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Experimentelle Untersuchung zur Auflösungskinetik von Kaolinit und Montmorillonit in Anwesenheit von Sulfat, Phosphat, Amino- und Carbonsäuren sowie Harnstoff im offenen und geschlossenen System / Experimental study on the dissolution kinetics of kaolinite und montmorillonite in the presence of sulfate, phosphate, amino and carboxylic acids as well as urea in open and closed systemsHillebrecht, Jens 27 October 2005 (has links)
No description available.
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Terrestrial Archives of Meteoric 10BeAdrian A Singleton (11814842) 19 December 2021 (has links)
<div><div><div><p>The radionuclide 10Be is produced in the atmosphere and is delivered to Earth’s surface in meteoric rain and aerosols. The stable nuclide 9Be is present in trace concentrations within rocks in Earth’s crust and is released via chemical weathering. Together, these two isotopes have been employed to study a wide range of Earth processes. Here I explore new terrestrial archives of Be isotopes: cave speleothems and terrestrial Mn-oxides. Until this point, these archives have barely been studied. Only one published dataset of Be isotopes in cave speleothems exists (Lundblad, 2006), and to my knowledge, terrestrial manganese oxides are yet to be explored. However, since speleothems and Mn-oxides precipitate from groundwater, they have the potential to encode temporal variations in the 10Be/9Be ratio of water and colloids in the vadose zone.</p><p>I develop a framework for using the 10Be/9Be ratio in the dissolved phase and/or secondary weathering products as a metric of chemical weathering rate. I am motivated by several over-arching questions:</p><ol><li><p>1) Which factor, or factors, is/are dominant in controlling Be isotopes in speleothems and terrestrial Mn-oxides?</p></li><li><p>2) Can Be isotopes in speleothems be used as a metric of weathering rate over time, particularly across glacial/interglacial cycles?</p></li><li><p>3) Can Be isotopes be used to date the formation of terrestrial Mn-oxides?</p></li></ol><p>I measure Be-isotope concentrations in speleothems from Soreq Cave, Israel. By applying an equation that I derive in this thesis, I use the temporal variation in the speleothem10Be/9Be ratio to calculate chemical weathering rates over the last 168 ka. Chemical weathering varies with independent proxies for temperature. The weathering-temperature relationship can be fit to an Arrhenius relationship, and the calculated activation energy (Ea) matches other field-based estimates for feldspar, an abundant mineral in the soil above the cave. In the Appendices I present additional results of Be-isotope measurements in a flowstone from Buffalo Cave in South Africa, as well as Mn-oxides from the Appalachians.</p></div></div></div>
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Altération de l'île volcanique de Mayotte (Comores) : approches par géochimie des eaux et isotopie du silicium sur les roches de profils d'altération / Alteration of the volcanic island of Mayotte (Comoros) : approaches by water geochemistry and silicon isotopes on rock weathering profilesPuyraveau, Romain-Arnaud 05 October 2016 (has links)
Dans cette étude, nous cherchons à dresser le bilan de l’altération à l’échelle de l’île de Mayotte (en surface et en souterrain), à contraindre l’impact des facteurs de contrôle dominant l’altération, puis à caractériser les processus impliqués dans les fractionnements des isotopes du silicium à l’échelle du profil d’altération.Deux campagnes d’échantillonnage incluant des eaux de rivières et des eaux souterraines ont été réalisées en saison humide et sèche, complétées par le prélèvement mensuel de 5 rivières. La prise en compte des crues (3 % de l’année) dans le calcul des taux d’altération moyens annuels en rivière a entraîné une augmentation de ≈32 % du bilan annuel. Le taux d’altération chimique global de l’île de Mayotte s’élève à 94 t/km²/an (81 t/km²/an en surface & 131 t/km²/an en souterrain). Nos résultats mettent en avant le rôle prépondérant des écoulements souterrains dans le transport de matériel dissous directement à l’océan. La contribution du domaine souterrain au bilan de l’altération diminue avec l’âge des formations, soulignant l’implication de l’âge des roches du bassin versant comme paramètre clé dans le contrôle des taux d’altération.Les isotopes du Si ont été analysés sur des roches totales le long de profils d’altération associés à différentes conditions d'altération du régolite : météorique (basse température) ou hydrothermale (haute température). À l’échelle du profil, les deux types de régimes ont montré un appauvrissement en 30Si en fonction du degré d’altération. À l’échelle du minéral, le fractionnement des isotopes du Si s’est révélé plus négatif pendant la précipitation de kaolinite secondaire à haute température qu’à basse température. / In this study, we seek to establish the weathering budget at the scale of the island of Mayotte (rivers and groundwater), to constrain the impact of dominant control factors to the weathering both locally and at a global scale, and then to characterize the processes involved in the fractionation of silicon isotopes across the weathering profile.Two field campaigns, in order to sample river water and groundwater, were carried out during wet and dry season, supplemented by the monthly monitoring of 5 rivers. By taking account of river floods (3% of the year) in the calculation of average annual weathering rates in the river has increased the annual weathering budget by ≈32%. The overall rate of Mayotte Island chemical weathering is 94 t/km²/yr (81 t/km²/yr from surface & 131 t/km²/yr from underground). Our results highlight the important role of groundwater flow to the dissolved material export directly to the ocean. The contribution of groundwater to the weathering budget decreases with the age of the geological formations, highlighting the involvement of the age of the rocks of the watershed as a key parameter in the weathering rates control.Si isotopes were analyzed for whole rock along two weathering profiles associated with different alteration conditions of the regolith: meteoric (low temperature) or hydrothermal (high temperature). At the weathering profile scale, the two types of alteration regimes showed 30Si depletion as a function of the degree of weathering. At the mineral scale, Si isotope fractionation was more negative during the secondary kaolinite precipitation at high temperatures than at low temperatures.
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