The making and breaking power of leadership has never been disputable. It is believed to be the single most important factor by which organizations used to exploit opportunities and survive hardships. Despite the fact that all functional areas are not immune to the consequences of good and bad leadership, marketing is uniquely sensitive. Unarguably, all leadership styles are not expected to equally impact marketing performance. A leader of character who inspires followers, helps employees to use their potentials, allows employees to make and fix errors, and pave ways for employee advancement is a one typically needed by organizations. This kind of leader is even more critical for those organizations operating in a brutally competitive market; like the brewing one in Ethiopia. This study is designed to investigate the direct and indirect impact of Transformational Leadership on marketing performance. Moreover, the moderating effect of leaders’ experience and the impact of group difference in leaders’ gender, leaders position and brewery sizes are studied. The unit of analysis are managers and decision makers (committee members) from the four sample breweries (St. George Brewery, Meta Abo Brewery, Raya Brewery, and Habesha Brewery). The data are collected from 211 respondents. In the study, in addition to the data cleaning procedures, all the multivariate data analysis assumptions are ensured. A model is developed and tested using a survey methodology. Four properly validated instruments, one selfdesigned (for marketing performance construct) and three adopted (for transformational leadership, organizational learning, and customer orientation constructs) are used. The validation work is ensured through factor analysis (exploratory and confirmatory). Exploratory factor analysis (EFA) and confirmatory factor analysis (CFA) are worked out using SPSS 21 and AMOS 21 packages respectively. Data is analysed through the structural equation modelling technique. Results show that, Transformational Leadership style is positively and significantly associated with marketing performance, organizational learning and customer orientation. Moreover, it is found that Transformational Leadership indirectly and positively impacts marketing performance. Nevertheless, the hypothesized moderation effect of experience for the impacts of Transformational Leadership on customer orientation is failed to be significant. The study contributes a lot by narrowing the wide literature gap existed in the topic area in the context of the developing world. Secondary evidences are strongly discussed on the antecedents and outcomes of Transformational Leadership and marketing performance. Thus, it is the researcher’s belief that now because of this study; value is added to the body of knowledge and the study can benefit practitioners and academicians alike. / Business Management / D.B.L.

This thesis focuses on the emergence of the teenaged consumer as a market segment in Canada during the 1930s, 1940s, and 1950s. It challenges the notion that teenagers were of little interest to retailers until economics and demographics shaped the more numerous and prosperous post-war teenagers of the Baby Boom generation. Using evidence from corporate records and analysis of mail order catalogues, the study examines how department store retailer, the T. Eaton Company, Limited, began to cultivate a distinct and lucrative teenaged consumer in the 1930s, and thereby began shaping the teenaged consumer. The thesis contextualizes the case study of Eaton’s by exploring the varied expectations that adults had of young people at the time, using census records and magazines (Chatelaine, Canadian Home Journal and Mayfair) to explore concerns about young people’s transition to adulthood. It then focuses on how Eaton’s made a concerted and sustained effort to attract teenager customers to its catalogue and stores. Analysis of its semi-annual catalogue highlights the emergence of specialized clothing size ranges and styles, revealing that Eaton’s increasingly viewed the teenaged years as an important in-between life stage. Eaton’s also instituted teenage advisory councils to both glean market trends and provide a venue for what it considered education for novice consumers. Eaton’s presented consumption as a way to prepare young people for adult roles, legitimizing teenaged participation in the consumer marketplace and contributing to wider debates about when and how teenaged Canadians should reach maturity.

The aim of this thesis is the design of laboratory crusher of mineral raw materials. This work is focused on the research of possible types of machinery for crushing process, list of shredders available at domestic and foreign markets, selection of the principle of diminution of mineral resources, the choice of approach, suggestion of calculation of the chosen design, creating a 3D model and drawings, making the strength analysis for selected parts, risk analysis.

Les déchets plastiques s'accumulent depuis plusieurs décennies dans les océans où ils se fragmentent en particules appelés microplastiques lorsque leur taille est inférieure à 5 mm. Ces microplastiques sont retrouvés dans toutes les eaux du globe, dans les sédiments ainsi que dans de nombreux organismes marins. Le devenir physicochimique à long terme de ces particules et leur possible fragmentation en nanoplastiques sont complexes, encore peu documentés et nécessitent des études en laboratoire.Afin de comprendre les processus liés à la photodégradation et à la fragmentation des polymères dans l’environnement, mais également dans le but d’'appréhender l’évolution des fragments générés au cours de l’irradiation, un protocole de vieillissement accéléré en milieu abiotique a été mis en place sur des polymères modèles. Le suivi de l’oxydation et de la fragmentation des deux polymères étudiés,polyéthylène basse densité et polypropylène, a été mené à l’aide de techniques spectroscopiques (infrarouge, Raman), DSC, angles de contact, et microscopiques (lumière polarisée, MEB, AFM…).Ce travail a permis de mettre en évidence l’influence significative de l’environnement et de la morphologie initiale des polymères sur leurs cinétiques de vieillissement et leurs mécanismes de fissuration. Ainsi des distributions en nombres, tailles et formes de fragments très différentes ont été obtenues pour les deux polymères selon la présence d’eau. Enfin, après un long temps d’irradiation, des produits de dégradation ont pu être détectés mais la production significative de nanoplastiques n’a pas été démontrée. L'hypothèse d'une taille limite de fragmentation devrait être envisagée. / Plastic wastes have been accumulating for several decades in the oceans where they break up into particles called microplastics when their size is less than 5 mm. These microplastics are found in all earth’s waters, in sediments and in many marine organisms. Their long-term physico-chemical fate and their possible fragmentation into nanoplastics are complex, still poorly documented and require laboratory studies.In order to understand the processes related to photodegradation and fragmentation of polymers, but also in order to understand the evolution of these fragments during irradiation, an accelerated aging protocol in abiotic conditions has been set up. The oxidation and fragmentation of two model polymers, low density polyethylene and polypropylene, were monitored using spectroscopic techniques (InfraRed, Raman), DSC, contact angles and microscopic technics (light microscopy, polarized light, SEM, AFM ...).This work has demonstrated a significant influence of the environment and the initial morphology of the polymers on their kinetics of aging and cracking mechanisms. This lead to significantly different distributions in numbers, sizes and shapes of the generated fragments. Moreover, after a long time of irradiaiton, other degradation products could be detected but the significant production of nanoplastics has not been demonstrated. The possibility of a size limit below which the fragmentation rate of plastics would strongly decrease should be considered.

The effects of metastable tetragonal zirconia on the properties of Ordinary Portland Cement were observed during which the effect of crystallite size pH on the preparation solution, precursor salt, and the presence of co-precipitates, Fe(OH)3, SnO2 and SiO2 on the crystallization temperature, enthalpy and crystal structure, immediately following the crystallization exothermic burst phenomenon in ZrO2 were measured. Thermal analysis and x-ray methods were used to determine crystallite sizes and structures immediately following the exothermic burst. Comparisons were made for zirconias prepared from oxychloride, chloride and nitrate solutions. The existence of tetrameric hydroxidecontaining ions in oxychloride precursor is used to rationalise low values of crystallization enthalpy. The position of the crystallization temperature, Tmax was not dependent on crystallite size alone but also on the pH at which the gel was made, the surface pH after washing, and the presence of diluent oxides. Enthalpy v r1/2 and Tmax v (diluent vol)1/3 relationships indicate that surface coverage effects dominate a surface nucleated phenomenon. The data established for ZrO2 systems was used to develop tetragonal-ZrO2-SnO2 powders capable of improving the mechanical properties of Ordinary Portland Cement discs. The ZrO2-OPC discs were prepared by powder mixing, water hydration and uniaxial pressing. Vicat needle tests showed that tetragonal-ZrO2 increases the initial setting rate. Microscopy indicated that porosity distribution changes near to ZrO2 particles. Zirconia has also been introduced into OPC discs by vacuum infiltration methods developed for solutions and colloidal suspensions. Comparisons between OPC discs and the OPCtetragonal ZrO2 composites have been made on the basis of diametral compression strength, Young’s modulus, hardness and toughness (K1c), as estimated by the cracked indentation method. Bell-shaped curves are found for the way the mechanical properties are changed as a function of Zirconia content.

No description available.

分析具有巢狀誤差結構的迴歸模式時，惹忽略隨機誤差項之間的相關性，而採用最小平方(OLS)估計量所導出的標準 F 統計量（以 F^S表之）進行檢定，會導致過大的型 I 錯誤機率；若將隨機誤差項之間的相關性納入考量，而採用廣義最小平方(GLS)估計量所導出的 F 統計量 （以 F^GLS表之），則計算上會較為繁雜。因此我們藉由轉換方式，將模式轉換成隨機誤差項之間彼此獨立的新模式後，再以 F^S 進行檢定，其結果與直接以 F^GLS 檢定相同，且可使計算較為方便。由於模式轉換所需的轉換矩陣為母體變異數的函數，因此當母體變異數未知時，我們以 Henderson 的常數配適 （fitting-of-constants）方法來估計之。藉由模擬結果得知，若各段的觀察個數相等，則不論巢狀誤差結構為二段式(two-stage)或三段式(three-stage)，廣義最小平方估計量(GLS)均較最小平方估計量(OLS)表現穩定，且 F^GLS 在檢定力及實際顯著水準方面的表現也都比 F^S 好。 / When analyzing the regression model with nested-error structure, if the correlations between errors are ignored, and conduting the model adequacy test by the standard F statistic (F^S) led from the ordinary leastsquares estimator (OLSE) , then the type I error rate will be inflated. However, if the corrlated structure is considered and the model is tested by F^GLS led from the general least-squares estimator (GLSE) , the calculation will be more complicate. The model can be transformed to a new model with independent random errors and then, tested by F^S . The result is the same as the one by F^GLS , also it is more convenient for calculation. Since the transformation matrix is a function of variance components, we estimate variance components by Henderson's fitting-of-constants when they are unknown. Through simulation, it is concluded that if the observations in each stage of nested-error structure are the same, the GLSE is more stable than the OLSE in both two-stage and tree-stage structures. Also, the power and the sizes of F^GLS will perform better than those of F^S .

Modern manufacturing systems need new types of scheduling methods. While traditional scheduling methods are primarily concerned with sequencing of jobs, modern manufacturing environments provide the additional possibility to process jobs in batches. This adds to the complexity of scheduling. There are two types of batching namely: (i) serial batching (jobs may be batched if they share the same setup on a machine and one job is processed at a time. The machine which processes jobs in this manner is called as discrete processor) and (ii) parallel batching (several jobs can be processed simultaneously on a machine at a time. The machine which processes jobs in this manner is called as batch processor or batch processing machine). Parallel batching environments have attracted wide attention of the researchers working in the field of scheduling. Particularly, taking inspiration from studies of scheduling batch processors in semiconductor manufacturing [Mathirajan and Sivakumar (2006b) and Venkataramana (2006)] and in steel casting industries [Krishnaswamy et al. (1998), Shekar (1998) and Mathirajan (2002)] in the Management Studies Department of Indian Institute of Science, this thesis addresses a special problem on scheduling batch processor, observed in the steel casting manufacturing. A fundamental feature of the steel casting industry is its extreme flexibility, enabling castings to be produced with almost unlimited freedom in design over an extremely wide range of sizes, quantities and materials suited to practically every environment and application. Furthermore, the steel casting industry is capital intensive and highly competitive. From the viewpoint of throughput and utilization of the important and costly resources in the foundry manufacturing, it was felt that the process-controlled furnace operations for the melting and pouring operations as well as the heat-treatment furnace operations are critical for meeting the overall production schedules. The two furnace operations are batch processes that have distinctive constraints on job-mixes in addition to the usual capacity and technical constraints associated with any industrial processes. The benefits of effective scheduling of these batch processes include higher machine utilization, lower work-in-process (WIP) inventory, shorter cycle time and greater customer satisfaction [Pinedo (1995)]. Very few studies address the production planning and scheduling models for a steel foundry, considering the melting furnace of the pre-casting stage as the core foundry operation [Voorhis et al. (2001), Krishnaswamy et al. (1998) and Shekar (1998)]. Even though the melting and pouring operations may be considered as the core of foundry operations and their scheduling is of central importance, the scheduling of heat-treatment furnaces is also of considerable importance. This is because the processing time required at the heat treatment furnace is often longer compared to other operations in the steel-casting foundry and therefore considerably affects the scheduling, overall flow time and WIP inventory. Further, the heat-treatment operation is critical because it determines the final properties that enable components to perform under demanding service conditions such as large mechanical load, high temperature and anti-corrosive processing. It is also important to note that the heat-treatment operation is the only predominantly long process in the entire steel casting manufacturing process, taking up a large part of total processing time (taking up to a few days as against other processes that typically take only a few hours). Because of these, the heat-treatment operation is a major bottleneck operation in the entire steel casting process. The jobs in the WIP inventory in front of heat-treatment furnace vary widely in sizes (few grams to a ton) and dimensions (from 10 mm to 2000 mm). Furthermore, castings are primarily classified into a number of job families based on the alloy type, such as low alloy castings and high alloy castings. These job families are incompatible as the temperature requirement for low alloy and high alloy vary for similar type of heat-treatment operation required. These job families are further classified into various sub-families based on the type of heat treatment operations they undergo. These sub-families are also incompatible as each of these sub-families requires a different combination of heat-treatment operation. The widely varying job sizes, job dimensions and multiple incompatible job family characteristic introduce a high degree of complexity into scheduling heat-treatment furnace. Scheduling of heat-treatment furnace with multiple incompatible job families can have profound effect on the overall production rate as the processing time at heat-treatment operation is very much longer. Considering the complexity of the process and time consumed by the heat treatment operation, it is imperative that efficient scheduling of this operation is required in order to maximize throughput and to enhance productivity of the entire steel casting manufacturing process. This is of importance to the firm. The concerns of the management in increasing the throughput of the bottleneck machine, thereby increasing productivity, motivated us to adopt the scheduling objective of makespan. In a recent observation of heat-treatment operations in a couple of steel casting industries and the research studies reported in the literature, we noticed that the real-life problem of dynamic scheduling of heat-treatment furnace with multiple incompatible job families, non-identical job sizes, non-identical job dimensions, non-agreeable release times and due dates to maximize the throughput, higher utilization and minimize the work-in-process inventory is not at all addressed. However, there are very few studies [Mathirajan et al. (2001, 2002, 2004a, 2007)] which have addressed the problem of scheduling of heat-treatment furnace with incompatible job families and non-identical job sizes to maximize the utilization of the furnace. Due to the difference between the real-life situation on dynamic scheduling of heat-treatment furnace of the steel casting manufacturing and the research reported on the same problem, we identified three new class of batch processor problems, which are applicable to a real-life situation based on the type of heat-treatment operation(s) being carried out and the type of steel casting industry (small, medium and large scale steel casting industry) and this thesis addresses these new class of research problems on scheduling of batch processor. The first part of the thesis addresses our new Research Problem (called Research Problem 1) of minimizing makespan (Cmax) on a batch processor (BP) with single job family (SJF), non-identical job sizes (NIJS), and non-identical job dimensions (NIJD). This problem is of interest to small scale steel casting industries performing only one type of heat treatment operation such as surface hardening. Generally, there would be only a few steel casting industries which offer such type of special heat-treatment operation and thus the customer is willing to accept delay in the completion of his orders. So, the due date issues are not important for these types of industries. We formulate the problem as Mixed Integer Linear Programming (MILP) model and validate the proposed MILP model through a numerical example. In order to understand the computational intractability issue, we carry out a small computational experiment. The results of this experiment indicate that the computational time required, as a function of problem size, for solving the MILP model is non-deterministic and non-polynomial. Due to the computational intractability of the proposed MILP model, we propose five variants of a greedy heuristic algorithm and a genetic algorithm for addressing the Research Problem 1. We carry out computational experiments to obtain the performance of heuristic algorithms based on two perspectives: (i) comparison with optimal solution on small scale instances and (ii) comparison with lower bound for large scale instances. We choose five important problem parameters for the computational experiment and propose a suitable experimental design to generate pseudo problem instances. As there is no lower bound (LB) procedure for the Research Problem1, in this thesis, we develop an LB procedure that provides LB on makespan by considering both NIJS and NIJD characteristics together. Before using the proposed LB procedure for evaluating heuristic algorithms, we conduct a computational experiment to obtain the quality of the LB on makespan in comparison with optimal makespan on number of small scale instances. The results of this experiment indicate that the proposed LB procedure is efficient and could be used to obtain LB on makespan for any large scale problem. In the first perspective of the evaluation of the performance of the heuristic algorithms proposed for Research Problem 1, the proposed heuristic algorithms are run through small scale problem instances and we record the makespan values. We solve the MILP model to obtain optimal solutions for these small scale instances. For comparing the proposed heuristic algorithms we use the performance measures: (a) number of times the proposed heuristic algorithm solution equal to optimal solution and (b) average loss with respect to optimal solution in percentage. In the second perspective of the evaluation of the performance of the heuristic algorithms, the proposed heuristic algorithms are run through large scale problem instances and we record the makespan values. The LB procedure is also run through these problem instances to obtain LB on makespan. For comparing the performance of heuristic algorithms with respect to LB on makespan, we use the performance measures: (a) number of times the proposed heuristic algorithm solution equal to LB on makespan (b) average loss with respect to LB on makespan in percentage, (c) average relative percentage deviation and (d) maximum relative percentage deviation. We extend the Research Problem 1 by including additional job characteristics: job arrival time to WIP inventory area of heat-treatment furnace, due date and additional constraint on non-agreeable release time and due date (NARD). Due date considerations and the constraint on non-agreeable release times and due date (called Research Problem 2) are imperative to small scale steel casting foundries performing traditional but only one type of heat treatment operation such as annealing where due date compliance is important as many steel casting industries offer such type of heat treatment operations. The mathematical model, LB procedure, greedy heuristic algorithm and genetic algorithm proposed for Research Problem 1, including the computational experiments, are appropriately modified and\or extended for addressing Research Problem 2. Finally, we extend the Research Problem 2 is by including an additional real life dimension: multiple incompatible job families (MIJF). This new Research Problem (called Research Problem 3) is more relevant to medium and large scale steel casting foundries performing more than one type of heat treatment operations such as homogenizing and tempering, normalizing and tempering. The solution methodologies, the LB procedure and the computational experiments proposed for Research Problem 2 are further modified and enriched to address the Research Problem 3. From the detailed computational experiments conducted for each of the research problems defined in this study, we observe that: (a) the problem parameters considered in this study have influence on the performance of the heuristic algorithms, (b) the proposed LB procedure is found to be efficient, (c) the proposed genetic algorithm outperforms among the proposed heuristic algorithms (but the computational time required for genetic algorithm increases as problem size keeps increasing), and (d) in case the decision maker wants to choose an heuristic algorithm which is computationally most efficient algorithm among the proposed algorithms, the variants of greedy heuristic algorithms : SWB, SWB(NARD), SWB(NARD&MIJF) is relatively the best algorithm for Research Problem 1, Research Problem 2 and Research Problem 3 respectively.

This article proposes the algorithm of a new control chart (loss function control chart) based on the Taguchi loss function with an adaptive scheme for binomial data. The loss function control chart is able to monitor cost variation from the process by applying loss function in the design. This new angle economically explores production cost. This research provides designs of the loss function control chart with specified VSI, optimal VSI, VSS and VP, respectively. Numerical analyses show that the specified VSI loss function chart, the optimal VSI loss function chart, the optimal VSS loss function chart and the optimal VP loss function chart outperform the Fp loss function chart significantly and show costs can be controlled systematically.

Σκοπός της διδακτορικής διατριβής είναι η ανάπτυξη κατάλληλων μεθόδων ψηφιακής επεξεργασίας εικόνας και αναγνώρισης προτύπων με τις οποίες θα προσδιορίζονται βιομετρικές και διαγνωστικές παράμετροι μέσω της αλληλεπίδρασης φωτονίων στο ορατό και υπέρυθρο φάσμα. Πιο συγκεκριμένα επιλύεται ένα αντίστροφο πρόβλημα σκέδασης ΗΜ ακτινοβολίας από ένα ανθρώπινο, υγιές και απαραμόρφωτο ερυθρό αιμοσφαίριο. Παρουσιάζονται μέθοδοι εκτίμησης και αναγνώρισης των γεωμετρικών χαρακτηριστικών απαραμόρφωτων υγιών ερυθρών αιμοσφαιρίων με χρήση εικόνων που προσομοιώνουν φαινόμενα σκέδασης ηλεκτρομαγνητικής ακτινοβολίας που διέρχεται από προσανατολισμένα ερυθρά αιμοσφαίρια. Η διαδικασία της ανάκτησης της πληροφορίας περιλαμβάνει, εξαγωγή χαρακτηριστικών με χρήση δισδιάστατων μετασχηματισμών, κανονικοποίηση των χαρακτηριστικών και την χρήση νευρωνικών δικτύων για την εκτίμηση των γεωμετρικών ιδιοτήτων του ερυθροκυττάρου. Παράλληλα σχεδιάστηκε και αξιολογήθηκε σύστημα αναγνώρισης των γεωμετρικών χαρακτηριστικών των ερυθρών αιμοσφαιρίων. Οι εικόνες σκέδασης δημιουργήθηκαν προσομοιώνοντας το πρόβλημα εμπρόσθιας σκέδασης ενός επίπεδου ηλεκτρομαγνητικού (ΗΜ) κύματος, χρησιμοποιώντας την μέθοδο των συνοριακών στοιχείων, λαμβάνοντας υπόψη τόσο την αξονοσυμμετρική γεωμετρία του ερυθροκυττάρου όσο και τις μη αξονοσυμμετρικές οριακές συνθήκες του προβλήματος. Η επίλυση του εν λόγω προβλήματος πραγματοποιήθηκε στα 632.8 nm και εν συνεχεία επεκτάθηκε σε 12 διακριτά ίσου βήματος μήκη κύματος από 432.8 nm έως 1032.8 nm. Επίσης, προτάθηκε μία νέα πειραματική διάταξη για την απόκτηση πολλαπλών εικόνων σκέδασης και την εκτίμηση των γεωμετρικών χαρακτηριστικών των ερυθρών αιμοσφαιρίων, αποτελούμενη από μία πολυχρωματική πηγή φωτός (Led) και πολλαπλά χρωματικά φίλτρα. Επίσης κατασκευάστηκε μέθοδος επίλυσης του σημαντικού προβλήματος εύρεσης της περιεκτικότητας του διαλύματος σε ερυθρά αιμοσφαίρια διαφορετικών μεγεθών στην περίπτωση απόκτησης πολλαπλών εικόνων σκέδασης από διαφορετικές φωτοδιόδους και πολλαπλά χρωματικά φίλτρα. Στα πειράματα αξιολόγησης της μεθόδου που προτείνεται με εικόνες προσομοίωσης δείχνεται ότι είναι ικανή η εύρεση της αναλογίας των ερυθρών αιμοσφαιρίων με πολύ μεγάλη ακρίβεια ακόμα και στη περίπτωση όπου στις εικόνες έχει προστεθεί λευκός κανονικός θόρυβος. Η βασική μεθοδολογία που παρουσιάζεται στην παρούσα δια-τριβή μπορεί να χρησιμοποιηθεί για την αναγνώριση παθολογικών αιμοσφαιρίων ή να χρησιμοποιηθεί στην αναγνώριση μικροσωματιδίων σε υγρά ή αέρια. / The aim of this PhD thesis is the development of digital image processing and pattern recognition methods to estimate biometric and diagnostic parameters using scattering phenomena in the visible and infrared spectrum. More concretely, several reverse scattering problems of EM radiation from a human, healthy and undistorted Red Blood Cell (RBC) is solved. Methods of estimation and recognition of geometrical characteristics of healthy and undistorted RBCs using simulating images are presented. The information retrieval process includes, features extraction using two-dimensional integral transforms, features normalization, and Neural Networks for estimation of three major RBC geometrical proper-ties. Using the same features set, a recognition system of the geometric characteristics of RBCs was developed and evaluated. The scattering images were created simulating the forward scattering problem of a plane electromagnetic wave using the Boundary Element Method, taking into account both axisymmetric geometry of the scatterer and the non-axisymmetric boundary conditions of the problem. Initially, the problem is solved at 632.8 nm and consequently the same problem was solved at 12 different wavelengths, from 432.8 to 1032.8 nm equally spaced. Also, a new device for acquisition of scattering images from RBCs-flow, consisting of a multi-color light source (Led) was proposed, for RBC size estimation and recognition. Finally, a system for the estimation of different RBCs concentration was developed when scattering images acquired using multiple scattering images acquired from multiple Leds and color filters. The system was evaluated using additive white regular noise.