Les objectifs principaux des travaux de recherche réalisés sont de caractériser, quantifier et corréler les changements induits lors du recyclage sur les fibres, la pâte et le papier. Pour ce faire, des techniques de caractérisation spécifique ont été utilisées telles que la chromatographie inverse d'exclusion stérique (ISEC), l'analyse mécanique dynamique (DMA), la microscopie électronique à balayage environnementale (ESEM), la microscopie à force atomique (AFM) et la tomographie à rayons X. Le racornissement des fibres à elle seule ne peut pas expliquer totalement la perte de résistance des fibres. Lors du recyclage la largeur des fibres, l'épaisseur des parois fibreuses, la courbure, le nombre de coudes et d'irrégularité diminuent. Les points faibles à l'intérieur de la paroi augmentent dans les premiers et les derniers cycles de recyclage. Les fibres deviennent plus dures et cassantes à l'état sec. Les forces capillaires et la friction de surface augmentent à l'état humide. La surface de liaison entre fibres dans le réseau fibreux diminue initialement à cause de la perte de la flexibilité des fibres à l'état humide et des éléments fins alors que l'augmentation qui suit peut être reliée au collapse du lumen. Comme la solidité des fibres de diminue pas, la baisse des caractéristiques mécaniques du papier pourrait être attribuée à la dégradation de la qualité des liaisons et plus particulièrement à une délamination partielle de la couche P/S1. / Incorporation of recycled fibres in high value paper products can reduce costand environmental loads. Papermaking potential of cellulosic fibres decreaseswith recycling. The phenomenon of fibre hornification during pressing anddrying is normally held responsible for the loss in strength. To study the impactsof recycling on pulp, fibre and paper properties some non conventionalcharacterisation techniques like fibre saturation point, X-rays microtomography,environmental scanning electron microscopic observations, atomic forcemicroscope (PeakForce QNM mode) and inverse size exclusion chromatography(ISEC) were used. In order to achieve good reproducibility of ISEC measurements,a semi-automatic column fabrication pilot system was built. Thetechniques were first validated on refining process before being applied to therecycling process. In this study, it was found that fibre hornification alone cannot fully explain loss in strength during recycling. The loss in strength is muchmore complex and it is required to understand the morphological and ultrastructural changes associated with recycling. Fibre width, cell wall thickness,curl, kink, irregularities decreased during recycling. Fibre became hard andbrittle in dry state. Number of weak points in the fibre wall were increasedinitially and in the later recyclings. The increase in wet breaking length indicatesincreased surface friction and capillary forces with recycling. Decreasein bonded area during first recycle may be caused by the loss of fines and fibreflexibility whereas the increase afterwards may be linked to the lumen collapse.The strength of fibres did not decrease with recycling as shown by zero-spanbreaking lengths therefore the quality of bond may be deteriorated. It wasthought that the partially delaminated P/S1 layers may be responsible for theloss of paper strength. It is suggested since the significant change is associatedwith the pressing and drying of never dried pulp therefore the drying processneeds to be revisited. The delaminated layer should be restored so as to increasethe recyclability of the recovered fibres for high value paper. Influenceof recycled pulp blends on physical properties of paper was also studied. It wasrevealed that small quantity of recycled pulp can be used without significantlyaffecting the mechanical strength properties.

The basic ingredient of paper is the individual wood fibers. The property of the fibers depends on a variety of factors e.g., method of pulp production and processing. The final sheet quality depends in part on how the fibers interface between each other and therefore factors that affect the fiber size are of interest. The flexibility of the fibers depends in part on the pore water i.e., the fiber swelling. The sheet becomes less flexible at low water content which gives a loss in strength. Thus it becomes desirable to increase the water uptake. The experimental investigation described in this report consists of exposing the wood fibers to different ions and ionic strength and then measure the pore size by thermoporosimetry where a DSC (Differential Scanning Calorimeter) is used. DSC measures the freezing point of water in the pores of the wood fibers. As the freezing point varies with the pore size the size distribution can be determined. The results show that there are complications with thermoporosimetry measurements at different ion concentrations. The strength of the ionic solutions will contribute to a fictitious pore volume, which makes analysis difficult to interpret.

No description available.

The durability of concrete is of major concern in all types of concrete structures where the combined effect of exposure conditions and the type and quality of the concrete material usually determines the rate of degradation. Furthermore, there are synergy effects between different deterioration mechanisms, which means that the combined rate of degradation is higher than the sum of the individual rates of each mechanism. Therefore, to accurately predict the residual service life of existing structures or when designing new structures, it is essential to consider all these aspects. This means that various chemical and physical processes, as well as how these interact, must be taken into account in models aiming to be used for service life predictions. This thesis presents the first part of a research project with the aim to investigate common deterioration mechanisms of concrete in hydraulic structures, and to improve the knowledge how these and other related phenomena can be described using mathematical models. The objective is also to study how different mechanisms interact and to find suitable approaches to account for these interactions in the models. To this end, a literature survey on commonly detected damage in hydraulic structures is presented. In addition, it also addresses in what types of and where in hydraulic structures the various damage types are usually observed. The mathematical models presented in this part of the project are focused on long-term water absorption in air-entrained concrete as well as on freezing of partially saturated air-entrained concrete. Both models are based on a multiphase description of concrete and poromechanics to describe the coupled hygro-thermo-mechanical behaviour. The thesis also presents some of the basic concepts of multiphase modelling of porous media, including discretization of the models using the finite element method (FEM). Furthermore, it covers the simplifications that are usually introduced in the general macroscopic balance equations for mass, energy and linear momentum when modelling cement-based materials. To verify the developed models and to show their capabilities, simulation results are compared with experimental data, in situ measurements and other simulations from the literature. The results indicate that both models perform well and can be used to predict long-term moisture conditions in hydraulic structures as well as freezing-induced strains in partially saturated air-entrained concrete, respectively. Even though no interactions with other deterioration mechanisms are included in the models, the development and use of these have given insights to which parameters that are important to consider in such extensions. Furthermore, based on the insights gained, the complexity of describing the full interactions between several mechanisms in mathematical models is also discussed. It is concluded that models aiming to be used for service life predictions of hydraulic structures in day-to-day engineering work need to be simplified. However, the type of advanced models presented in this thesis can serve as a basis to study which aspects and parameters that are essential to consider in simplified prediction models. / Beständigheten hos betong är av avgörande betydelse i alla typer av betongkonstruktioner där den kombinerade effekten av exponeringsförhållanden samt typ och kvalitet på betongmaterialet vanligtvis avgör nedbrytningshastigheten. Dessutom finns synergieffekter mellan olika nedbrytningsmekanismer som innebär att den kombinerade nedbrytningshastigheten är större än summan av de enskilda nedbrytningshastigheterna. För att noggrant kunna prediktera den återstående livislängden hos befintliga konstruktioner eller vid design av nya konstruktioner är det därför viktigt att ta hänsyn till samtliga av dessa aspekter. Detta innebär att olika kemiska och fysikaliska processer, samt hur dessa interagerar med varandra, måste tas i beaktande i modeller som avses användas för livslängdsbedömningar. Den här licentiatuppsatsen presenterar den första delen av ett forskningsprojekt där målet är att studera vanligt förekommande nedbrytningsmekanismer i vattenbyggnadskonstruktioner och att öka kunskapen om hur dessa och andra relaterade fenomen kan beskrivas med matematiska modeller. Målet är också att studera hur olika nedbrytningsmekanismer samverkar och att hitta lämpliga tillvägagångssätt att ta hänsyn till dessa interaktioner i modellerna. För detta ändamål presenteras en litteraturstudie avseende vanligt förekommande skador i vattenbyggnadskonstruktioner. Dessutom behandlar denna i vilka typer av vattenbyggnadskonstruktioner och var i dessa som de olika typerna av skador vanligtvis observeras. De matematiska modeller som presenteras i denna del av projektet är inriktade på långtidsabsorption av vatten i lufttillsatt betong samt på frysning i delvis vattenmättad lufttillsatt betong. Båda modellerna är baserade på en multifasbeskrivning av betong samt poromekanik för att beskriva det kopplade hydro-termo-mekaniska beteendet. Uppsatsen presenterar också några av de grundläggande koncepten gällande multifasmodellering av porösa material, inklusive diskretisering av modellerna genom användning av finita elementmetoden (FEM). Dessutom beskrivs de förenklingar som vanligtvis införs i de generella makroskopiska balansekvationerna för massa, energi och rörelsemängd då cementbaserade material modelleras. Simuleringsresultat från de utvecklade modellerna jämförs med försöksdata, fältmätningar samt andra simuleringsresultat från litteraturen för att verifiera modellerna samt visa hur de beter sig. Resultaten visar att båda modellerna ger tillfredställande resultat och kan användas för att uppskatta de långsiktiga fuktförhållandena i vattenbyggnadskonstruktioner samt frysinducerade töjningar i delvis vattenmättad lufttillsatt betong. Även om inga interaktioner mellan andra nedbrytningsmekanismer inkluderades i modellerna, så har utvecklingen samt användandet av dessa gett insikter gällande vilka parametrar som är viktiga att beakta i sådana vidareutvecklingar. Baserat på dessa insikter diskuteras också komplexiteten i att beskriva interaktionen mellan flertalet mekanismer i matematiska modeller. Det konstateras också att modeller som avses användas i dagligt ingenjörsarbete för livstidsbedömningar av vattenbyggnadskonstruktioner behöver förenklas. Däremot kan den typ av avancerade modeller som presenteras i denna uppsats användas som en grund för att studera vilka aspekter och parametrar som är viktiga att beakta i förenklade modeller. / <p>QC 20180403</p>

No description available.

O solo é um importante recurso natural e a sua conservação é essencial para uma produção sustentável. A qualidade de um solo, por sua vez, pode ser definida como a capacidade deste em exercer sua função em um ecossistema e pode ser descrita por meio de parâmetros físicos, químicos e biológicos. Os atributos físicos do solo descrevem a organização de sua estrutura, de modo que esta é responsável pela movimentação e disponibilidade da solução do solo para as plantas e depende da dimensão, forma e arranjo de suas partículas sólidas e de seus poros. Portanto, a discussão dos mecanismos de movimento e retenção da água no solo é relevante na inferência da sua qualidade física. A curva de retenção da água no solo é o gráfico da umidade do solo em função do potencial mátrico da água no solo, a qual é uma ferramenta importante na avaliação da qualidade física do solo. No Brasil, os Latossolos são de grande importância, devido a sua extensão e potencial produtivo. Estes solos são muito intemperizados, com elevada estabilidade de agregados e podem ser originados a partir de materiais distintos, o que interfere na resposta física. Portanto, o objetivo geral deste trabalho foi avaliar a qualidade físico-hídrica do solo por meio da análise da curva de retenção da água em três Latossolos, verificando entre dois modelos empíricos de ajuste (BROOKS; COREY, 1964; VAN GENUCHTEN, 1980). Também foram avaliadas a frequência de distribuição do tamanho de poros e a utilização do índice S como indicador da qualidade física do solo. Foram coletadas amostras indeformadas de três áreas para confecção das curvas de retenção de água no solo: (1) Latossolo Vermelho Amarelo Distrófico típico (pousio); (2) Latossolo Vermelho Distrófico típico álico (cana-de-açúcar); (3) Latossolo Vermelho Distrófico típico (cana-de-açúcar). Os resultados mostraram que a curva de retenção de água foi influenciada pela densidade do solo, porosidade, textura e conteúdo de carbono orgânico; o ajuste da curva de retenção de água no solo pelos dois modelos utilizados foi semelhante, porém o modelo de van Genuchten (1980) apresentou-se ligeiramente melhor que o modelo de Brooks e Corey (1964), principalmente nos pontos próximos à saturação; a frequência de distribuição de poros e o índice S foram sensíveis em diferenciar a qualidade estrutural de solos devido à textura e ao manejo. / Soil is an important natural resource and its conservation is essential for sustainable production. The quality of a soil can be defined as its ability to exert its function in an ecosystem and can be described by means of physical, chemical and biological parameters. The soil physical attributes describe the organization of its structure, that is responsible for the moviment and availability of soil solution for plants and it depends on the size, shape and arrangement of its solid particles and pores. Therefore, the discussion of the mechanisms of soil water movement and retention is important in inferring its physical quality. The soil water retention curve is an important tool to evaluate soil quality, is the graph of soil water content as a function of soil water matric potential. In Brazil, the Oxisols are of great importance due to their extent and productive potential. These soils are highly weathered, with high aggregate stability and can originate from different materials, which interfer on the physical response. Therefore, the aim of this work was to evaluate the physical-hydric quality of the soil by means of the soil water retention curve of three Oxisols, by using two empirical adjustment models (BROOKS; COREY, 1964; VAN GENUCHTEN, 1980). Pore-size distribution frequency and the use of the S index as an indicator of physical soil quality were also evaluated. Undisturbed soil samples were collected from three areas to obtain the soil water retention curves: (1) Typic Hapludox (fallow land), (2) Rhodic Hapludox (sugarcane), (3) Rhodic Hapludox (sugarcane). The results showed that the soil water retention curve was influenced by the soil bulk density, soil porosity, soil texture and soil organic carbon content. The fitness of the soil water retention curve by the two models was similar, however the van Genuchten\'s model (1980) was slightly better than the model of Brooks and Corey (1964), especially in the points near saturation; the pore-size distribution frequency and the S index were sensitive in differentiating the structural quality of soil due to the texture and management.

O solo é um importante recurso natural e a sua conservação é essencial para uma produção sustentável. A qualidade de um solo, por sua vez, pode ser definida como a capacidade deste em exercer sua função em um ecossistema e pode ser descrita por meio de parâmetros físicos, químicos e biológicos. Os atributos físicos do solo descrevem a organização de sua estrutura, de modo que esta é responsável pela movimentação e disponibilidade da solução do solo para as plantas e depende da dimensão, forma e arranjo de suas partículas sólidas e de seus poros. Portanto, a discussão dos mecanismos de movimento e retenção da água no solo é relevante na inferência da sua qualidade física. A curva de retenção da água no solo é o gráfico da umidade do solo em função do potencial mátrico da água no solo, a qual é uma ferramenta importante na avaliação da qualidade física do solo. No Brasil, os Latossolos são de grande importância, devido a sua extensão e potencial produtivo. Estes solos são muito intemperizados, com elevada estabilidade de agregados e podem ser originados a partir de materiais distintos, o que interfere na resposta física. Portanto, o objetivo geral deste trabalho foi avaliar a qualidade físico-hídrica do solo por meio da análise da curva de retenção da água em três Latossolos, verificando entre dois modelos empíricos de ajuste (BROOKS; COREY, 1964; VAN GENUCHTEN, 1980). Também foram avaliadas a frequência de distribuição do tamanho de poros e a utilização do índice S como indicador da qualidade física do solo. Foram coletadas amostras indeformadas de três áreas para confecção das curvas de retenção de água no solo: (1) Latossolo Vermelho Amarelo Distrófico típico (pousio); (2) Latossolo Vermelho Distrófico típico álico (cana-de-açúcar); (3) Latossolo Vermelho Distrófico típico (cana-de-açúcar). Os resultados mostraram que a curva de retenção de água foi influenciada pela densidade do solo, porosidade, textura e conteúdo de carbono orgânico; o ajuste da curva de retenção de água no solo pelos dois modelos utilizados foi semelhante, porém o modelo de van Genuchten (1980) apresentou-se ligeiramente melhor que o modelo de Brooks e Corey (1964), principalmente nos pontos próximos à saturação; a frequência de distribuição de poros e o índice S foram sensíveis em diferenciar a qualidade estrutural de solos devido à textura e ao manejo. / Soil is an important natural resource and its conservation is essential for sustainable production. The quality of a soil can be defined as its ability to exert its function in an ecosystem and can be described by means of physical, chemical and biological parameters. The soil physical attributes describe the organization of its structure, that is responsible for the moviment and availability of soil solution for plants and it depends on the size, shape and arrangement of its solid particles and pores. Therefore, the discussion of the mechanisms of soil water movement and retention is important in inferring its physical quality. The soil water retention curve is an important tool to evaluate soil quality, is the graph of soil water content as a function of soil water matric potential. In Brazil, the Oxisols are of great importance due to their extent and productive potential. These soils are highly weathered, with high aggregate stability and can originate from different materials, which interfer on the physical response. Therefore, the aim of this work was to evaluate the physical-hydric quality of the soil by means of the soil water retention curve of three Oxisols, by using two empirical adjustment models (BROOKS; COREY, 1964; VAN GENUCHTEN, 1980). Pore-size distribution frequency and the use of the S index as an indicator of physical soil quality were also evaluated. Undisturbed soil samples were collected from three areas to obtain the soil water retention curves: (1) Typic Hapludox (fallow land), (2) Rhodic Hapludox (sugarcane), (3) Rhodic Hapludox (sugarcane). The results showed that the soil water retention curve was influenced by the soil bulk density, soil porosity, soil texture and soil organic carbon content. The fitness of the soil water retention curve by the two models was similar, however the van Genuchten\'s model (1980) was slightly better than the model of Brooks and Corey (1964), especially in the points near saturation; the pore-size distribution frequency and the S index were sensitive in differentiating the structural quality of soil due to the texture and management.

Die vorliegende Arbeit befasst sich mit Untersuchung der gekoppelten Einflüsse ‎von Gasart, Porengröße und Porengrößenverteilung auf die effektive ‎Wärmeleitfähigkeit nicht-durchströmter poröser Materialien (Dämmstoffe). Diese ‎Zusammenhänge sind bisher nur ansatzweise bekannt und für eine spätere ‎praktische Anwendung von zunehmend großer Bedeutung. Um dies zu erreichen ‎wurden 12 verschiedene hoch poröse Materialien (Porosität höher als 70 %) ‎ausgewählt, die unterschiedlichen Porengrößenverteilungen im Makro- Mikro- und ‎Nanobereich haben. Die effektive Wärmeleitfähigkeit wurde hauptsachlich in zwei ‎unterschiedlichen Messverfahren untersucht. Die Messungen erfolgt bei normalem ‎Druck in vier Gas Atmosphären ‎(Kr, Ar, N2 and He) bei Temperaturen bis maximal 900 °C. Kritische Analyse zum ‎jeweiligen Messverfahren und Auswertungsalgorithmus wurden durchgeführt. Ein ‎mathematisches Model basiert auf die Porengrößenverteilung mit Berücksichtigung ‎des Knudsen Effekts wurde entwickelt um die Änderung der effektiven ‎Wärmeleitfähigkeit beim Wechsel der Gas Atmosphäre auszuwerten. Diese führt zu ‎besser Ergebnisse als die ausgewertet Ergebnisse von den vorhandenen Modellen ‎aus der Literatur. ‎ / In the present work, the influences of exchanging the filling gas accompanied with Knudsen effect on effective thermal conductivity were investigated with experiments and physical mathematical modeling. This work is thought to be the first intensive study in this area of the research, which includes twelve different porous insulation materials. Analysis of the huge number of experimental results leaded to new observations regarding various coupling effects. An improved model for predicting the change in effective thermal conductivity due to exchanging the filling gas has been developed with regards to the Knudsen effect based on models for rarefied gases and parallel arrangements models for effective thermal conductivity.

It is well known that nanostructures possess unique electronic, optical, magnetic, ferroelectric and piezoelectric properties that are often superior to traditional bulk materials. In particular, one dimensional (1D) nanostructured inorganic materials including nanofibres, nanotubes and nanobelts have attracted considerable attention due to their distinctive geometries, novel physical and chemical properties, combined effects and their applications to numerous areas. Metal ion doping is a promising technique which can be utilized to control the properties of materials by intentionally introducing impurities or defects into a material. γ-Alumina (Al2O3), is one of the most important oxides due to its high surface area, mesoporous properties, chemical and thermal properties and its broad applications in adsorbents, composite materials, ceramics, catalysts and catalyst supports. γ-Alumina has been studied intensively over a long period of time. Recently, considerable work has been carried out on the synthesis of 1D γ-alumina nanostructures under various hydrothermal conditions; however, research on the doping of alumina nanostructures has not been forthcoming. Boehmite (γ-AlOOH) is a crucial precursor for the preparation of γ-Alumina and the morphology and size of the resultant alumina can be manipulated by controlling the growth of AlOOH. Gallium (Ga) is in the same group in the periodic table as aluminum. β-Gallium (III) oxide (β-Ga2O3), a wide band gap semiconductor, has long been known to exhibit conduction, luminescence and catalytic properties. Numerous techniques have been employed on the synthesis of gallium oxide in the early research. However, these techniques are plagued by inevitable problems. It is of great interest to explore the synthesis of gallium oxide via a low temperature hydrothermal route, which is economically efficient and environmentally friendly. The overall objectives of this study were: 1) the investigation of the effect of dopants on the morphology, size and properties of metal ion doped 1D alumina nanostructures by introducing dopant to the AlOOH structure; 2) the investigation of impacts of hydrothermal conditions and surfactants on the crystal growth of gallium oxide nanostructures. To achieve the above objectives, trivalent metal elements such as iron, gallium and yttrium were employed as dopants in the study of doped alumina nanostructures. In addition, the effect of various parameters that may affect the growth of gallium oxide crystals including temperature, pH, and the experimental procedure as well as different types of surfactants were systematically investigated. The main contributions of this study are: 1) the systematic and in-depth investigation of the crystal growth and the morphology control of iron, gallium and yttrium doped boehmite (AlOOH) under varying hydrothermal conditions, as a result, a new soft-chemistry synthesis route for the preparation of one dimensional alumina/boehmite nanofibres and nanotubes was invented; 2) systematic investigation of the crystal growth and morphology and size changes of gallium oxide hydroxide (GaOOH) under varying hydrothermal conditions with and without surfactant at low temperature; We invented a green hydrothermal route for the preparation of α-GaOOH or β-GaOOH micro- to nano-scaled particles; invented a simple hydrothermal route for the direct preparation of γ-Ga2O3 from aqueous media at low temperature without any calcination. The study provided detailed synthesis routes as well as quantitative property data of final products which are necessary for their potential industrial applications in the future. The following are the main areas and findings presented in the study: • Fe doped boehmite nanostructures This work was undertaken at 120ºC using PEO surfactant through a hydrothermal synthesis route by adding fresh iron doped aluminium hydrate at regular intervals of 2 days. The effect of dopant iron, iron percentage and experimental procedure on the morphology and size of boehmite were systematically studied. Iron doped boehmite nanofibres were formed in all samples with iron contents no more than 10%. Nanosheets and nanotubes together with an iron rich phase were formed in 20% iron doped boehmite sample. A change in synthesis procedure resulted in the formation of hematite large crystals. The resultant nanomaterials were characterized by a combination of XRD, TEM, EDX, SAED and N2 adsorption analysis. • Growth of pure boehmite nanofibres/nanotubes The growth of pure boehmite nanofibres/nanotubes under different hydrothermal conditions at 100ºC with and without PEO surfactant was systematically studied to provide further information for the following studies of the growth of Ga and Y doped boehmite. Results showed that adding fresh aluminium hydrate precipitate in a regular interval resulted in the formation of a mixture of long and short 1D boehmite nanostructures rather than the formation of relatively longer nanofibres/nanotubes. The detailed discussion and mechanism on the growth of boehmite nanostructure were presented. The resultant boehmite samples were also characterized by N2 adsorption to provide further information on the surface properties to support the proposed mechanism. • Ga doped boehmite nanostructures Based on this study on the growth of pure boehmite nanofibre/nanotubes, gallium doped boehmite nanotubes were prepared via hydrothermal treatment at 100ºC in the presence of PEO surfactant without adding any fresh aluminium hydrate precipitate during the hydrothermal treatment. The effect of dopant gallium, gallium percentage, temperature and experimental procedure on the morphology and size of boehmite was systematically studied. Various morphologies of boehmite nanostructures were formed with the increase in the doping gallium content and the change in synthesis procedure. The resultant gallium doped boehmite nanostructures were characterized by TEM, XRD, EDX, SAED, N2 adsorption and TGA. • Y doped boehmite nanostructures Following the same synthesis route as that for gallium doped boehmite, yttrium doped boehmite nanostructures were prepared at 100ºC in the presence of PEO surfactant. From the study on iron and gallium doped boehmite nanostructures, it was noted both iron and gallium cannot grow with boehmite nanostructure if iron nitrate and gallium nitrate were not mixed with aluminium nitrate before dissolving in water, in particular, gallium and aluminium are 100% miscible. Therefore, it’s not necessary to study the mixing procedure or synthesis route on the formation of yttrium doped boehmite nanostructures in this work. The effect of dopant yttrium, yttrium percentage, temperature and surfactant on the morphology and size of boehmite were systematically studied. Nanofibres were formed in all samples with varying doped Y% treated at 100ºC; large Y(OH)3 crystals were also formed at high doping Y percentage. Treatment at elevated temperatures resulted in remarkable changes in size and morphology for samples with the same doping Y content. The resultant yttrium doped boehmite nanostructures were characterized by TEM, XRD, EDX, SAED, N2 adsorption and TGA. • The synthesis of Gallium oxide hydroxide and gallium oxide with surfactant In this study, the growth of gallium oxide hydroxide under various hydrothermal conditions in the presence of different types of surfactants was systematically studied. Nano- to micro-sized gallium oxide hydroxide was prepared. The effect of surfactant and synthesis procedure on the morphology of the resultant gallium oxide hydroxide was studied. β-gallium oxide nanorods were derived from gallium oxide hydroxide by calcination at 900ºC and the initial morphology was retained. γ-gallium oxide nanotubes up to 65 nm in length, with internal and external diameters of around 0.8 and 3.0 nm, were synthesized directly in solution with and without surfactant. The resultant nano- to micro-sized structures were characterized by XRD, TEM, SAED, EDX and N2 adsorption. • The synthesis of gallium oxide hydroxide without surfactant The aim of this study is to explore a green synthesis route for the preparation of gallium oxide hydroxide or gallium oxide via hydrothermal treatment at low temperature. Micro to nano sized GaOOH nanorods and particles were prepared under varying hydrothermal conditions without any surfactant. The resultant GaOOH nanomaterials were characterized by XRD, TEM, SAED, EDX, TG and FT-IR. The growth mechanism of GaOOH crystals was proposed.

Cette étude a pour but de documenter la relation qui existe entre les propriétés de transfert d’un matériau (répartition en taille de pores, porosité totale accessible à l’eau, saturation en eau), et son coefficient de diffusion. Pour cela, des matériaux ayant une porosité quasi-monomodale sont utilisés : verres Vycor® et géopolymères ; ainsi que des matériaux ayant une porosité complexe : pâtes de ciment CEM V. L’utilisation des verres Vycor® et des géopolymère permet de quantifier la diffusion gazeuse, en fonction de la saturation en eau, de matériaux ayant des pores de même dimension, ou du moins, de même ordre de grandeur. L’utilisation des pâtes de ciment permet quant à elle, de vérifier s’il est possible de décomposer le coefficient de diffusion d’un matériau dont la porosité est complexe, en un assemblage de coefficients de diffusion de matériaux dont la porosité est quasi-monomodale. Pour cela, on s’attachera à particulièrement à étudier l’impact de l’agencement du réseau poreux sur le coefficient de diffusion.Les travaux se décomposent en trois parties :• Etude des caractéristiques géométriques du réseau poreux des matériaux étudiés. Il sera utilisé la porosimétrie par intrusion de mercure, la porosimétrie à eau, des essais de sorption / désorption d’azote, et des essais de désorption d’eau.• Mesure expérimentale du coefficient de diffusion des matériaux, en fonction de leur humidité relative de stockage et de leur saturation en eau.• Modélisation du coefficient de diffusion des matériaux utilisés, et étude de l’impact de l’agencement de leur réseau poreux (tortuosité, connexion des pores entre eux) / This work documents the relationship that exists between the transfer properties of a material (pore size distribution, total porosity accessible to water, water saturation degree), and its diffusion coefficient. For this sake, materials having a quasi mono modal porosity are used: Vycor® glasses and geopolymers. We also use materials having a complex porosity: CEM V cement pastes. The use of Vycor® glasses and geopolymers allows quantifying the gas diffusion coefficient through materials having known pores size, as a function of their water saturation degree. The use of cement pastes allows checking if it is possible to decompose the diffusion coefficient of a complex porosity material, in an assembling of diffusion coefficients of quasi mono modal porosity materials. For this sake, the impact of pore network arrangement on the diffusion coefficient is studied in great details. This study is divided into three parts:• Measurement of the geometric characteristics of materials porous network by means of the mercury intrusion porosimetry, water porosimetry, isotherms of nitrogen sorption / desorption, and water desorption tests.• Measurement of the materials diffusion coefficient, as a function of their relative humidity storage, and their water saturation degree.• Modeling the diffusion coefficient of the materials, and study the impact of the pore network (tortuosity, pores connection)