Soil organic matter (SOM) contains about twice the amount of carbon in the atmosphere. With global changes, the potential shifts in SOM quantity and quality are a major concern. Due to its heterogeneity, SOM remains largely unknown in terms of its molecular composition and responses to climatic events. Traditional bulk soil analysis cannot depict the structural changes in SOM. This thesis applies two complementary molecular-level methods, i.e., SOM biomarker gas chromatography/mass spectrometry (GC/MS) and nuclear magnetic resonance (NMR) spectroscopy, to examine the origin and degradation of various SOM components in grassland and temperate forest soils, and to investigate the shifts in microbial community and SOM composition with both laboratory- and field-simulated global changes, such as frequent freeze-thaw cycles, increasing soil temperatures, elevated atmospheric CO2 levels, and nitrogen (N) deposition. This thesis has several major findings. First, as the most active component in soil, microbial communities were sensitive to substrate availability changes resulting from prolonged soil incubation, freeze-thaw-induced cell lyses, N fertilization and increased plant inputs under elevated CO2 or soil warming. Microbial community shifts have direct impacts on SOM decomposition patterns. For instance, an increased fungal community was believed to contribute to the enhanced lignin oxidation in an in situ soil warming experiment as the primary degrader of lignin in terrestrial environments. Second, contrast to the conventional belief that aromatic structure was recalcitrant and stable in SOM, ester-bond aliphatic lipids primarily originating from plant cutin and suberin were preferentially preserved in the Canadian Prairie grassland soil profiles as compared with lignin-derived phenols. Cutin- and suberin-derived compounds also demonstrated higher stability during soil incubation. With an increased litter production under elevated CO2 or global warming, an enrichment of alkyl structures that had strong contributions from leaf cuticles was observed in the Duke Forest Free Air CO2 Enrichment (FACE) and soil warming experiments, suggesting an accumulation of plant-derived recalcitrant carbon in the soil. These results have significant implications for carbon sequestration and terrestrial biogeochemistry. Overall, this thesis represents the first of its kind to employ comprehensive molecular-level techniques in the investigation of SOM structural alterations under global changes.

Soil organic matter (SOM) contains about twice the amount of carbon in the atmosphere. With global changes, the potential shifts in SOM quantity and quality are a major concern. Due to its heterogeneity, SOM remains largely unknown in terms of its molecular composition and responses to climatic events. Traditional bulk soil analysis cannot depict the structural changes in SOM. This thesis applies two complementary molecular-level methods, i.e., SOM biomarker gas chromatography/mass spectrometry (GC/MS) and nuclear magnetic resonance (NMR) spectroscopy, to examine the origin and degradation of various SOM components in grassland and temperate forest soils, and to investigate the shifts in microbial community and SOM composition with both laboratory- and field-simulated global changes, such as frequent freeze-thaw cycles, increasing soil temperatures, elevated atmospheric CO2 levels, and nitrogen (N) deposition. This thesis has several major findings. First, as the most active component in soil, microbial communities were sensitive to substrate availability changes resulting from prolonged soil incubation, freeze-thaw-induced cell lyses, N fertilization and increased plant inputs under elevated CO2 or soil warming. Microbial community shifts have direct impacts on SOM decomposition patterns. For instance, an increased fungal community was believed to contribute to the enhanced lignin oxidation in an in situ soil warming experiment as the primary degrader of lignin in terrestrial environments. Second, contrast to the conventional belief that aromatic structure was recalcitrant and stable in SOM, ester-bond aliphatic lipids primarily originating from plant cutin and suberin were preferentially preserved in the Canadian Prairie grassland soil profiles as compared with lignin-derived phenols. Cutin- and suberin-derived compounds also demonstrated higher stability during soil incubation. With an increased litter production under elevated CO2 or global warming, an enrichment of alkyl structures that had strong contributions from leaf cuticles was observed in the Duke Forest Free Air CO2 Enrichment (FACE) and soil warming experiments, suggesting an accumulation of plant-derived recalcitrant carbon in the soil. These results have significant implications for carbon sequestration and terrestrial biogeochemistry. Overall, this thesis represents the first of its kind to employ comprehensive molecular-level techniques in the investigation of SOM structural alterations under global changes.

The structural behaviour of pavements in cold regions can considerably be affected by seasonal variation in environmental factors such as temperature and moisture content. Along with the destructive effect of heavy traffic loads, climatic and environmental factors can considerably contribute to pavement deterioration. These factors can influence the structural and functional capacity of the pavement structures which, as a result, can trigger and accelerate pavement deterioration mechanisms. Studies on the influence of variation of the environmental factors on the response and behaviour of pavement materials have shown that proper consideration to these factors must be given in realistic pavement design and analysis. In flexible pavement structures, particularly with a thin hot mix asphalt (HMA) layer, unbound materials and subgrade soil largely contribute to the overall structural behaviour of the pavement system. In unbound materials, moisture content and its variation can significantly affect pavement layer stiffness and permanent deformation characteristics. Therefore, the moisture condition of pavements and its influence on the mechanical behaviour of pavement materials has been of interest among the pavement research community. A proper understanding of moisture transformation in pavement systems and its effects on pavement performance are important for mechanistic pavement design. The present summary of this doctoral thesis is based on four main parts. The first part of the thesis covers field measurements and findings from a test section along county road 126 in southern Sweden and consists of two journal papers (paper I and II) tackling different aspects of the research topic. This test section is located in a relatively wet ground condition and consists of a thin flexible pavement structure with a deep drainage system. It is instrumented with subsurface temperature, volumetric moisture content and groundwater probes. The mechanical response of the pavement structure was investigated using Falling Weight Deflectometer (FWD) measurements. The second part of the thesis (paper III and IV) are based on laboratory experiments and investigates different recent approaches that have been proposed to apply principles of unsaturated soil mechanics for incorporating seasonal variation of moisture content into the resilient modulus models using matric suction. The third part of the thesis (paper V) builds a bridge that spans between the laboratory and field investigations with an attempt to evaluate one of the predictive models presented in Paper III. The fourth part of the thesis (paper VI) mainly focuses on the laboratory-based investigation of the permanent deformation characteristic of subgrade soils. In this part, the permanent deformation characteristics of two different silty sand subgrade soils were investigated and modelled using the data obtained from repeated load traxial tests. Paper I mainly focuses on the spring-thaw weakening of the pavement structure. The environmental data collected using different sensors and the FWD tests were used to investigate variations in moisture content with thaw penetration and its influence on the stiffness of unbound layers and the pavement’s overall bearing capacity. Using the backcalculated layer stiffness and corresponding in situ moisture measurements in the unbound layers, a degree of saturation-based moisture-stiffness model was developed for the granular material and the subgrade. In Paper II, the drainage system of the structure was manually clogged during a three month period in summer to raise the groundwater level and increase the moisture content of the layers. Along with the subsurface groundwater level and moisture content monitoring, the structural response of the pavement was studied. In this research work, the FWD tests were conducted at three different load levels. The stress dependent behaviour of the unbound granular layer and the subgrade soil were further studied using the multilevel loads FWD test data. Additionally, parameters of a nonlinear stress-dependent stiffness model were backcalculated and their sensitivity to in situ moisture content was studied. In Paper III and IV, series of suction-controlled repeated load triaxial (RLT) tests were conducted on two silty sand (SM) subgrade materials. Several resilient modulus prediction models that account for seasonal moisture content variation through matric suction were summarized and after optimizing the model parameters, the capability of the prediction models in capturing the material response were evaluated. In Paper V, an attempt was made to evaluate the proficiency of one of the suction-resilient modulus models using the field moisture content and FWD measurements from the Torpsbruk test site. The backcalculated subgrade stiffness dataset at different moisture contents were compared with resilient modulus models obtained from the suction-resilient modulus predictive model. Paper VI presents an evaluation of several permanent deformation models for unbound pavement materials that incorporate the time-hardening concept using a series of multistage repeated load triaxial (RLT) tests conducted on silty sand subgrade materials. The permanent deformation tests were conducted at four different moisture contents with pore suctions measurement throughout the test. The effect of moisture content (matric suction) on the permanent deformation characteristics of the materials and the predictive model parameters were further investigated. / <p>QC 20150324</p>

Global warming is forecast to cause significant thawing of the permafrost that surrounds lakes and rivers across the Arctic, with potential wide-scale effects on the water quality and biotic characteristics of these water bodies. The benthic environment is believed to be especially sensitive to permafrost-induced ecological change, and this has been the focus of recent field intensive research. Five lakes disturbed and three lakes undisturbed by retrogressive permafrost thaw slumps were sampled during late summer of 2006 to assess the potential effects of slumping on benthos. Water quality parameters, submerged macrophytes, benthic invertebrates, and sediment were collected. A significant difference (p < 0.05) between disturbed and undisturbed lakes was found for macrophyte, invertebrates, underwater light attenuation, and some sediment variables. The results suggest that thaw slumps can affect submerged macrophyte biomass, benthic invertebrate abundance, and also community structure in upland tundra lakes. Such differences between undisturbed and disturbed lakes are suggested to be related to changes in water column transparency, sediment nutrient availability, soil and terrestrial vegetation loading from the landscape, and changes in slope angle of the littoral zone.

On s'intéresse dans le présent travail au comportement au gel des sols fins limono-argileux traités à la chaux seule, sols valorisables qui sont couramment rencontrés sur les chantiers de terrassement. Trois sols appartenant aux classifications A1, A2, A3 selon la norme NF P 11300, ont été choisis pour cette étude. Ces sols sont traités à 3 dosages en chaux correspondant à 3 objectifs : 1) amélioration (dosage en chaux minimal), 2) stabilisation et insensibilité à l'eau (dosage en chaux intermédiaire), 3) stabilisation et résistance au gel (dosage en chaux le plus élevé). Les sols traités sont ensuite conservés pendant quatre périodes de cure : 7 jours, 28 jours, 90 jours et 365 jours. Les deux processus de gel - le géligonflement et la gélifraction sont étudiés, parallèlement à l'évaluation des performances mécaniques, hydrauliques et microstructurales. Les résultats expérimentaux ont montré que les propriétés hydrauliques (la succion au front de gel, sp et la conductivité hydraulique à l'état non-saturé, kunsat) sont les paramètres qui gouvernent le phénomène de géligonflement des sols, traités ou non. Les résultats ont également mis en évidence le lien direct existant entre la microstructure (la distribution porale) et les propriétés hydrauliques du sol, principalement en termes de capacité de rétention d'eau et conductivité hydraulique. Le traitement augmente les performances mécaniques des sols d'une part, et amène d'autre part à des modifications de leur microstructure ; ceci induit des changements vis-à-vis de leur sensibilité au gel. Les sols sont plus gélifs directement après le traitement, cette sensibilité au gel diminuant avec le temps de cure. Une modélisation simple permettant d'estimer le gonflement au gel à partir de la succion au front de gel et de la valeur de conductivité hydraulique à l'état non-saturé a été proposée et validée. Vu que la détermination de la conductivité hydraulique à l'état non-saturé n'est pas un essai couramment pratiqué au sein de la plupart des laboratoires, un critère basé sur la succion au front de gel, sp, et la conductivité hydraulique à l'état saturé, ksat a été proposé pour évaluer la sensibilité des sols au gel. L'essai de gélifraction consiste à évaluer un coefficient de résistance de l'éprouvette de sol après 10 cycles de gel/dégel, RFT (%) - « retained strength factor after freeze-thaw testing ». Les résultats expérimentaux montrent que la valeur RFT des sols traités varie de 0% (lorsque les éprouvettes de sol perdent totalement leur résistance à la compression simple et sont détruites après 10 cycles de gel/dégel) à 90%. Quand RFT ≥ 60%, aucune dégradation visuelle de la surface des éprouvettes des sols traités n'est constatée. Ainsi, cette valeur est proposée comme critère d'acceptation des matériaux constitutifs d'une couche de forme subissant le gel avant son recouvrement. L'étude de l'effet du nombre des cycles de gel/dégel montre une diminution importante de la performance mécanique (RFT) durant trois premiers cycles de gel/dégel, et ce paramètre se stabilisant après 10 cycles. A l'aide de la technique de µ Tomographie X, l'endommagement interne des éprouvettes de sol ayant subi des cycles de gel/dégel a été quantifié. Une corrélation directe entre la diminution de performance mécanique et l'augmentation de l'indice de l'endommagement de l'éprouvette a été mise en évidence. Enfin, un modèle d'endommagement permettant d'évaluer la dégradation de la performance mécanique avec l'augmentation de l'indice d'endommagement a été établi / The present work deals with the behaviour of fine-grained silty and clayey soils treated with lime under frost. Those soils are frequently encountered in earthworks. Three soils corresponding to A1, A2, A3 classes according French NF P 11-300 standard were chosen for this study. These soils were treated with 3 lime dosages corresponding to three objectives: 1) improvement (minimum dosage), 2) stabilization and insensitivity to water (intermediate dosage), 3) stabilization and frost resistance (highest dosage). Lime-treated soils were subsequently cured for different times: 7, 28, 90, 365 days. Two frost processes, frost heave and freeze-thaw cycles, were applied in parallel with the assessment of mechanical, hydraulic and microstructural properties. Experimental results evidenced that it is the hydraulic properties (suction at frost front, sp and unsaturated hydraulic conductivity, kunsat) that govern the frost heave phenomenon of soils, treated or not. In addition, this study demonstrates the direct link between the microstructure (the pore size distribution) and the hydraulic properties (water retention curve and hydraulic conductivity). The treatment on one hand improves the mechanical performances of soils, and on the other hand modify their microstructure, and thus changes their frost sensitivity. The frost susceptibility increases directly after treatment, and then decreases with curing time. Based on the suction at frost front and the unsaturated hydraulic conductivity, a simple model was proposed and validated allowing to estimate the frost heave. Considering that the determination of unsaturated hydraulic conductivity is not a test commonly performed by most laboratories, a criterion based on the suction at frost front and the saturated hydraulic conductivity was proposed to estimate the frost sensibility of soils. The second frost resistance test consists of measuring the retained strength factor after 10 freeze-thaw cycles, RFT (%). The results obtained show that RFT of lime treated soil varies from 0% (when soil specimen completely loses its resistance and collapses after 10 freezethaw cycles) to 90%. When RFT is higher than 60%, no visual damage was observed on the specimen surface; consequently, this value is proposed as a criterion for acceptance of lime treated soil in capping layer before covering. In addition, the study of effect of freeze-thaw cycles showed a significant decrease of mechanical performance (RFT) during the first three cycles, and a stabilization after 10 cycles. Using X-ray Tomography, the intern damage of specimens due to freeze-thaw cycles was quantified. A correlation between the decrease of mechanical performance and the increase of damage index was evidenced. A model was then developed to evaluate the degradation of mechanical performance with the increase of damage index

The presented dissertation concerns selected topics on flat construction in the 60's - experiments and prefabricated housing estates - and examines them closely in four different layers - political, ideological, architectonic and social. The work is structured into four main chapters, which constitute four pillars to uncover the history of flat construction and its context. The initial hypothesis of the dissertation was that the birth of panel housing estates at the end of the 50's, as well as its form and content in the upcoming decade, was influenced by the different starting points of the four mentioned layers. The viewpoint of state socialism and its ideology stemmed from the situation, when architecture in the whole socialistic block seized to be the instrument of Stalinist political representation in the spirit of the socialist realism and it became an important instrument of social reform on the promoted path to communism. This opinion, projected on an economic level, lead to an assumption that an affordable and high-quality collective housing makes the society effectively economically modernized. The living in these housing estates was intended to become the "display window" of the socialist lifestyle as well as the means of a morally higher type of consumer society. In the atmosphere of...

On s'intéresse dans le présent travail au comportement au gel des sols fins limono-argileux traités à la chaux seule, sols valorisables qui sont couramment rencontrés sur les chantiers de terrassement. Trois sols appartenant aux classifications A1, A2, A3 selon la norme NF P 11300, ont été choisis pour cette étude. Ces sols sont traités à 3 dosages en chaux correspondant à 3 objectifs : 1) amélioration (dosage en chaux minimal), 2) stabilisation et insensibilité à l'eau (dosage en chaux intermédiaire), 3) stabilisation et résistance au gel (dosage en chaux le plus élevé). Les sols traités sont ensuite conservés pendant quatre périodes de cure : 7 jours, 28 jours, 90 jours et 365 jours. Les deux processus de gel - le géligonflement et la gélifraction sont étudiés, parallèlement à l'évaluation des performances mécaniques, hydrauliques et microstructurales. Les résultats expérimentaux ont montré que les propriétés hydrauliques (la succion au front de gel, sp et la conductivité hydraulique à l'état non-saturé, kunsat) sont les paramètres qui gouvernent le phénomène de géligonflement des sols, traités ou non. Les résultats ont également mis en évidence le lien direct existant entre la microstructure (la distribution porale) et les propriétés hydrauliques du sol, principalement en termes de capacité de rétention d'eau et conductivité hydraulique. Le traitement augmente les performances mécaniques des sols d'une part, et amène d'autre part à des modifications de leur microstructure ; ceci induit des changements vis-à-vis de leur sensibilité au gel. Les sols sont plus gélifs directement après le traitement, cette sensibilité au gel diminuant avec le temps de cure. Une modélisation simple permettant d'estimer le gonflement au gel à partir de la succion au front de gel et de la valeur de conductivité hydraulique à l'état non-saturé a été proposée et validée. Vu que la détermination de la conductivité hydraulique à l'état non-saturé n'est pas un essai couramment pratiqué au sein de la plupart des laboratoires, un critère basé sur la succion au front de gel, sp, et la conductivité hydraulique à l'état saturé, ksat a été proposé pour évaluer la sensibilité des sols au gel. L'essai de gélifraction consiste à évaluer un coefficient de résistance de l'éprouvette de sol après 10 cycles de gel/dégel, RFT (%) - « retained strength factor after freeze-thaw testing ». Les résultats expérimentaux montrent que la valeur RFT des sols traités varie de 0% (lorsque les éprouvettes de sol perdent totalement leur résistance à la compression simple et sont détruites après 10 cycles de gel/dégel) à 90%. Quand RFT ≥ 60%, aucune dégradation visuelle de la surface des éprouvettes des sols traités n'est constatée. Ainsi, cette valeur est proposée comme critère d'acceptation des matériaux constitutifs d'une couche de forme subissant le gel avant son recouvrement. L'étude de l'effet du nombre des cycles de gel/dégel montre une diminution importante de la performance mécanique (RFT) durant trois premiers cycles de gel/dégel, et ce paramètre se stabilisant après 10 cycles. A l'aide de la technique de µ Tomographie X, l'endommagement interne des éprouvettes de sol ayant subi des cycles de gel/dégel a été quantifié. Une corrélation directe entre la diminution de performance mécanique et l'augmentation de l'indice de l'endommagement de l'éprouvette a été mise en évidence. Enfin, un modèle d'endommagement permettant d'évaluer la dégradation de la performance mécanique avec l'augmentation de l'indice d'endommagement a été établi / The present work deals with the behaviour of fine-grained silty and clayey soils treated with lime under frost. Those soils are frequently encountered in earthworks. Three soils corresponding to A1, A2, A3 classes according French NF P 11-300 standard were chosen for this study. These soils were treated with 3 lime dosages corresponding to three objectives: 1) improvement (minimum dosage), 2) stabilization and insensitivity to water (intermediate dosage), 3) stabilization and frost resistance (highest dosage). Lime-treated soils were subsequently cured for different times: 7, 28, 90, 365 days. Two frost processes, frost heave and freeze-thaw cycles, were applied in parallel with the assessment of mechanical, hydraulic and microstructural properties. Experimental results evidenced that it is the hydraulic properties (suction at frost front, sp and unsaturated hydraulic conductivity, kunsat) that govern the frost heave phenomenon of soils, treated or not. In addition, this study demonstrates the direct link between the microstructure (the pore size distribution) and the hydraulic properties (water retention curve and hydraulic conductivity). The treatment on one hand improves the mechanical performances of soils, and on the other hand modify their microstructure, and thus changes their frost sensitivity. The frost susceptibility increases directly after treatment, and then decreases with curing time. Based on the suction at frost front and the unsaturated hydraulic conductivity, a simple model was proposed and validated allowing to estimate the frost heave. Considering that the determination of unsaturated hydraulic conductivity is not a test commonly performed by most laboratories, a criterion based on the suction at frost front and the saturated hydraulic conductivity was proposed to estimate the frost sensibility of soils. The second frost resistance test consists of measuring the retained strength factor after 10 freeze-thaw cycles, RFT (%). The results obtained show that RFT of lime treated soil varies from 0% (when soil specimen completely loses its resistance and collapses after 10 freezethaw cycles) to 90%. When RFT is higher than 60%, no visual damage was observed on the specimen surface; consequently, this value is proposed as a criterion for acceptance of lime treated soil in capping layer before covering. In addition, the study of effect of freeze-thaw cycles showed a significant decrease of mechanical performance (RFT) during the first three cycles, and a stabilization after 10 cycles. Using X-ray Tomography, the intern damage of specimens due to freeze-thaw cycles was quantified. A correlation between the decrease of mechanical performance and the increase of damage index was evidenced. A model was then developed to evaluate the degradation of mechanical performance with the increase of damage index

This dissertation thesis focuses on a topic that is of growing interest among scholars, and for which there is still plenty of room for analysis and interpretation, namely the role of the Ukrainian Sixtiers during the Khrushchev Thaw in the USSR in the period 1956-1964. This cultural phenomenon is analysed within a broader socio-cultural context with the help of the approach of colonial studies. The key research question is "How did the worldview of the Sixtiers develop during the Khrushchev Thaw (1956-1964) from the point of view of colonial studies and how was this reflected in their literary works?" The first chapter describes the historical, political and cultural context of this period. It includes an analysis of the circumstances surrounding the proclamations made in Khrushchev's secret speech in 1956, the beginning of the policy of de-Stalinization, and its impact on the political and cultural life in Soviet Ukraine. Particular attention is paid to the development of the official discourse of socialist realism as an official and dominant cultural concept, which was to be applied in artistic and literary works. The main principle of socialist realism, so-called "internationalism", is analysed in terms of its role as an element of colonial discourse. The second chapter focuses on the...

This diploma thesis describes research and following development of lightweight cement mortars with alternative raw materials. Attention was focused on study of the effects of extreme influences such as high temperature (up to 1200 °C), freeze-thaw and agressive sulfur dioxide. Verification of durability of developed mortars was realized using physical and mechanical tests (density and strength), physical and chemical methods (computed tomography) and scanning electron microscopy. Assessment of durability was realized in a longer period of time (90 days).

The diploma thesis deals with different methods of determining levels of degradation of concrete due to freezing, also considering the options of freeze thaw resistance determination in structure. At first the properties of concrete and possible mechanisms of concrete degradation are described – mainly the effects of freezing water in the inner structure and of the combination of freezing water and de-icing chemicals on the surface. Principle and properties of air-entrained concrete are also mentioned. An overview of the approaches that current standards use to determine the freeze-thaw resistance of concrete is listed, followed by description of the tests that are used on air-entrained concrete specimens in the main part of the thesis. A portion of the test specimens was made in moulds while the rest was obtained from structure (concrete block). The non-destructive tests used are evaluated in several different ways and their results are compared with the destructive tests. Comparison and evaluation of different approaches used to determine the freeze-thaw resistence of concrete are the main outcome of this thesis.