Växthus används för att ge ett bättre odlingsklimat åt grödor och växter. För ytterligare förbättring av förhållandena används växthusvävar som exempelvis kan reglera temperatur, fuktighet och ljustillförsel. Väven som behandlas i denna rapport är en så kallad energiväv som främst har till uppgift att minska energiåtgången vid uppvärmning.När väven är fördragen nattetid, ökar luftfuktigheten då grödorna avger fukt dygnet runt. Fukten kan kondenseras mot energiväven, vilket gör att det bildas droppar på väven som kan falla ned på växtligheten. Den höga luftfuktigheten kan medföra svampsjukdomar och i övrigt också bidra till att tillväxten avstannar. Ludvig Svensson AB i Kinna som tillverkar växthusvävar vill undersöka hur struktur och materialval påverkar energivävens fuktgenomsläpplighet. Detta skall göras genom framtagning av ett antal olika provmaterial, där modifieringar av energiväven görs. Provmaterialens fukttransmission mäts med fyra metoder, saltmetoden (EN ISO 15 496:2004), kanadensiska burkmetoden (CAN2-4.2-metod 49:1977), hudmodellen (ISO 11 092:1993 (E)) och Permatran-W som baseras på ASTM E96/E96M-05. De två förstnämnda metoderna utfördes på Swerea IVF AB i Mölndal. Ett antal förändringar gjordes på väven, däribland byte av material, ändring av masklängd och bindningstyp. Resultaten visade att en modifiering av plastsorten i väven gav störst förändring av fuktgenomsläppligheten. De flesta provmaterialen påvisade en mindre fukttransmission än hos den ursprungliga energiväven, dessa värden kan i sig ge användbar data inför framtida produktutveckling. / <p>Greenhouses are used for the improvement of the cultivation climate for crops and plants. For further improvement of the environment, climate screens can be used, they control for example the temperature, humidity and brightness. The screen which is treated in this report is an energy saving screen that lowers the energy consumption.</p><p></p><p>When the greenhouse is covered at night, the humidity increases, since the crops transpire round the clock. The moisture can condense on the cold screen which contributes to the forming of drops that fall down on the vegetation. This effect and the high humidity level in the greenhouse could lead to fungus disease and a decrease in the growth of the cultivation.</p><p></p><p>Ludvig Svensson AB in Kinna who produces different climate screens, would like to investigate how structure and choice of material affects the energy saving screens water vapour transmission. This should be done by modifying the existing climate screen. The modified materials will be tested with four water vapour transmission methods, ISO 15496:2004, the cup method (CAN2-4.2-method 49:1977), the sweating hotplate method (ISO 11092:1993 (E)) and Permatran-W (based on ASTM - E 96/E 96M -05). The first two methods will be executed at Swerea IVF in Mölndal.</p><p></p><p>A few changes were made on the original screen, for example an exchange of materials, a change of looplenght and a change of binding. The results showed that a modification of the plastic band in the screen gave the largest vapour transmission. The most of the modified materials showed a lower humidity transport then the now existing screen. The given results can still offer useful information for future product development.</p><p>Program: Textilingenjörsutbildningen</p>

La capture du carbone de combustion implique le transport de gaz riches en CO2 a haute temperature. Cette etude vise a preciser les facteurs controlant l'oxydation d'alliages chromino-formeurs dans ces environnements. Des alliages modeles Fe–Cr et Fe–Cr–Ni ont ainsi ete exposes a des melanges Ar–CO2–H2O a 650 et 800 °C, et les produits de reaction examines a l'aide de techniques de metallographie conventionnelles. La precipitation de carbures sous des couches d'oxyde indique une sursaturation en carbone a l'interface metal/oxyde, par rapport a l'atmosphere exterieure. Sur la base d'un modele d'equilibre thermodynamique local, les vitesses de carburation et fractions volumiques de precipites mesurees sont utilisees pour evaluer l'influence de la composition de l'oxyde et de la presence d'H2O dans le gaz sur le transport du carbone. En analysant la depletion en chrome dans l'alliage sous-jacent, nous montrons que la carburation limitee sous une couche de chromine n'altere pas la stabilite de l'oxyde. L'evolution morphologique des nodules d'oxydes riches en fer formes a la suite de la rupture localisee de la chromine est mise en relation avec la capacite de l'alliage a fournir du chrome a l'interface metal/oxyde. L'application de modeles de germination-croissance aux cinetiques de developement de nodules permet d'evaluer la resistance des couches de chromine via des frequences de germination determinees a partir des taux de recouvrement de nodules et des gains de masse des echantillons. Nous examinons enfin l'importance relative de la germination et de la croissance des nodules dans le controle de la performance globale des alliages en fonction de la temperature de reaction. / Materials to convey hot CO2-rich gases are needed in carbon capture technologies currently being developed. This work is aimed at investigating the factors controlling the oxidation of chromia-forming alloys in these atmospheres. To do so, model Fe–Cr and Fe–Cr–Ni alloys were exposed to Ar–CO2–H2O gas mixtures at 650 and 800 °C,and the reaction products examined using conventional metallography techniques. Carbide precipitation beneath oxide scales reflects a carbon supersaturation at the metal/oxide interface relative to the external atmosphere: as a gradient of oxygen potential is established across the growing scale, an elevated carbon activity results at the interface if the scale transmits carbon. On the basis of a local equilibrium model, measured carburisation rates and precipitate volume fractions were used to evaluate the influence of oxide composition and of the presence of H2O in the gas on carbon uptake/transport in the scales. Limited carburisation beneath Cr2O3 scales was shown by means of an analysis of subscale chromium depletion not to alter the oxide stability. The morphological evolution of Fe-rich oxide nodules formed as a result of localised Cr2O3 failure was studied in relation to the alloy ability to supply chromium to the metal/oxide interface. Application of nucleation-growth models to the kinetics of nodule development allowed the resistance of Cr2O3 scales to be evaluated in terms of nodule nucleation rates determined from experimental nodule surface coverages and specimen weight gains. The relative importance of nodule nucleation and growth in determining the overall alloy performance as a function of reaction temperature is discussed.

Cette thèse s'intéresse aux liens entre l'évolution du contenu en eau de l'atmosphère et la formation des précipitations. L'objectif général des travaux qui y sont présentés est d'améliorer la compréhension des mécanismes de formation des précipitations en se basant sur des mesures de vapeur d’eau effectuées principalement par GPS. Une étude statistique originale effectuée à partir de 5 années de mesures (GPS, pluviomètre et capteurs météorologiques au sol, situés sur le campus des Cézeaux, Clermont-Ferrand) a permis de mettre en évidence qu'en moyenne l'augmentation du contenu intégré en vapeur d'eau (IWV) est un précurseur de la formation des pluies, et que les variations de l'humidité dans la colonne atmosphérique toute entière sont pour l'essentiel découplées de celles observées à la surface. En effet, contrairement à l'humidité au sol, l'IWV atteint son maximum en moyenne 20 minutes avant le pic de précipitations. Cela semble indiquer que lorsque les précipitations commencent la condensation devient prépondérante à l'échelle de la colonne atmosphérique toute entière tandis qu'au niveau du sol il y a une forte évaporation. L'étude détaillée des précipitations convectives qui se sont produites sous le vent des Vosges le 18 Juillet 2007 (période d'observation intensive 9a de la campagne Convective and Orographically- induced Precipitation Study - COPS), a permis de mettre en évidence l'apport essentiel du GPS pour l'étude des précipitations convectives dans une région de moyenne montagne. En effet, grâce à une utilisation combinée de mesures radar à haute résolution, d'analyses de surface et de stations GPS (permettant d’observer des structures du champ de vapeur d’eau à petite échelle et haute résolution temporelle, à 2D et 3D), nous avons montré que l'accumulation d'humidité précédait de plusieurs heures l'initiation de la convection et que le déclenchement convectif est favorisé par la convergence du flux d'humidité. Cette dernière est associée à une convergence du vent dans les basses couches, ce qui entraîne un important transport vertical de la vapeur d'eau, observé grâce à la tomographie GPS. La direction du vent en amont du relief s'est révélée contrôler pour beaucoup la localisation des zones de convergence. Le forçage local dû à l'orographie à petite échelle (< 5km) a également été mis en évidence, en complétant les observations par des résultats de simulations numériques à haute résolution. / This thesis focuses on the links between the evolution of atmospheric water vapour content and precipitation formation. The general goal of the works presented is to improve the understanding of the precipitation formation mechanisms using water vapour measurements, primarily made by GPS. An original statistical study based on 5 years of data (from GPS, rain gauge, and other meteorological probes collocated on a platform in Clermont-Ferrand, France) shows that the increase of integrated water vapour amount (IWV) is, on average, a precursor for rain formation. We also show that the IWV evolution is primarily disconnected from the variations in water vapour mixing ratio measured at the surface. Indeed, unlike moisture at the surface, the IWV reaches its maximum on average 20 minutes before the precipitation peak. This could indicate that the condensation dominates in the whole column, while at the surface there is a strong evaporation. The detailed study of convective precipitations which occurred on 18th of July 2007 (Intensive Operation Period 9a of the Convective and Orographically- induced Precipitation Study COPS) on the lee side of the Vosges Mountains shows the significant contribution of GPS measurement for the study of convective precipitations in mountainous areas. Indeed, Thanks to a synergic use of radars, surface meteorological analysis and GPS receivers (which allow the observation of small scale water vapour field features, with a high temporal resolution), we show that the moisture accumulation occurs several hours before convective initiation and we also show that the triggering of the convection is favoured by moisture flux convergence (MFC). This MFC is associated with surface wind convergence leading to a substantial vertical transport of water vapour, which is observed by the GPS tomography. The wind direction on the windward side of the mountains appears to control the location of this convergence zone. The role of local forcing due to small scale orography (< 5km) is also shown, complementing the observations by the results from high resolution numerical model simulations.

The eddy covariance (EC) technique was used to measure half hourly fluxes of energy and evaporation from 15 December 2007 to 30 November 2008 at the Scott Research Farm, located 7 km east of Hamilton. Many other supporting measurements of climate and soil variables were also made. The research addressed three objectives: 1. To examine the accuracy of the eddy covariance measurement technique. 2. Understand the surface partitioning of energy and water vapour on a diurnal to annual timescale. 3. Compare measurements of evaporation to methods of estimation. Average energy balance closure at Scott Farm was deficient by 24%, comparable to published studies of up to 30%. Three lysimeter studies were carried out to help verify eddy covariance data. These resulted in the conclusions that; 1) lysimeter pots needed to be deeper to allow for vegetation rooting depths to be encompassed adequately; 2) forcing energy balance closure was not supported by two of the studies (summer and winter); 3) latent heat flux (λE) gap filling of night time EC data during winter over estimated values by about 10 W m-2; and 4) the spring lysimeter study verified eddy covariance measurements including the closure forcing method. Some uncertainty still exists as to the accuracy of both lysimeter and EC methods of evaporation measurement because both methods still have potential biases, however for the purpose of this study, it would appear data are sufficiently accurate to have confidence in results. Energy and water vapour fluxes varied on both a diurnal and seasonal timescale. Diurnally, fluxes were small or negative at night and were highest during the day, usually at solar noon. Seasonally, spring and summer had the highest energy and evaporation fluxes and winter rates were small but tended to exceed available energy supply. Evaporation was constrained by soil moisture availability during summer and by energy availability during winter. Estimated annual evaporation at Scott Farm was 755 mm, 72% of precipitation. Two evaporation models were compared to eddy covariance evaporation (EEC) measurements; the FAO56 Penman-Monteith model (Eo) and the Priestley-Taylor model (EPT). Both models over estimated evaporation during dry conditions and slightly under estimated during winter. The α coefficient that is applied to EPT was not constant and a seasonally adjusted value would be most appropriate. A crop coefficient of 1.13 is needed for Eo measurements during moist conditions. Eo began over estimating evaporation when soil moisture contents dropped below ~44%. A water stress adjustment was applied to both models which improved evaporation estimates, however early onset of drying was not able to be adjusted for. The adjusted Eo model is the most accurate overall, when compared to EEC.

Hypersonic vehicles, based on scramjet engines, have the potential to deliver inexpensive access to space when compared with rocket propulsion. The technology, however, is in its infancy and there is still much to be learned from fundamental studies.¶ Flows that represent the conditions inside a scramjet engine can be generated in ground tests using a free-piston shock tunnel and a combustor model. These facilities provide a convenient location for fundamental studies and principles learned during ground tests can be applied to the design of a full-scale vehicle.¶ A wide range of diagnostics have been used for studying scramjet flows, including surface measurements and optical visualisation techniques.¶ The aim of this work is to test the effectiveness of tunable diode laser absorption spectroscopy (TDLAS) as a scramjet diagnostic.¶ TDLAS utilises the spectrally narrow emission from a diode laser to probe individual absorption lines of a target species. By varying the diode laser injection current, the laser emission wavelength can be scanned to rapidly obtain a profile of the spectral line. TDLAS has been used previously for gas-dynamic sensing applications and, in the configuration used in this work, is sensitive to temperature and water vapour concentration.¶ The design of the sensor was guided by previous work. It incorporated aspects of designs that were considered to be well suited to the present application. Aspects of the design which were guided by the literature included the laser emission wavelength, the use of fibre optics and the detector used. The laser emission wavelength was near 1390 nm to coincide with relatively strong water vapour transitions. This wavelength allowed the use of telecommunications optical fibre and components for light delivery. Detection used a dual-beam, noise cancelling detector.¶ The sensor was validated before deployment in a low-pressure test cell and a hydrogen–air flame. Temperature and water concentration measurements were verified to within 5% up to 1550 K. Verification accuracy was limited by non-uniformity along the beam path during flame measurements.¶ Measurements were made in a scramjet combustor operating in a flow generated by the T3 shock tunnel at the Australian National University. Within the scramjet combustor, hydrogen was injected into a flame-holding cavity and the sensor was operated downstream in the expanded, supersonic, post-combustion flow. The sensor was operated at a maximum repetition rate of 20 kHz and could resolve variation in temperature and water concentration over the 3ms running time of the facility.¶ Results were repeatable and the measurement uncertainty was smaller than the turbulent fluctuations in the flow. The scramjet was operated at two fuel-lean equivalence ratios and the sensor was able to show differences between the two operating conditions. In addition, vertical traversal of the sensor revealed variation in flow conditions across the scramjet duct.¶ The effectiveness of the diagnostic was tested by comparing results with those from other measurement techniques, in particular pressure and OH fluorescence measurements, as well as comparison with computational simulation.¶ Combustion was noted at both of the tested operating conditions in data from all three measurement techniques.¶ Computation simulation of the scramjet flow significantly under-predicted the water vapour concentration. The discrepancy between experiments and simulation was not apparent in either the pressure measurements or the OH fluorescence, but was clear in the diode laser results.¶ The diode laser sensor, therefore, was able to produce quantitative results which were useful for comparison with a CFD model of the scramjet and were complimentary to information provided by other diagnostics.

<p>Water vapour is the most important greenhouse gas and plays a fundamental role in the climate system and for the chemistry of the Earth's atmosphere. This thesis presents observations of water vapour in the middle atmosphere with a particular focus on the mesosphere. The majority of these observations presented in this thesis have been performed by the Swedish satellite Odin, providing global observations since 2001. Further observations come from the Hygrosonde-2 campaign in December 2001 based on balloon and rocket-borne measurements. A general overview of Odin's water vapour measurements in the middle atmosphere is given. The optimisation of the mesospheric water vapour retrieval is presented in detail.</p><p>The analysis of the observations has focused mainly on different dynamical aspects utilising the characteristic of water vapour as a dynamical tracer in the middle atmosphere. One application is the mesospheric part of the semi-annual oscillation (SAO). The observations reveal that this oscillation is the dominant pattern of variability between 30°S and 10°N in the mesosphere up to an altitude of 80 km. Above 90 km the SAO is dominating at all latitudes in the tropics and subtropics. It is shown that the SAO exhibits a distinct phase change between 75 km and 80 km in the tropical region.</p><p>This thesis also presents the first satellite observations of water vapour in the altitude range between 90 km and 110 km, extending the observational database up into the lower thermosphere. In the polar regions water vapour exhibits the annual maximum during winter time above 95 km, mainly caused by upwelling during this season. This behaviour is different from that observed in the subjacent part of the mesosphere where the annual maximum occurs during summer time.</p><p>The Hygrosonde-2 campaign provided a high resolution measurement of water vapour in the vicinity of the polar vortex edge. This edge prevents horizontal transport causing different water vapour characteristics inside and outside the polar vortex. The observations show that this separating behaviour extends high up into the mesosphere. Small scale transitions in the Hygrosonde-2 profile between conditions inside and outside the vortex coincided with wind shears caused by gravity waves.</p>

Water vapour is the most important greenhouse gas and plays a fundamental role in the climate system and for the chemistry of the Earth's atmosphere. This thesis presents observations of water vapour in the middle atmosphere with a particular focus on the mesosphere. The majority of these observations presented in this thesis have been performed by the Swedish satellite Odin, providing global observations since 2001. Further observations come from the Hygrosonde-2 campaign in December 2001 based on balloon and rocket-borne measurements. A general overview of Odin's water vapour measurements in the middle atmosphere is given. The optimisation of the mesospheric water vapour retrieval is presented in detail. The analysis of the observations has focused mainly on different dynamical aspects utilising the characteristic of water vapour as a dynamical tracer in the middle atmosphere. One application is the mesospheric part of the semi-annual oscillation (SAO). The observations reveal that this oscillation is the dominant pattern of variability between 30°S and 10°N in the mesosphere up to an altitude of 80 km. Above 90 km the SAO is dominating at all latitudes in the tropics and subtropics. It is shown that the SAO exhibits a distinct phase change between 75 km and 80 km in the tropical region. This thesis also presents the first satellite observations of water vapour in the altitude range between 90 km and 110 km, extending the observational database up into the lower thermosphere. In the polar regions water vapour exhibits the annual maximum during winter time above 95 km, mainly caused by upwelling during this season. This behaviour is different from that observed in the subjacent part of the mesosphere where the annual maximum occurs during summer time. The Hygrosonde-2 campaign provided a high resolution measurement of water vapour in the vicinity of the polar vortex edge. This edge prevents horizontal transport causing different water vapour characteristics inside and outside the polar vortex. The observations show that this separating behaviour extends high up into the mesosphere. Small scale transitions in the Hygrosonde-2 profile between conditions inside and outside the vortex coincided with wind shears caused by gravity waves.

The compatibility properties of some contemporary finish coats together with their complementary layers used in insulated exterior walls were examined in terms of water vapour permeability and modulus of elasticity. Basic physical and mechanical properties of some synthetic-, cement- and polymer-based external finish coats were analyzed in laboratory. Some additional samples, complementing the wall section, were also examined for their water vapour permeability. Results showed that the finish coats were high vapour permeable although they had high resistance to water vapour permeation, which was achieved by their application in thin layers. Cement-based undercoats were found to be medium permeable. The application of primer and/or paint was found to decrease the permeability of finish coats in different ranges. Thermal insulation layer was found to interrupt water vapour flow considerably. Among polystyrene- and mineral-wool-based thermal insulation boards, rockwool was recommended as the insulation layer due to its medium vapour permeability. In conclusion, walls insulated externally with rockwool boards and plastered with polymer-based finish coat, FC8ACB or synthetic-based finish coat FC3SB were found to be the most proper combination in terms of breathing and thermal resistance capabilities. All finish coats seemed to have sufficient strength and except the synthetic-based finish coat, FC2SB, they seemed to be compatible with each other and with the masonry in terms of their Emod values. Further studies were recommended on some other compatibility properties of finishing systems, such as thermal and moisture dilatation properties, and on the relation between the resistance to water vapour permeation and water permeability.

Der Wasserdampfgehalt der Atmosphäre gehört zu den Hauptkontrolleuren des Treibhauseffektes und spielt eine Schlüsselrolle im globalen Energiekreislauf, wobei den Polargebieten als globale Wärmesenken eine besondere Bedeutung zukommt. Im Rahmen dieser Arbeit wurde aus Messungen des Global Positioning System (GPS) der integrierte Wasserdampfgehalt innerhalb der letzten Dekade bestimmt und analysiert. Die Untersuchungen stützen sich auf die Reprozessierung eines aus 195 Stationen bestehenden globalen GPS-Netzes. Die aus den geschätzten GPS-Troposphärenparameter bestimmten Wasserdampf- zeitreihen wurden hinsichtlich Genauigkeit und Homogenität untersucht. Nach Korrektion der Inhomogenit äten ist es möglich, mit GPS mehrjährige Schwankungen im potenziellen Niederschlagswasser mit einer Genauigkeit besser als 0,3 mm Höhe der Wassersäule zu erfassen. Als Ergebnis der Untersuchungen zeigen sich in Europa und großen Teilen Nordamerikas Anomalien des Wasserdampfgehaltes im Bereich eines Millimeters, welche sich vor allem auf thermodynamische Effekte zurückführen lassen. In den Tropen und im Südosten der USA können die Wasserdampfanomalien 3 bis 5 mm betragen. Sie sind durch dynamische Prozesse bedingt, die mit der Südlichen Oszillation im Zusammenhang stehen. Eine Anwendung der aus GPS-Beobachtungen bestimmten Wasserdampfzeitreihen ist die Validierung des Wasserdampfes im globalen Wettervorhersagemodell des National Center for Environmental Predicton (NCEP). Über Europa und großen Teilen Nordamerikas reproduziert NCEP die Schwankungen des Wasserdampfgehaltes sehr gut und stellt damit eine gute Datengrundlage für ?ächendeckende Untersuchungen langfristiger Veränderungen im Wasserdampfgehalt dar. In der Antarktis und den Tropen wird jedoch das saisonale und mehrjährige Signal des Wasserdampfes von NCEP um 25% bis 40% unterschätzt. Als zweite Anwendung der GPS-Wasserdampfzeitreihen erfolgt die Validierung satellitenbasierter Radiometermessungen über der Antarktis. Sie zeigt eine gute Übereinstimmung der Wasserdampfwerte aus GPSund Radiometermessungen. Die im Rahmen dieser Arbeit aus GPS-Beobachtungen bestimmten Wasserdampfzeitreihen bilden eine sehr gute Datengrundlage für weitergehende Untersuchungen der Wetter- und Klimaforschung. / The atmospheric water vapour is one of the main variables controlling the greenhouse effect and it plays a crucial role in the global energy cycle. In this context the polar regions which act as global heat sinks are especially important. This study uses observations from the Global Positioning System (GPS) to investigate changes of the integrated atmospheric water vapour. It is based on a reprocessing of a global GPS network consisting of 195 stations. A strong emphasis was placed on the investigation of the accuracy and the homogeneity of the GPS derived water vapour time series. After correcting the inhomogeneities interannual ?uctuations in the precipitable water can be determined from GPS data with an accuracy of 0.3 mm in water column height. As a result, the interannual variations in the water vapour content are in the order of one millimetre over Europe and over large areas of North America. They are mainly related to thermodynamic effects. In the tropics and in the south east of the USA water vapour anomalies can reach 3 to 5 mm caused by dynamic processes connected to the Southern Oscillation. As one application of the estimated GPS water vapour time series a validation of water vapour from the global numerical weather prediction model of the National Center for Environmental Prediction (NCEP) was carried out. Over Europe and large parts of North America the seasonal signal and the interannual variations of the water vapour are very well reproduced by NCEP. Hence, in these regions NCEP presents a good database for area-wide investigations of long-term changes in the water vapour content. However, in Antarctica and in the Tropics the seasonal and also the interannual signals of the NCEP water vapour are strongly underestimated by 25% to 40%. A second application of the estimated GPS water vapour time series is the validation of satellite-based radiometer measurements over Antarctica. A good agreement was found between the water vapour derived from GPS and radiometer data. The water vapour time series estimated in this study provide a good basis for further weather and climate related investigations.

The Global Positioning System (GPS) has been used for more than a decade for the accurate determination of position on the earth's surface, as well as navigation. The system consists of approximately thirty satellites, managed by the US Department of Defense, orbiting at an altitude of 20 200 kilometres, as well as thousands of stationary ground-based and mobile receivers. It has become apparent from numerous studies that the delay of GPS signals in the atmosphere can also be used to study the amosphere, particularly to determine the precipitable water vapour (PWV) content of the troposphere and the total electron content (TEC) of the ionosphere. This dissertation gives an overview of the mechanisms that contribute to the delay of radio signals between satellites and receivers. The dissertation then focuses on software developed at the Hartebeesthoek Radio Astronomy Observatory's (HartRAO's) Space Geodesy Programme to estimate tropospheric delays (from which PWV is calculated) in near real-time. In addition an application of this technique, namely the improvement of tropospheric delay models used to process satellite laser ranging (SLR) data, is investigated. The dissertation concludes with a discussion of opportunities for future work. / Thesis (M.Sc. (Physics))--North-West University, Potchefstroom Campus, 2004.