The need for wireless connectivity is ever increasing while conventional radio frequency (RF) communications are limited by the amount of available spectrum. Visible light communications (VLC) are emerging as a promising complementary to the RF wireless, thanks to the enormous available bandwidth in the visible spectrum. Moreover, VLC integrates into the ubiquitous illumination infrastructures to satisfy the need for wireless connectivity indoors. Commercially available light-emitting diodes (LEDs) are low-cost, simple, and have a small modulation bandwidth. For the small modulation bandwidth, VLC systems must enjoy high spectral efficiency to achieve high-rate transmission. Additionally, VLC systems must have high power efficiency to help preserve the critical advantage of LEDs for illumination applications. Furthermore, since LED luminaires are constrained by cost, deployed VLC systems must be low-complexity. Indoor VLC channels are dispersive due to multipath propagation indoors and due to the limited bandwidth of the optoelectronics. However, time-domain equalization on such channels can be prohibitively expensive for long serials. These challenges motivate extensive research on optical orthogonal frequency division multiplexing (OFDM). Given those problems and challenges, this thesis introduces novel spectrum- and power-efficient optical OFDM modulation schemes to implement with low complexity in VLC systems. Firstly, absolute value layered asymmetrically clipped optical OFDM (ALACO-OFDM) is presented to achieve high spectral efficiency and high power efficiency with fewer layers, thus requiring low complexity. Compared to its counterparts, ALACO-OFDM can achieve higher spectral efficiency and information rate even with fewer layers. Antisymmetry-constructed clipped optical OFDM (AC-OFDM) is then introduced as a novel low-complexity modulation scheme. To enhance the spectral efficiency and retain low-complexity, layered AC-OFDM (LAC-OFDM) is introduced, consisting of several layers of AC-OFDM signals. LAC-OFDM is shown to be less complex compared to its state-of-the-art counterparts. Concerning a practical VLC dispersive channel, low-complexity layered ACO-OFDM (L-LACO) is introduced with simple equalization. Mathematically, L-LACO generates identical signals to the existing layered asymmetrically-clipped optical OFDM (LACO-OFDM); however, it requires only half arithmetic operations at both the transmitter and the receiver. For a practical bandlimited VLC dispersive channel, the previous optical OFDM modulation schemes will be no longer non-negative after interpolation with sinc(t) pulse. This thesis presents Kramers-Kronig (KK) optical OFDM (KKO-OFDM) to enhance the spectral efficiency and power efficiency for such bandlimited VLC channels. The KKO-OFDM transmit signal is constructed to be real-valued, non-negative, and strictly bandlimited. Numerical results show that KKO-OFDM outperforms DCO-OFDM and LACO-OFDM in bandlimited VLC channels in terms of optical power efficiency. / Thesis / Doctor of Philosophy (PhD) / Visible light communications (VLC) integrate into the ubiquitous light-emitting diode (LED) luminaires, providing lighting and communication simultaneously. Commercially available LEDs are low-cost, simple, and have a limited modulation bandwidth. These LEDs demand that VLC orthogonal frequency division multiplexing (OFDM) modulation schemes be spectrum- and power-efficient with low complexity. Concerning these challenges, this thesis presents a novel spectrum- and power-efficient VLC OFDM scheme with low complexity. Firstly, absolute value layered asymmetrically clipped optical OFDM (ALACO-OFDM) is presented to achieve high spectral and power efficiency while requiring fewer layers. Then layered antisymmetry-constructed clipped optical OFDM (LAC-OFDM) is introduced, which requires low complexity as compared to existing layered asymmetrically-clipped optical OFDM (LACO-OFDM). Given a VLC dispersive channel, low-complexity LACO-OFDM (L-LACO) is furthermore introduced with simple equalization but generates an identical signal to the existing LACO-OFDM. Finally, for a bandlimited VLC channel, Kramers-Kronig optical OFDM (KKO-OFDM) is presented to achieve high spectral and power efficiency. The ALACO-OFDM and LAC-OFDM work in flat VLC line-of-sight links while L-LACO in VLC dispersive links and KKO-OFDM in bandlimited VLC dispersive links with simple equalizer.

Visible light communication (VLC) systems take advantage of ubiquitous light-emitting diodes (LED) and leverage existing illumination infrastructure to provide broadband optical communication links. Multiple-input multiple-output (MIMO) VLC systems are among the well studied topics in VLC research. However, most traditional MIMO VLC systems require accurate alignment and have to adjust to different magnifications at various link distances. Consequently, the alignment and calibration modules increase the complexity of the receiver structures. A pixelated MIMO VLC system is introduced in this thesis, which transmits a series of time-varying coded images that can be received and decoded by commercial digital cameras. Using a convex lens placed in front of the transmitter at its focal length, the system exploits the Bokeh effect to obtain fixed-scale images at all link distances. Compared with traditional pixelated MIMO VLC systems, which send information directly in space, this spatial-angular mapping system sends information in different angles instead. In contrast to the complex receiver structures in traditional setups, the proposed system can capture fixed-scale images with a simple receiver requiring no re-focusing as the camera moves. The channel model of the system is measured and modeled and a rateless code is applied to track the truncation of receive images for various link ranges and angular offsets. A proof-of-concept optical communication system is implemented with an LCD display and a high speed CMOS camera. Performance of the system is measured and analysed. The experimental system can achieve a throughput of approximately 10 bit per frame over 90 cm. This fixed-scale pixelated MIMO wireless optical communication system provides a less expensive option for short-range indoor broadcasting optical links and inter-vehicle communications due to its mobility, stability and simpler receiver structure compared to traditional designs in different working conditions. / Thesis / Master of Applied Science (MASc)

The growing demand for wireless communication capacity and the overutilisation of the conventional radio frequency (RF) spectrum have inspired research into using alternative spectrum regions for communication. Using optical wireless communications (OWC), for example, offers significant advantages over RF communication in terms of higher bandwidth, lower implementation costs and energy savings. In OWC systems, the information signal has to be real and non-negative. Therefore, modifications to the conventional communication algorithms are required. Multicarrier modulation schemes like orthogonal frequency division multiplexing (OFDM) promise to deliver a more efficient use of the communication capacity through adaptive bit and energy loading techniques. Three OFDM-based schemes – direct-current-biased OFDM (DCO-OFDM), asymmetrically clipped optical OFDM(ACO-OFDM), and pulse-amplitude modulated discrete multitone (PAM-DMT) – have been introduced in the literature. The current work investigates the recently introduced scheme subcarrier-index modulation OFDM as a potential energy-efficient modulation technique with reduced peak-to-average power ratio (PAPR) suitable for applications in OWC. A theoretical model for the analysis of SIM-OFDMin a linear additive white Gaussian noise (AWGN) channel is provided. A closed-form solution for the PAPR in SIM-OFDM is also proposed. Following the work on SIM-OFDM, a novel inherently unipolar modulation scheme, unipolar orthogonal frequency division multiplexing (U-OFDM), is proposed as an alternative to the existing similar schemes: ACO-OFDMand PAM-DMT. Furthermore, an enhanced U-OFDMsignal generation algorithm is introduced which allows the spectral efficiency gap between the inherently unipolar modulation schemes – U-OFDM, ACO-OFDM, PAM-DMT – and the conventionally used DCO-OFDM to be closed. This results in an OFDM-based modulation approach which is electrically and optically more efficient than any other OFDM-based technique proposed so far for intensity modulation and direct detection (IM/DD) communication systems. Non-linear distortion in the optical front-end elements is one of the major limitations for high-speed communication in OWC. This work presents a generalised approach for analysing nonlinear distortion in OFDM-based modulation schemes. The presented technique leads to a closed-form analytical solution for an arbitrary memoryless distortion of the information signal and has been proven to work for the majority of the known unipolar OFDM-based modulation techniques - DCO-OFDM, ACO-OFDM, PAM-DMT and U-OFDM. The high-speed communication capabilities of novel Gallium Nitride based μm-sized light emitting diodes (μLEDs) are investigated, and a record-setting result of 3.5Gb/s using a single 50-μm device is demonstrated. The capabilities of using such devices at practical transmission distances are also investigated, and a 1 Gb/s link using a single device is demonstrated at a distance of up to 10m. Furthermore, a proof-of-concept experiment is realised where a 50-μm LED is successfully modulated using U-OFDM and enhanced U-OFDM to achieve notable energy savings in comparison to DCO-OFDM.

Titania-based photocatalysts have been extensively studied for the oxidative photodestruction of organic pollutants in wastewaters, releasing non-toxic substances such as CO2, HCl, and water. However, commercial exploitation of this process is limited by the fact that titania is only active under UV irradiation (wavelength below about 388 nm), which is only less than 5% of solar light energy. Sol-gel synthesised catalyst specimens were characterised to determine the correlation between preparation conditions on morphology (XRD, SEM), optical (bandgap energy level) and physicochemical properties (BET surface area, pore volume, acid site density, acid site strength and type) of the photocatalysts. These spesific properties would then be linked to their photoactivity using aqueous aliphatic and aromatic model pollutants. This study has demonstrated that sol-gel synthesised doped titania photocatalysts, especially Pt/TiO2, may be used to effectively degrade non-volatile acids (DL-malic acid, dichloroacetic acid, and p-hydroxybenzoic acid) under visible light and UV irradiation with significant photoactivity suitable for the solar light application of photocatalytic wastewater treatment. A significant drop in band-gap energy was found for all titania sol-gel catalysts doped with Pt, Co, and Ce with values between 1.41 to 1.78 eV. The BET areas of the photocatalysts were also higher (65-117 m2/g) than that of Degussa P25 (50 m2/g). The visible-light photomineralisation of the three pollutants with Pt-TiO2 specimen were further extended to evaluate the effects of major variables in a bubble-column photoreactor on the photodegradation activities. Those major variables were lamp intensity, oxygen concentration, initial pH, catalyst dosage, and inital pollutant concentration. All the three pollutants seemed to follow the Langmuir-Hinselwood model with dual adsorption sites which implicated a bimolecular surface rate-limiting step probably between the adsorbed organic substrate and a surface hydroxyl (or peroxy) radical. A study of the CeyCoxTi(1-x)O3+d perovskite was conducted to investigate the influence of metal composition and pH on the intrinsic optophysical attributes as well as p-hydroxybenzoic acid degradation under UV irradiation. The perovskite UV photoactivities were lower than that of pure TiO2 likely due to excessive loading (metal content) creating new oxide phases act as electron-hole recombination center, regardless better physicochemical attributes of some of the perovskite samples. The role of aging time and calcination temperature on the sol-gel synthesised TiO2 was also explored. Higher calcination temperature (from 250 to 700 0C) resulted in TiO2 photocatalysts with better crystallinity, which is important for OH group formation as active sites for photodegradation. Despite of some advantages from higher temperature preparation, some detrimental effects such as decreased acidity attributes, surface area, and pore volume were also observed. The significant red-shift of sol-gel synthesized TiO2 into visible light, especially for 250 0C specimen since 600 or 700 0C had extremely low activities, has promising implications that this specimen might be used for solar application to substitute Pt-doped TiO2 in order to produce a more cost effective photocatalyst. Aging period (1 to 14 days) did not have any discernible effect on the band-gap value and acid-site density. Even so, the highest acid site strength was obtained with an aging time of 10 days. From the overall perspective, aging time longer than 3 days did not bring noticeable benefits to both catalyst attributes and photoactivities.

Nitrogen-doped TiO2 nanotubes with enhanced visible light photocatalytic activity have been synthesized using commercial titania P25 as raw material by a facile P25/urea co-hydrothermal method. Morphological and microstructual characteristics were conducted by transmission electron microscopy, powder X-ray diffraction, and nitrogen adsorption/desorption isotherms; chemical identifications were performed using X-ray photoelectron spectroscopy, and the interstitial nitrogen linkage to the TiO2 nanotubes is identified. The photocatalytic activity of all nitrogen-doped TiO2 nanotubes synthesized by different urea content, evaluated by the decomposition of rhodamine B dye solution under visible light using UV¡VVis absorption spectroscopy, is found to exhibit higher degradation rate than that of P25. Factors affecting the photocatalytic activity of RB were analyzed and a possible mechanism of photodegradation was also proposed. The high photocatalytic activity was attributed to the process of two different mechanisms, one was the direct degradation of the chromophoric system and the other was successive deethylation of the four ethyl groups.

Titanium Dioxide (TiO2) emerged as one of the most popular photocatalysts since 1970's. However, its photocatalytic activity requires UV irradiation due to its large band gap unless further functionalization or modifications are performed. Furthermore, recovery issue has always been a major drawback, if the more effective form nano particles are utilized. The key objectives of this research were synthesizing new TiO2 based photocatalyst systems that are effective with both the UV and the visible light while utilizing novel superior environmentally friendly techniques enabling development of nano-structured photocatalysts that can be easily recovered. In this dissertation research, highly porous nano-structured TiO2/WO3/Fe3+ aerogel composite photocatalyst are prepared, characterized, and tested for model photocatalytic reactions. The photocatalyst structure is tailored to capture environmental pollutants and enable their decomposition in-situ under both UV and visible light through photodecomposition to smaller benign substances. A novel and green method is applied to prepare unique surfactant templated aerogel photocatalysts with highly porous nano-structure, high surface area, and tailored pore size distribution. Sol-gel process followed by supercritical fluids extraction and drying allowed synthesis of highly porous composite TiO2/WO3 aerogel. The surfactant template was completely removed with the aid of a supercritical solvent mixture followed with heat treatment. Fe3+ ion was incorporated within the composite aerogel photocatalyst as dopant either at the sol-gel co-precipitation step or at a subsequent supercritical impregnation process. Supercritical drying followed with heat treatment results in titanium dioxide with the most profound anatase crystal structure. Neutral templates were used to further enhance retention and tuning of the nano-pore structure and the surface properties. The Nitrogen adsorption-desorption isotherms methods were used to follow the removal of solvents and templates as well as tracking the textural properties of the synthesized aerogel. Surfactant-templated aerogels, which show remarkable thermal stability and uniform pore size distribution, exhibit specific surface areas three times more than the highly optimized commercial nano-particles, industry standard TiO2 photocatalyst Degussa P-25, even after heat treatment. The synthesized catalysts were characterized by using SEM, FIB, EDS, XRD, XPS and porosimetry prior to post photocatalytic activity evaluation through a model photocatalytic reaction. The band gaps of the catalysts were also determined by using diffuse reflectance spectroscopy. The model reaction employed Methylene Blue (MB) photo-oxidation under UV and visible light. Resulting aerogel TiO2/WO3/Fe3+ photocatalyst exhibited comparable photocatalytic capability to Degussa P25 under UV light exposure and offered much superior photocatalytic capability under visible light exposure.

White LEDs (Light Emitting Diodes) in Visible Light Communication (VLC) is an emerging technology that is being researched so it can eventually be used for common communications systems. LEDs have a number of advantages, one of which is long life expectancy. However, like many emerging technologies, VLC has many technical issues that need to be addressed. We proposed an optical indoor wireless communication system that used white LEDs like plug-in devices. We developed a practical implementation of VLC and demonstrated it experimentally. In particular we focused on designing a prototype of VLC that can be used without having to make major changes to the present infrastructure with two types of protocol — namely RS-232 and USB — for data transmission.

京都大学 / 新制・課程博士 / 博士(工学) / 甲第23911号 / 工博第4998号 / 新制||工||1780(附属図書館) / 京都大学大学院工学研究科物質エネルギー化学専攻 / (主査)教授 阿部 竜, 教授 陰山 洋, 教授 藤田 晃司 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DFAM

Titania-based photocatalysts have been extensively studied for the oxidative photodestruction of organic pollutants in wastewaters, releasing non-toxic substances such as CO2, HCl, and water. However, commercial exploitation of this process is limited by the fact that titania is only active under UV irradiation (wavelength below about 388 nm), which is only less than 5% of solar light energy. Sol-gel synthesised catalyst specimens were characterised to determine the correlation between preparation conditions on morphology (XRD, SEM), optical (bandgap energy level) and physicochemical properties (BET surface area, pore volume, acid site density, acid site strength and type) of the photocatalysts. These spesific properties would then be linked to their photoactivity using aqueous aliphatic and aromatic model pollutants. This study has demonstrated that sol-gel synthesised doped titania photocatalysts, especially Pt/TiO2, may be used to effectively degrade non-volatile acids (DL-malic acid, dichloroacetic acid, and p-hydroxybenzoic acid) under visible light and UV irradiation with significant photoactivity suitable for the solar light application of photocatalytic wastewater treatment. A significant drop in band-gap energy was found for all titania sol-gel catalysts doped with Pt, Co, and Ce with values between 1.41 to 1.78 eV. The BET areas of the photocatalysts were also higher (65-117 m2/g) than that of Degussa P25 (50 m2/g). The visible-light photomineralisation of the three pollutants with Pt-TiO2 specimen were further extended to evaluate the effects of major variables in a bubble-column photoreactor on the photodegradation activities. Those major variables were lamp intensity, oxygen concentration, initial pH, catalyst dosage, and inital pollutant concentration. All the three pollutants seemed to follow the Langmuir-Hinselwood model with dual adsorption sites which implicated a bimolecular surface rate-limiting step probably between the adsorbed organic substrate and a surface hydroxyl (or peroxy) radical. A study of the CeyCoxTi(1-x)O3+d perovskite was conducted to investigate the influence of metal composition and pH on the intrinsic optophysical attributes as well as p-hydroxybenzoic acid degradation under UV irradiation. The perovskite UV photoactivities were lower than that of pure TiO2 likely due to excessive loading (metal content) creating new oxide phases act as electron-hole recombination center, regardless better physicochemical attributes of some of the perovskite samples. The role of aging time and calcination temperature on the sol-gel synthesised TiO2 was also explored. Higher calcination temperature (from 250 to 700 0C) resulted in TiO2 photocatalysts with better crystallinity, which is important for OH group formation as active sites for photodegradation. Despite of some advantages from higher temperature preparation, some detrimental effects such as decreased acidity attributes, surface area, and pore volume were also observed. The significant red-shift of sol-gel synthesized TiO2 into visible light, especially for 250 0C specimen since 600 or 700 0C had extremely low activities, has promising implications that this specimen might be used for solar application to substitute Pt-doped TiO2 in order to produce a more cost effective photocatalyst. Aging period (1 to 14 days) did not have any discernible effect on the band-gap value and acid-site density. Even so, the highest acid site strength was obtained with an aging time of 10 days. From the overall perspective, aging time longer than 3 days did not bring noticeable benefits to both catalyst attributes and photoactivities.

Ultraviolet radiation reaching the Earth’s surface (UVR, 280-400 nm) may penetrate deep into the clear oligotrophic waters influencing a large part of the euphotic layer. Marine heterotrophic bacteria at the surface of the oceans are especially sensitive to the damaging solar radiation due to their haploid genome with little or no functional redundancy and lack of protective pigmentation. In a context of climate change and ozone depletion, it is clearly important to understand the physiology and underlying molecular UVR responses of abundant marine bacteria species. We chose the marine ultramicrobacterium Sphingopyxis alaskensis as a reference species to study the impact of solar radiation due to its numerical abundance in oligotrophic waters and its photoresistance, previously reported. For this purpose, we focused on the formation of the two major UVB-induced DNA photoproducts (CPDs and 6-4PPs) as well as the differential protein expression under solar radiation. We first demonstrated that the GC content of prokaryotic genome had a major effect on the formation of UVB-induced photoproducts, quantified by HPLC-MS/MS. Due to its high GC content, S. alaskensis presented a favoured formation of highly mutagenic cytosine-containing photoproducts and therefore would be more susceptible to UVinduced mutagenesis. By comparing S. alaskensis to another marine bacterium Photobacterium angustum, we observed for the latter strain a remarkable resistance to high UVB doses associated with a decrease in the rate of formation of CPDs explained by a non-conventional activity of photolyase. We also demonstrated that DNA damage in S. alaskensis was markedly modulated by growth temperature and time spent in stationary phase. In order to assess the effects that environmental UV-R had on regulatory networks and pathways of S. alaskensis, and determine how the cell’s physiology was affected, a quantitative proteomics investigation was performed. Changes in proteome were analyzed, with the recent and powerful mass spectrometry based approach using iTRAQ methodology. Approximately, one third of the proteome of S. alaskensis was identified, with 119 statistically and significantly differentially abundant proteins. Cellular processes, pathways and interaction networks were determined and gave us unique insight into the biology of UV response and adaptation of S. alaskensis.