We have investigated single-walled carbon nanotube (SWCNT) networks wrapped with the cationic surfactant sodium dodecyl-benzenesulfonate (SBDS) as promising candidates for water detection. This is the first time that the humidity behavior of endohedral Li-doped (Li@) and undoped SWCNTs/SDBS has been shown. We identified a strong and almost monotonic decrease in resistance as humidity increased from 11 to 97%. Sensitivities varied between −3 and 65% in the entire humidity range. Electrical characterization, Raman spectroscopy, and high-resolution transmission electron microscopy (HRTEM) analysis revealed that a combination of the electron donor behavior of the water molecules with Poole-Frenkel conduction accounted for the resistive humidity response in the Li@SWCNT/SDBS and undoped SWCNT/SDBS networks. We found that Li@SWCNTs boosted the semiconducting character in mixtures of metallic/semiconducting SWCNT beams. Moreover, electrical characterization of the sensor suggested that endohedral Li doping produced SWCNT beams with high concentration of semiconducting tubes. We also investigated how frequency influenced film humidity sensing behavior and how this behavior of SWCNT/SDBS films depended on temperature from 20 to 80 ∘ C. The present results will certainly aid design and optimization of SWCNT films with different dopants for humidity or gas sensing in general.

<p>  </p> <p>Cold chain logistics comprise a large portion of transported pharmaceutical medications and raw materials which must be preserved at specified temperatures to maintain consumer safety and efficacy. An immutable record of temperatures of transported pharmaceutical goods allows for mitigation of temperature-related issues of such drugs and their raw components. The recording of this information on a blockchain creates such an immutable record of this information which can be readily accessed by any relevant party. This can allow for any components which have not been kept at the appropriate temperatures to be removed from production. These data can also be used as inputs for smart contracts or for data analytic purposes. </p> <p>A theoretical framework for such a system, referred to as “TempEnsure” is described, which provides digital capture of the internal temperature of temperature-controlled shipping containers. The data are recorded in a blockchain system. Real world testing of this system was not possible due to monetary constraints, but the functional elements of the system, as well as potential improvements for the system, are discussed.</p>

The monitoring of pharmaceuticals, heavy metal, pH and free chlorine concentration in drinking water is important for public health and the environment. However, conventional laboratory-based analytical methods are labor-intensive, expensive, and time consuming. This thesis focuses on developing an integrated, highly sensitive, easy-to-use, and low-cost pharmaceuticals, heavy metal, pH and free chlorine sensing system for drinking water quality monitoring. A low-temperature, solution-processed modification of multi-walled carbon nanotubes (MWCNT) with β-cyclodextrin (βCD) on glassy carbon electrode is developed for detecting low levels of acetaminophen. The adsorption properties of βCD are combined with the high surface area of carbon nanotubes towards enhanced electrochemical sensing of acetaminophen with a limit of detection of 11 nM and linear range from 0.05-300 μM. Also, a systematic investigation is carried out using four types of modified MWCNT-βCD. A novel, one-step approach called Steglich esterification modified MWCNT-βCD results in large effective surface area, and fast electron transfer towards sensitive detection of acetaminophen and 17β-estradiol (E2, primary female sex hormone) in the range of 0.005–20 and 0.01–15 μM, with low detection limits of 3.3 and 2.5 nM, respectively. The similar MWCNT-βCD modified electrodes can also detect heavy metal ion (lead, Pb2+) with a limit of detection of <10 ppb. Low frequency noise behavior of these sensors are studied. A spin-coated Pd/PdO based pH sensor, and amine-modified carbon electrode-based free chlorine sensor are fabricated on a common substrate together with the pharmaceuticals and heavy metal sensors. A Wheatstone-bridge temperature sensor is fabricated based on silicon and PEDOT:PSS on another substrate. All the sensors are connected to an Arduino microcontroller based data acquisition system with a smartphone application interface. The integrated sensing system is easy-to-use, low-cost, and can provide accurate monitoring data with real drinking water samples. / Dissertation / Doctor of Philosophy (PhD) / Low-cost, easy-to-use, and sensitive monitoring system for pharmaceuticals, heavy metal, pH and free chlorine in drinking water is crucial for public health safety. In this thesis, we develop solution-based synthesis of multi-walled carbon nanotubes modified by β-cyclodextrin for electrochemical sensing of pharmaceuticals and heavy metal. The modification approaches are compared and characterized to analyze their electrochemical behavior and sensing performances. The developed sensors are highly sensitive toward the detection of acetaminophen (a widely used pain-killer) and estrogen hormone in drinking water. We also develop a modified spin-coating technique to deposit palladium/palladium oxide films for potentiometric pH sensor, a calibration-free free chlorine sensor based on modified carbon electrode, and a resistive temperature sensor. The developed pH, free chlorine and temperature sensors are highly sensitive, and stable with fast response time. All the sensors are integrated and interfaced with a custom-made and smartphone-controlled electronic readout system for accurate and on-site drinking water quality monitoring at low cost.

Orientadores: Cristiano Monteiro de Barros Cordeiro, Marcos Antonio Ruggieri Franco / Dissertação (mestrado) - Universidade Estadual de Campinas, Instituto de Física Gleb Wataghin / Made available in DSpace on 2018-08-22T12:56:38Z (GMT). No. of bitstreams: 1 PinillaPachon_EdwinGerman_M.pdf: 12541930 bytes, checksum: 74a0367c344ded9c8891d11280568b6b (MD5) Previous issue date: 2013 / Resumo: Nesta dissertação se estudou por simulação numérica o efeito de interferência multimodal (MMI, do inglês "multimode interference") em guias de onda, com atenção especial a fibras ópticas, e a resposta óptica do dispositivo MMI a parâmetros externos como temperatura, curvatura e índice de refração. Dispositivos baseados em MMI são formados, em geral, por três guias de onda concatenados sendo as extremidades compostas de guias monomodo e a parte central composta de um guia que permite a propagação de muitos modos, tipicamente, mais do que três. Nesta situação, na seção multimodo, são formadas reimagens que aproximadamente replicam fase e amplitude do campo óptico de entrada. A observação do espectro de transmissão correspondente à primeira reimagem, em dispositivos MMI, permite desenvolver sensores de índice de refração, temperatura e curvatura. A sensibilidade dos sensores foi avaliada frente às variações do mensurando, ou seja, variações no índice de refração, temperatura e curvatura da estrutura MMI em fibra óptica. / Abstract: In this work the effect of multimodal interference (MMI) in waveguides was studied by numerical simulation. Special attention was given to optical fibers and its the optical response when external parameters such as temperature, curvature or refractive índex were varied. MMI devices are usually formed by connecting three waveguides being the input and output ones single mode waveguides while the middle one is a waveguide that allows the propagation of many optical modes, typically more than three. In this situation re-images that replicate both the phase and the amplitude of the input optical field are formed periodically within the multimode section. The analysis of the transmission spectrum of the first re-image in MMI devices were realized in order to get information about the fiber environment, in particular the surrounding refractive índex, radius of curvature and temperature. The sensors sensitivity was evaluated. / Mestrado / Física / Mestre em Física

The master‘s thesis deals with utilization of infrared camera for temperature measurement of electrical machines. The first part describes non-contact temperature measuring, the second part describes principle of sensors that evaluate quantity of incident infrared radiation. In the next part there is termovision camera SAT-HY 6800 presented and the instructional manual for SAT Report computer programme created. This computer programme is used for analyzing of termovision pictures from the SAT-HY 6800 termovison camera. The chapter 7 describes temperature measuring of one-phase asynchronous motor type J22TO484. The chapter 8 describes temperature measuring of semiconductor components of EC motor G6 series. Both of these motors are produced by ATAS elektromotory Náchod a.s. The last part of the thesis describes creation of animation of one-phase asynchronous motor type J22TO455. The animation was created in 3ds Max computer programme.

Master’s thesis deals with a design and a realization of multifunction board computer for motorcycles. The goal of the device is measuring speed, rotation speed of engine, temperature of ambient, temperature of engine, temperature in intake including signalization of overvoltage and hightemperature. The device is completed by above standard function such as measuring titl of motorcycle, climbing of route, route recording and data transmission to the computer. The thesis includes a complete solution of hardware and software part of the device.

This work is processed like a proposal of heating for a part of seminar centre in Hostětín names Veronika. This current object is built in passive standard. In a part of building there is heating which it is suggested with help by singletube heating system. There is intake of air by recuperator without heating or cooling of air. Heat source is boiler room functional on renewable. Target of this work is analyze of current singletube heating system and find out cause it´s incompletely functionality. Further, design a new heating system which it suppose to be singletube and doubletube heating system.

The thesis is aimed on measurement and modeling of MEMS gyroscopes based on input-output characteristics. The first part briefs the state of the art. The second part is dedicated to measurement methodology. Critical points and sources of uncertainty are discussed and evaluated using measurements or simulations. The last part shows key characteristics of MEMS gyroscopes based on the survey of a group of different sensor types. The results have revealed significant influence of supply voltage that causes bias drift of the gyroscope and bias drift of the internal temperature sensor. The error can be comparable to temperature drift; however, this effect is not addressed in the literature. The second observed effect is temperature dependency of angle random walk. In the last part, a general model of a MEMS gyroscope is rewritten to reflect observed effects. Moreover, the structure is selected to be easily extendable and the coefficients are expressed to allow a comparison of nominal parameters of different sensors.

This thesis is focused on the creation of measuring workplace for remote power supply system. This is the measuring of the workplace, engaged in the processing of measured data, the production of electrical energy made by a photovoltaic panel and wind turbines. In the theoretical part, the reader is familiar with the issue of renewable energy sources. The first chapter is about the energy of the wind. Here is described the emergence of the wind, the basic division of wind power, through the production of electrical energy to the measurement itself. The second chapter deals with the solar energy. This chapter describes the emergence of the solar energy, photoelectric effect, description of characteristic features and related evaluation of the photovoltaic panel. The reader learns the basic distribution photovoltaic panels here and their manufacturing. The third chapter is devoted to measurement methods and specifying the basic conditions for the evaluation of the operation of wind turbines and photovoltaic panel. In the fourth chapter describes the basic data on individual facilities, which have been selected for this thesis and the involvement of the measuring site. There is also included wind power JPT-100 photovoltaic panels A-130 anemometer TX20ETH, pyranometer SG420 and temperature sensor PT100. Measuring software is described in the fifth chapter. In the last chapter, contains the experimental measurements in the selected time interval and the actual evaluation.

No description available.