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Studded tires are widely used in Nordic areas like Sweden for its good road-gripping performance on icy roads. However, the pavement wear and aerosol caused by studded tires become big concerns considering the usage of studded tires. Studies are carried to quantify the wear and aerosol generated during the process. Among the existing test rigs, most of them which includes a full wheel as specimen have relatively large size. This thesis aims on designing a full wheel testrig with small scale which can fit in a common lab room and be easy to operate. / Dubbdäck används i stor utsträckning i nordiska områden som Sverige för sin goda väggreppande prestanda på isiga vägar. Trottoarslitage och aerosol som orsakas av dubbdäck blir dock stora bekymmer med tanke på användning av dubbdäck. Studier genomförs för att kvantifiera slitage och aerosol som genereras under processen. Bland de befintliga testriggarna har de flesta, som innehåller ett helhjul som prov, en relativt stor storlek. Denna avhandling syftar till att designa en fullhjulstestrigg med liten skala som kan passa i ett gemensamt labbrum och vara lätt att använda.

Silicones elastomers are widely used all over the world due to their unusual properties when compared to their carbon-based counterparts. Synthetic methods for their synthesis are still quite limited and the traditional silicone products are not able to completely meet the requirement for modern materials. Silicone elastomers with customized structures and with higher levels of sustainability will be the research focus for the development of next generation materials. The element sulfur and its functional groups are growing players in modern polymer and materials science, since sulfur reactions are exceptionally versatile. The incorporation of sulfur reactions into the design and preparation of silicone materials can lead to silicones with unique properties for various research interests. Initial exploration was focused on the creation of general and simple methods for 3D printing silicone elastomers using thiol-ene chemistry. However, silicone inks suitable for 3D printing are still quite limited. Photo-initiated thiol-ene chemistry was proposed to design a rapid cure silicone ink for extrusion 3D printing. Unlike other radical reactions, the relatively oxygen insensitive thiol-ene was able to provide the necessary rapid reaction rate and build up the necessary viscosity for practical printing in less than 2 seconds in the presence of air. Various customized silicone structures with different moduli were obtained with a relative fast printing speed. The use of thiol oxidation reactions in the synthesis of silicone elastomers is also demonstrated in this thesis. Reductive cleavage of the resulting disulfide bridge was successfully performed with the presence of hydrosilane and B(C6F5)3 catalyst. Herein, a synthetic method to reversible silicone elastomers based on the disulfide linkage is described. This method could be extended to cleave the disulfide and polysulfide linkage in used automotive rubber materials. Various kinds of sulfur-cured rubbers were successfully devulcanized to polymeric oil. This simple and efficient method could potentially offer a solution for the huge amount of tire waste produced every year. Finally, a new method for preparing thermoplastic silicone elastomers with ionic linkages is reported. A novel dicarboxylic acid-modified silicone was synthesized though thiol-Michael additions. The resulting ionic crosslinked networks were built though the neutralization between carboxylic and amino silicone. Thermoplastic silicone elastomers with unique viscoelastic behavior can be obtained. In summary, the thesis demonstrates that sulfur chemistry is an exceptional synthetic tool for the silicone chemist. / Thesis / Doctor of Philosophy (PhD)

Applications like military, agriculture, and extra-planetary explorations require the successful navigation of vehicles across different types of terrain like soil, mud, and snow. As the properties of the terrain heavily influence the interaction with the tire, it is necessary to characterize the terrain from a tire performance and vehicle mobility perspective. Failure to properly understand the tire-terrain interaction can lead to undesirable conditions like loss of vehicle mobility due to excessive sinkage. As a result, it is essential to understand the tire terrain interaction between an off-road tire and a sandy terrain. This study was done to assess the performance of tires in both pure slip (only traction and braking) and combined slip conditions (steering and acceleration). A single-wheel indoor test rig was used to conduct tests under different conditions and a force transducer was used to capture the forces and moments generated in the tire hub. In addition to this, the tire footprint was captured with the help of a light-based 3-D scanner. Key parameters were defined in the 3D scan, and these parameters were correlated to the input test conditions. Additionally, a grid of force sensors was made, and measurements of the normal force acting at a depth below the undisturbed terrain were taken. Inferences were made about the linear speed of the wheel and the length of the pressure bulb under the tire. / Master of Science / Several applications like military, extra-terrestrial exploration, and motor racing require vehicles to navigate off-road terrains like soil, snow, and ice. The tire interacts with these off-road terrains very differently from the way it interacts with the road. It is important to understand this interaction correctly as this interaction generates all the forces needed by a vehicle to perform various maneuvers like acceleration, braking, and turning. If not accounted for properly, there can be undesirable conditions like loss of vehicle mobility due to excessive sinkage in sand. Tests were performed where an off-road tire ran on a non-cohesive, loose soil under different slip ratios, slip angles, and camber angles in an indoor test rig. The forces and moments acting on the tire during the tests were measured and its variation with input conditions was studied. A light-based 3D scanner was used to capture the tire rut profile on the soil after each test. The important parameters of the tire rut were defined and the variation of these parameters with input parameters were studied. Additionally, the stresses developed below the soil surface were measured with the help of a sensor grid, which was also used to verify the linear speed of the tire and infer the length of the zone inside the soil that is affected by the tire.

Fiber reinforced polymer (FRP) composites are considered very promising for infrastructure applications such as repair, rehabilitation and replacement of deteriorated bridge decks. However, there is lack of proper understanding of the structural behavior of FRP decks. For example, due to the localization of load under a truck tire, the conventionally used uniform patch loading is not suitable for performance evaluation of FRP composite deck systems with cellular geometry and relatively low modulus (compared to concrete decks). In this current study, a simulated tire patch loading profile has been proposed for testing and analysis of FRP deck. The tire patch produced significantly different failure mode (local transverse failure under the tire patch) compared to the punching-shear mode obtained using the conventional rectangular steel plate. The local response of a cellular FRP composite deck has been analyzed using finite element simulation and results are compared with full scale laboratory experiment of bridge deck and structure. Parametric studies show that design criteria based on global deck displacement is inadequate for cellular FRP deck and local deformation behavior must be considered. The adhesive bonding method is implemented for joining of bridge deck panels and response of structural joint analyzed experimentally. Strength, failure mode and fatigue life prediction methodologies for a cellular FRP bridge deck are presented in this dissertation. / Ph. D.