Streamflow dynamics in mountainous environments are controlled by runoff generation processes in the basin upstream. Runoff generation processes are thus a major control of the terrestrial part of the water cycle, influencing both, water quality and water quantity as well as their dynamics. The understanding of these processes becomes especially important for the prediction of floods, erosion, and dangerous mass movements, in particular as hydrological systems often show threshold behavior. In case of extensive environmental changes, be it in climate or in landuse, the understanding of runoff generation processes will allow us to better anticipate the consequences and can thus lead to a more responsible management of resources as well as risks. In this study the runoff generation processes in a small undisturbed catchment in the Chilean Andes were investigated. The research area is characterized by steep hillslopes, volcanic ash soils, undisturbed old growth forest and high rainfall amounts. The investigation of runoff generation processes in this data scarce area is of special interest as a) little is known on the hydrological functioning of the young volcanic ash soils, which are characterized by extremely high porosities and hydraulic conductivities, b) no process studies have been carried out in this area at either slope or catchment scale, and c) understanding the hydrological processes in undisturbed catchments will provide a basis to improve our understanding of disturbed systems, the shift in processes that followed the disturbance and maybe also future process evolution necessary for the achievement of a new steady state. The here studied catchment has thus the potential to serve as a reference catchment for future investigations. As no long term data of rainfall and runoff exists, it was necessary to replace long time series of data with a multitude of experimental methods, using the so called "multi-method approach". These methods cover as many aspects of runoff generation as possible and include not only the measurement of time series such as discharge, rainfall, soil water dynamics and groundwater dynamics, but also various short term measurements and experiments such as determination of throughfall amounts and variability, water chemistry, soil physical parameters, soil mineralogy, geo-electrical soundings and tracer techniques. Assembling the results like pieces of a puzzle produces a maybe not complete but nevertheless useful picture of the dynamic ensemble of runoff generation processes in this catchment. The employed methods were then evaluated for their usefulness vs. expenditures (labour and financial costs). Finally, the hypotheses - the perceptual model of runoff generation generated from the experimental findings - were tested with the physically based model Catflow. Additionally the process-based model Wasim-ETH was used to investigate the influence of landuse on runoff generation at the catchment scale. An initial assessment of hydrologic response of the catchment was achieved with a linear statistical model for the prediction of event runoff coefficients. The parameters identified as best predictors give a first indication of important processes. Various results acquired with the "multi-method approach" show that response to rainfall is generally fast. Preferential vertical flow is of major importance and is reinforced by hydrophobicity during the summer months. Rapid lateral water transport is necessary to produce the fast response signal, however, while lateral subsurface flow was observed at several soil moisture profiles, the location and type of structures causing fast lateral flow on the hillslope scale is still not clear and needs to be investigated in more detail. Surface runoff has not been observed and is unlikely due to the high hydraulic conductivities of the volcanic ash soils. Additionally, a large subsurface storage retains most of the incident rainfall amount during events (>90%, often even >95%) and produces streamflow even after several weeks of drought. Several findings suggest a shift in processes from summer to winter causing changes in flow patterns, changes in response of stream chemistry to rainfall events and also in groundwater-surface water interactions. The results of the modelling study confirm the importance of rapid and preferential flow processes. However, due to the limited knowledge on subsurface structures the model still does not fully capture runoff response. Investigating the importance of landuse on runoff generation showed that while peak runoff generally increased with deforested area, the location of these areas also had an effect. Overall, the "multi-method approach" of replacing long time series with a multitude of experimental methods was successful in the identification of dominant hydrological processes and thus proved its applicability for data scarce catchments under the constraint of limited resources. / Die Abflussdynamik in Mittel- und Hochgebirgen wird durch die Abflussbildungsprozesse im Einzugsgebiet bestimmt. Diese Prozesse kontrollieren damit zu großen Teilen den terrestrischen Teil des Wasserkreislaufs und beeinflussen sowohl Wasserqualität als auch -quantität. Das Verständnis von Abflussbildungsprozessen ist besonders wichtig für die Vorhersage von Hochwasser, Erosion und Massenbewegungen (z.B. Erdrutsche) da hydrologische Systeme oft Schwellenwertverhalten aufweisen. Im Falle weit reichender Umweltveränderungen, wie z.B. Klima- oder Landnutzungsänderungen kann das Verständnis der Abflussbildungsprozesse ein verantwortungsvolleres Management sowohl der Ressourcen als auch der Risiken ermöglichen. In dieser Studie wurden die Abflussbildungsprozesse in einem kleinen, anthropogen unbeeinflussten Einzugsgebiet in den Chilenischen Anden untersucht. Das Untersuchungsgebiet ist durch steile Hänge, vulkanische Ascheböden, ungestörten Naturwald und hohe Niederschlagsmengen charakterisiert. Die Erforschung von Abflussbildungsprozessen ist hier von besonderem Interesse, da a) wenig über das hydrologische Verhalten der hochporösen und hochleitfähigen jungen Ascheböden bekannt ist, b) in dieser Region bisher keine Studien auf Hang- oder Einzugsgebietsskala durchgeführt wurden, und c) das Prozessverständnis in ungestörten Einzugsgebieten als Basis zum besseren Verständnis bereits anthropogen beeinflusster Gebiete dienen kann. Das hier untersuchte Gebiet hat daher das Potential zum Referenzgebiet für zukünftige Studien und Forschungsprojekte. Bedingt durch die Kürze der vorliegenden Abfluss- und Niederschlagszeitreihen war es nötig, den bestehenden Datenmangel durch eine Vielzahl von experimentellen Methoden und Ansätzen auszugleichen. Dieser Ansatz wird im Folgenden der "Multi-Methoden-Ansatz" genannt. Die ausgewählten Methoden sollten dabei so viele Aspekte der Abflussbildung abdecken wie möglich. Es wurden daher nicht nur Zeitreihen von Abfluss, Niederschlag, Bodenfeuchte- und Grundwasserdynamik gemessen, sondern auch eine große Zahl an Kurzzeitmessungen und Experimenten durchgeführt. Diese beinhalteten u.a. Messung des Bestandesniederschlags, Bestimmung der Wasserchemie, Bestimmung bodenphysikalischer Parameter und der Bodenmineralogie, sowie geophysikalische Messungen und Tracermethoden. Die Synthese der Resultate gleicht dem Zusammensetzen eines Puzzles. Das so entstandene Bild des dynamischen Prozess-Ensembles ist trotz möglicher fehlender Puzzlestücke hochinformativ. In einem nächsten Schritt wurden die ausgewählten Methoden im Hinblick auf Erkenntnisgewinn und Kosten (d.h. finanzielle Kosten und Arbeitszeit) evaluiert. Das durch die experimentellen Ergebnisse gewonnene Bild der Abflussbildung wurde anschließend mit Hilfe des physikalisch basierten Modells Catflow überprüft. Weiterhin wurde mit dem prozessbasierten Modell Wasim-ETH der Einfluss der Landnutzung auf die Abflussbildung auf Einzugsgebietsskala untersucht. Die Ergebnisse des "Multi-Methoden-Ansatzes" zeigen, dass die Abflussreaktion in diesem Gebiet sehr schnell erfolgt. Vertikales präferenzielles Fliessen ist hier von großer Bedeutung und wird in den Sommermonaten noch durch Hydrophobizitätseffekte verstärkt. Schneller lateraler Fluss im Untergrund ist eine weitere Vorraussetzung für die schnelle Reaktion des Abflusses (Oberflächenabfluss ist hier aufgrund der hohen hydraulischen Leitfähigkeiten unwahrscheinlich). Obwohl bei der Untersuchung der Bodenfeuchtedynamik in einigen Profilen laterale Fließmuster beobachtet wurden, ist die Art und Lage der Untergrundstrukturen, die auf der Hangskala schnellen lateralen Fluss verursachen, noch unklar und sollte genauer untersucht werden. Die Tatsache, dass bei Niederschlagsereignissen der Großteil der Niederschlagsmenge nicht zum Abfluss kommt (>90%, oft auch >95%), sowie der kontinuierliche Abfluss selbst nach Wochen der Trockenheit, lassen auf einen großen unterirdischen Speicher schließen. Der Wechsel von Winter (nass) zu Sommer (trocken) scheint Veränderungen im Prozess-Ensemble hervorzurufen, die sich in der Änderung von Fließmustern, von Grundwasser-Oberflächenwasser-Interaktionen, sowie veränderter Reaktion der Wasserchemie auf Niederschlagsereignisse beobachten ließ. Die Modellstudie bestätigte die Bedeutung der schnellen Fließwege. Als Folge von Informationsdefiziten über die Strukturen des Untergrunds ließ sich jedoch die Abflussbildung noch nicht vollständig reproduzieren. Die Untersuchung zur Bedeutung der Landnutzung für die Abflussbildung mit Hilfe eines Einzugsgebietsmodells zeigte die Zunahme der maximalen Abflüsse mit zunehmender Entwaldung. Weiterhin erwies sich auch die Lage der abgeholzten Flächen als ein wichtiger Faktor für die Abflussreaktion. Der "Multi-Methoden-Ansatz" lieferte wichtige Erkenntnisse zum Verständnis der Abflussbildungspozesse in den Anden Südchiles und zeigte sich als adäquates Mittel für hydrologische Prozess-Studien in datenarmen Gebieten.

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Geological evidence suggests large-scale continental extension during the breakup of the eastern Gondwana margin was the predominant force controlling rifting of New Caledonia from the eastern Gondwana margin and formation of the Tasman Sea in the Late Cretaceous. Tectonic models suggest slab-rollback forces elongated and thinned the crustal lithosphere detaching crustal fragments from the Gondwana margin. Current tectonic models lack detailed timing and placement of this crustal detachment with respect to New Caledonia based on lack of evidence (rocks). An isotope and paleomagnetic study was carried out on a bi-modal assemblage of volcanic rock exposed on the southwest side of New Caledonia in the Nouméa Basin. U/Pb isotope ages of zircon grains found within siliceous volcanic rock in the Nouméa Basin provide temporal evidence that volcanism persisted both before and after the breakup of the eastern Gondwana Continent (100-90 Ma) in the Late Cretaceous. Four isotope ages >97 Ma and a series (11 samples) ranging from 91-76 Ma constrain the siliceous volcanism of the Nouméa Basin to the Late Cretaceous. A paleomagnetic inquiry utilizing statistics of both McFadden/Reid and Fisher carried out on 16 Nouméa Basin siliceous and mafic in situ formations place the oldest volcanic units found within the Nouméa Basin at 650 S latitude as New Caledonia began to separate from Gondwana (~100 Ma). The data suggests a well-developed arc signature in the region, which persisted for at least 15 Ma in the Late Cretaceous. Compared to current tectonic models of the southwest Pacific Region from the Late Cretaceous to Eocene, our data suggests New Caledonia was further south on the eastern Gondwana supercontinent prior to rifting in the Late Cretaceous than current models. / Geologic background -- Tectonic setting -- Methods -- Sampling -- Results -- Discussion. / Department of Geological Sciences

The purpose of this study is to investigate the origin, source characteristics, evolution petrogenesis and emplacement mechanisms of Beypazari-Oymaaga&ccedil / granitoids. These granitoids are intruded into a metamorphic basement and nonconformably overlain by Neogene clastic rocks. Field work, petrographical and geochemical studies are carried out to determine the petrologic features and tectonic setting of the granitoid body. The Beypazari-Oymaaga&ccedil / pluton is a composite pluton with its host batholith, enclaves, aplite dykes and a pegmatite. The batholith is generally composed of quartz, K-feldspar, plagioclase and hornblende. Field observations and petrographic investigations indicate that the host batholith has granodiorite composition and shows distinct differences in the abundances of quartz, amphibole minerals (e.g., hornblende) and of enclaves. The samples taken from TavuktaSi Tepe contain relatively less amphibole and enclaves but more quartz. Compared with them, samples from the rest of the batholith have relatively abundant amphibole, K-feldspar megacrysts, and enclaves but less quartz. Enclaves derived from magma mixing/mingling processes are dioritic in composition. Geochemical data obtained from whole rock analyses show that the pluton is shallowly emplaced and has calc-alkaline, metaluminous to peraluminous chemistry. It is characterized by enrichments in LIL and LREE, especially in K, Rb and Th. Although, there is a distinct petrographic variation in the batholith, the geochemical characteristics are uniform throughout the pluton. The Oymaaga&ccedil / Granitoids which have I-type identity are typical representatives of magmatic arc environment. The present study suggests that the possible source of magma is the upper crust and can be compared with the coeval volcanism in Galatean Volcanic Arc.

Modelling of volcanic ashfall has been attempted by volcanologists but very little work has been done by mathematicians. In this thesis we show that mathematical models can accurately describe the distribution of particulate materials that fall to the ground following an eruption. We also report on the development and analysis of mathematical models to calculate the ash concentration in the atmosphere during ashfall after eruptions. Some of these models have analytical solutions. The mathematical models reported on in this thesis not only describe the distribution of ashfall on the ground but are also able to take into account the effect of variation of wind direction with elevation. In order to model the complexity of the atmospheric flow, the atmosphere is divided into horizontal layers. Each layer moves steadily and parallel to the ground: the wind velocity components, particle settling speed and dispersion coefficients are assumed constant within each layer but may differ from layer to layer. This allows for elevation-dependent wind and turbulence profiles, as well as changing particle settling speeds, the last allowing the effects of the agglomeration of particles to be taken into account.

Two mid-Miocene (16.5-15 Ma) rhyolite volcanic centers in eastern Oregon, the Buchanan rhyolite complex and Dooley Mountain rhyolite complex, were investigated to characterize eruptive units through field and laboratory analysis. Results of petrographic and geochemical analysis add to field observations to differentiate and discriminate the eruptive units. Additionally, new geochemical data are used to correlate stratigraphically younger and older basalt and ash-flow tuff units with regional eruptive units to constrain the eruptive periods with modern Ar-Ar age dates. Previous work at the Buchanan rhyolite complex was limited to regional mapping (Piper et al., 1939; Greene et al., 1972) and brief mention of the possibility of multiple eruptive units (Walker, 1979). Observed stratigraphic relationships and geochemical analysis were used to identify eight distinct eruptive units and create a geologic map of their distribution. Slight differences in trace element enrichment are seen in mantle normalized values of Ba, Sr, P, Ti and Nd-Zr-Hf and are used to differentiate eruptive units. New geochemical analyses are used to correlate the overlying Buchanan ash-flow tuff (Brown and McLean, 1980) and two underlying mafic units to the Wildcat Creek ash-flow tuff (~15.9 Ma, Hooper et al., 2002) and flows of the Upper Steens Basalt (~16.57 Ma, Brueseke et al., 2007), respectively, bracketing the eruptive age of the Buchanan rhyolite complex to between ~16.5 and ~15.9 Ma (Brueseke et al., 2007; Hooper et al., 2002). The Dooley Mountain rhyolite complex was thoroughly mapped by the U.S. Geological Survey (Evans, 1992) and geochemically differentiated in a previous Portland State University M.S. thesis (Whitson, 1988); however, discrepancies between published interpretations and field observations necessitated modern geochemical data and revisions to geologic interpretations. Field and laboratory studies indicate that the Dooley Mountain rhyolite complex consists of multiple eruptive units that were effusive domes and flows with associated explosive eruptions subordinate in volume. At least four geochemically distinct eruptive units are described with variations in Ba, Sr, Zr and Nb. Picture Gorge Basalt flows and Dinner Creek Tuff units found within the study area both overlay and underlie the Dooley Mountain rhyolite complex. These stratigraphic relationships are consistent with the one existing Ar-Ar age date 15.59±0.04 Ma (Hess, 2014) for the Dooley rhyolite complex, bracketing the eruptive period between ~16.0 and ~15.2 Ma (Streck et al., 2015; Barry et al., 2013). The findings of this study indicate that the Buchanan rhyolite complex and the Dooley Mountain rhyolite complex are the westernmost and northernmost rhyolite complexes among the earliest (16-16.5 Ma) mid-Miocene rhyolites associated with initiation of Yellowstone hot spot related volcanism.

Lead isotope compositions have been obtained from five major volcanic and intrusive rock suites and several ore deposits on Vancouver Island. Lead, uranium and thorium concentrations and strontium isotope ratios have been obtained for a subset of these samples. The rock suites examined are the Paleozoic Sicker Group, Triassic Karmutsen Formation, Jurassic Island Intrusions and Bonanza Group volcanic rocks, and the Eocene Catface intrusions. Isotope geochemistry of the Sicker Group is consistent with the interpretation that it formed as an island arc. Relatively high 207pb/204pb ratios indicate sediment involvement in the subduction process, which suggests that the Sicker Group formed close to a continent. Buttle Lake ore deposits display decreasingly radiogenic lead isotope ratios with time, suggesting that the associated magmas become increasingly primitive. This supports the hypothesis that these deposits formed during the establishment of rifting in a back-arc environment. Karmutsen Formation flood basalts display isotopic mixing between an ocean island-type mantle source and average crust. Isotopic evidence is used to support a Northern Hemisphere origin for these basalts. Mixing is apparent in the lead and strontium isotope signatures of the Island Intrusions and Bonanza Group volcanic rocks, between depleted mantle and crustal (possibly trench sediments) components. This is consistent with formation of these rocks in an island arc environment. Eocene Catface intrusions have relatively high 207pb/204pb indicating that crustal material was involved in their formation. There are two groups of plutons corresponding to an east belt and west belt classification. Galena from the Zeballos mining camp related to the Eocene Zeballos pluton indicates that the mineralization was derived from the pluton. Galena lead isotope data from Vancouver Island may be interpreted in a general way by comparison with data from deposits elsewhere of known age and origin. No single growth curve model can be applied. Lead isotope characteristics of Vancouver Island are clearly different from those of the North American craton, reflecting the oceanic affinities of this terrane. A new technique has been developed to compare 207pb/204pb ratios between samples with differing 206pb/204pb ratios. The procedure projects 207pb/204pb ratios along suitable isochrons until they intersect a reference value of 206pb/204pb. This technique can be used for interpreting lead isotope data from old terranes, in which lead and uranium may have undergone loss or gain, and if lead and uranium abundances have not been measured. / Science, Faculty of / Earth, Ocean and Atmospheric Sciences, Department of / Graduate

The Lower Cretaceous Cedar Mountain Formation preserves several vertebrate faunas and has the potential of providing critical timing information pertaining to Early Cretaceous dinosaurs and the Sierran magmatic arc. Historically, the Morrison/Cedar Mountain contact and the duration of the unconformity between them have been difficult or impossible to determine because 1) the formations were deposited in similar environments, 2) the basal Cedar Mountain Formation is composed of reworked Morrison Formation, and 3) there are no radiometric ages for the lower Cedar Mountain Formation. A stratigraphic study through central Utah reveals a diagnostic suite of pedogenic and sedimentologic characters across the previously enigmatic boundary. The uppermost Morrison Formation is characterized by redoximorphic paleosol features, including iron concentrations, manganese-coated grains, and intense red-purple-green mottling. Upsection increases in chert-pebble lags and channelized conglomerates within the paleosol section indicate a period of reduced accommodation space in the Tithonian. The paleosols are usually capped by a groundwater or pedogenic carbonate. This unit is consistently present from Green River, Utah to the Utah-Colorado border. The lower Cedar Mountain Formation above this package is a poorly sorted mixture of fine-grained material and sand-gravel sized chert grains. Within a sequence stratigraphic framework, these characters record a terrestrial sequence boundary in the uppermost Morrison Formation and degradational-aggradational systems tracts in the Cedar Mountain Formation. To resolve the lack of age control for the basal Cedar Mountain Formation, a geochronologic zircon study was conducted near the Dalton Wells dinosaur quarry, Moab, Utah. The Dalton Wells quarry, along with numerous other fossil assemblages occurs in the basal Yellowcat Member. Zircons from the Dalton Wells quarry and a correlative eggshell site place the age of this horizon near the Barremian/Aptian boundary at ~124 Ma. Thus, the Yellowcat fauna is time equivalent with the feathered dinosaurs of the Yixian Formation, of Liaoning, China. This age constrains the Morrison/Cedar Mountain unconformity to a period of magmatic quiescence in western North America from 148 Ma-124 Ma. The basal Cedar Mountain age coincides with renewed magmatic activity at ~125 Ma. The Cedar Mountain Formation covers a period of 27 Myr and likely contains numerous small unconformities.

En el Perú existen zonas afectadas por la geología volcánica ya que disponen de insumos naturales llamados cenizas volcánicas. Este es un material formado por pequeños fragmentos de lavas silíceas de granos finos de colores blanquecinos, blandos y deleznables. Suelen presentar diversos grados de cementación, de tipo fisil, lo que los identifica en la categoría de suelos colapsables. Es por ello, que para la construcción del pavimento se requiere realizar la estabilización o mejoramiento de la subrasante para el siguiente proyecto que se desarrolla entre Arequipa y Moquegua. La presente investigación tiene como objetivo evaluar el uso de agregados marginales con cenizas volcánicas para el diseño de losa de concreto hidráulico referida, la misma que como estructura será evaluada con los resultados del módulo de flexión y esfuerzo crítico. Los resultados demostraron que, en la caracterización de agregados finos al contener cenizas volcánicas, no cumplan con todos los requerimientos propuestos en la norma peruana (EG-2013) del manual de carreteras. Sin embargo, el American Concrete Institute (ACI) incorpora excepciones para condiciones particulares de los áridos, posibilitando su uso a partir del cumplimiento de la resistencia y durabilidad requerida. Se propuso realizar el diseño de una mezcla de concreto para una resistencia teórica de f´c= 280 kg/cm2. Sin embargo, al ensayar las probetas a los 28 días de curado se obtuvo una resistencia de f´c= 380 kg/cm2 esto se debe a la estrecha relación positiva que presenta la ceniza volcánica con el cemento puzolánico empleado para la mezcla. / In Peru there are areas affected by volcanic geology and that have natural inputs called volcanic ash. This is a material formed by small fragments of siliceous lavas of fine grains of whitish, soft and delectable colors. They usually present varying degrees of cementation, of the fisile type, which identifies them in the category of collapsible soils. That is why, for the construction of the pavement it is necessary to perform the stabilization or improvement of the subgrade for the next project that is developed between Arequipa and Moquegua. The purpose of this research is to evaluate the use of marginal aggregates with volcanic ash for the design of the loss of referred hydraulic concrete, which will be determined as a structure with the results of the flexural and critical stress module. The results showed that, in the characterization of fine aggregates containing volcanic ash, they do not require all the requirements proposed in the Peruvian standard (EG-2013) of the road manual. However, the American Concrete Institute (ACI) incorporates the specific conditions of the aggregates, which allows its use based on compliance with the required strength and durability. It was proposed to design a concrete mix for a theoretical strength of f´c = 280 kg / cm2. However, when testing the probes after 28 days of curing, a resistance of f'c = 380 kg / cm2 was obtained, due to the close positive relationship between volcanic ash and the pozzolanic cement used for the mixture. / Tesis