Thesis (Master of Engineering in Electrical Engineering)--Cape Peninsula University of Technology, 2018. / In Sub-Saharan Africa (SSA), there are several challenges that hinder development. One of these challenges is access to electricity. There are numerous benefits to having access to reliable electricity. These include less time spent fetching water from rivers and dams, as water purification systems for households could be used in villages; children in villages would be able to spend more time doing their schoolwork and not fetching wood for fire; and automated irrigation systems could be used for villagers to farm and make an income. Finding alternative ways to generate electricity would enable access to electricity for regions that currently do not have the electricity. This means that large organisations need to find alternative ways of generating electricity, as they have the means to do so. With the current renewable energy technologies available, there are now more ways in which electricity could be generated. The use of biomass is no exception to this. With constant developments in the renewable energy sector, waste-to-energy (WtE) is proving to be a viable method to generate electricity. The main aim of this research was to determine if a commercial food retailing organisation could use their food waste for generating electricity for their own use to reduce their demand from the central grid. A way of determining the viability of this type of technology is using a software that simulates renewable energy projects. In this research, an organisation was contacted for waste data. Systems for two of the stores will be simulated and results will be discussed. The organisation will remain anonymous. The software used in this research is System Advisor Model (SAM), which was developed by the National Renewable Energy Laboratory (NREL) in the United States. In the results, three results were discussed. These are the monthly energy, monthly heat rate and the monthly boiler efficiency for each of the stores for Store 1, the annual energy simulated was 138,509 kWh and 131,677 kWh for Store 2. Monthly energy averages for each store were 11,542 kWh for Store 1 and 10,973 kWh for Store 2, respectively. There are several opportunities for research based on the findings. These include researching other food sectors in the study; conducting a financial analysis of small-scale WtE systems; constructing a prototype of the system; and using three different softwares to simulate a system for the same project.

Thesis ( MPH.) --University of Limpopo, 2014 / The purpose of this study was to investigate the knowledge and practices among households at Ga-Mokgwathi Village regarding the disposal of mercury coated bulbs. Cross-sectional design with quantitative approach was used in this study. The study objectives were to determine the knowledge about the disposal methods of mercury coated bulbs and also to determine the practices of handling broken mercury coated bulbs among the villagers of Ga-Mokgwathi. Data collection was done using self-administered questionnaires. Cluster random sampling was used in the study where a total number of 338 households were randomly selected to participate in the study. The results indicated that 36.7 % of the households at Ga-Mokgwathi Village had knowledge of safe disposal methods of mercury coated bulbs, 7.7% were not sure and 55.6% did not have such knowledge. Furthermore, the results indicated that 51.5% of the households had improper practices regarding the handling of broken mercury coated bulbs, 6.2% were not sure and 42.3% had proper practices regarding the handling of broken mercury coated bulb. The results of the study concluded that the majority of people were lacking knowledge of proper disposal methods and the handling of mercury coated bulbs. These results necessitate education of people about the disposal methods and handling of mercury coated bulbs.

This document reports on a research project aimed at developing a concrete acoustic barrier made from Recycled Aggregate (RA) Concrete. The research project was undertaken in response to the needs expressed by the Victorian concrete recycling industry. The industry, the scientific community conducting research into relevant disciplines, and the community at large, represented by Victorian government agencies, are of the opinion that there is a need to devise a higher value utilisation application for selected concrete recycling products. This document outlines the rationale and objectives of the research project which involves the examination of Recycled Concrete (RC) Aggregate, the design and examination of RA Concrete, and finally the development of an acoustic barrier made from RA Concrete. The literature review presented in this report examines aspects of concrete recycling and concrete technology pertaining to traditional and alternative constituent materials for concrete production. Firstly, the importance and influence of fine and coarse aggregate on basic properties of concrete is introduced. Secondly, an account on the use of alternative materials in concrete technology, especially of coarse recycled aggregates and supplementary cementitious materials (SCM) is described. Thirdly, some of the physical and mechanical properties and how the use of RC Aggregate and SCM changes these properties are discussed. Fourthly, a number of commonly used techniques and neutron scattering techniques to investigate aggregate and concrete properties are introduced and discussed. Fifthly, the porosity of aggregate and concrete including durability are specifically discussed and testing methods are reasoned. The literature review also discusses the use of no-fines concrete; its physical, mechanical and acoustic properties. Finally it presents an account of the use of concrete in transportation traffic noise attenuation devices. This document continues with an outline of a methodology that was adopted in this research project. It outlines experimental work aimed at examining the properties of RC Aggregate which amongst other properties includes porosity, particle size distribution, water absorption, shape and density. It continues examining RA Concrete properties and includes, among other properties, compressive strength, porosity and durability as well as sound absorption of acoustic barrier. The methodology introduces standard and purposely modified test procedures used in the examination of aggregates, concrete and acoustic barrier. An account of various research techniques is presented, spanning from simple visual observations to more sophisticated neutron scattering techniques. The summary of test procedures follows a description of test specimen composition and their sizes, and a suite of tested specimens. It also introduces statistical methods used to analyse test results. After a detailed description of the aggregate, concrete and RA Concrete acoustic barrier, the document outlines a summary of data generated through the experimental program of this research project. The data on fine aggregate, on selected 14/10mm coarse RC Aggregate, on concrete made from natural and recycled aggregate and on acoustic barrier are presented and discussed. Test results of various physical, mechanical and acoustic properties of aggregate, concrete and barrier are reported, analysed and discussed. The data from observations, visual assessment and scientific experimentation of specific properties are then crossed analysed in a search for relationships between properties of fine and coarse aggregates and properties of concrete made from such aggregates. A cross analysis of data on ?less-fines? RA Concrete and on the acoustic performance of barrier is examined, and the relationship between the volume of interconnected voids in a porous part of ?less-fines? concrete, and the sound absorption of acoustic barrier is discussed and reported. The document then presents a synthesis of the literature review results, project aims adopted within the experimental program and test results in the three main areas of this research project. These areas include recycled concrete aggregate, recycled aggregate concrete and acoustic barrier made from RA Concrete. Finally, conclusions reached through the course of this investigation are summarised and recommendations are proposed in relation to the RA Concrete acoustic barrier. The main conclusion is that selected RC Aggregate can be used in the production of concrete of a compressive strength of 25MPa, if the moisture content and water absorption in the aggregate are closely monitored, and the foreign material content is kept below 1.5%. The author concludes that acoustic barrier made from selected RC Aggregate has unique sound absorption characteristics that can easily be tunable by a selection of appropriate aggregate and by specific concrete mix designs. Recommendations for further research are also proposed.

The use of municipal refuse (RDF) as fuels has received widespread attention for reason of its energy equivalence and the increasing lack of available landfill sites. The principal obstacle to the construction of combustion facilities is that RDF produces toxic compounds, including heavy metals and such organic compounds as PCDD and PCDF. In this study, the emissions of metal and organic compounds were investigated under oxygen deficient and oxygen surplus conditions for the RDF and such high volume contributors as office papers and magazines. The principal metal emissions of the RDF were Al, Ca, K, Si, and Zn. Magazines significantly contribute B, Mg, Mn, Ti emissions, whereas office papers contributed Ti and Zn emissions. The metal emissions were not significantly different between oxygen deficient and oxygen surplus conditions at a temperature of 750��C. The combustion of RDF produced a full range of PCDFs and PCDFs, the source of which was determined to be RDF, papers, and even untreated wood combustion effluents in the parts-per-billion range. In contrast to metal emissions, emission rates were higher under the oxygen surplus condition than for the oxygen deficient condition and PCDD and PCDF emissions were significant in relation to the chloride contents of fuel, rather than by fuel type as was the case for the large volume contributors. With the exception of Hg, Se, S, Sr, and Pb, the metal emissions were largely derived from the particles in the effluent. / Graduation date: 1993 / Text is slanted on original. Best scan available.

Thesis (Ph. D.)--University of Hong Kong, 2006. / Title proper from title frame. Also available in printed format.

<p>It was hypothesized that South African FA and brine could sequester CO2 through mineral carbonation. A statistical approach was undertaken to optimize the % CaCO3 formed from FA/brine/CO2 interaction with input parameters of temperature, pressure, particle size and solid/liquid ratio (S/L) being varied. The ranges adopted for the input parameters were: temperature of 30 &ordm / C or 90 &ordm / C / pressure of 1 Mpa or 4 Mpa / four particle sizes namely bulk ash, &gt / 150 &mu / m, &lt / 20 &mu / m and 20 &mu / m- 150 &mu / m particle size range / S/L ratios of 0.1, 0.5 or 1. The FA/ brine dispersions were carbonated in a high pressure reactor varying the above mentioned input parameters. The fresh Secunda FA of various size fractions was characterized morphologically using scanning electron microscopy, chemically using X-ray fluorescence and mineralogically using qualitative X-ray diffraction. The carbonated solid residues on the other hand were characterized using quantitative X-ray diffraction, scanning electron microscopy, thermal gravimetic analysis and Chittick tests. The raw brine from Tutuka together with the carbonation leachates were characterized using inductively coupled mass spectrometry and ion chromatography. Total acid digestion was carried out to evaluate the differences in the total elemental content in both the fresh ash and the carbonated solid residues. The results suggested that South African FA from Secunda belongs to class F based on the CaO content as well as the total alumina, silica and ferric oxide content, while the RO brine from Tutuka were classified as NaSO4 waters...</p>

Effective combustion of waste fuels requires an understanding of the fuels characteristics. Gaseous and particulate emissions, ash residues and combustion properties are of interest to many; those that produce and sell heating units, utilities interested in using the fuels for power generation, regulatory agencies, municipalities needing to solve a disposal problem, and environmentally conscious people interested in maximum utilization of resources. A study was conducted at Oregon State University to test and evaluate the use of two types of waste: mixed waste paper (MWP) and refuse derived fuel (RDF). Wood biomass (ponderosa pine) was used as a benchmark and also cofired with MWP. Samples collected from the Pacific Northwest were tested for physical, chemical, combustion, and emission characteristics. Raw fuel samples were tested for moisture content and bulk density. The samples were then shredded and pelletized. Pelletized fuels were tested for ultimate and proximate analyses, ash fusion temperature, elemental ash analysis, higher heating value, moisture content, bulk density, and pellet durability. Using an existing biomass combustion facility, the samples were fired to determine the optimum thermodynamic conversion combustion condition for each fuel. Observations were made of physical problems associated with firing of the samples. Combustion products were continuously monitored for temperature and composition with a combustion analyzer. An EPA Method 5 sampling train was used to determine particulate, heavy metals, chloride, fluoride, and sulfate emissions. Leachate testing was performed on the bottom ash residue to determine heavy metal concentrations. Waste fuels provided a challenge for combustion study in a biomass combustion unit. Modifications were required to alleviate high ash content problems. Observations of corrosion and clinkers provided another comparison for fuel evaluation. Comparison of emissions resulting from different fuel types provided good practical information for industrial purposes. Observed trends indicated possible minimization of emissions corresponding to optimum thermodynamic conversion. Cofiring analysis revealed possible increases and decreases of heavy metal emissions for MWP and wood. / Graduation date: 1992

The first part of the thesis presents a study based on the forest biorefinery concept, which involves converting a pulp mill into a multi-purpose biofuels, biomaterials, and biopower production facility in which these products are produced in an environmentally compatible and sustainable manner. A key challenge in this process is the recovery of lignin from process streams such that it can be utilized in a variety of innovative green chemistry processes The first study examines the fundamental chemical structure of LignoBoost derived lignin recovered from Kraft pulping streams using an acid precipitation/washing methodology. Functional group analysis and molecular weight profiles were determined by nuclear magnetic resonance (NMR) and size exclusion chromatography. These findings gave valuable insight into the physical properties and the determining chemical properties of this currently underutilized, renewable bioresource. The second study is based on the future second generation bioethanol production process, where ethanol produced from lignocellulosic materials will bring about the co-production of significant amounts of under-utilized lignin. The study examines the potential of conventional heterogeneous and novel homogeneous catalysts for the selective cleavage of the aryl-O-aryl and aryl-O-aliphatic linkages of ethanol organosolv lignin to convert it from a low grade fuel to potential fuel precursors or other value added chemicals. The experimental data demonstrated that aryl-O-aryl and aryl-O-aliphatic linkages could be cleaved and the hydrogenated lignin had a decrease in oxygen functionality and the formation of products with lower oxygen content. The second part of this thesis reports the development and optimization of a novel qualitative method for the determination of the various types of hydroxyl groups present in biodiesel production streams. In the first study, the use of 2-chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane as a phosphitylation reagent for quantitative ³¹P-NMR analysis of the hydroxyl groups in biodiesel process samples has been developed. Subsequently a characteristic chemical shifts library is developed with model compounds to provide quantitative data on the concentration of biodiesel precursors, intermediates and final product. The last part of this thesis depicts the results of an industrial trial based on the novel biodiesel analytical method developed earlier.

Thesis (Ph. D.)--University of Missouri-Columbia, 1999. / Typescript. Vita. Includes bibliographical references. Also available on the Internet.

Thesis (Ph. D.)--University of Missouri-Columbia, 2000. / Typescript. Vita. Includes bibliographical references. Also available on the Internet.