This thesis deals with several statistical and probabilistic aspects of symmetry and asymmetry, both in a univariate and multivariate context, and is divided into three distinct parts.<p><p>The first part, composed of Chapters 1, 2 and 3 of the thesis, solves two conjectures associated with multivariate skew-symmetric distributions. Since the introduction in 1985 by Adelchi Azzalini of the most famous representative of that class of distributions, namely the skew-normal distribution, it is well-known that, in the vicinity of symmetry, the Fisher information matrix is singular and the profile log-likelihood function for skewness admits a stationary point whatever the sample under consideration. Since that moment, researchers have tried to determine the subclasses of skew-symmetric distributions who suffer from each of those problems, which has led to the aforementioned two conjectures. This thesis completely solves these two problems.<p><p>The second part of the thesis, namely Chapters 4 and 5, aims at applying and constructing extremely general skewing mechanisms. As such, in Chapter 4, we make use of the univariate mechanism of Ferreira and Steel (2006) to build optimal (in the Le Cam sense) tests for univariate symmetry which are very flexible. Actually, their mechanism allowing to turn a given symmetric distribution into any asymmetric distribution, the alternatives to the null hypothesis of symmetry can take any possible shape. These univariate mechanisms, besides that surjectivity property, enjoy numerous good properties, but cannot be extended to higher dimensions in a satisfactory way. For this reason, we propose in Chapter 5 different general mechanisms, sharing all the nice properties of their competitors in Ferreira and Steel (2006), but which moreover can be extended to any dimension. We formally prove that the surjectivity property holds in dimensions k>1 and we study the principal characteristics of these new multivariate mechanisms.<p><p>Finally, the third part of this thesis, composed of Chapter 6, proposes a test for multivariate central symmetry by having recourse to the concepts of statistical depth and runs. This test extends the celebrated univariate runs test of McWilliams (1990) to higher dimensions. We analyze its asymptotic behavior (especially in dimension k=2) under the null hypothesis and its invariance and robustness properties. We conclude by an overview of possible modifications of these new tests./<p><p>Cette thèse traite de différents aspects statistiques et probabilistes de symétrie et asymétrie univariées et multivariées, et est subdivisée en trois parties distinctes.<p><p>La première partie, qui comprend les chapitres 1, 2 et 3 de la thèse, est destinée à la résolution de deux conjectures associées aux lois skew-symétriques multivariées. Depuis l'introduction en 1985 par Adelchi Azzalini du plus célèbre représentant de cette classe de lois, à savoir la loi skew-normale, il est bien connu qu'en un voisinage de la situation symétrique la matrice d'information de Fisher est singulière et la fonction de vraisemblance profile pour le paramètre d'asymétrie admet un point stationnaire quel que soit l'échantillon considéré. Dès lors, des chercheurs ont essayé de déterminer les sous-classes de lois skew-symétriques qui souffrent de chacune de ces problématiques, ce qui a mené aux deux conjectures précitées. Cette thèse résoud complètement ces deux problèmes.<p><p>La deuxième partie, constituée des chapitres 4 et 5, poursuit le but d'appliquer et de proposer des méchanismes d'asymétrisation très généraux. Ainsi, au chapitre 4, nous utilisons le méchanisme univarié de Ferreira and Steel (2006) pour construire des tests de symétrie univariée optimaux (au sens de Le Cam) qui sont très flexibles. En effet, leur méchanisme permettant de transformer une loi symétrique donnée en n'importe quelle loi asymétrique, les contre-hypothèses à la symétrie peuvent prendre toute forme imaginable. Ces méchanismes univariés, outre cette propriété de surjectivité, possèdent de nombreux autres attraits, mais ne permettent pas une extension satisfaisante aux dimensions supérieures. Pour cette raison, nous proposons au chapitre 5 des méchanismes généraux alternatifs, qui partagent toutes les propriétés de leurs compétiteurs de Ferreira and Steel (2006), mais qui en plus sont généralisables à n'importe quelle dimension. Nous démontrons formellement que la surjectivité tient en dimension k > 1 et étudions les caractéristiques principales de ces nouveaux méchanismes multivariés.<p><p>Finalement, la troisième partie de cette thèse, composée du chapitre 6, propose un test de symétrie centrale multivariée en ayant recours aux concepts de profondeur statistique et de runs. Ce test étend le célèbre test de runs univarié de McWilliams (1990) aux dimensions supérieures. Nous en analysons le comportement asymptotique (surtout en dimension k = 2) sous l'hypothèse nulle et les propriétés d'invariance et de robustesse. Nous concluons par un aperçu sur des modifications possibles de ces nouveaux tests. / Doctorat en Sciences / info:eu-repo/semantics/nonPublished

Fischer-Tropsch Synthesis (FTS) is a promising technology for the production of ultra-clean fuels and chemical feedstocks from biomass, coal, or natural gas. Iron catalysts are ideal for conversion of coal and biomass. However, precipitated iron catalysts used in slurry-bubble column reactors suffer from high attrition resulting in difficulty separating catalysts from product and increased slurry viscosity. Thus, development of an active and selective-supported iron catalyst to manage attrition is needed. This thesis focuses on the development of a supported iron catalyst and kinetic models of FTS on the catalyst using advanced statistical methods for experimental design and analysis. A high surface area alumina, modified by the addition of approximately 2 wt% lanthanum, was impregnated with approximately 20 wt% Fe and 1% Pt in a two step procedure. Approximately 10 wt% Fe and 0.5 wt% Pt was added in each step. The catalyst had a CO uptake of 702 μmol/g, extent of reduction of 69%, and was reduced at 450°C. The catalyst was stable over H2 partial pressures of 4-10 atm, CO partial pressures of 1-4 atm, and temperatures of 220-260°C. Weisz modulus values were less than 0.15. A Langmuir-Hinshelwood type rate expression, derived from a proposed FTS mechanism, was used with D-optimal criterion to develop experiments sequentially at 220°C and 239°C. Joint likelihood confidence regions for the rate expression parameters with respect to run number indicate rapid convergence to precise-parameter estimates. Difficulty controlling the process at the designed conditions and steep gradients around the D-optimal criterion resulted in consecutive runs having the same optimal condition. In these situations another process condition was chosen to avoid consecutive replication of the same process condition. A kinetic model which incorporated temperature effects was also regressed. Likelihood and bootstrap confidence intervals suggested that the model parameters were precise. Histograms and skewness statistics calculated from Bootstrap resampling show parameter-effect nonlinearities were small.

股票市場的報酬率相對於金融市埸是非常重要的，因為其背後的真實機率分配對各種資產定價及選擇權的評價模型都有決定性的影響。本文考慮台灣股票市埸具有漲跌停板的限制來驗證實證中股票報酬機率分配的「厚尾」的現象，希望透過我們的研究能對財務理論在國內金融市埸的應用有更進一步的了解。我們選定了常態分配、對數常態分配及一般化第二種貝它分配 (GB2)來當作是台灣股票報酬率的真實機率分配，以動差法比較再以概似比檢定法(LR test)選出一表現最好的機率分配。由選取的25支國內股票中發現一般化第二種貝它分配 (GB2)可以解釋偏態和峰態對報酬率的影響並且也是概似比檢定法所選出的最適報酬率分配，由此可知一般化第二種貝它分配 (GB2)較為適合作為台灣股票報酬的真實機率分配。