Surface metrology has been widely used in manufacturing for many years. There has been a wide range of techniques applied for measuring surface topography. A photometric stereo technique is one of the best ways for the analysis of three-dimensional (3D) surface textural patterns. Many published works are concerned the developed approach for recovering the 3D profiles from surface normal. This research not only presents a methodology used to retrieve the profiles of surface roughness standards but also investigates the uncertainty estimation of textural measurement determined by the photometric stereo method. Various input quantities have been studied such as pixel error from recovered 3D surface textural patterns, the power of light source which involved with surface roughness average (Ra) value and the effect of room temperature. The surface roughness standards were utilized as the reference value. In term of increasing accuracy of the reference value, a contact method (stylus instrument) was used to calibrate them. Illumination angles of light source had some influence on the measurement results. A coordinate measuring machine (CMM) was used for holding the light source in order to study the effects of tilt and slant angles. The effect of tilt and slant angles were investigated. The results of these experiments successfully indicated that the angle used in photometric stereo method played an important role to the accuracy level of the roughness measurement results. The surface roughness specimen manufactured by a Computer Numerical Control (CNC) was applied to validate the capability of the photometric stereo system.

Transition metals represent some of the first catalysts used in industrial processes and are still used today to produce many of the most needed chemicals. Adopting from ancient metallurgical techniques, it followed that the performance of these basic transition metals can be refined by adding multiple components. Since that time, improvements to these alloy catalysts has been mostly incremental due to the difficulty of producing new catalysts experimentally and a lack of fundamental understanding of the underlying physics. More recently, computational chemistry has proven itself an increasingly effective means for identifying these underlying physics. Through the use of d-band interactions of adsorbates with the surface, basic adsorption characteristics can be predicted across transition metals with limited initial information. However, although these models function well as high-level screening tools, much work is yet to be done before optimal catalysts can be comfortably designed from properties which experimentalists can directly control. This remains particularly challenging for alloy modeling, primarily due to the large number of possible atomic configurations, even for two metal systems. This work focuses on developing the methods for modeling optimal reaction properties at the surface of a transition metal alloy. Based on thermodynamic equilibrium between the surface, bulk, and gas reservoir, a model for the prediction of segregation under vacuum and adsorbate conditions can be predicted. Furthermore, by relating strain in the bulk lattice constant to the adsorption energies of varying local active sites, the optimal surface compositions can be related to bulk composition; a feature which can easily be selected for. Although useful for identifying trends across bulk composition space, these methods are limited to a small subset of active site configurations. To capture the complexity of more sophisticated processes, such as segregation, higher-timescale methods are required. Traditional computational tools are often too expensive to implement for these methods, and as such, they are usually completed with less-accurate potentials. In this work, we demonstrate that machine learning techniques have improved accuracy compared to physical potentials. We then go on to demonstrate how this improved accuracy can lead to experimentally accurate predictions of segregation.

L'atmosphère et la surface terrestre interagissent en permanence par le biais des échanges d'énergie et de matière. Ces flux jouent un rôle important dans l'étude de l'hydrologie des surfaces ou de l'écologie terrestre, ou bien encore l'étude des phénomènes météorologiques et climatiques. En effet, ils représentent les conditions aux limites des différents compartiments du système Terre et la quantification de ces échanges à différentes échelles spatiales est indispensable pour les modèles de prévision. Les mesures de flux d'énergie sont très répandues pour des mesures très localisées, in situ et au sol. Cependant, peu d'instruments de mesures permettent d'obtenir des flux intégrés sur des distances de l'ordre de la centaine de mètres à quelques kilomètres, c'est-à-dire des distances correspondant à la représentativité des pixels des images satellitaires. On compte parmi eux les scintillomètres, instrument de mesure optique, permettant de calculer les flux intégrés de chaleur sensible à partir des mesures de paramètres caractérisant l'intensité turbulente de l'atmosphère tels que le paramètre de structure de l'indice de réfraction de l'air Cn². La présence de vapeur d'eau dans l'atmosphère peut cependant perturber le signal de ces instruments. L'objectif de ce travail est le développement et la mise en oeuvre d'un scintillomètre optique permettant de mettre en évidence la contribution de l'absorption par la vapeur d'eau sur les scintillations. Les études menées à partir du développement instrumental ne s'orienteront qu'autour de la bande d'absorption à 940nm, longueur d'onde d'émission de certains scintillomètres LAS (Large Aperture Scintillometer). Au début de ma thèse, un prototype de scintillomètre, type LAS, a été conçu de façon à maitriser complètement la technologie : partie optique électronique et le traitement du signal reçu. Celui-ci a ensuite été installé au-dessus d'un site de cultures dans les environs de Toulouse, au cours des années 2007 et 2008. Les résultats obtenus avec ce prototype ont permis d'optimiser le choix de la méthode de calcul H à partir du Cn², en fonction du rapport de Bowen (rapport du flux de chaleur sensible sur le flux de chaleur latente). Les variations de l'intensité lumineuse de l'onde, menant au Cn², sont principalement dues à des effets de réfraction et de dispersion, maissont aussi sensibles à l'absorption de la vapeur d'eau. Afin de quantifier l'influence de 'absorption sur le signal Cn², j'ai utilisé 2 approches : une première approche par filtrage numérique (‘Gabor Transform'), et une seconde, par méthode chromatique. Cette dernière a nécessité de modifier considérablement le système optique du prototype LAS. Les résultats obtenus expérimentalement montrent que la contribution de l'absorption à la mesure du Cn² est en moyenne assez faible, mais qu'elle peut prendre de forte valeur, principalement lors de faibles flux H. La quantification de l'absorption par méthode hromatique est pour l'instant limité au développement technique de l'instrument. / Atmosphere, soil and vegetation are in interactions by the bias of energetic or matter exchanges. This latters have an important impact on hydrology, ecology, meteorology. Actually, they represent the boundary conditions of the Earth-Atmosphere system. Then, the quantification of these exchanges or fluxes is necessary to understand large scales phenomena and to improve forecasting models. Numerous devices are able to quantify these fluxes at local scales, but few are available to measure them over kilometres, which mean at the resolution of remote sensing datas. Amongst them, we can notice the scintillometers that are able to calculate sensible heat fluxes over distances from hundred meters to few kilometres. Actually, these devices are sensitive to variations of the refractive index of air, mainly due to turbulent eddies, defined by the structure parameter of refractive index : Cn². However, this measurement can be altered by the presence of water vapour in the air. Thus, the aim of this work is to design and make a scintillometer which is able to quantify the water vapour contribution on the Cn² measurement. In this thesis, we will focus on this contribution in the 940nm band which is the wavelength of various scintillometers LAS (Large Aperture Scintillometers). At the beginning of my PhD thesis, un scintillometer prototype has been realised in order to master the technology : optics, electronics, signal processing…This latter has been set up over crops at a few kilometres from Toulouse, between 2007 and 2008. Thanks to the results of this scintillometer, we optimize the choice on the Cn² to H algorithm, according to the Bowen ratio ß (ratio of sensible to latent heat flux). Variations of the light beam, leading to the Cn², are mainly due to refraction and dispersion effect. However, absorption can be important. In order to quantify the contribution of absorption on the Cn², 2 methods are suggested : one based on signal processing aspect (Gabor filtering), and the second one on two wavelengths propagation. To realize this latter the optics and electronics of the device have been really modified. Results show that absorption contribution is small, but can be important for low H values. Finally, the quantification of absorption by two wavelengths approach is nowadays bounded to instrumental development.

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No description available.

The acoustoelectric effect in graphene and graphene nanoribbons (GNRs) on lithium niobate surface acoustic wave (SAW) devices was studied experimentally. Monolayer graphene produced by chemical vapour deposition was transferred to the SAW devices. The photoresponse of the acoustoelectric current (Iae) was characterised as a function of SAW frequency and intensity, and illumination wavelength (using 450 nm and 735 nm LEDs) and intensity. Under illumination, the measured Iae increased by more than the measured decrease in conductivity, while retaining a linear dependence on SAW intensity. The latter is consistent with the piezoelectric interaction between the graphene charge carriers and the SAWs being described by a relatively simple classical relaxation model. A larger increase in Iae under an illumination wavelength of 450 nm, compared to 735 nm at the same intensity, is consistent with the generation of a hot carrier distribution. The same classical relaxation model was found to describe Iae generated in arrays of 500 nm-wide GNRs. The measured acoustoelectric current decreases as the nanoribbon width increases, as studied for GNRs with widths in the range 200 – 600 nm. This reflects an increase in charge carrier mobility due to increased doping, arising from damage induced at the nanoribbon edges during fabrication. 2 Lastly, the acoustoelectric photoresponse was studied as a function of graphene nanoribbon width (350 – 600 nm) under an illumination wavelength of 450 nm. Under illumination, the nanoribbon conductivity decreased, with the largest percentage decrease seen in the widest GNRs. Iae also decreased under illumination, in contrast to the acoustoelectric photoresponse of continuous graphene. A possible explanation is that hot carrier effects under illumination lead to a greater decrease in charge carrier mobility than the increase in acoustoelectric attenuation coefficient. This causes the measured decrease in Iae.

A surface acoustic wave (SAW) is a combination of a mechanical wave and a potential wave propagating on the surface of a piezoelectric substrate at the speed of sound. Such waves are widely applied in not only the communication industry, but also in quantum physics research, such as nanoelectronics, spintronics, quantum optics, and even quantum information processing. Here, I focus on low-dimensional electron transport and SAWs in GaAs and ZnO semiconductor heterostructures. The ability to pattern quantum nanostructures using gates has stimulated intense interest in research into mesoscopic physics. We have performed a series of simulations of gate structures, and having with the optimised boundary conditions and we find them to match experimental results, such as the pinch-off voltage of one-dimensional channels and SAW charge transport in induced n-i-n and n-i-p junctions. Using the improved boundary conditions, it is straightforward to model quantum devices quite accurately using standard software. With the calculated potential, we have modelled the process how a dynamic quantum dot is driven by a SAW and have analysed error mechanisms in SAW-driven quantisation (I=Nef, where N is the number of electrons in each SAW minimum, and f is the SAW resonant frequency). From energy spectroscopy measurements, we probe the electron energy inside a SAW-driven dynamic quantum dot and find that the small addition energy, which is around 3meV, is the main limitation for the SAW quantisation. To increase the confinement of SAW-driven quantum dots, we deposit a thin ZnO film, with a better piezoelectric coupling than GaAs, on a GaAs/AlGaAs heterostructure using high-target-utilisation sputtering (an Al2O3 buffer layer is deposited to protect the 2DEG during sputtering). With the ZnO, the SAW amplitude is greatly improved to 100 meV and the RF power required for pumping electrons using a SAW is greatly reduced. Finally, we have studied low-dimensional electron transport in a MgZnO/ZnO heterostructure. We have developed a technique for patterning gates using a parylene insulator, and used these to create one-dimensional quantum wires and observe electron ballistic transport with conductance quantised in units of 2e2/h The increasing electron effective mass as the 1D electron density decreases indicate that the electron-electron interaction in this MgZnO/ZnO heterostructure is strong. Because of these strong interactions, the 0.7 anomaly is observed just below each quantised plateau, and are much stronger than in GaAs quantum wires. Furthermore, we have also calculated the SAW-modulated spontaneous and piezoelectric polarisation in the ZnO heterostructure, and have observed a sign of this SAW-modulation in 2DEG density, which is different from the classical SAW-pumping mechanism. Our results show that a ZnO heterostructure should provide a good alternative to conventional III-V semiconductors for spintronics and quantum computing as they have less nuclear spins. This paves the way for the development of qubits benefiting from the low scattering of an undoped heterostructure together with potentially long spin lifetimes.

Shao, Lei = 金顆粒納米晶中角度、能量和空間位置分辨的表面等離子共振耦合 / 邵磊. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2010. / Includes bibliographical references. / Abstracts in English and Chinese. / Shao, Lei = Jin ke li na mi jing zhong jiao du, neng liang he kong jian wei zhi fen bian de biao mian deng li zi gong zhen ou he / Shaolei. / Abstract --- p.1 / 摘要 --- p.iii / Acknowledgement --- p.v / Table of Contents --- p.vii / List of Figures --- p.ix / List of Tables --- p.xiv / Chapter 1. --- Introduction --- p.1 / Chapter 1.1 --- Localized Surface Plasmon Resonances of Noble Metal Nanocrystals --- p.3 / Chapter 1.1.1 --- Dielectric Functions of Noble Metal Nanocrystals --- p.3 / Chapter 1.1.2 --- Absorption and Scattering of Light by Noble Metal Nanoparticles --- p.7 / Chapter 1.2 --- Coupling between Localized Surface Plasmons --- p.14 / Chapter 1.2.1 --- Theoretical Treatments for Plasmon Coupling --- p.14 / Chapter 1.2.2 --- Unique Properties Resulting from Plasmon Coupling --- p.15 / Chapter 1.2.3 --- Applications Based on Plasmon Coupling --- p.17 / Chapter 1.3 --- Outline of Thesis --- p.18 / Chapter 2. --- Growth of Gold Nanocrystals and Characterization Techniques --- p.26 / Chapter 2.1 --- Growth of Gold Nanocrystals --- p.26 / Chapter 2.2 --- Characterization Techniques --- p.29 / Chapter 3. --- Surface Plasmon Coupling in Homodimers of Elongated Gold Nanocrystals --- p.34 / Chapter 3.1 --- Formation of Homodimers of Elongated Gold Nanocrystals --- p.35 / Chapter 3.2 --- Angle-Resolved Plasmon Coupling in Gold Nanorod Dimers --- p.37 / Chapter 3.2.1 --- Experimental Results --- p.39 / Chapter 3.2.2 --- FDTD Calculations --- p.43 / Chapter 3.2.3 --- Dipolar Modeling --- p.49 / Chapter 3.3 --- Effect of the Head Shape on the Plasmon Coupling --- p.57 / Chapter 3.4 --- Summary --- p.60 / Chapter 4. --- Surface Plasmon Coupling in Heterodimers of Gold Nanocrystals --- p.64 / Chapter 4.1 --- Formation of Heterodimers of Gold Nanocrystals --- p.65 / Chapter 4.2 --- Energy-Resolved Plasmon Coupling in Gold Nanorod Heterodimers --- p.67 / Chapter 4.3 --- Position-Resolved Plasmon Coupling in Gold Nanorod-Nanosphere Heterodimers --- p.70 / Chapter 4.3.1 --- Experimental Results --- p.71 / Chapter 4.3.2 --- FDTD Calculations --- p.75 / Chapter 4.4 --- Summary --- p.83 / Chapter 5. --- Summary and Conclusion --- p.87

Yu, Tsz Tat. / "December 2010." / Thesis (M.Phil.)--Chinese University of Hong Kong, 2011. / Includes bibliographical references (leaves 143-147). / Abstracts in English and Chinese. / Abstract --- p.2 / 摘要 --- p.4 / Acknowledgements --- p.5 / List of Figures --- p.6 / List of Tables --- p.12 / List of Abbreviations --- p.13 / Table of Contents --- p.14 / Chapter Chapter 1 --- Introduction --- p.17 / Chapter Chapter 2 --- Literature Review / Chapter 2.1 --- Surface Plasmon Wave --- p.19 / Chapter 2.2 --- Excitation of Surface Plasmon --- p.23 / Chapter 2.3 --- Surface Plasmon Coupling --- p.24 / Chapter 2.4 --- Surface Plasmon Resonance Detection Techniques --- p.33 / Chapter 2.5 --- Applications of SPR biosensors --- p.39 / Chapter Chapter 3 --- Theory of irradiance modulator / Chapter 3.1 --- Polarization --- p.44 / Chapter 3.2 --- Optical polarizer --- p.45 / Chapter 3.3 --- Liquid Crystal Modulator --- p.49 / Chapter 3.4 --- Irradiance Modulator --- p.52 / Chapter Chapter 4 --- LCM characterization / Chapter 4.1 --- Single LCM Transmittance driven by pure square wave --- p.66 / Chapter 4.2 --- Single LCM Reflectance driven by 50:50 STAM wave --- p.70 / Chapter 4.3 --- Multiple LCMs Reflectance driven by 90:10 STAM wave --- p.73 / Chapter Chapter 5 --- Background of phase measurement / Chapter 5.1 --- From holography to shearography --- p.77 / Chapter 5.2 --- From static Mach-Zehnder interferometer to differential-phase Mach-ZehnderZ interferometer --- p.81 / Chapter 5.3 --- From differential-phase imaging to pixel-referencing imaging --- p.86 / Chapter Chapter 6 --- Pixel-referencing data processing / Chapter 6.1 --- Background --- p.89 / Chapter 6.2 --- Procedures --- p.94 / Chapter 6.3 --- Experimental results --- p.98 / Chapter 6.4 --- Sensor resolution --- p.116 / Chapter 6.5 --- Performance comparison between single-beam LCM and Mach Zehnder configuration --- p.119 / Chapter Chapter 7 --- Discussions / Chapter 7.1 --- Experiment precautions --- p.136 / Chapter 7.2 --- Linear curve fitting --- p.137 / Chapter 7.3 --- Hardware limitation: Low frame rate --- p.138 / Chapter 7.4 --- Matching oil and glass slide --- p.139 / Chapter Chapter 8. --- Conclusions --- p.141 / References --- p.143 / Appendix / Chapter A1 --- "Concentration, Refractive Index and Dielectric constant of Sodium Chloride Solution (20°C)" --- p.148 / Chapter A2 --- Liquid Crystal Modulator Specification --- p.149 / Chapter A3 --- "Digital-to-analogue Converter Device (NI, PCI6036E) Datasheet" --- p.150 / Chapter A4 --- "CCD Camera (Lumenera, Infinity) Datasheet" --- p.151 / Chapter A5 --- Flow chart of SPR phase extraction --- p.152 / Chapter A6 --- Codes of SPR phase extraction in modules --- p.153

Mercury (Hg) has always been a serious risk to the environment and human health. It is a very common contamination in petroleum industry, which may lower product quality, threaten operation safety and worker’s health even at a very low concentration. Consequently the detection of mercury is very necessary. Gold is widely used as sensing material of mercury because it has a specific affinity with mercury and the adsorption of mercury changes characteristics of gold such as resistivity and effective mass density. In this thesis, common methods for sensing mercury vapor concentration were summarized and a surface acoustic wave (SAW) sensor utilizing the adsorption of mercury on gold electrodes was proposed for 1 μg/m3 level low concentration mercury vapor detection. The working principle of SAW sensor was studied and finite element method models were built to optimize the sensor design. The influence of several physical structure parameters such as electrode width and pitch on the sensor sensitivity and response time were studied using the simulation model. According to the simulation results a prototype of SAW sensor was designed and fabricated. The sensor was then analyzed with network analyzer and tested with mercury vapor. Preliminary results were presented and analyzed in this work. Finally potential future work was proposed and discussed.