Rhyolite lava flows are found at two dome complexes at Graveyard Butte and Gordon Butte, Mount Hood Quadrangle, Oregon. At Graveyard Butte, the White River has cut a winding canyon 150 m deep, exposing at its base, a 40-meter-thick outcrop of flow-banded rhyolite (73 wt.% SiO2, 3.67±0.01 Ma) that laterally extends along the canyon wall for about 1 km. Stratigraphically above the flow-banded rhyolite is locally-erupted iron-rich andesites (lava flows, agglutinate and other pyroclastic rocks as well as clastic debris), a rhyolitic ash-flow tuff (74 wt.% SiO2), and the 2.77±0.36 Ma tholeiitic basalt lava flows of Juniper Flat (Sherrod and Scott, 1995). Roughly 2 km downstream, a phenocryst-poor, maroon-colored rhyolite (3.65±0.01 Ma) is visible again, forming steep canyon walls for about 1.6 km. A compositionally similar silicic unit is found 18 km to the northwest of Graveyard Butte at Gordon Butte. Exposed units along Gordon Butte's Badger Creek (3.64±0.03 Ma) and the southeastern upper slopes of Gordon Butte include rhyolite flows (69.6-72.1 wt.% SiO 2). The rhyolite lava flows at Graveyard Butte and Gordon Butte's Badger Creek are nearly chemically indistinguishable and both contrast with the younger rhyolitic ash-flow tuff at Graveyard Butte and lava flows on Gordon Butte's Upper Slopes. The rhyolites of Graveyard Butte and Badger Creek are richer in Nb and Zr (30-40 ppm and 487-530 ppm, respectively) than the younger rhyolitic tuff and Upper Slopes flows (13-19 ppm and 235-364 ppm, respectively) and share characteristics with A-type granitoids. The rhyolite lavas are porphyritic (~7%) with the porphyroclasts comprising primarily individual feldspars (250-500 µm in length) with ragged margins, oscillatory zoning and less commonly, spongy cores. Other phenocrystic phases include fayalitic olivine, Fe-rich clinopyroxene, and Fe-Ti oxides. A-type-like incompatible trace-element-enriched compositions as well as mineralogical indicators suggest rhyolite lava flows at Graveyard Butte and Gordon Butte's Badger Creek are likely generated in an extensional tectonic setting. A possible geotectonic framework for generation of these rhyolite lavas is the northward propagating intra-arc rift of the Oregon Cascades.

Volcanic rocks typically have only low to moderate arsenic concentrations, none-the-less, elevated levels of arsenic in ground waters have been associated with pyroclastic and volcaniclastic rocks and sediments in many parts of the world. The potential for arsenic leaching from these deposits is particularly problematic as they often comprise important water-bearing units in volcanic terrains. However, the role that chemical and mineralogical variations play in controlling the occurrence and mobility of arsenic from pyroclastic rocks is largely unexplored. This study uses chemical and X-ray diffraction data to characterize and classify 49 samples of ash-flow tuffs, and 11 samples of tuffaceous sediments. The samples exhibit a range of devitrification and chemical weathering. Total and partial digestion, and water extractions of samples are used to determine the total, environmentally available, and readily leachable fractions of arsenic present in all tuff samples. Leaching experiments were also performed with buffered solutions to determine the influence of elevated pH levels on arsenic mobility. The 49 tuff samples have a mean arsenic content of 7.5 mg kg-1, a geometric mean arsenic content of 4.8 mg kg-1, a median arsenic content of 5.2 mg kg-1, and a maximum arsenic concentration of 81 mg kg-1. The mean and median values are 2.8 - 4.4x the average crustal abundance of 1.7 mg kg-1 (Wedepohl, 1995), and consistent with previously reported values for volcanic glasses and felsic volcanic rocks (Onishi and Sandell, 1955; Wedepohl, 1995), although the maximum arsenic content is higher than previously reported (e.g., Casentini et al., 2010; Fiantis et al., 2010; Nobel et al., 2004). In addition, the arsenic concentrations of tuffs were found to be highly heterogenous, both between and within individual units, and in some cases, individual outcrops. Results of whole rock and leachate analyses indicate that there is no significant difference in the total arsenic content of tuffs as a result of devitrification or weathering, but both devitrified and weathered tuffs contain higher levels of environmentally available arsenic than unweathered glassy tuffs. Glassy tuffs did not produce any readily leachable arsenic, while individual devitrified and weathered tuffs both generated aqueous concentrations that exceeded regulatory limits after 18 hours. Leaching of weathered tuffs produced higher levels of arsenic at high (~9-11) pH than in tests conducted at circum-neutral pH. Devitrified and glassy tuffs showed no increase in leachable arsenic with increasing pH. The results of this study indicate that devitrification and weathering processes determine the host phases, degree of adsorption, and overall mobility of arsenic from ash-flow tuffs. Tuffs that have undergone different types of alteration are likely to have different host phases of arsenic, and different mechanisms that mobilize arsenic into the environment. Potential host phases and mobility mechanisms are discussed, and a conceptual model of arsenic behavior in ash-flow tuffs is proposed.

No description available.

Master of Science / Department of Geology / Matthew W. Totten / Sedimentary beds rich in volcanic ash have been reported throughout Kansas. It is believed the source of these ashes are the large-scale eruptions from the Yellowstone Calderas. Very few of these ash units have been dated, however, and the vast majority simply reported as “Pearlette Ash.” The objective of this research was to investigate the potential of trace element geochemistry in correlating individual ash outcrops in Kansas to their eruptive source. Thirty-six previously reported ash occurrences of unknown age in Kansas were reoccupied and sampled. In addition, three unreported ash deposits were discovered and sampled. Two ash units previously identified as Huckleberry Ridge-aged and three as Lava Creek B were also collected. The samples were processed using the method of Hanan and Totten (1998) to concentrate ash shards. These ash concentrates were analyzed for specific trace and rare earth element (REE) concentrations using inductively coupled mass-spectrometry (ICP-MS) at the University of Kansas. The ash samples from known eruptions have distinct trace and REE signatures, allowing comparison to the unknown ash units. Most of the unknown ash samples correlate with specific Yellowstone eruptions. The majority of the undifferentiated “Pearlette Ash” samples correlate with the most recent Lava Creek B eruption and several unknown ashes correlate to the Huckleberry Ridge eruption. The distribution of ash units in Kansas being dominated by Lava Creek (0.60 ma) is expected because it is the most recent of the Yellowstone eruptions. The abundance of the older Huckleberry Ridge (2.10 ma) over the more recent Mesa Falls (1.27 ma) is likely the result of the much larger Huckleberry Ridge eruption.

Volcanic tuffs and tuffaceous sediments are frequently associated with elevated As groundwater concentrations even though their bulk As contents (~ 5 mg kg-1; Savoie, 2013) are only marginally greater than the average crustal abundance of 4.8 mg g-1 (Rudnick & Gao, 2003). Thus, As mobilization must be facilitated by conditions particular to these rocks. Alkaline desorption, anionic competition, reactive glass dissolution, and reductive dissolution of iron oxides are proposed processes of As release from volcanic rocks. Geogenic As contamination of groundwater in the southern Willamette Valley in western Oregon has been well-documented since the early 1960s, and previous studies have identified the Little Butte Volcanics Series and Fisher and Eugene Formations as the source of As contamination. This study examines 19 samples from 10 units of ash flow tuffs and tuffaceous sediments within the Fisher Formation and Little Butte Volcanics Series, representing a range of weathering and devitrification, to determine conditions of mobilization and mineralogical constraints that control As release into solution. Leachate studies were conducted over a range of pH from 7 to 11, phosphate concentrations from 10 μM to 100 mM, and in time series from 4 to 196 hours. Results demonstrate that silicic volcanic tuffs are capable of mobilizing As in concentrations above regulatory limits at pH conditions produced naturally by the tuffs (pH 8-9) or with moderate concentrations of P (10-100 μM). Alteration products, e.g. zeolites and clays, appear to be the primary host phases for mobile As. Samples that do not contain these alteration products tend to produce concentrations of As well below regulatory limits and often below the instrument detection limits of this study. The type of alteration may influence As mobilization: tuffs containing more clays tend to mobilize As through surficial desorption, and tuffs containing more zeolites tend to mobilize As by dissolution or formation of colloids. Additionally, one volcaniclastic sample demonstrates that extremely elevated concentrations of As, up to 1000 μg/L are possible as a result of oxidative dissolution of As-bearing sulfide phases.

Abstract not available

<p>Volcanic ash and Moringa oleifera (M. oleifera) were investigated as indigenous materials for drinking water treatment based on problems identified at Kampala and Masaka water treatment plants in Uganda. Coagulation experiments were done using swamp raw water at Masaka National Water & Sewerage Corporation water treatment plant and pilot-scale filtration experiments carried out at Ggaba II (Kampala) water treatment plant. The results from the study indicated that there were both operational and design handicaps at the treatment plants in Kampala. There is need to modify the filtration and clarification units to enable production of water meeting both the national and international standards. At Masaka water treatment, there was increase in trihalomethanes concentration as a result of pre-chlorination. Following aeration and pre-chlorination processes, the average increase of total trihalomethanes concentration was over 4000% with over 99% being chloroform. Preliminary results from the jar test experiments indicated that use of alum with MOCSC as coagulant aid is promising as a first stage in the treatment train for waters with a humic materials and high content of iron, typical of swamp water sources. This would probably eliminate the formation of unwanted by-products by eliminating the pre-chlorination process. Assessment of the characteristics of the volcanic ash showed that it meets the requirements for a filtration material; and results obtained from the pilot study showed that it was a suitable alternative material for use in a dual media filtration system. There was an increase in the filter run length of about two and half fold in the dual media filtration column compared to the mono medium column. Both columns produced similar water quality levels. Therefore, conversion of the rapid sand filters at Ggaba and similar water treatment plants in the country to dual media (volcanic ash on top of sand) systems would probably significantly improve the performance of the filtration systems.</p>

Perched water zones have been identified in the fractured, welded tuff in the semiarid to arid environments of Yucca Mountain, Nevada and near Superior, Arizona. An understanding of the formation of such zones is necessary in order to predict where future perched water might form at Yucca Mountain, the proposed site of a high-level nuclear waste repository. The formation or growth of a perched zone above a repository is one factor of the factors to be considered in the risk assessment of the Yucca Mountain site. The Apache Leap Research Site (ALRS) near Superior, Arizona is a natural analog to the Yucca Mountain site in terms of geology, hydrology, and climate. Perched water has been identified over an area of at least 16 km² in the Apache Leap Tuff, a mid- Miocene fractured, welded ash-flow tuff. A primary goal of this investigation was to characterize the physical and hydrologic properties of the tuff in the region above and including the perched zone, and to evaluate those characteristics to develop a model for a perching mechanism in the tuff. A second goal was to determine what fraction of water entering a watershed reaches the subsurface, to potentially recharge the perched zone. The Apache Leap Tuff has been subject to considerable devitrification and vapor phase crystallization, which dominate the character of the rock. With depth to the perched zone, pumice fragments become increasingly flattened and segregated; the pumice fragments are the primary locations of porosity in the rock, therefore porosity also becomes greatly reduced with depth, to the extent that the rock matrix is virtually impermeable at the perched water zone. Fractures are the primary pathways by which water moves through the rock; fracture hydraulic conductivity values were determined to be nine orders of magnitude greater than measured matrix hydraulic conductivity at the perched zone. An increase in fracture filling by silica mineralization beneath the perched zone reduces the secondary permeability, enhancing the formation of perched water. Thus, the primary mechanisms for the formation of the perched zone include fracture flow bringing water into the subsurface, combined with extremely low matrix hydraulic conductivity at depth, and reduced secondary permeability by filled fractures and lower fracture density. Water budgets were calculated for two years in a 51.4-ha watershed. Direct measurements were made of precipitation and runoff', evapotranspiration was both directly measured, and modeled based on measurement of a number of weather parameters. Infiltration was calculated as the residual of precipitation after runoff and evapotranspiration were removed. Infiltration was determined to be less than 10% of the annual water budget; evapotranspiration removes on the order of 90% of precipitation on an annual basis.

No description available.

No description available.