Yes / To support various fifth generation (5G) wireless applications, a small, printed bowtie-shaped microstrip antenna with meandered arms is reported in this article. Because it spans the broad legal range, the developed antenna can serve or reject a variety of applications such as wireless fidelity (Wi-Fi), sub-6 GHz, and ultra-wideband (UWB) 5G communications due to its multiband characterization and optimized rejection bands. The antenna is built on an FR-4 substrate and powered via a 50-Ω microstrip feed line linked to the right bowtie’s side. The bowtie’s left side is coupled via a shorting pin to a partial ground at the antenna’s back side. A gradually increasing meandering microstrip line is connected to both sides of the bowtie to enhance the rejection and operating bands. The designed antenna has seven operating frequency bands of (2.43–3.03) GHz, (3.71–4.23) GHz, (4.76–5.38) GHz, (5.83–6.54) GHz, (6.85–7.44) GHz, (7.56–8.01) GHz, and (9.27–13.88) GHz. The simulated scattering parameter S11 reveals six rejection bands with percentage bandwidths of 33.87%, 15.73%, 11.71, 7.63%, 6.99%, and 12.22%, respectively. The maximum gain of the proposed antenna is 4.46 dB. The suggested antenna has been built, and the simulation and measurement results are very similar. The reported antenna is expanded to a four-element design to investigate its MIMO characteristics. / Partially funded by British Council “2019 UK-China-BRI Countries Partnership Initiative” program, with project titled “Adapting to Industry 4.0 oriented International Education and Research Collaboration.

Cette thèse s’intéresse aux problèmes de tournées de véhicules où l’on retrouve des contraintes de chargement ayant un impact sur les séquences de livraisons permises. Plus particulièrement, les items placés dans l’espace de chargement d’un véhicule doivent être directement accessibles lors de leur livraison sans qu’il soit nécessaire de déplacer d’autres items. Ces problèmes sont rencontrés dans plusieurs entreprises de transport qui livrent de gros objets (meubles, électroménagers). Le premier article de cette thèse porte sur une méthode exacte pour un problème de confection d’une seule tournée où un véhicule, dont l’aire de chargement est divisée en un certain nombre de piles, doit effectuer des cueillettes et des livraisons respectant une contrainte de type dernier entré, premier sorti. Lors d’une collecte, les items recueillis doivent nécessairement être déposés sur le dessus de l’une des piles. Par ailleurs, lors d’une livraison, les items doivent nécessairement se trouver sur le dessus de l’une des piles. Une méthode de séparation et évaluation avec plans sécants est proposée pour résoudre ce problème. Le second article présente une méthode de résolution exacte, également de type séparation et évaluation avec plans sécants, pour un problème de tournées de véhicules avec chargement d’items rectangulaires en deux dimensions. L’aire de chargement des véhicules correspond aussi à un espace rectangulaire avec une orientation, puisque les items doivent être chargés et déchargés par l’un des côtés. Une contrainte impose que les items d’un client soient directement accessibles au moment de leur livraison. Le dernier article aborde une problème de tournées de véhicules avec chargement d’items rectangulaires, mais où les dimensions de certains items ne sont pas connus avec certitude lors de la planification des tournées. Il est toutefois possible d’associer une distribution de probabilités discrète sur les dimensions possibles de ces items. Le problème est résolu de manière exacte avec la méthode L-Shape en nombres entiers. / In this thesis, we study mixed vehicle routing and loading problems where a constraint is imposed on delivery sequences. More precisely, the items in the loading area of a vehicle must be directly accessible, without moving any other item, at delivery time. These problems are often found in the transportation of large objects (furniture, appliances). The first paper proposes a branch-and-cut algorithm for a variant of the single vehicle pickup and delivery problem, where the loading area of the vehicle is divided into several stacks. When an item is picked up, it must be placed on the top of one of these stacks. Conversely, an item must be on the top of one of these stacks to be delivered. This requirement is called “Last In First Out” or LIFO constraint. The second paper presents another branch-and-cut algorithm for a vehicle routing and loading problem with two-dimensional rectangular items. The loading area of the vehicles is also a rectangular area where the items are taken out from one side. A constraint states that the items of a given customer must be directly accessible at delivery time. The last paper considers a stochastic vehicle routing and loading problem with two- dimensional rectangular items where the dimensions of some items are unknown when the routes are planned. However, it is possible to associate a discrete probability distribution on the dimensions of these items. The problem is solved with the Integer L-Shaped method.

Investigamos o sistema formado por dois condensados aprisionados em estados hiperfinos diferentes do Rubídio, num potencial em forma de charuto, ou seja, num sistema físico real e quase-unidimensional. É investigada a dependência das soluções das equações de Gross-Pitaevski com a separação entre as armadilhas, bem como com o parâmetro de acoplamento de Josephson, para três valores diferentes do número total de átomos aprisionados. Para alguns conjuntos de parâmetros constatamos a existência de estados metaestáveis. O observável que escolhemos para caracterizar tal sistema físico foi a separação média entre os pacotes, pois os dois ramos de soluções encontramos correspondem a soluções mais juntas ou mais separadas espacialmente. / We study the system formed by two coupled condensates of different Rubidium hyperfine states trapped in a cigar shaped potential, that is, a real quasi one-dimensional system. The dependency of the solution of the Gross-Pitaevski equations is investigated as a function of trap displacement and Josephson coupling parameter for three different values of the total trapped atoms number. For some sets of parameters we report the existence of metastable states. The observable we chose to characterize this system was the mean separation between the packages, because we found two branches which correspond to closer or more separated solutions.

Cette thèse s’intéresse aux problèmes de tournées de véhicules où l’on retrouve des contraintes de chargement ayant un impact sur les séquences de livraisons permises. Plus particulièrement, les items placés dans l’espace de chargement d’un véhicule doivent être directement accessibles lors de leur livraison sans qu’il soit nécessaire de déplacer d’autres items. Ces problèmes sont rencontrés dans plusieurs entreprises de transport qui livrent de gros objets (meubles, électroménagers). Le premier article de cette thèse porte sur une méthode exacte pour un problème de confection d’une seule tournée où un véhicule, dont l’aire de chargement est divisée en un certain nombre de piles, doit effectuer des cueillettes et des livraisons respectant une contrainte de type dernier entré, premier sorti. Lors d’une collecte, les items recueillis doivent nécessairement être déposés sur le dessus de l’une des piles. Par ailleurs, lors d’une livraison, les items doivent nécessairement se trouver sur le dessus de l’une des piles. Une méthode de séparation et évaluation avec plans sécants est proposée pour résoudre ce problème. Le second article présente une méthode de résolution exacte, également de type séparation et évaluation avec plans sécants, pour un problème de tournées de véhicules avec chargement d’items rectangulaires en deux dimensions. L’aire de chargement des véhicules correspond aussi à un espace rectangulaire avec une orientation, puisque les items doivent être chargés et déchargés par l’un des côtés. Une contrainte impose que les items d’un client soient directement accessibles au moment de leur livraison. Le dernier article aborde une problème de tournées de véhicules avec chargement d’items rectangulaires, mais où les dimensions de certains items ne sont pas connus avec certitude lors de la planification des tournées. Il est toutefois possible d’associer une distribution de probabilités discrète sur les dimensions possibles de ces items. Le problème est résolu de manière exacte avec la méthode L-Shape en nombres entiers. / In this thesis, we study mixed vehicle routing and loading problems where a constraint is imposed on delivery sequences. More precisely, the items in the loading area of a vehicle must be directly accessible, without moving any other item, at delivery time. These problems are often found in the transportation of large objects (furniture, appliances). The first paper proposes a branch-and-cut algorithm for a variant of the single vehicle pickup and delivery problem, where the loading area of the vehicle is divided into several stacks. When an item is picked up, it must be placed on the top of one of these stacks. Conversely, an item must be on the top of one of these stacks to be delivered. This requirement is called “Last In First Out” or LIFO constraint. The second paper presents another branch-and-cut algorithm for a vehicle routing and loading problem with two-dimensional rectangular items. The loading area of the vehicles is also a rectangular area where the items are taken out from one side. A constraint states that the items of a given customer must be directly accessible at delivery time. The last paper considers a stochastic vehicle routing and loading problem with two- dimensional rectangular items where the dimensions of some items are unknown when the routes are planned. However, it is possible to associate a discrete probability distribution on the dimensions of these items. The problem is solved with the Integer L-Shaped method.

[pt] Este trabalho apresenta uma proposta de aceleração da decomposição de Benders aplicada a uma versão mais geral e compacta (menos restrições e variáveis) do modelo de gestão de estoques, otimizado via programação estocástica de dois estágios que considera uma camada, um item, demanda incerta e política de controle (R, S). De maneira a ser possível considerar problemas de grande porte, foram aplicados os métodos L-Shaped tradicional com corte único e a sua forma estendida com múltiplos cortes. Resultados computacionais preliminares mostraram um substancial melhor desempenho computacional do método L-Shaped tradicional em relação à sua forma multi-cut L-Shaped, mesmo o primeiro necessitando de mais iterações para convergir na solução ótima. Tal observação motivou o desenvolvimento de uma nova técnica de aceleração da decomposição de Benders e de um conjunto de desigualdades válidas. Experimentos numéricos mostram que a abordagem proposta de combinar a técnica de aceleração elaborada com as desigualdades válidas desenvolvidas provê significativa redução do tempo computacional necessário para a solução de instâncias de grande porte. / [en] This dissertation presents a speed up proposal for the Benders decomposition applied to a more general and compact version (less constraints and variables) of inventory management model, optimized via two-stage stochastic programming, which considers one layer, one item, uncertain demand and control policy (R, S). In order to be possible to consider large scale problems, the L-Shaped traditional method with single cuts and its extended form with multiple cuts were applied. Preliminary computational results showed a substantially better computational performance of the traditional L-Shaped method in comparison to the multi-cut L-Shaped method, even with the first requiring more iterations to converge on optimum solutions. This observation led to the development of a new technique to accelerate the decomposition of Benders and a set of valid inequalities. Numerical experiments show that the proposed approach of combining the elaborate acceleration technique with the developed valid inequalities, provide significant reduction in the computational time required to solve large scale instances.

Investigamos o sistema formado por dois condensados aprisionados em estados hiperfinos diferentes do Rubídio, num potencial em forma de charuto, ou seja, num sistema físico real e quase-unidimensional. É investigada a dependência das soluções das equações de Gross-Pitaevski com a separação entre as armadilhas, bem como com o parâmetro de acoplamento de Josephson, para três valores diferentes do número total de átomos aprisionados. Para alguns conjuntos de parâmetros constatamos a existência de estados metaestáveis. O observável que escolhemos para caracterizar tal sistema físico foi a separação média entre os pacotes, pois os dois ramos de soluções encontramos correspondem a soluções mais juntas ou mais separadas espacialmente. / We study the system formed by two coupled condensates of different Rubidium hyperfine states trapped in a cigar shaped potential, that is, a real quasi one-dimensional system. The dependency of the solution of the Gross-Pitaevski equations is investigated as a function of trap displacement and Josephson coupling parameter for three different values of the total trapped atoms number. For some sets of parameters we report the existence of metastable states. The observable we chose to characterize this system was the mean separation between the packages, because we found two branches which correspond to closer or more separated solutions.

Thesis (MSc (Earth Sciences))--University of Stellenbosch, 2009. / Fan 3 is one of four basin-floor fans that form part of the Tanqua Karoo Fan Complex in South Africa. It can be subdivided into several sandstone lobes, based on the presence of thin-bedded siltstone intervals above and below major sandstone packages. Six lobes are identified in the mid fan section, as well as two older groups of thin, low-volume turbidite deposits at the base. Some of the lobes are further divided into an upper and lower lobe-element based on depositional behaviour. The volumetrically and spatially larger lobes have a finger-like appearance in plan view, which is attributed to multiple lobe-scale axial zones. This is especially visible towards the eastern margins of Lobes 2, 4 and 5. The stratigraphy and facies distribution are presented on several 2D panels. Computer generated isopach maps are presented for each lobe, lobe-element and interlobe unit. Autogenic control on the depositional pattern of the Fan 3 lobe complex was inferred from the palaeoflow patterns of the composing lobes and lobe-elements. The majority of the lobes show a north-eastern palaeoflow direction in the south, with a gradual westward shift in the north. Inferred controls are basin-floor topography, the presence of pre-existing lobes, and characteristics of the depositional flow, such strength, density, sediment load, palaeoflow direction.

O poli(ε-caprolactona) (PCL) é um polímero biocompatível e biodegradável, aprovado pelo Food and Drug Administration (FDA) para ser usado como biomaterial. Diversos estudos utilizando sua forma linear ou ramificada têm demonstrado resultados promissores para seu uso no desenvolvimento de dispositivos médicos e em aplicações na área farmacêutica. O objetivo deste trabalho foi utilizar o PCL com estrutura estrelada (PCLE) para obter microesferas biorreabsorvíveis. Primeiramente realizou-se a avaliação das propriedades físico-químicas do PCLE por meio da cromatografia de permeação em gel (GPC), ressonância magnética de prótons (1H-RMN) e carbono (13C-RMN), calorimetria exploratória diferencial (DSC) e espectrometria por infravermelho com transformada de Fourier (FT-IR). A avaliação toxicológica do PCLE foi obtida por meio do ensaio de citotoxicidade utilizando células CHO-K1 e o corante vital 5-(3-carboximethoxifenil)-2-(4,5-dimetiltiazolil)-3-(4-sulfofenil) tetrazolium e do acoplador de elétrons fenazine metilssulfato (MTS/PMS). O ensaio de biodegradação foi conduzido em pH 7,4 na presença de lipase a 37 ºC. Após essas análises o PCLE foi utilizado para preparação de esferas por meio de emulsão complexa A/O/A. O PCLE foi caracterizado como um polímero de baixa massa molar, com dispersão de tamanho unimodal e cerca de 68,8 % de suas moléculas apresentaram estrutura estrelada com três braços. Em relação às propriedades térmicas o PCLE apresentou temperatura de fusão de 57,3 ºC e temperatura de transição vítrea de -54,3 ºC. A avaliação da citotoxicidade mostrou que o extrato de PCLE é compatível com o metabolismo celular. As microesferas obtidas a partir do PCLE, por emulsão A/O/A apresentaram polidispersão de tamanho. / The poly(ε-caprolactone) (PCL) is a biocompatible and biodegradable polymer which has been approved by Food and Drug Administration (FDA). Many studies that are using its linear or branched form have showed promising results for medical devices and controlled drug delivery applications. The aim of this research was the use of star-shaped PCL (PCLE) to prepare bioreabsorbable microspheres. At first, the physical-chemical properties were characterized by Gel Permeation Chromatography (GPC), Protons Resonance Magnetic Nuclear (1H-RMN), Carbon Resonance Magnetic Nuclear (13C-RMN), Differential Scanning Calorimetry (DSC) and Fourier Transformed Infrared Spectroscopy (FT-IR). The toxicological property was investigated by colorimetric assay using CHO-K1 cells and the vital dye (3-(4,5-dimethylthiazol-2-yl)-5-(3-carboxymethoxyphenyl)-2-(4-sulfophenyl)-2H-tetrazolium) (MTS) and the electron acceptor phenazine methosulfate (PMS). The biodegradation behavior was evaluated in the presence of lipase at 37 ºC and pH 7.4. The microspheres were prepared by complex emulsion W/O/W. The PCLE was characterized as low molecular weight polymer with monomodal distribution and about 68,8 % of the molecules were three-arm branched. The melting and glass transition temperatures were 57.3 ºC and -54.3 ºC, respectively. The cytotoxicity evaluation showed that PCLE extract was cell compatible. The obtained microspheres showed diameter polydispersity.

O Grupo Corumbá, SW Brasil, documenta uma etapa importante na evolução da vida por causa de seu registro fóssil de microbialitos, microfósseis, e organismos multicelulares indicativos da complexidade cada vez maior da biosfera no final do período Ediacarano. A importância paleobiológica da Formação Bocaina, inserido no meio do Grupo Corumbá, e datado em cerca de 560 Ma, é embasada em sua diversidade de microbialitos e registro de significativo evento fosfogenético, associados a supostos \"microfósseis em forma de vaso\", semelhantes à tecamebas, interpretadas como os primeiros protistas heterótrofos. Estes fósseis, bem como formas semelhantes reconhecidos em outras unidades geológicas do mundo, precedem o registro da explosão de organismos multicelulares macroscópicos esqueléticos (Cloudina, Corumbella) na formação sobrejacente Tamengo (543 Ma). A morfologia do microbialitos fornece evidências de variação local do nível do mar durante a deposição da Form ação Bocaina. As análises morfológicas e químicas dos microfósseis usando microscopia óptica e eletrônica de varredura, EDS e espectroscopia Raman ajudaram a esclarecer a natureza biológica desses objetos e, assim, contribuir para a compreensão da importância da evolução da vida no Ediacarano, na Formação Bocaina, Grupo Corumbá. / The Corumbá Group, SW Brazil, documents an important stage in the evolution of life because of its fossil record of microbialites, microfossils, and early multicellular organisms indicative of the rapidly increasing complexity of the biosphere at the very end of the Ediacaran period. The paleobiological importance of the Bocaina Formation, in middle of the Corumbá Group and dated at about 560 Ma, lies in its diversity of microbialites and its record of a significant phosphogenesis event with associated putative \"vase-shaped microfossils\", similar to testate amoebae, interpreted as early protistan heterotrophs. Th ese fossils, as well as similar forms recognized in other geologic units in the world precede the record of the explosion of macroscopic multicellular skeletal organisms (Cloudina, Corumbella) in the overlying Tamengo Formation (543 Ma). The morphology of microbialites provides evidence of local sea level variation during deposition of the Bocaina Formation. Morphological and chemical analyses of the microfossils using optical and scanning electron microscopy, EDS and Raman spectroscopy helped clarify the biological nature of these objects and thereby contribute to the understanding of the importance of the Bocaina Formation the evolution of late Ediacaran life in the Corumbá Group.

O poli(ε-caprolactona) (PCL) é um polímero biocompatível e biodegradável, aprovado pelo Food and Drug Administration (FDA) para ser usado como biomaterial. Diversos estudos utilizando sua forma linear ou ramificada têm demonstrado resultados promissores para seu uso no desenvolvimento de dispositivos médicos e em aplicações na área farmacêutica. O objetivo deste trabalho foi utilizar o PCL com estrutura estrelada (PCLE) para obter microesferas biorreabsorvíveis. Primeiramente realizou-se a avaliação das propriedades físico-químicas do PCLE por meio da cromatografia de permeação em gel (GPC), ressonância magnética de prótons (1H-RMN) e carbono (13C-RMN), calorimetria exploratória diferencial (DSC) e espectrometria por infravermelho com transformada de Fourier (FT-IR). A avaliação toxicológica do PCLE foi obtida por meio do ensaio de citotoxicidade utilizando células CHO-K1 e o corante vital 5-(3-carboximethoxifenil)-2-(4,5-dimetiltiazolil)-3-(4-sulfofenil) tetrazolium e do acoplador de elétrons fenazine metilssulfato (MTS/PMS). O ensaio de biodegradação foi conduzido em pH 7,4 na presença de lipase a 37 ºC. Após essas análises o PCLE foi utilizado para preparação de esferas por meio de emulsão complexa A/O/A. O PCLE foi caracterizado como um polímero de baixa massa molar, com dispersão de tamanho unimodal e cerca de 68,8 % de suas moléculas apresentaram estrutura estrelada com três braços. Em relação às propriedades térmicas o PCLE apresentou temperatura de fusão de 57,3 ºC e temperatura de transição vítrea de -54,3 ºC. A avaliação da citotoxicidade mostrou que o extrato de PCLE é compatível com o metabolismo celular. As microesferas obtidas a partir do PCLE, por emulsão A/O/A apresentaram polidispersão de tamanho. / The poly(ε-caprolactone) (PCL) is a biocompatible and biodegradable polymer which has been approved by Food and Drug Administration (FDA). Many studies that are using its linear or branched form have showed promising results for medical devices and controlled drug delivery applications. The aim of this research was the use of star-shaped PCL (PCLE) to prepare bioreabsorbable microspheres. At first, the physical-chemical properties were characterized by Gel Permeation Chromatography (GPC), Protons Resonance Magnetic Nuclear (1H-RMN), Carbon Resonance Magnetic Nuclear (13C-RMN), Differential Scanning Calorimetry (DSC) and Fourier Transformed Infrared Spectroscopy (FT-IR). The toxicological property was investigated by colorimetric assay using CHO-K1 cells and the vital dye (3-(4,5-dimethylthiazol-2-yl)-5-(3-carboxymethoxyphenyl)-2-(4-sulfophenyl)-2H-tetrazolium) (MTS) and the electron acceptor phenazine methosulfate (PMS). The biodegradation behavior was evaluated in the presence of lipase at 37 ºC and pH 7.4. The microspheres were prepared by complex emulsion W/O/W. The PCLE was characterized as low molecular weight polymer with monomodal distribution and about 68,8 % of the molecules were three-arm branched. The melting and glass transition temperatures were 57.3 ºC and -54.3 ºC, respectively. The cytotoxicity evaluation showed that PCLE extract was cell compatible. The obtained microspheres showed diameter polydispersity.