 423 K) jusqu'à des températures sur-liquidus (T = 1823 K), documentent nos connaissances des processus physiques de diffusion dans ces milieux. Un modèle numérique intègre ces données et permet de suivre en continue la variation des coefficients de diffusion lors de la trempe d'une lave. On a pu ainsi montré : - La relation particulière entre la structure du milieu diffusif et les espèces diffusantes. La quantité de formateurs de réseaux (SiO2) et de modificateurs (CaO - MgO - etc.), joue sur la connectivité des chemins de diffusions de chaque gaz rare, avec un effet antagoniste entre l'ouverture globale du réseau et la connexion des tétraèdres de la structure. - La présence de comportements non-arrheniens des gaz rares proches de la Tg, due à la relaxation du réseau silicate. - L'importance des données expérimentales dans l'étude des mécanismes de dégazage des magmas basaltiques. En effet, les études précédentes utilisent des extrapolations des coefficients de diffusions, mesurés dans le verre pour extrapoler les diffusivités dans le liquide silicaté. Nos données montrent que le fractionnement cinétique des gaz rares pendant le dégazage de lave basaltique, est surestimé par ces extrapolations basées sur les vitesses de diffusions aux basses températures (T << Tg) / Noble gas geochemistry is an important tool for constraining the history of the volatile phase during magmatic eruptions. Degassing processes control the gas flux from liquid to bubble, leading to solubility- or kinetic-control of the fractionation mechanisms. Noble gases have no chemical interactions at magmatic conditions and are therefore well adapted to tracing gas fractionation mechanisms during the evolution of the gas phase. Well constrained diffusion coefficients, and their dependence on temperature, of several noble gases are critical for estimating the timescale of a plinian eruption, for example. During the quench phase of the lava ejected in the plume, atmospheric noble gases will diffuse through the liquid/glass shell surrounding gas bubbles. Diffusion of these atmospheric gases determine the gas content measured in the eruption products, which are therefore a function of the timescale of the eruption, the initial and final temperatures, the glass/liquid shell thickness and the cooling rate of the magma. Therefore, it should be possible to calculate plinian eruption timescales from noble gas fractionation patterns trapped in pumice. However, in order to perform the diffusion calculations, it is first necessary to model the diffusive system: a numerical resolution of the diffusion equations for hollow sphere geometry is required as there are no analytical solutions (for complex thermal histories such as for a plinian ash column). In order to constrain the diffusion mechanisms (He, Ne and Ar) in silicate glasses and liquids, several synthetic basaltic glasses were produced. Diffusion coefficients were measured from low temperatures (423 K) to the Tg (glass transition temperature) of the system (1005 K). These experiments allowed us to investigate the physical processes that limit diffusion in glassy media: He, Ne and Ar diffusion in silicate glasses show non-Arrhenian behavior as the Tg is approached thought to be due to structural relaxation of the silicate network itself. Complementary diffusion experiments (on He and Ar) at super-liquidus conditions (1673 K and 1823 K) provide important information on the temperature dependency of He/Ar fractionation in silicate liquids. These diffusion measurements required that a new experimental protocol was developed in order to investigate noble gas diffusivities in silicate melts. The results show that relative He and Ar diffusion (i.e. DHe/DAr) decreases with temperature, from 165 at temperatures close to the Tg to 3.2 at high (>1823K) temperature. The measured coefficient diffusions are incorporated to a numerical model of the diffusion equations for a hollow sphere geometry that were developed as a MatLab code as part of this thesis work. This enabled us to determine the likely timescales of plinian eruptions from existing noble gas measurements. These results also have important implications for mechanisms of degassing in basaltic magmas: previous work used diffusivities measured on glasses in order to extrapolate to noble gas diffusivities at magmatic temperatures. Our measurements show that kinetic fractionation of noble gases during degassing of basaltic magmas has likely been overstated because noble gas diffusion in the glass cannot be extrapolated to the liquid state

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