In this thesis, exergy based SI engine model optimisation (EBSIEMO) is studied and evaluated. A four-stroke bi-fuel spark ignition (SI) engine is modelled for optimisation of engine performance based upon exergy analysis. An artificial neural network (ANN) is used as an emulator to speed up the optimisation processes. Constrained particle swarm optimisation (CPSO) is employed to identify parameters such as equivalence ratio and ignition time for optimising of the engine performance, based upon maximising 'total availability'. In the optimisation process, the engine exhaust gases standard emission were applied including brake specific CO (BSCO) and brake specific NOx (BSNOx) as the constraints. The engine model is developed in a two-zone model, while considering the chemical synthesis of fuel, including 10 chemical species. A computer code is developed in MATLAB software to solve the equations for the prediction of temperature and pressure of the mixture in each stage (compression stroke, combustion process and expansion stroke). In addition, Intake and exhaust processes are calculated using an approximation method. This model has the ability to simulate turbulent combustion and compared to computational fluid dynamic (CFD) models it is computationally faster and efficient. The selective outputs are cylinder temperature and pressure, heat transfer, brake work, brake thermal and volumetric efficiency, brake torque, brake power (BP), brake specific fuel consumption (BSFC), brake mean effective pressure (BMEP), concentration of CO2, brake specific CO (BSCO) and brake specific NOx (BSNOx). In this model, the effect of engine speed, equivalence ratio and ignition time on performance parameters using gasoline and CNG fuels are analysed. In addition, the model is validated by experimental data using the results obtained from bi-fuel engine tests. Therefore, this engine model was capable to predict, analyse and useful for optimisation of the engine performance parameters. The exergy based four-stroke bi-fuel (CNG and gasoline) spark ignition (SI) engine model (EBSIEM) here is used for analysis of bi-fuel SI engines. Since, the first law of thermodynamic (the FLT), alone is not able to afford an appropriate comprehension into engine operations. Therefore, this thesis concentrates on the SI engine operation investigation using the developed engine model by the second law of thermodynamic (the SLT) or exergy analysis outlook (exergy based SI engine model (EBSIEM)) In this thesis, an efficient approach is presented for the prediction of total availability, brake specific CO (BSCO), brake specific NOx (BSNOx) and brake torque for bi-fuel engine (CNG and gasoline) using an artificial neural network (ANN) model based on exergy based SI engine (EBSIEM) (ANN-EBSIEM) as an emulator to speed up the optimisation processes. In the other words, the use of a well trained an ANN is ordinarily much faster than mathematical models or conventional simulation programs for prediction. The constrained particle swarm optimisation (CPSO)-EBSIEM (EBSIEMO) was capable of optimising the model parameters for the engine performance. The optimisation results based upon availability analysis (the SLT) due to analysing availability terms, specifically availability destruction (that measured engine irreversibilties) are more regarded with higher priority compared to the FLT analysis. In this thesis, exergy based SI engine model optimisation (EBSIEMO) is studied and evaluated. A four-stroke bi-fuel spark ignition (SI) engine is modelled for optimisation of engine performance based upon exergy analysis. An artificial neural network (ANN) is used as an emulator to speed up the optimisation processes. Constrained particle swarm optimisation (CPSO) is employed to identify parameters such as equivalence ratio and ignition time for optimising of the engine performance, based upon maximising 'total availability'. In the optimisation process, the engine exhaust gases standard emission were applied including brake specific CO (BSCO) and brake specific NOx (BSNOx) as the constraints. The engine model is developed in a two-zone model, while considering the chemical synthesis of fuel, including 10 chemical species. A computer code is developed in MATLAB software to solve the equations for the prediction of temperature and pressure of the mixture in each stage (compression stroke, combustion process and expansion stroke). In addition, Intake and exhaust processes are calculated using an approximation method. This model has the ability to simulate turbulent combustion and compared to computational fluid dynamic (CFD) models it is computationally faster and efficient. The selective outputs are cylinder temperature and pressure, heat transfer, brake work, brake thermal and volumetric efficiency, brake torque, brake power (BP), brake specific fuel consumption (BSFC), brake mean effective pressure (BMEP), concentration of CO2, brake specific CO (BSCO) and brake specific NOx (BSNOx). In this model, the effect of engine speed, equivalence ratio and ignition time on performance parameters using gasoline and CNG fuels are analysed. In addition, the model is validated by experimental data using the results obtained from bi-fuel engine tests. Therefore, this engine model was capable to predict, analyse and useful for optimisation of the engine performance parameters. The exergy based four-stroke bi-fuel (CNG and gasoline) spark ignition (SI) engine model (EBSIEM) here is used for analysis of bi-fuel SI engines. Since, the first law of thermodynamic (the FLT), alone is not able to afford an appropriate comprehension into engine operations. Therefore, this thesis concentrates on the SI engine operation investigation using the developed engine model by the second law of thermodynamic (the SLT) or exergy analysis outlook (exergy based SI engine model (EBSIEM)) In this thesis, an efficient approach is presented for the prediction of total availability, brake specific CO (BSCO), brake specific NOx (BSNOx) and brake torque for bi-fuel engine (CNG and gasoline) using an artificial neural network (ANN) model based on exergy based SI engine (EBSIEM) (ANN-EBSIEM) as an emulator to speed up the optimisation processes. In the other words, the use of a well trained an ANN is ordinarily much faster than mathematical models or conventional simulation programs for prediction. The constrained particle swarm optimisation (CPSO)-EBSIEM (EBSIEMO) was capable of optimising the model parameters for the engine performance. The optimisation results based upon availability analysis (the SLT) due to analysing availability terms, specifically availability destruction (that measured engine irreversibilties) are more regarded with higher priority compared to the FLT analysis.

La réduction des émissions de polluants et la diminution de la consommation sont deux challenges fortement liés auxquels les constructeurs automobiles doivent faire face tout en maintenant les performances des moteurs. Les nouvelles stratégies telle que la réduction de la cylindrée associée à une optimisation de la boucle d'air (forte suralimentation et recirculation de gaz brûlés) possèdent ce potentiel. Cependant elles affectent la stabilité du moteur en favorisant les variations cycle à cycle (VCC) qui correspondent à une fluctuation de la combustion d'un cycle sur l'autre. L'objectif de cette thèse est de développer une méthodologie s'appuyant sur la Simulation aux Grandes Echelles (SGE) capable de prédire les VCC d'un moteur à allumage commandé. Les prédictions sont validées grâce à une base de données expérimentale conçue à l'IFP qui leur est dédiée. Une approche graduelle est employée : l'outil numérique est tout d'abord évalué sur une configuration simplifiée de moteur à piston sans combustion, puis appliqué à un moteur à allumage commandé entraîné pour valider la prédiction de l'aérodynamique interne. Sur cette dernière configuration le couplage avec le modèle de combustion DTFLES est rajouté pour simuler deux points de fonctionnement réactifs. Chacune de ces simulations intègre un ou plusieurs points de modélisation (les tétraèdres en maillage mobile, les modèles de choc et d'allumage, et la cinétique chimique) au préalable testés sur des configurations académiques. Ce travail de recherche montre que l'approche SGE, dans un contexte de calcul massivement parallèle, est un outil prometteur dans l'étude des VCC d'un moteur à allumage commandé de conception récente. / A major challenge for the development of internal combustion engines is to improve fuel economy and to reduce pollutant emissions while maintaining or enhancing engine performances. New strategies using downsizing with high levels of exhaust gas recirculation have this potential, but can impact on the combustion stability and trigger high cycle-to-cycle variations (CCV). The objective of this thesis is to set a methodology based on Large Eddy Simulation (LES) to study CCV of a Spark-Ignition (SI) engine. A gradual approach is used : the numerical tool is first evaluated on a motored axisymmetric piston-cylinder assembly, and then applied on a motored SI engine to validate the in-cylinder aerodynamic predictions. On this last configuration, the coupling with the turbulent combustion model DTFLES is added to simulate two operating points of the indirect injection engine mode. Each of these simulations takes into account one or several modeling key points (tetrahedra with moving mesh, the modelings of shock and ignition, and chemical kinetics) previously tested in academic configurations. This research work shows that LES approach, in the context of massively parallel computing, can be used to study the CCV of a realistic SI engine.

在科技持續進步的時代，金融市場發展隨著社會的演進不斷地成長與活絡，金融商品也從原本單純的本國存放款、外幣投資衍生出票券、債券等利率投資工具；除此之外，隨著資本市場的擴張，股票、基金、期貨與選擇權等投資標的更是琳瑯滿目。 而後產生了許多人使用資料探勘工具預測市場的買賣時機。如Baba N., Asakawa H. and Sato K.(1999)使用倒傳遞類神經網路來預測到股市未來的漲跌，而後又在2000年研究當中加入基因演算法來求得倒傳遞類神經網路的權重，得到最後的類神經網路模型。 在做資料探勘的同時，我們得在希望預測目標(Target)上事先定義好一套固定規則，這會使得模型的彈性與可預測度降低，本研究希望能透過資料探勘工具增加預測目標規則的彈性，增加模型最後的預測準確度。 本研究樣本區間選用2010年到2015年的台指期貨數據做為資料，並結合羅吉斯回歸與粒子群演算法建構更加有彈性的預測模型結果，最後發現在未來10分鐘，若漲幅超過0.1114%做為買進訊號的話，其建立出的模型可達到84%的預測準確度。

L'allumage et le réallumage de haute altitude présentent de grandes difficultés dans le cadre des chambres de combustion aéronautiques. Le succès d'un allumage dépend de multiples facteurs, des caractéristiques de l'allumeur à la taille des gouttes du spray en passant par le niveau de turbulence au point d'allumage. Déterminer la position optimale de l'allumeur ou le potentiel d'allumage d'une source d'énergie donnée à une position donnée sont ainsi des paramètres essentiels lors du design de chambre de combustion. Le but de ces travaux de thèse est d'étudier l'allumage forcé des chambres de combustion aéronautiques. Pour cela, des Simulation numériques aux Grandes Echelles (SGE) d'écoulements diphasiques réactifs sont utilisées et analysées. Afin de les valider, des données expérimentales issues du banc MERCATO installé à l'ONERA Fauga-Mauzac sont utilisées. Cela permet dans un premier temps de valider la méthodologie ainsi que les modèles utilisés pour les SGE diphasiques évaporantes avant leur utilisation dans d'autres conditions d'écoulement. Le cas diphasique réactif statistiquement stationnaire est ensuite comparé aux données disponibles pour évaluer les modèles en condition réactives. Ce cas est étudié plus en détail à travers l'analyse de caractéristiques de la flamme. Celle-ci semble être le théâtre de régimes de combustion très différents. On note aussi que la détermination de la méthode numérique la plus appropriée pour le calcul d'écoulements diphasiques n'est pas évidente. De plus, deux méthodes numériques différentes peuvent donner des résultats en bon accord avec l'expérience et pourtant avoir des modes de combustion différents. Les capacités de la SGE à correctement calculer un écoulement diphasique réactif étant validé, des SGE du phénomène transitoire d'allumage sont effectuées. La sensibilité observée expérimentalement de l'allumage aux conditions initiales, i.e. à l'instant de claquage, est retrouvé par les SGE. L'analyse met en évidence le rôle prépondérant de la dispersion du spray dans le développement initial du noyau de flamme. L'utilisation des SGE pour calculer les séquences d'allumage fournie de nombreuses informations sur le phénomène d'allumage, cependant d'un point de vue industriel, cela ne donne pas de résultat optimal, à moins de ne tester toutes les positions, ce qui rendrait le coût CPU déraisonnable. Des alternatives sont donc nécessaires et font l'objet de la dernière partie de ces travaux. On propose de dériver un critère local d'allumage, donnant la probabilité d'allumage à partir d'un écoulement diphasique (air et carburant) non réactif instationnaire. Ce modèle est basé sur des critères liés aux différentes phases menant à un allumage réussi, de la formation d'un premier noyau à la propagation de la flamme vers l'injecteur. Enfin, des comparaisons avec des données expérimentales sur des chambres aéronautiques sont présentées et sont en bon accord, indiquant que le critère d'allumage proposé, couplé avec une SGE d'écoulement diphasique non réactif, peut être utilisé pour optimiser la puissance et la position du système d'allumage. / Ignition and altitude reignition are critical issues for aeronautical combustion chambers. The success of ignition depends on multiple factors, from the characteristics of the igniter to the spray droplet size or the level of turbulence at the ignition site. Finding the optimal location of the igniter or the potential of ignition success of a given energy source at a given location are therefore parameters of primary importance in the design of combustion chambers. The purpose of this thesis is to study forced ignition of aeronautical combustion chambers. To do so, Large Eddy Simulations (LES) of two-phase reacting flows are performed and analyzed. First, the equations of the Eulerian formalism used to describe the dispersed phase are presented. To validate the successive LES, experimental data from the MERCATO bench installed at ONERA Fauga-Mauzac are used. It allows to validate the two-phase evaporating flow LES methodology and models prior to its use to other flow conditions. The statistically stationary two-phase flow reacting case is then compared to available data to evaluate the model in reacting conditions. This case is more deeply studied through the analysis of the characteristics of the flame. This last one appears to experience very different combustion regimes. It is also seen that the determination of the most appropriate methodology to compute two-phase flow flame is not obvious. Furthermore, two different methodologies may both agree with the data and still have different burning modes. The ability of the LES to correctly compute burning two-phase flow being validated, LES of the transient ignition phenomena are performed. The experimentally observed sensitivity of ignition to initial conditions, i.e. to sparking time, is recovered with LES. The analysis highlights the major role played by the spray dispersion in the development of the initial flame kernel. The use of LES to compute ignition sequences provides a lot of information about the ignition phenomena, however from an industrial point of view, it does not give an optimal result, unless all locations are tested, which brings the CPU cost to unreasonable values. Alternatives are hence needed and are the objective of the last part of this work. It is proposed to derive a local ignition criterion, giving the probability of ignition from the knowledge of the unsteady non-reacting two-phase (air and fuel) flow. This model is based on criteria for the phases of a successful ignition process, from the first kernel formation to the flame propagation towards the injector. Then, comparisons with experimental data on aeronautical chambers are done and show good agreement, indicating that the proposed ignition criterion, coupled to a Large Eddy Simulation of the stationary evaporating two-phase non-reacting flow, can be used to optimize the igniter location and power.

L'amélioration des moteurs à allumage commandé représente un défi de première importance pour les ingénieurs afin de produire plus d'énergie, de consommer moins de matière première et de réduire les émissions polluantes. Les nouvelles technologies apparues ces dernières années amènent les moteurs de plus en plus proches de leurs limites de fonctionnement, favorisant ainsi des phénomènes néfastes qui doivent être contrôlés. Parmi ces phénomènes, les variations cycle-à-cycle (VCC) doivent être minimisées pour garder une performance optimale et éviter une dégradation rapide du moteur. La Simulation aux Grandes Echelles (SGE) est un outil prometteur afin de prédire numériquement les niveaux de variabilités obtenues lors du design d'un moteur (limitant ainsi les coûteuses campagnes de mesures expérimentales). Ce manuscrit s'est attaché à développer une méthodologie numérique pour la prédiction des variabilités cycliques, à simuler un nombre suffisant de cycles pour pouvoir estimer les niveaux de VCC et à valider les résultats obtenus par rapport aux résultats expérimentaux. La SGE semble capter les points de fonctionnements stable et instable étudiés. Les sources qui provoquent ces VCC ont aussi été analysées et une modification du fonctionnement du moteur a été proposée afin de réduire les VCC. / The improvement of the spark ignition engines is a major challenge for engineers in order to produce more energy, to minimize fuel consumption and to reduce the pollutant emissions. The new technologies which appear in the last years bring the engines closer to their stability limit while increasing various unwanted phenomena. Among these phenomena, cycle-to-cycle variation (CCV) need to be minimized in order to keep the performances as high as possible and avoid damages on the engines. Large Eddy Simulation (LES), which is a very promising tool in order to predict the level of CCV of a given engine, has been used in the present document to simulate a mono-cylinder spark ignition engine. The present document presented a numerical methodology for the prediction of CCV, numerous engine cycles were simulated by LES in order to validate the results in comparison to the experimental findings. The LES seems to be able to capture stable and instable (in terms of CCV) operating points of the engine. In addition, the sources of CCV were also analyzed and a modification of the engine has been proposed to reduce CCV.

Sintering is an important processing step for obtaining the necessary mechanical stability and rigidity of ceramic bulk materials. Both mass and heat transfer are essential in the sintering process. The importance of radiation heat transfer is significantly enhanced at high temperatures according to the well-known Stefan-Boltzmann’s law. In this thesis, we modified the pressure-less spark plasma sintering set-up to generate intense thermal radiation, aiming at rapid consolidation of ceramic bulk materials. This approach was named as “Sintering by Intense Thermal Radiation (SITR)” as only thermal radiation contributed. Firstly, the heat and mass transfer mechanisms during the SITR process were studied by choosing zirconia ceramics as references. The results revealed that the multiple scattering and absorption of radiation by the materials contributed to the heat diffusion. The observed enhanced densification and grain growth can be explained by a multiple ordered coalescence of zirconia nanocrystals using high heating rates. Secondly, the temperature distribution during the SITR process was investigated by both numerical simulation and experimental verifications. It showed that the radiator geometry, sample geometry and radiating area were influencing factors. Besides, the change of material and geometry of the radiators resulted in an asymmetric temperature distribution that favored the formation of SiC foams. The foams had gradient structures with different open porosity levels and pore sizes and size distributions. Finally, ceramic bulk materials were successfully fabricated by the SITR method within minutes. These materials included dense and strong ZrO2 ceramics, Si3N4 foams decorated with one-dimensional nanostructures, and nasal cavity-like SiC-Si3N4 foams with hierarchical heterogeneities. Sufficient densification or formed strong necks were used for tailoring these unique microstructures. The SITR approach is well applicable for fast manufacture of ceramic bulk materials because it is clean and requires low energy consumption and properties can be controlled and tuned by selective heating, heating speed or temperature distribution. / <p>At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 3: Submitted. Paper 4: Manuscript.</p><p> </p>

O etanol (álcool etílico) tem sido cada vez mais estudado e testado como combustível alternativo para substituição do uso de alguns derivados de petróleo em motores de combustão interna. O presente trabalho procura abordar o emprego do etanol na forma vaporizada em motores do ciclo Otto, objetivando a obtenção de melhores níveis de rendimento térmico total. Deste modo, um motor para teste de octanagem (motor CFR) foi equipado com um vaporizador de álcool instalado no coletor de escapamento, e após uma série de ensaios, várias análises puderam ser feitas. Essas considerações procuraram se ater a aspectos como rendimento térmico, relação ar/combustível, ângulo de avanço da centelha, temperatura de escape, assim como potência e eficiência volumétrica, levando em conta, sempre, a sua influência no funcionamento geral do motor. Ficou constatado que o motor movido a etanol vaporizado apresenta rendimento consideravelmente maior, menor consumo de combustível e funcionamento mais suave que aqueles verificados quando o mesmo motor e alimentado com álcool líquido. / The ethanol (ethyl alcohol) has been studied more and more as alternative fuel to replace some petroleum derivatives for internal combustion engines. The attached study examines the application of vaporized ethanol for Otto cycle engines, searching for better levels of total thermal efficiency. Therefore, an engine for test of octane number (CFR motor) was equipped with an alcohol vaporizer installed inside the escape pipe, and after many experiences, several analysis were made. The various analysis included aspects as thermal efficiency, air/fuel ratio, advance ignition, escape temperature, power and volumetric efficiency, always considering their influence on the operation of the engine. It was confirmed that the engine moved by vaporized ethanol presents higher thermal efficiency, smaller fuel consumption and smoother working than in case of alimentation by liquid alcohol.

O álcool etílico ou etanol vem se tornando, neste novo século, uma importante referência para estudos e aplicações que procuram um combustível alternativo ao uso de derivados de petróleo em motores de combustão interna. Neste trabalho, o uso do etanol vaporizado pelos gases de escape em motores do ciclo Otto busca a obtenção de melhores níveis de rendimento térmico e emissões de poluentes. Assim sendo, um motor de 1.0 litro foi montado em laboratório com um trocador de calor instalado ao lado do coletor de escapamento, e uma série de testes foram feitos, possibilitando uma cuidadosa análise quanto a rendimento térmico, relação ar/álcool, ângulo de avanço da centelha, temperatura de escape e gases de emissão, entre outros aspectos. Conclui-se que o motor a álcool vaporizado, em certos regimes de funcionamento, apresenta rendimento maior e emissões menores que aqueles verificados no motor a álcool líquido. / The ethyl alcohol or ethanol is becoming, in this new century, an important reference for studies and applications that search for an alternative fuel to be used in internal combustion engines, replacing oil derivatives. In this study, an Otto cycle engine is fueled with ethanol vaporized by the exhaust gases, aiming for better levels of thermal efficiency and exhaust emissions. Therefore, a 1.0 liter engine with a heat exchanger connected to the exhaust manifold was prepared in a test bench, and several tests were made, which allowed a criterious analysis about air/alcohol ratio, spark ignition time, exhaust temperature and exhaust emissions, and others. It was concluded that the engine fueled with vaporized alcohol presents, in some operation points, higher thermal efficiency and less emissions compared to the case of engine fueled with liquid alcohol.

This thesis explores the figure of the trickster in the works of Elizabeth Bowen, Elizabeth Taylor, Iris Murdoch and Muriel Spark. By looking at these writers’ treatment of elusive, illusive and allusive characters, the thesis argues that they each incorporated what can be read as “trickster” figures in their fiction as a means of addressing anxieties about art, society and the self. The trickster is a character-type found in narratives from a multitude of cultures and eras, and is typically characterised by his subversive presence, his boundary-crossing and his role as a healer of predicament. While the trickster is often perceived as a universal phenomenon arising from a collective unconscious, this thesis instead focusses on writers’ intentional inclusion of trickster characters in literature as a way of thinking through specific problems. Bowen, it will be shown, interpolated tricksy characters drawn from myth and fairy-tale into her fiction in order to expose a perceived rift between art and academia; Taylor used the trickster to think about the construction of identity in post-war Britain; Murdoch took models from Shakespeare to create tricksters that helped her explore the ethics of writing fiction; and Spark’s tricksters allowed her to conceptualise truth and lies, and good and evil. Concentrating on four mid-century writers whose works have been seen to vary in genre and style, this thesis demonstrates that a trickster paradigm emerged in mid-twentieth-century British fiction – a period not previously associated with the trickster. Influenced by converging strands of trickery and allusion in art through the early decades of the twentieth century, notable mid-century British writers used outsider characters to probe social and artistic shifts in a landscape fractured by war and to reach for a sense of healing. By identifying such characters as trickster figures, this thesis sheds new light on patterns of subversion, healing and character in mid-century fiction. It explores the particular affinity the trickster had with women’s writing, and illustrates how the trickster was important to twentieth-century concerns surrounding metafiction and the role of the reader.

A obtenção da sílica vítrea pelo processo de sinterização por plasma pulsado (SPS), a partir de matérias-primas de diferentes estruturas (cristalina e amorfa) e diferentes granulometrias, foi investigada. Análises de difração de raios X, transmitância óptica, microscopia óptica e eletrônica de varredura, e medições de densidade foram realizadas nas amostras sinterizadas. Sílicas vítreas transparentes foram fabricadas a partir de pós de quartzo atingindo-se temperaturas finais entre 1450 e 1600°C, enquanto que nanopó e pó amorfo de sílica formaram consolidados transparentes com temperaturas máximas próximas de 1200° C. Taxas de aquecimento entre 40 e 150°C/min. foram utilizadas nas sinterizações, com tempos de processo menores que 40 minutos. As maiores taxas de aquecimento exigiram uma maior temperatura final para a fusão completa do material cristalino e causaram, de forma indireta, a presença de aglomerações de micro-bolhas nas amostras obtidas com o nanopó. Um gradiente radial de temperatura (decrescente do centro para as bordas) foi observado nos consolidados fabricados com os pós cristalinos, facilitando o processo de fechamento da porosidade aberta. A presença ou ausência de material não fundido e de bolhas nas amostras foram analisadas por difratogramas de raios X, microscopia óptica e medidas de densidade. A análise da transmitância indicou uma quantidade praticamente nula de grupos OH nos compactos sinterizados com os pós cristalinos e em torno de 20 ppm no caso dos sólidos fabricados com matéria-prima sol-gel. Amostras de nanopós de sílica dopada com titânia (~6% em massa) foram processadas com temperaturas finais de 1200 e 1400°C apresentando coloração azulada e negra, respectivamente, e aumento dos clusters de titânia para a temperatura mais elevada. A sinterização a uma temperatura em torno 1200°C mantida por apenas 4 minutos resultou na conversão completa da fase anatase para a fase rutilo da titânia. / The production of vitreous silica by the spark plasma sintering (SPS) process, starting from raw materials of different structures (crystalline and amorphous) and granulometry were investigated. Analysis of X-ray diffraction, optical transmittance, optical and scanning electron microscopy, and density measurements were performed on the sintered compacts. Transparent vitreous silica was fabricated from quartz powder at final temperatures ranging from 1450 and 1600°C while silica nanopowder and silica powder formed transparent compacts at temperatures around 1200°C. Heating rates between 40 and 150° C/min. were used in processes with durations smaller than 40 minutes. Higher heating rates demanded higher final temperatures to complete the fusion process and caused, indirectly, the formation of micro-bubbles agglomerations in the samples produced from the nanopowder. A radial gradient of temperature (decreasing from the center to the border) was observed at the compacts fabricated with the crystalline powders favoring the closure of the open porosity. The presence or the absence of non-fused material and bubbles in the samples was analyzed by X-ray diffraction, optical microscopy and density measurements. The transmittance analysis indicated an almost zero quantity of OH groups in the compacts sintered from crystalline powders and about 20 ppm in the solids fabricated from the sol-gel raw material. Nanopowder samples of silica titania (~6 wt % of titania) were processed with final temperatures of 1200°C and 1400°C presenting blue and black coloration, respectively, and an increase of the titania clusters for the highest temperature. The sintering at temperatures near 1200°C with a holding time of just 4 minutes caused the complete anatase-rutile conversion in titania.