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Quantum mechanics, arguably one of the greatest achievements of modern physics, has not only fundamentally changed our understanding of nature but is also taking an ever increasing role in engineering. Today, the control of quantum systems has already had a far-reaching impact on time and frequency metrology. By gaining further control over a large variety of different quantum systems, many potential applications are emerging. Those applications range from the development of quantum sensors and new quantum metrological approaches to the realization of quantum information processors and quantum networks. Unfortunately most quantum systems are very fragile objects that require tremendous experimental effort to avoid dephasing. Being able to control the interaction between a quantum system with its local environment embodies therefore an important aspect for application and hence is at the focus of this thesis. / Physics

<div>Optical signals are a necessary tool for quantum technologies to carry information both for long-range and on-chip application. The scope of their use is determined by their ability to effectively interact with qubits. The deep-subwavelength interaction volume demands the understanding of the properties of optical fields in the near-field and light-matter interaction in this regime. Recent studies have unraveled the rich characteristics in the physical quantity known as the near-field photonic spin density (PSD). Photonic spin density is the spatial distribution of light's spin angular momentum. It is characterized by the degree of circular polarization of an optical field in deep-subwavelength volumes. In this thesis we study the properties of PSD in the near-field regime and demonstrate a platform for coherent light-spin-qubit interaction based on PSD. We show that nitrogen-vacancy (NV) centers in diamond can coherently interact with an optical beam where the interaction strength is determined by PSD in the nanoscale. To understand the near-field characteristics of PSD we study the evanescent waves and spin-momentum locking of light.</div><div><br></div><div>Evanescent electromagnetic waves possess spin-momentum locking, where the direction of propagation (momentum) is locked to the inherent polarization of the wave (transverse spin). We study the optical forces arising from this universal phenomenon and show that the fundamental origin of recently reported optical chiral forces is spin-momentum locking. For evanescent waves, we show that the direction of energy flow, direction of decay, and direction of spin follow a right hand rule for three different cases of total internal reflection, surface plasmon polaritons, and HE₁₁ mode of an optical fiber.</div><div>Furthermore, we explain how the recently reported phenomena of lateral optical force on chiral and achiral particles is caused by the transverse spin of the evanescent field and the spin-momentum locking phenomenon. Our work presents a unified view on spin-momentum locking and how it affects optical forces on chiral and achiral particles. </div><div><br></div><div>To probe the near-field properties of PSD, we propose and employ a single NV center in diamond as a nanoscale sensor. NV centers have emerged as promising room-temperature quantum sensors for probing condensed matter phenomena ranging from spin liquids, two-dimensional (2D) magnetic materials, and magnons to hydrodynamic flow of current. Here, we demonstrate that the NV center in diamond can be used as a quantum sensor for detecting the photonic spin density. We exploit a single spin qubit on an atomic force microscope tip to probe the spinning field of an incident Gaussian light beam. The spinning field of light induces an effective static magnetic field in the single spin qubit probe. We perform room-temperature sensing using Bloch sphere operations driven by a microwave field (XY8 protocol). This nanoscale quantum magnetometer can measure the local polarization of light in ultra-sub-wavelength volumes. We also put forth a rigorous theory of the experimentally measured phase change using the NV center Hamiltonian and perturbation theory involving only virtual photon transitions. </div><div><br></div><div>In order to study the wavelength dependence of the optically induced magnetic field, we demonstrate this effect for an ensemble of NV centers. We characterize the wavelength dependence of the effective static magnetic field caused by the interaction of PSD and the spin qubit. We show that the strength of the field is inversely dependent on the detuning between the frequency of the optical beam and the optical transition of the NV centers. We show an optically induced rotation of over 10 degrees in the spin qubit of NV centers at room temperature. The direct detection of the photonic spin density at the nanoscale using NV centers in diamond opens interesting quantum metrological avenues for studying exotic phases of photons, nanoscale properties of structured light as well as future on-chip applications. </div><div><br></div>

京都大学 / 新制・課程博士 / 博士(工学) / 甲第23221号 / 工博第4865号 / 新制||工||1759(附属図書館) / 京都大学大学院工学研究科分子工学専攻 / (主査)教授 水落 憲和, 教授 浜地 格, 教授 SIVANIAH Easan / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DGAM

In the rapidly advancing field of quantum technologies, integrated quantum photonics merges quantum mechanics with photonics, promising breakthroughs in communication, sensing, computing, and security. This doctoral thesis investigates the generation of correlated photons via spontaneous four-wave mixing (sFWM) on silicon-based platforms. Through a comparative analysis of various intramodal and intermodal sources, the research focuses on two main areas: applications in sensing within the 2 μm region and the development of sources and other integrated structures in the visible-near infrared region for quantum algorithms, such as variational quantum eigensolver and boson sampler. For sensing, the study enhances quantum ghost spectroscopy to enable efficient gas detection using non-degenerate intermodal silicon sFWM. In the context of quantum simulation, silicon-nitride-based integrated photonic structures were realized to generate and manipulate quantum light within a photonic integrated circuit. Additionally, a proof-of-concept implementation of a two-qubit SWAP test in silicon nitride material showcased significant potential in quantum machine learning.

Quantum sensing, a protocol that takes advantage of the extreme sensitivity of quantum systems to their environment, enables many applications of quantum systems for sensing. Inspired by direct electric field sensing using the Stark effect of a nitrogen-vacancy(NV) center, this work implements an NV-magnet hybrid way to explore the possibilities of overcoming NV’s relatively weak coupling strength to electric fields. The magnetic-noise-induced population relaxation of the NV center serves as the mechanism for sensing. Within this scheme, the magnetic noise spectrum is tuned by modulating the magnetic properties via voltage-controlled magnetic anisotropy (VCMA) or electric-field-induced magnetoelastic effect. In this way, the noise carrying the information of the electric field is taken as a signal - the shift of the noise spectrum leads to a population difference of NV energy levels, which is used for evaluating electric fields. The investigation of the relation between sensitivities and operation points reveals that lower operation frequency is desirable for better performance. The comparison between VCMA and electric-field-induced magnetoelastic effect indicates that the efficiency of converting electric field into magnetic property modulation is a critical parameter for sensitivity enhancement.

<p dir="ltr">This work is the first report of optically addressable spin qubits in a semi-1D material, Boron Nitride Nanotubes (BNNTs). We perform the characterization of these spin defects and utilize their properties to do omnidirectional magnetic field sensing. We transfer these BNNTs with spin defects onto an AFM cantilever and perform scanning probe magnetometry of a 2D Nickel pattern on a gold waveguide. </p>

<p dir="ltr">Quantum information science and technology has been at the forefront of science and technology since MIT mathematician Peter Shor discovered a quantum algorithm to factor large numbers in 1994. Advancement in quantum theory also advances practical technological applications. Quantum technology can be applied both in civilian society and the military field from encryption, artificial intelligence, sensing, to communications. This multi-purpose applicability, therefore, has the potential to alter international security as scientifically advanced nation-states vie for quantum supremacy. This research examines the applications of quantum science and how these applications can potentially impact international security. Because nation-states fund and support quantum science research, sources of method will include academic journals and online resources as well as government reports. Practical applications of quantum technology, including quantum computing, quantum sensing, and quantum communication, will constitute the primary scope of this research.</p>

The absence of a cheap and easily scalable synthesis technique for nitrogen-vacancy (NV) centers enriched nanodiamonds (NDs) is a critical factor for the development of devices based on this very peculiar nanoparticle. Indeed, the combination between the unique NV fluorescence properties and NDs characteristics allow to obtain a tool having quantum sensing capabilities, with nanometric spatial resolution, which is able to operate in a wide range of temperature, pressures and in harsh chemical conditions. NVenriched NDs applications in nanothermometry, nanomagnetometry and in bio-imaging have already been reported. However, most of the standard fluorescent NDs production techniques present common drawbacks: poor control in NDs size distribution and in nitrogen concentration, as well as the need of post-synthesis process to clean the NDs surface from impurities and to increase the NV density. In this thesis, an alternative method for fluorescent NDs synthesis based on pulsed laser ablation (PLA) of graphite is demonstrated. After the introductory chapters on NV-centers physics and NDs properties (Chapter 2 and 3), the demonstration that PLA is a viable route for synthesis of NDs is given in Chapter 4. In particular, PLA of graphite and of diamond-like carbon is performed in water. Here, a thermodynamic model taking into account the peculiar physical processes occurring during PLA is developed to explain NDs formation. Then, synthesis of NV-enriched NDs is demonstrated through PLA of graphite in a nitrogen atmosphere (Chapter 5) and in liquid nitrogen (Chapter 6). In both chapters, the thermodynamic model is adapted to explain diamond phase formation in a gaseous environment and in a cryogenic liquid. Furthermore, NV centers optical properties are fully characterized with optically detected magnetic resonance (ODMR) spectroscopy. Finally, in Chapter 7, fluorescent NDs are produced by laser ablation of N-doped graphite in water. This particular target is then used for a quantitative comparison between the other fluorescent NDs laser-synthesis, with the aim of establishing in which condition the highest NV-center formation efficiency is achieved.

<p><br></p><p dir="ltr">Over the past decade, optical frequency combs have spurred significant advancements in both classical ultrafast optics and quantum optics. My research contributes to these two fields, catering to applications in precision metrology and optical networking. In the domain of quantum optics, the study delves into biphoton frequency combs with time-energy entanglement, employing novel electro-optic modulation schemes to enhance sensitivity and enable precise measurements of temporal correlations. Additionally, Bell states, a crucial class of entangled quantum bases, are generated in the frequency domain, showcasing their utility in delay metrology and quantum cryptographic protocols. </p><p dir="ltr">In the realm of classical optical frequency combs, this work explores dynamic steering of pulsed optical beams, holding promise for applications in imaging and remote sensing. The concept of time-efficient dynamic beam steering using a spatial array of optical frequency combs is elucidated and experimentally demonstrated through the utilization of a high-resolution spectral disperser, specifically a virtually imaged phased array (VIPA). Furthermore, integrated photonic designs featuring wavelength-selective switches and spectral dispersers are proposed to enable a versatile on-chip implementation of the beam steering approach. In sum, this research leverages the capabilities of classical and quantum optical frequency combs, with implications for emerging applications such as distributed sensing, quantum networking, and light detection and ranging (LIDAR).</p>