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With the ongoing COVID-19 pandemic being spread all over the world, lockdown measures are being implemented making air pollution levels go down in several countries. In this context, the air quality changes in the highly populated and trafficked Brazilian states of Sao Paulo (SP) and Rio de Janeiro (RJ) are hereby going to be addressed using a combination of satellite and ground-based data analysis. We explored nitrogen dioxide (NO2) and particulate matter (PM2.5) daily levels for the month of May during different years within 2015-2020. Daily measurements of NO2 column concentrations from the Ozone Monitoring Instrument (OMI) aboard NASA's Aura satellite were also gathered and averaged decreases of 42% and 49.6% were found for the year of 2020 compared to previous averaged 2015-2019 years. In parallel to the NO2 column retrieval, the ground-based data, measured by the Brazilian States Environmental Institutions, is analyzed, and correlated with satellite retrievals. Correlation coefficients between column and ground-based concentrations were 77% and 53% in SP and RJ, respectively. It was found a 13.3% (p-value = 0.099) and 18.8% (p-value = 0.077) decrease in NO2 levels for SP and RJ, respectively, in 2020 compared to 2019. For PM2.5, no significant change was observed for the same time period in the SP region, although the high number of fire burnings in the Southeast region seemed to be affecting PM2.5 levels. In addition to natural emissions (fire burnings), the combined data was also evaluated taking meteorological parameters, such as temperature and wind speed, into account. No interference of weather or fire was found in 2020 NO2 ground levels compared to previous years, This integrated analysis is innovative and has yet to be more explored in Brazilian studies. This is true specifically because the ground-based stations are spatially and temporally sparse in Brazil. / Master of Science / This study aims to explore satellite data applied to the lockdown context resultant from the COVID-19 pandemic in Brazil. Satellite data usage in air quality management is yet to be explored to its full potential. Two highly populated states were chosen: Sao Paulo (SP) and Rio de Janeiro (RJ). Local governments have been imposing limitations on private and public vehicle circulation, inducing a decrease in atmospheric pollutant levels, specifically nitrogen dioxide (NO2), which is directly emitted to the air by fuel combustion. NO2 is also short-lived in the atmosphere, so its variation within days can be easily captured. PM2.5, a category of fine inhalable particles, can be produced by wildfires, in addition to fuel burning and mechanical processes such as resuspension by cars. Here we retrieved daily NO2 vertical column densities for the month of May within the 2015-2020 years from the OMI instrument onboard of NASA's Aura satellite. Ground daily NO2 and PM2.5 measurements were also collected from local environmental agencies. Results showed an average 42% decrease of the NO2 column values in SP in 2020 compared to 2015-2019. The decrease was 49.6% in RJ for the same timeframe. Correspondent surface data showed a decrease of 13.3% (p-value = 0.099) and 18.8% (p-value = 0.077) during 2020 compared to 2019 in SP and RJ stations, respectively. No significant divergence in PM2.5 values was found between 2019 and 2020. Finally, weather data was added to the pollutant analysis. PM2.5 concentrations were associated with wildfires, while the NO2 levels found in 2020 for SP and RJ were attributed to local lockdown decrees. Satellite retrievals showed significant potential in filling out ground datasets, correlating with the SP and RJ surface data in 77% and 53%, respectively.

A new German research consortium is investigating the causes and effects of the rapid rise of near-surface air temperatures in the Artic. Within the last 25 years a remarkable increase of the Arctic near-surface air temperature exceeding the global warming by a factor of two to three has been observed. The phenomenon is commonly referred to as Arctic Amplification. The warming results in rather drastic changes of a variety of climate parameters. For example, the Arctic sea ice has declined significantly. This ice retreat has been well identified by satellite measurements. However, coupled regional and global climate models still fail to reproduce it adequately; they tend to systematically underestimate the observed sea ice decline. This model observation difference implies that the underlying physical processes and feedback mechanisms are not appropriately represented in Arctic climate models. Thus, the predictions of these models are also likely to be inadequate. It is mandatory to identify the origin of this disagreement. / Ein neu geschaffenes deutsches Forschungskonsortium untersucht die Ursachen und Effekte des rapiden Anstiegs der bodennahen Lufttemperatur in der Arktis. Innerhalb der letzten 25 Jahre wurde ein bemerkenswerter Anstieg der Bodenlufttemperatur in der Arktis beobachtet, welcher die globale Erwärmung um den Faktor 2 bis 3 übersteigt. Dieses Phänomen wird als arktische Verstärkung bezeichnet. Diese Erwärmung resultiert vielmehr in einer drastischen Änderung einer Vielzahl von Klimarparametern. Beispielsweise ist das arktische Meereis deutlich zurückgegangen. Dieser Eisrückgang wurde durch Satellitenbeobachtungen gut beobachtet. Dagegen haben regionale und globale Klimamodelle immer noch Probleme, den Rückgang entsprechend zu reproduzieren. Sie tendieren dazu, den Meereisrückgang systematisch zu unterschätzen. Die Unterschiede zwischen Modell und Beobachtungen legen nahe, dass die grundlegenden physikalischen Prozesse und Rückkopplungsmechanismen nicht entsprechend in arktischen Klimamodellen repräsentiert werden. Somit sind wahrscheinlich auch die Vorhersagen der Modelle unzureichend. Es ist notwendig, den Ursprung dieser Unstimmigkeit zu identifizieren.

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Beryllium-7 is a cosmogenic radionuclide produced in the atmosphere through the spallation of nitrogen and oxygen nuclei by cosmic-ray-produced neutrons and protons. It is carried in the atmosphere attached to aerosols and is deposited on land and ocean surfaces by wet and dry deposition processes. Beryllium-7 decays by electron capture to lithium-7 and has a half-life of approximately 53 days. It is a potentially useful radionuclide for studying different natural processes. This thesis presents a collection of scientific papers on the occurrence of beryllium-7 in the natural environment, particularly in the Southeast Queensland region of Australia. It shows the results of experimental measurements and discusses their implications. Overall, this thesis contributes to advancing our understanding of the distribution and behaviour of beryllium-7 in the natural environment and provides a foundation for the development of nuclear techniques for the evaluation of environmental problems.

<p>The study of Surface Air Cooled Oil Coolers (SACOC) is motivated by the need for new cooling concepts for compact machinery designs with high thermal load. Installing finned heat exchangers in the bypass duct of a turbofan engine provides an additional cooling source having transonic flow as a heat sink. The characterization of the heat transfer and the aerodynamics of the design are essential to minimize the impact on the overall efficiency of the engine. In the present study, the SACOC is studied numerically and experimentally. Two geometries are tested in a high-speed linear wind tunnel where measurements are taken with multiple sensors and optical techniques. For the heat transfer characterization, an Inverse Heat Conduction Methodology (IHCM) based on a Levenberg-Marquardt Algorithm is developed. The experimental results are matched to numerical simulations using a Reynolds Averaged Navier-Stokes (RANS) solver. Finally, a multi-objective optimization algorithm is coupled <a>with the RANS solver</a> to explore new geometries that maximize the heat transfer and minimize the pressure drop across the studied domain. The 400 profiles generated allow for the identification of the features that have a higher influence on the performance of the fins and six profiles that present large improvements are chosen for further analysis.</p>

Title: Links between atmospheric circulation and surface air temperature distributions in climate models Abstract: This thesis comprises a collection of five papers dealing with validation of regional climate model (RCM) simulations over Central Europe. The first paper illustrates and discusses problems with observed data that are used for model validation and how the choice of reference dataset affects the outcomes in validating the RCMs' performances. The second paper evaluates daily temperatures, and it indicates that some temperature biases may be related to deficiencies in the simulations of large- scale atmospheric circulation. RCMs' ability to simulate atmospheric circulation and the observed links between circulation and surface air temperatures are examined in detail in the third paper. This article also compares performances of individual RCMs with respect to the driving data by analysing the results for the driving data themselves. The fourth paper focuses on biases in the diurnal temperature range within RCMs and their possible causes by examining links of the errors to the at- mospheric circulation and cloud amount. The last paper investigates the observed relationships between atmospheric circulation and daily precipitation amounts over three regions in the Czech Republic, as well as how these...

Abstract This thesis studies the long-term relation between the solar wind driven energetic particle forcing into the atmosphere and the tropospheric circulation in the Northern Hemisphere winter. The work covers the period of more than one hundred years since the turn of the 20th century to present. The thesis makes a statistical analysis of satellite measurements of precipitating energetic electrons, sunspot number data and geomagnetic activity, and compares them with temperature and pressure measurements made at the Earth's surface. Recent results, both observational and from chemistry climate models, have indicated significant effects in the Earth's middle atmosphere due to the energetic electrons precipitating from the magnetosphere. These effects include the formation of reactive hydrogen and nitrogen oxides in the high latitude mesosphere and the depletion of ozone caused by them. Ozone is a radiatively active and important gas, which affects the thermal structure and dynamics of the middle atmosphere. Accordingly, the depletion of ozone can intensify the large scale stratospheric circulation pattern called the polar vortex. Winter weather conditions on the surface have been shown to be dependent on the polar vortex strength. This thesis shows that there is a significant relation between the average fluxes of medium energy (ten to hundred keVs) precipitating electrons and surface temperatures in parts of the Northern Hemisphere in winter time. Temperatures are positively correlated with electron fluxes in North Eurasia and negatively correlated in Greenland during the period 1980-2010 which is covered by direct satellite observations of precipitating particles. This difference is especially notable when major sudden stratospheric warmings and the quasi-biennial oscillation (QBO), which both are known to affect the polar vortex strength, are taken into account. When extended to the late 19th century, the analysis shows that a similar temperature pattern is predominated during the declining phase of the sunspot cycle. The high speed solar wind streams and energetic particle precipitation typically maximize also at the declining phase of the solar cycle. This specific temperature pattern is related to the variability of the northern annular mode (NAM), which is the most significant circulation pattern in the Northern Hemisphere winter. Before the space era, geomagnetic activity measured by ground observations can be used as a proxy for energetic particle precipitation. Earlier studies have found a significant positive correlation between geomagnetic activity and NAM since the 1960s. We find that, when the QBO measured at 30 hPa height is in the easterly phase, a positive correlation is extended to the beginning of 1900s. We also show that high geomagnetic activity causes a stronger effect in the Northern Hemisphere winter than high sunspot activity, especially in the Atlantic and Eurasia. A comprehensive knowledge of the Earth's climate system and all its drivers is crucial for the future projection of climate. Solar variability effects have been estimated to produce only a small factor to the global climate change. However, there is increasing evidence, including the results presented in this thesis, that the different forms of solar variability can have a substantial effect to regional and seasonal climate variability. With this new evidence, the solar wind related particle effects in the atmosphere are now gaining increasing attention. These effects will soon be included in the next coupled model inter comparison project (CMIP6) as an additional solar related climate effect. This emphasizes the relevance of this thesis.

[ES] En un presente marcado por la continua lucha contra la contaminación y el cambio climático, la investigación en mejoras tecnológicas que permitan una transición aceptable para la sociedad hacia un futuro más ecológico ocupa un papel fundamental. En concreto, la aviación es un foco constante de innovación, ya que es considerada una función indispensable en una sociedad tan globalizada como la actual, pero con unos niveles de contaminación preocupantes. En este aspecto, el desarrollo de motores con altas eficiencias es un paso clave para la transición medioambiental. Sin embargo, estas alternativas presentan un reto tecnológico en cuanto a su gestión térmica basado, principalmente, en la necesidad de aumentar la refrigeración. En este contexto e impulsada por el proyecto "Aerodynamic upgrade of Surface Air Cooled Oil Cooler (SACOC)" de Clean Sky 2, esta tesis doctoral se centra en el estudio experimental de geometrías de intercambiadores de calor de superficie para la refrigeración del aceite motor mediante el uso del aire del flujo secundario del turbofan. Actualmente, existen una serie de limitaciones en cuanto a las capacidades para llevar a cabo un análisis y diseño detallado de este tipo de intercambiadores de calor debido a la falta de instalaciones que permitan un correcta, completa y robusta caracterización experimental. Las principales fuentes de datos se basan en cálculos numéricos validados a partir de extrapolaciones en condiciones de cuestionable aplicabilidad. A lo largo de la tesis se presentan los resultados obtenidos tras una detallada caracterización de cuatro diferentes geometrías de intercambiadores de calor empleando tanto técnicas intrusivas como ópticas. Se utiliza un banco de flujo capaz de generar una corriente de aire típica alrededor de los intercambiadores, mientras que un sistema de acondicionamiento de aceite controla el punto de operación por el lado caliente. Para recrear de manera más realista las condiciones de funcionamiento, se presenta una metodología para generar de manera automática pantallas de distorsión que pueden reproducir una distribución bidimensional de velocidades objetivo mediante la manufactura aditiva de paneles de porosidad variable. Este modelo, analizado mediante CFD y validado experimentalmente, se utiliza para reproducir el perfil de velocidades típico presente en torno al intercambiador en una circunstancia real de operación. Tras definir métricas relevantes que permitan analizar el comportamiento de las distintas geometrías, se llega a la conclusión de que los problemas aerodinámico y térmico están altamente acoplados en estos dispositivos, demostrando la necesidad de un cuidadoso diseño para mejorar las actuaciones del intercambiador. Los resultados muestran que puede llegar a obtenerse una mejora de más de un 12% en la caída de presión y casi un 20% en el intercambio de calor. Además, se ha confirmado el impacto del uso de la pantalla de distorsión, con variaciones del orden de 10% en ambas variables. Los resultados también muestran que es posible realizar una caracterización preliminar de manera fiable con un modelo impreso en 3D, en cuanto campos de velocidades, pérdidas de presión y frecuencias propias corregidas. Con el análisis llevado a cabo en esta tesis, se puede concluir que es fundamental tener una instalación experimental que reproduzca las condiciones de funcionamiento reales de un motor para realizar estudios relevantes de intercambiadores de calor. Además, es necesario el uso de métricas adecuadas junto con el desarrollo de una metodología exhaustiva, fiable y robusta. Los resultados y metodología presentados en en esta investigación pueden llegar a tener un impacto importante tanto a nivel académico como industrial, ya que abren la puerta a desarrollar sistemas de gestión térmica más eficiente en unas etapas de diseño preliminares que son más asequibles económicamente, consumen menos tiempo y tienen mayor flexibilidad para introducir modificaciones. / [CAT] En un present marcat per la lluita contínua contra la contaminació i el canvi climàtic, la recerca en millores tecnològiques que permetin una transició acceptable per a la societat cap a un futur més ecològic ocupa un paper fonamental. En concret, l'aviació és un focus constant d'innovació, ja que és considerada una funció indispensable en una societat tan globalitzada com l'actual però amb uns nivells de contaminació preocupants. En aquest aspecte, el desenvolupament de motors amb altes eficiències és un pas clau per a la transició mediambiental. Tot i això, aquestes alternatives presenten un repte tecnològic quant a la seva gestió tèrmica basat, principalment, en la necessitat d'augmentar la refrigeració. En aquest context i impulsada pel projecte "Aerodynamic upgrade of Surface Air Cooled Oil Cooler (SACOC)" de Clean Sky 2, aquesta tesi doctoral se centra en l'estudi experimental de geometries d'intercanviadors de calor de superfície per a la refrigeració de l'oli motor mitjançant l'ús de l'aire del flux secundari del turbofan. Actualment, hi ha una sèrie de limitacions quant a les capacitats per dur a terme una anàlisi i disseny detallat d'aquest tipus d'intercanviadors de calor a causa de la manca d'instal·lacions que permetin una caracterització experimental correcta, completa i robusta. Les fonts de dades principals es basen en càlculs numèrics validats a partir d'extrapolacions en condicions de qüestionable aplicabilitat. Al llarg de la tesi es presenten els resultats obtinguts després d'una detallada caracterització de quatre geometries diferents d'intercanviadors de calor emprant tant tècniques intrusives com òptiques. Sutilitza un banc de flux capaç de generar un corrent daire típic al voltant dels intercanviadors, mentre que un sistema de condicionament doli controla el punt doperació pel costat calent. Per recrear de manera més realista les condicions de funcionament, es presenta una metodologia per generar de manera automàtica pantalles de distorsió que poden reproduir una distribució bidimensional de velocitats objectiu mitjançant la manufactura additiva de panells de porositat variable. Aquest model, analitzat mitjançant CFD i validat experimentalment, sutilitza per reproduir el perfil de velocitats típic present al voltant de lintercanviador en una circumstància real doperació. Després de definir mètriques rellevants que permetin analitzar el comportament de les diferents geometries, s'arriba a la conclusió que els problemes aerodinàmic i tèrmic estan altament acoblats en aquests dispositius, demostrant la necessitat d'un disseny acurat per millorar les actuacions de l'intercanviador. Els resultats mostren que es pot arribar a obtenir una millora de més d'un 12% a la caiguda de pressió i gairebé un 20% a l'intercanvi de calor. A més, s'ha confirmat l'impacte de l'ús de la pantalla de distorsió, amb variacions de l'ordre del 10% a les dues variables. Els resultats també mostren que és possible fer una caracterització preliminar de manera fiable amb un model imprès en 3D, en tant que camps de velocitats, pèrdues de pressió i freqüències pròpies corregides. Amb l'anàlisi duta a terme en aquesta tesi, es pot concloure que és fonamental tenir una instal·lació experimental que reprodueixi les condicions de funcionament reals d'un motor per fer estudis rellevants d'intercanviadors de calor. A més, cal fer servir mètriques adequades juntament amb el desenvolupament d'una metodologia exhaustiva, fiable i robusta. Els resultats i metodologia presentats en aquesta investigació poden arribar a tenir un impacte important tant a nivell acadèmic com industrial, ja que obren la porta a desenvolupar sistemes de gestió tèrmica més eficient en unes etapes de disseny preliminars que són més assequibles econòmicament, consumeixen menys temps i tenen més flexibilitat per introduir modificacions. / [EN] In a present marked by the continuous fight against pollution and climate change, research into technological improvements that allow an acceptable transition for society towards a greener future occupies a fundamental role. Specifically, aviation is a constant focus of innovation, since it is considered an essential function in a society as globalized as today's, but with worrying levels of pollution. In this regard, the development of motors with high efficiencies is a key step for the environmental transition. However, these alternatives present a technological challenge in terms of their thermal management, based mainly on the need to increase cooling. In this context and promoted by the Clean Sky 2 "Aerodynamic upgrade of Surface Air Cooled Oil Cooler (SACOC)" project, this doctoral thesis focuses on the experimental study of surface heat exchanger geometries for engine oil cooling using the use of secondary flow air from the turbofan. Currently, there are a number of limitations regarding the capacity to carry out a detailed analysis and design of this type of heat exchanger due to the lack of facilities that allow a correct, complete and robust experimental characterization. The main data sources are based on numerical calculations validated from extrapolations under conditions of questionable applicability. The thesis presents results after a detailed characterization of four different geometries of heat exchangers using both intrusive and optical techniques. A flow bench capable of generating a typical air current around the exchangers is used, while an oil conditioning system controls the point of operation on the hot side. To more realistically recreate operating conditions, a methodology is presented to automatically generate distortion screens that can reproduce a two-dimensional distribution of target velocities through additive manufacturing of variable porosity panels. This model, analyzed by means of CFD and validated experimentally, is used to reproduce the typical speed profile present around the exchanger in a real operating circumstance. After defining relevant metrics that allow analyzing the behaviour of the different geometries, it is concluded that aerodynamic and thermal problems are highly coupled in these devices, demonstrating the need for careful design to improve the exchanger's performance. The results show that an improvement of more than 12% in pressure drop and almost 20% in heat exchange can be obtained. In addition, the impact of using the distortion screen has been confirmed, with variations of the order of 10% in both variables. The results also show that it is possible to carry out a preliminary characterization in a reliable way with a 3D printed model, in terms of velocity fields, pressure losses and corrected eigenfrequencies. With the analysis carried out in this thesis, it can be concluded that it is essential to have an experimental installation that reproduces the real operating conditions of an engine to carry out relevant studies of heat exchangers. In addition, the use of appropriate metrics is necessary together with the development of a comprehensive, reliable and robust methodology. The results and methodology presented in this research can have a significant impact both at an academic and industrial level, since they open the door to developing more efficient thermal management systems in preliminary design stages that are more affordable, consume less time and have more flexibility to make changes. / The respondent wishes to acknowledge the financial support received through the Programa de Apoyo para la Investigación y Desarrollo (PAID) of Univer- sitat Politècnica de València under grant PAID-01-20 n◦ 21589. This project has received funding from the Clean Sky 2 Joint Undertak- ing under the European Unions Horizon 2020 research and innovation pro- gramme under grant agreement No 831977 Aerodynamic upgrade of Sur- face Air-Cooled Oil Coolers (SACOC) / Felgueroso Rodríguez, A. (2023). Aerothermal Characterisation of Surface Heat Exchangers for Turbofans [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/195852