In recent years, the Asian dust storms occurred frequently. It was estimated that approximately eight hundred million metric tons of Asian dusts transported to the atmosphere yearly. During the dust storm period, Asian dusts not only induce poor air quality, but also reduce atmospheric visibility and influence human health. In order to investigate the physicochemical characteristics and source allocation of Asian dusts, this study collect the Asian dusts in the Pescadores Islands during the years of 2002~2006. In addition, this study collected top soils in three regions of Inner Mongolia and resuspended the soil samples in a resuspension chamber to analyze their chemical composition. Moreover, this study applied enrichment factor analysis (EF) and grey relational analysis to allocate the potential sources of Asian dusts and compare them with the transportation routes obtained from backward trajectory. During Asian dust storm periods, the concentration of atmospheric particulate matter (PM10) in the Pescadores Islands increased significantly, probably is 3~6 times of PM10 during non-dust storm periods. Among them, coarse particles (PM2.5-10) particularly rose from 10~30 £gg/m3 to 80~130 £gg/m3 and the size distribution changed from bi-modal distribution to single modal distribution of coarse particles during Asian dust storm periods. This study further analyzed the chemical composition of Asian dusts, including water-soluble ionic species, carbon contents, and metallic contents. For fine particles (PM2.5), the order of water-soluble ionic species was SO42- > NH4+ > NO3- > Cl- > Ca2+ > Na+ > K+ > Mg2+ > F-. For coarse particles (PM2.5-10), the order of water-soluble ionic species was Cl- > SO42- > NO3- > Na+ > Ca2+ > NH4+ > Mg2+ > K+ > F-. The carbon contents distributes mainly in fine particles. The major contents of both fine and coarse particles were crustal elements (i.e. Al, Fe, Na, Mg, K, Ca, and Sr). In addition to the analysis of physicochemical characteristics of Asian dusts, this study applied HYSPLIT MODEL to figure out their transportation routes by backward trajectory. According to the backward trajectories, this study compartmentalized Asian dusts storm transportation routes into three categories: Eastward Transportation and Retraced (ETR), Southeasterly Transportation and Circumrotated (STC), and Straight Southeasterly Transportation (SST). Analyzing the spatial and temporary background variables to investigate the influence of transportation routes on Asian dusts¡¦ physicochemical characteristic. This study revealed that the physicochemical characteristics were very similar for same category of Asian dust storms, which can be used to allocate the source regions of Asian dust storms. This study resuspended the soil samples collected in Inner Mongolia inside a resuspension chamber and collected the suspended particles (PM2.5, PM2.5-10) for chemical analysis. Chemical analysis results indicated that the fingerprints of chemical composition for different regions were similar but still distinguishable, which can be used to identify the source areas of Asian dusts. This study further compare and correlate the Asian dusts collected at the Pescadores Islands during Asian dust storm periods with the soils collected in Inner Mongolia chemically by enrichment factor and grey relational analysis. This study further compared the source allocation of Asian dust storms obtained from enrichment factor, grey relational analysis, and backward trajectory and found the results of these three methods were quite similar. For enrichment factor analysis, 88% of similarity was obtained by using two separate reference elements (Al and Fe). The similarity of backward trajectory and grey relational analysis reached as high as 83%. Moreover, the backward trajectory and enrichment factor were similar up to 75%, while the grey relational analysis and enrichment factor were similar up to 69%. Overall, two out of three aforementioned methods can effectively allocate the source regions of Asian dusts by 94%, while all three methods can successfully allocate the source regions of Asian dusts by 56%. Comparison of three aforementioned methods showed that they can be applied to allocate the source regions of Asian dusts.

In addition to air pollutants index (i.e. PSI), ambient air quality can be described by atmospheric visibility since it can be observed directly by general publics. In this study, atmospheric visibility observation, meteorological parameter monitoring, and aerosol particle sampling were conducted to investigate the influences of physicochemical properties of suspended particles and meteorological parameters on atmospheric visibility. This study further applied receptor model and multiple regression linear analysis to forecast atmospheric visibility and develop strategies for improving urban visual air quality at Taipei region. Results from regular visibility observation indicated that the average visibilities were 10.30, 8.05 and 6.00 km in the directions of Tamsui, Sonshan, and Shindian, respectively. Similar trend of visibility variation was also observed for intensive observation. Further analysis of synoptic chart and regular observation data during the period of January 2007¡VMarch 2008 showed that the lowest atmospheric visibility commonly occurred whenas the weather patterns were in sequence of eastward movement of rainy areas in southern China, southerly airstream, strong northeast monsoon, circus-sluice of high pressure outflow, and weak northeast monsoon. Results from chemical analysis of suspended particles at Taipei region indicated that major water-soluble ionic species were SO42-, NO3-, and NH4+ and followed by Cl-, while major metallic content were Ca and K. Carbonaceous analysis showed that the mass ratio of OC/EC ranged from 1.65 to 1.91 for PM2.5 and from 1.37 to 1.88 for PM2.5-10. Ammonium nitrate, organic carbon, and ammonium sulfate were the major chemical species that influenced atmospheric visibility at Taipei region. In this study, we choose the averaged atmospheric visibility in Sonshan as a dependent variable and PM10, NO2, SO2, O3, relative humidity (RH), wind direction (WD), and wind speed (WS) as independent variables to establish multiple linear regression models for forecasting the atmospheric visibility. Results of statistical analysis indicated that high correlation between forecasted and observed atmospheric visibilities was observed (R=0.7167). Furthermore, atmospheric visibility forecasting models were established for various weather patterns. The accuracies of atmospheric visibility verification (September~December, 2007) and forecasting (January~March, 2008) were 91.80% and 87.97%, respectively. This study further applied SPSS stastistic software to conduct factor analysis for atmospheric visibility. Results from factor analysis of visibility indicated that the top three factors (PM10, NO2, and SO2) accounted for 71.13% of variance. Furthermore, variable correlation analysis showed that atmospheric visibility had positive correlation with wind speed and negative correlation with other variables (PM10, NO2, SO2, O3, RH, and WD). Besides, for the significant levels of £\=0.01 or £\=0.05, all variables were proven to be significantly correlated with atmospheric visibility except O3. At Taipei region, the automobile tail emission was the major emission source causing low visibility, thus the most effective strategy for improving atmospheric visibility was to reduce the mission of automobiles and the formation of secondary aerosols containing ammonium nitrate and ammonium sulfate, which could effectively increase the atmospheric visibility at Taipei region.

Thesis (Ph. D.)--Mississippi State University. Department of Computational Engineering. / Title from title screen. Includes bibliographical references.

published_or_final_version / Civil Engineering / Doctoral / Doctor of Philosophy

Particle-laden jets are an important type of multiphase flow which can be found in various natural and technical processes. This study focuses on the flow mechanisms in a horizontally discharging sediment-laden jet that is of particular interest in environmental science and engineering. Experimental techniques and mathematical models are developed to investigate horizontal sediment-laden jets, both for the buoyant and non-buoyant jet discharge cases. In the laboratory, the separation of images of the fluid and the particulate phases is achieved by harnessing light signals of visualization at different wavelengths. Whole field measurements of velocities of the two phases are made by the adoption of particle image velocimetry (PIV) algorithms. Numerical models are developed in two approaches with regard to the treatment of the particulate phase. In the Lagrangian approach, individual sediment particles are tracked while the flow field of the fluid phase is computed with large-eddy simulation (LES). This simulation successfully captures the transient nature of the particle-laden flow. In the Eulerian approach, a two-phase model is used to obtain steady flow simulations in a much shorter computation time. The experimental and numerical results for the horizontal momentum jets show that, at low initial particle concentrations, the sediment particles generally follow the jet flow but with some levels of deficit velocities. In the upper layer of the jet the particles do not follow the fluid flow as well as in its lower layer. More particles are observed in the lower layer than in the upper one. For the momentum-dominated zone of a horizontal buoyant jet, the flow exhibits similar behaviors as the horizontal particle-laden momentum jet, except that there are some slight modifications from the effects of buoyancy. In the bending zone of the buoyant jet, the effects of buoyancy become significant. Notably, the locations of maximum velocity magnitude and those of maximum turbulence intensity are well separated in this zone. A strong correlation of particle abundance and high turbulence intensity is observed in the lower outer jet layer in this bending zone. Significant modifications to the global behaviors of horizontal sediment jets are observed as the particle concentration increases to relatively high levels. The jet trajectories are brought downwards by the particle loads and the jet widths are also increased. For the flow regime being investigated, turbulence intensity in the fluid flow is found to be increased by the presence of sediment particles. The results suggest that turbulence helps suspend sediment particles in horizontally discharging jets. A Stokes number is proposed to represent the ability of particles to follow the fluid flow. It is defined as St=W_s/U_j , where ws is the particle settling velocity in still fluid and Uj is the jet exit velocity, which indirectly governs the turbulence characteristics of the jet flow. The advecting large eddies in a turbulent jet are found to play the role of organizing particles in patches. Interaction and coalescence between particle-concentrated eddies may result in the sudden drop of a group of particles, which contributes to sediments falling from a horizontal jet in the form of particle-rich “fingers”. / published_or_final_version / Civil Engineering / Doctoral / Doctor of Philosophy

Sediment-laden turbulent buoyant jets are commonly encountered in the natural and man-made environments. Examples of sediment-laden buoyant jets include volcanic eruptions, deep ocean hydrothermal vents (“black smokers”), ocean dumping of dredged spoils and sludge, and submarine discharge of wastewater effluent. It is important to understand the fluid mechanics of sediment jets for environmental impact assessment, and yet there is currently no general model for predicting the mixing of sediment-laden jets. This study reports a theoretical and experimental investigation the sediment mixing, fall-out and deposition from sediment-laden buoyant jets. It is well known that turbulence generates fluctuations to the particle motion, modulating the particle settling velocity. A general three-dimensional (3D) stochastic particle tracking model is developed to predict the particle settling out and deposition from a sediment-laden jet. Particle velocity fluctuations are modelled by a Lagrangian velocity autocorrelation function that accounts for the loitering and trapping of sediment particles in turbulent eddies which results in the reduction of settling velocity. The model is validated against results of independent experimental studies. Consistent with basic experiments using grid-generated turbulence, the model predicts that the apparent settling velocity can be reduced by as much as 30% of the stillwater settling velocity. The mixing and deposition of sediment-laden horizontal momentum jets are studied using laboratory experiments and 3D computational fluid dynamics (CFD) modelling. It is shown that there is a significant settling velocity reduction up to about 25-35%, dependent on jet turbulent fluctuations and particle properties. The CFD approach necessitates an ad hoc adjustment/reduction on settling velocity and lacks generality. Using classical solutions of mean velocity, and turbulent fluctuation and dissipation rate profiles derived from CFD solutions, 3D particle tracking model predictions of sediment deposition and concentration profiles are in excellent agreement with measured data over a wide range of jet flow and particle properties. Unlike CFD calculations, the present method does not require any a priori adjustment of particle settling velocity. A general particle tracking model for predicting sediment fall-out and deposition from an arbitrarily inclined buoyant jets in stagnant ambient is successfully developed. The model incorporates the three flow regimes affecting the sediment dynamics in a buoyant jet, namely turbulent jet flow, jet entrainment-induced external flow and surface spreading current. The jet mean flow velocity is determined using a well-validated jet integral model. The external jet-induced irrotational flow field is computed by a distribution of point sinks along the jet trajectory. The surface spreading current is predicted using an integral model accounting for the interfacial shear. The model is validated against experimental data of sediment deposition from vertical and horizontal sediment-laden buoyant jets. / published_or_final_version / Civil Engineering / Doctoral / Doctor of Philosophy

Pattern formation in buckled membranes was studied along with the morphology of flowers formed at the tip of silicon nanowires and ripples formed in suspended graphene sheets. Nash's perturbation method was tested for a simple case where initial and final metrics embed smoothly and there is a smooth path from one surface to another and was found to work successfully. The method was tested in more realistic conditions where a smooth path was not known and the method failed. Cylindrical flower-like membranes with a metric of negative Gaussian curvature were simulated in three and four dimensions. These four dimensional flowers had 2 orders of magnitude less energy than their three dimensional counterparts. Simulations were used to show that the addition of a fourth spatial dimension did not relieve all bending energy from the cylindrical membranes. Patterns formed at the tip of silicon nanowires were studied and found to be of the Dense Branching Morphology type. The rate of branching is dependent on the curvature of the gold bubble on which they are grown. Graphene was simulated using the modified embedded atom method potential and buckles were found to form if the carbon bonds were stretched. An energy functional was found for the energy of a sheet with a metric different from that of flat space. / text

Balm Road Treatment Marsh is a 12 ha constructed wetland treatment system in south-central Hillsborough County, Florida created to improve water quality in Bullfrog Creek and ultimately Tampa Bay. The treatment system was designed to treat runoff from approximately 741 ha of upstream agricultural land prior to discharging into the creek, with the primary goals of reducing sediment and nutrient loads. Water quality data from four sites on Bullfrog Creek were analyzed to determine impacts to ambient water quality and pollutant load reductions downstream. Results were compared to the performance of other wetlands to treat both nonpoint and point source pollution. Impacts to ambient water quality in the creek were found to be minimal, if any, and although significant load reductions were found downstream, they could not be attributed to wetland treatment affects with confidence. In general, nonpoint source pollution, particularly from agriculture, was found to be treated less effectively than point sources. The importance of monitoring the performance of stormwater projects while employing a strategic sample design and including receiving water impacts is highlighted.

BNFL Sellafield has been authorised to discharge radionuclides to the Irish Sea since 1952. In the aquatic environment the radionuclides are adsorbed by sediments and are thus redistributed by sediment transport mechanisms. This sediment is known to accumulate in the estuaries of the Irish Sea. BNFL Springfields is also licensed to discharge isotopically different radionuclides directly to the Ribble estuary. Thus there is a need to understand the sediment dynamics of the Ribble estuary in order to understand the fate of these radionuclides within the Ribble estuary. Estuaries are highly dynamic environments that are difficult to monitor using the conventional sampling techniques. However, remote sensing provides a potentially powerful tool for monitoring the hydrodynamics of the estuarine environment by providing data that are both spatially and temporally representative. This research develops a methodology for mapping suspended sediment concentration (SSC) in the Ribble estuary using airborne remote sensing. The first hypothesis, that there is a relationship between SSC and l37Cs concentration is proven in-situ (R2=O.94), thus remotely sensed SSC can act as a surrogate for \37Cs concentration. Initial in-situ characterisation of the suspended sediments was investigated to identify spatial and temporal variability in grain size distributions and reflectance characteristics for the Ribble estuary. Laboratory experiments were then perfonned to clearly define the SSC reflectance relationship, identify the optimum CASI wavelengths for quantifying SSC and to demonstrate the effects on reflectance of the environmental variables of salinity and clay content. Images were corrected for variation in solar elevation and angle to give a ground truth calibration for SSC, with an R2=O.76. The remaining scatter in this relationship was attributed to the differences in spatial and temporal representation between sampling techniques and remote sensing. The second hypothesis assumes that a series of images over a flood tide can be animated to provide infonnation on the hydrodynamic regime, erosion, and deposition. Spatial and temporal data demonstrated the complex controls on sediment transport. The data also showed the importance of microphytobenthos in the stabilisation of intertidal sediments, highlighting their importance in defining sources and sinks of radionuclides in intertidal areas. Water volume data from the VERSE model were combined with SSC from the imagery to calculate the total sediment in suspension for each flight line. This provided the figures used to detennine total erosion and deposition, which were then used to derive net suspended sediment and l37Cs influxes of 2.01xl06kg and 604MBq per flood tide.

Στην παρούσα εργασία μελετάται η συμπεριφορά ιζήματος σε αιώρηση που προκαλείται λόγω θραύσης κύματος σε πυθμένα σταθερής κλίσης. Η αριθμητική προσομοίωση επιτυγχάνεται με παράλληλη επίλυση των εξισώσεων κίνησης (Navier-Stokes και Συνέχειας) και της εξίσωσης Μεταγωγής-Διάχυσης για τη μεταφορά ιζήματος σε αιώρηση. Επιλέγονται οι κατάλληλες οριακές συνθήκες ελεύθερης επιφάνειας, εισόδου και εξόδου, ενώ για την οριακή συνθήκη πυθμένα χρησιμοποιούνται εμπειρικοί τύποι που συνδέουν τη διατμητική τάση πυθμένα με τη συγκέντρωση πυθμένα. Οι εξισώσεις μετασχηματίζονται κατάλληλα ώστε το υπολογιστικό πεδίο να γίνει ανεξάρτητο του χρόνου. Για τη χρονική διακριτοποίηση χρησιμοποιείται ένα σχήμα κλασματικής μεθόδου ολοκλήρωσης με σταθερό χρονικό βήμα. Για τη χωρική διακριτοποίηση χρησιμοποιείται ένα υβριδικό σχήμα, το οποίο περιλαμβάνει διακριτοποίηση των εξισώσεων με χρήση πεπερασμένων διαφορών κατά τη διεύθυνση της ροής και εφαρμογή της φασματικής μεθόδου παρεμβολής με πολυώνυμα Chebyshev για την κατακόρυφη διεύθυνση. Μελετώνται περιπτώσεις κόκκων ιζήματος με διάμετρο κανονικοποιημένη ως προς το χαρακτηριστικό βάθος ροής, =10-4, =2∙10-4 και =5∙10-4. Κατά την θραύση παρατηρείται σημαντική ανύψωση του ιζήματος πυθμένα στη στήλη του ύδατος και για τις τρεις περιπτώσεις. Η καθαρή παροχή ιζήματος σε αιώρηση παρουσιάζει τη τάση να κινείται προς τα ανάντη της ροής με τη μέγιστη τιμή να εμφανίζεται μετά τη θραύση. Τέλος, διαπιστώνεται ότι η καθαρή παροχή αιωρούμενου ιζήματος είναι σημαντικά μεγαλύτερη από αυτή του ιζήματος κλίνης. / The simulations are based on the coupled numerical solution of the flow equations (continuity and Navier-Stokes) with the transport equation for suspended sediment load subject to the fully nonlinear free-surface boundary conditions and appropriate bottom, inflow and outflow boundary conditions. The equations are properly transformed so that the computational domain becomes time-independent. A hybrid scheme is used for the spatial discretization with finite differences in the streamwise direction and a pseudospectral approximation with Chebyshev polynomials in the vertical direction. A fractional time-step scheme is used for the temporal discretization. We seek results for the behavior of the suspended sediment load induced by broken waves for different particle sizes of bed material. The aim is to identify critical particle sizes for strong uplift and transport of sediment.