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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
231

The polychaetes Australonereis ehlersi (Augener) and Simplisetia aequisetis (Augener) within the eutrophic Swan river estuary, Western Australia : life history, population structure and effects on sedimentary microbial nitrogen cycling

De Roach, Robert John January 2007 (has links)
[Truncated abstract] In my study of Australonereis ehlersi and Simplisetia aequisetis [Polychaeta: Nereididae] from the Swan River Estuary, Western Australia, I assessed the life history, geographical population structure and production of both species, then measured their roles in microbial denitrification and nitrogen cycling within the sediments of the estuary. Both species exhibit a mean life-span of approximately 1 year, a production:biomass turnover rate of about 3 and potentially are capable of reproducing throughout the year, peaking during winter to spring. A. ehlersi exhibited a marine euryhaline distribution, occurring only in the main basin and lower estuary, typically at a very low density of adults; S. aequisetis exhibited a euryhaline distribution, occurring estuary-wide during both summer and winter. High density and biomass of A. ehlersi occurred in the middle estuary (at Como), predominantly as winter- recruiting juveniles. Gravid, atokous adults spawned pelagically, with a 2 to 4 month larval development period preceding settlement. Intolerance of freshwater by the pelagic larvae possibly is the major reason excluding specimens from the upper reaches of the Estuary. Adult S. aequisetis brood eggs and embryonic larvae in tubiculous burrows; the life-cycle presumably progresses entirely in sediments of relatively stable interstitial salinity (compared to pelagic fluctuations), enabling recruitment by larvae and adults into the upper reaches of the Estuary. ... The ammonification rate was higher for A. ehlersi than S. aequisetis-inhabited cores, and lowest in uninhabited cores where polychaete excretion was absent. In the absence of C2H2, sediments of S. aequisetis inhabited cores indicated a lower net NH4+ influx than uninhabited cores, whereas A. ehlersi inhabited cores exhibited a slight net efflux of NH4+ from the sediment. The difference in magnitude of nitrogenous fluxes imparted by the two polychaete species is hypothesised to relate to the influence of their respective habits on the composition and activity of their associated sedimentary microbial community. Juvenile S. aequisetis are hypothesised to homogenise and aerate sediment continually, enhancing microbial nitrification and retarding anaerobic denitrification. Permanent A. ehlersi burrows would facilitate vertical and radial oxic/anoxic stratification of sediment which, combined with enhanced substrate supply through burrow ventilation, resulted in increased rates of microbial denitrification and nitrification. I have proposed a preliminary framework by which guilds of benthic fauna, each with similar designated habits, may be tested for predictable bioturbative influence on nitrogen cycling, i.e. whether particular habits may be considered 'functional groups'. In conclusion, the fine-scale effects of A. ehlersi and S. aequisetis on microbial nitrogen cycling are integrated with details of broader-scale population dynamics to define the role of polychaetes in estuarine nitrogen cycling, with a view to managing eutrophication.
232

Assessment and prevalence of dementia in indigenous Australians

Smith, Kathryn Elizabeth January 2009 (has links)
Until recently, there was no dementia screening tool for Indigenous Australians and a paucity of information on the extent of dementia in Indigenous Australians. This thesis describes the development and validation of a tool to assess cognitive impairment in remote Indigenous Australians with the primary purpose of determining the prevalence of dementia and other associated conditions in this population. The tool was reevaluated with the larger prevalence sample and a short version of the tool was developed and evaluated. The Kimberley Indigenous Cognitive Assessment (KICA) tool was validated with Indigenous Australians aged over 45 years from the Kimberley region of Western Australia (n=70). The results were later confirmed in a larger sample from the remote Kimberley (n=363), and an additional sample in rural and remote areas of the Northern Territory (n=47). The KICA results were compared to independent consensus diagnoses using DSM-IV and ICD-10. Interpreters were used whenever participants were not proficient in English. These data led to the determination of a cut-off score of 33/34 out of a possible total score of 39 for the cognitive component of the KICA (KICA-Cog), with a sensitivity of 0.93 and specificity of 0.95 and AUC of 0.98. The tool is now widely used within remote areas of Australia. A short version of the KICACog (sKICA-Cog) was developed and found to be a valid brief screening tool for dementia in the Kimberley population, and had a cut-off score of 20/21 out of a possible 25, with a sensitivity of 0.89, specificity of 0.95 and AUC of 0.98. The sKICA-Cog should be used in combination with the KICA cognitive informant questionnaire (KICA-IQ). The KICA-IQ cut-off score of 2/3 out of a possible 16 was determined, with a sensitivity of 0.76 and specificity of 0.84 and AUC of 0.91. Using the validated KICA, the prevalence of dementia and cognitive impairment not dementia (CIND) was determined in a semi-purposive sample consisting of 363 Indigenous Australians aged over 45 years from 6 Aboriginal communities and one town in the Kimberley region. Participants were screened with the full KICA and 165 participants had an independent specialist review with consensus diagnoses. The prevalence of dementia was 12.4%, 5.2 times greater than the Australian prevalence of 2.4%, after age adjustment. The prevalence of CIND was 8.0%. Characteristics associated with dementia included older age, male gender (OR 3.1, 95% CI 1.4, 6.8), no formal education (OR 2.7, 95% CI 1.1, 6.7), smoking (OR 4.5, 95% CI 1.1, 18.6), previous stroke (OR 17.9, 95% CI 5.9, 49.7), epilepsy (OR 33.5, 95% CI 4.8, 232.3) and head injury (OR 4.0, 95% CI 1.7, 9.4). Other factors associated with dementia included incontinence, falls and poor mobility. The KICA is a valid assessment tool for rural and remote Indigenous Australians. The prevalence of dementia amongst Indigenous Australians is substantially higher than generally found in non - Indigenous Australians and other populations in the developed and developing world.
233

Playas of the Yarra Yarra drainage system, Western Australia

Boggs, Dimity January 2009 (has links)
This thesis examines playas as integrated ecosystems, through investigation of long- and short-term processes associated with playa geomorphology, hydrology and diatom ecology, in playas of the Yarra Yarra drainage system of Western Australia. This landscape approach was conducted at a range of scales and consequently revealed a level of heterogeneity not previously described in Australian playas. The key result and common thread linking the three facets of the playas investigated is the importance of hydroperiod in defining the playa environment. The morphology and distribution of playas are described and the results presented of an examination of potential mechanisms determining intra-system variability. Measurements of the physical attributes of the playas, including length, area, shape, density and orientation, were made through Geographic Information System analysis and detailed interpretation of aerial photography. Two main morphological groups are distinguished: small (<10 ha), elliptical to circular playas with a NNW-SSE orientation; and large (>30 ha), elongated playas. Regional patterns in geomorphic attributes are markedly different between the west and east sides of the system. The boundary between the two regions coincides approximately with rainfall distribution. In this respect, climate is an overarching driver of geomorphological variation but sub-catchment characteristics are also critical determinants. Littoral drift and segmentation processes that are common to coastal lagoons but not commonly described in playas were identified from visual interpretation of aerial photographs of spits, bars and cuspate shorelines. Six small playas, representing an hydrological continuum from mostly wet to mostly dry, were selected for investigation of their hydrology and diatom ecology, enabling assessment ii of the variability of hydrology, hydrochemistry and of the effects of different hydrological environments on the distribution of taxa. Hydroperiod was highly variable and central to determining playa geomorphology and biology. In the six playas it ranged from 19 to over 211 days, and filling frequency from 1 to 3 cycles between 2002 and 2004, reflecting rainfall and sub-catchment variability. Monitoring a series of nested piezometers revealed that the playas were net discharge points for ground water over the period of survey. However, small local vertical head variations indicate ground water does not discharge at the same rate across the playa surfaces and that playas may have short-lived phases of ground water recharge. Hydrochemically, the playas are typical of salt lakes in Australia. They displayed a wide range of salinity values, neutral to alkaline pH and ionic composition similar to sea water. It is postulated that the geochemical evolution of waters in the playas follows a pathway where low salinity recharge waters with dilute sea water salts progress to Na-Cl dominated brines through evaporative concentration. Surface waters showed an ionic dominance consistent with sea water with minor variations attributed to transitional phases in the geochemical evolution of the waters. Shallow ground waters showed a common and consistent pattern of ionic dominance: Na+ >Mg2+ >K+ >Ca2+ : Cl- >SO4 2- >HCO3 ->CO3 2-.
234

Psychopathic-like-traits and aggression in suspended mainstream school children and adolescents

Cordin, Robin M. January 2008 (has links)
[Truncated abstract] The overall aim of the research reported in this thesis was to explore the viability and utility of the construct of psychopathy and aggression in children and adolescents. Specifically, by taking a developmentally informed approach it sought to develop new instrumentation which measured psychopathic-like-traits, and verbal proactive and reactive aggression in non-referred mainstream school children and adolescents. To achieve this, four separate yet interrelated studies were conducted. Study One comprised three phases relating to the development and validation of two new instruments. In Phase One the instruments currently used to measure psychopathy were reviewed and items relevant to young persons were selected for inclusion in a draft version of the new psychopathy screening instrument. Phase Two, which sought to further explore the construct of psychopathy in children and adolescents, comprised a series of interviews with school principals, deputy principals, psychologists, and education officers at the main juvenile detention centre in Perth, Western Australia. These interviews provided information relating to the behaviour and characteristics of children and adolescents who present with psychopathic-like-traits. As a consequence of the feedback from the Phase Two data, Phase Three reviewed the instrumentation currently used to measure aggression in children and adolescents. From this items were selected for possible inclusion in an aggression questionnaire. The data gathered over these three phases resulted in 117 psychopathy related items being generated for the new instrument, which were subsequently reduced to 56 when duplicated items were identified and the extant knowledge of the construct applied. The 56 items were retained in a draft version of the newly developed instrument, which was named the Child and Adolescent Psychopathy Screening Instrument (CAPSI). The Study One data revealed the instrumentation used to date provided few measures of physical and verbal aggression - a characteristic of psychopathic-like behaviour. Thus, a review of instrumentation together with the information from the interviews resulted in 63 aggression items being generated. ... Study Four utilised information from the CAPSI and the CASA in conjunction with in-depth interviews to generate case studies to further elucidate the characteristics of children and adolescents with psychopathic-like-traits and extreme aggression. Case studies were undertaken with seven male students ranging in age from 8 to 15 years who had been suspended from mainstream schools. All boys scored very highly on the new instruments. All presented with extreme aggression, with some exhibiting proactive or premeditated aggression combined with a superficially engaging personality, insincere charm, lack of remorse, and lack of empathy. The findings from all four research studies are discussed in the light of the literature reviewed and the aims of the research. Implications are then drawn for researchers and clinicians, and directions for further research are suggested.
235

Development and use of a Monte Carlo-Markov cycle tree model for coronary heart disease incidence-mortality and health service usage with explicit recognition of coronary artery revascularization procedures (CARPs)

Mannan, Haider Rashid January 2008 (has links)
[Truncated abstract] The main objective of this study was to develop and validate a demographic/epidemiologic Markov model for population modelling/forecasting of CARPs as well as CHD deaths and incidence in Western Australia using population, linked hospital morbidity and mortality data for WA over the period 1980 to 2000. A key feature of the model was the ability to count events as individuals moved from one state to another and an important aspect of model development and implementation was the method for estimation of model transition probabilities from available population data. The model was validated through comparison of model predictions with actual event numbers and through demonstration of its use in producing forecasts under standard extrapolation methods for transition probabilities as well as improving the forecasts by taking into account various possible changes to the management of CHD via surgical treatment changes. The final major objective was to demonstrate the use of model for performing sensitivity analysis of some scenarios. In particular, to explore the possible impact on future numbers of CARPs due to improvements in surgical procedures, particularly the introduction of drug eluting stents, and to explore the possible impact of change in trend of CHD incidence as might be caused by the obesity epidemic. ... When the effectiveness of PCI due to introduction of DES was increased by reducing Pr(CABG given PCI) and Pr(a repeat PCI), there was a small decline in the requirements for PCIs and the effect seemed to have a lag. Finally, in addition to these changes when other changes were incorporated which captured that a PCI was used more than a CABG due to a change in health policy after the introduction of DES, there was a small increase in the requirements for PCIs with a lag in the effect. Four incidence scenarios were developed for assessing the effect of change in secular trends of CHD incidence as might be caused by the obesity epidemic in such a way that they gradually represented an increasing effect of obesity epidemic (assuming that other risk factors changed favourably) on CHD incidence. The strategy adopted for developing the scenarios was that based on past trends the most dominant component of CHD incidence was first gradually altered and finally the remaining components were altered. iv The results showed that if the most dominant component of CHD incidence, eg, Pr(CHD - no history of CHD) levelled off and the trends in all other transition probabilities continued into future, then the projected numbers of CABGs and PCIs for 2001-2005 were insensitive to these changes. Even increasing this probability by as much as 20 percent did not alter the results much. These results implied that the short-term effect on projected numbers of CARPs caused by an increase in the most dominant component of CHD incidence, possibly due to an ?obesity epidemic, is small. In the final incidence scenario, two of the remaining CHD incidence components-Pr(CABG - no history of CHD) and Pr(CHD death - no CHD and no history of CHD) were projected to level off over 2001-2005 because these probabilities were declining over the baseline period of 1998-2000. The projected numbers of CABGs were more sensitive (compared to the previous scenarios) to these changes but PCIs were not.
236

Curriculum contestation : analysis of contemporary curriculum policy and practices in government and non-government education sectors in Western Australia

Griffiths, Joanne January 2008 (has links)
[Truncated abstract] The aim of this study was to analyse the changing dynamics within and between government and non-government education sectors in relation to the Curriculum Framework (CF) policy in Western Australia (WA) from 1995 to 2004. The Curriculum Council was established by an act of State Parliament in 1997 to oversee the development and enactment of the CF, which was released in 1998. A stated aim of the CF policy was to unify the education sectors through a shared curriculum. The WA State government mandated that all schools, both government and non-government, demonstrate compliance by 2004. This was the first time that curriculum was mandated for non-government schools, therefore the dynamics within and between the education sectors were in an accelerated state of transformation in the period of study. The timeframe for the research represented the period from policy inception (1995) to the deadline for policy enactment for Kindergarten to Year 10 (2004). However, given the continually evolving and increasingly politicised nature of curriculum policy processes in WA, this thesis also provides an extended analysis of policy changes to the time of thesis submission in 2007 when the abolition of the Curriculum Council was formally announced - a decade after it was established. ... The research reported in this thesis draws on both critical theory and post-structuralist approaches to policy analysis within a broader framework of policy network theory. Policy network theory is used to bring the macro focus of critical theory and the micro focus of post-structuralism together in order to highlight power issues at all levels of the policy trajectory. Power dynamics within a policy network are fluid and multidimensional, and power struggles are characteristic at all levels. This study revealed significant power differentials between government and non-government education sectors caused by structural and cultural differences. Differences in autonomy between the education sectors meant that those policy actors within the non-government sector were more empowered to navigate the competing and conflicting forms of accountabilities that emerged from the changes to WA curriculum policy. Despite both generalised discourses of blurring public/private boundaries within the context of neoliberal globalisation and specific CF goals of bringing the sectors together, the boundaries continue to exist. Further, there is much strategising about how to remain distinct within the context of increased market choice. This study makes a unique and significant contribution to the understanding of policy processes surrounding the development and enactment of the CF in WA and the implications for the changing dynamics within and between the education sectors. Emergent themes and findings may potentially be used as a basis for contrast and comparison in other contexts. The research contributes to policy theory by arguing for closer attention to be paid to power dynamics between localised agency in particular policy spaces and the state-imposed constraints.
237

Kinematics of bidirectional extension and coeval NW-directed contraction in orthogneisses of the biranup complex, Albany Fraser Orogen, Southwestern Australia

Barquero-Molina, Miriam 18 March 2011 (has links)
Granulite-facies orthogneisses of the Mesoproterozoic Albany-Fraser Orogen from the locality of Bremer Bay, in southwestern Australia, record at least three phases of widespread, pervasive NW- and NE-trending bidirectional extension that alternate with shortening and/or shear related structures. Crustal extension occurred ca. 1180 Ma, based on SHRIMP U–Pb zircon geochronology of melts generated during deformation, which coincided with Stage II (1215-1140 Ma) of the Albany-Fraser Orogeny, a period of NW-directed contraction. Eight different deformation phases can be recognized in the Bremer Bay area: (1) formation of a pervasive migmatitic fabric, defined by alternating leucosomes and melanosomes, parallel to the main compositional layering, and axial planar to localized isoclinal folds of cm-wide melt bands; (2) first bidirectional extension phase, which formed cm-scale square boudins of mafic layers parallel to the main migmatitic fabric; (3) formation of open to isoclinal, upright to overturned, SW-plunging, NW-verging m-scale folds of early square and rectangular boudins and dominant migmatitic foliation; (4) renewed coeval NE- and NW-directed extension that produced intermediate (< 1 meter to a few meters) boudins of the migmatitic fabric and compositional layering; (5) formation of regional-scale, NW-verging, SW-plunging overturned folds of all previous structures; (6) third phase of bidirectional extension that formed large, decameter-scale boudins of the migmatitic fabric; (7) late folding phase that resulted in the formation of m-scale open to tight, SW-plunging, upright to moderately overturned, NW-verging folds; and (8) fracturing related to the intrusion of dominantly N-NW- and N-NE-trending intermediate and felsic few cm- to few dm-wide pegmatite veins. Melt generation was concurrent with all stages of deformation. The Albany-Fraser Orogen is reinterpreted as a diachronous orogen, resulting from the closure of the asymmetrically shaped ocean basin between the West Australian and Mawson cratons, which widens considerably from NE to SW along the length of the orogenic front. Subduction on the western side of the orogen was the driving force for NW-directed collision during Stage II of the orogeny. Slab breakoff and orogenic collapse following closure of an intracratonic ocean basin could account for the multiple phases of bidirectional extension, granulite facies metamorphism and pervasive partial melting throughout deformation. / text
238

Physical processes along the southern continental shelf and slope of Western Australia

Mohd Akhir, Mohd Fadzil January 2010 (has links)
The circulation along the south coast of Western Australia was examined using field data and numerical modelling. Physical processes in this region, particularly along the continental shelf and slope regions, were poorly understood due to a paucity of field measurements. Data were collected during a research cruise on RV Southern Surveyor (04/2006) during April 2006 consisting of 18 CTD transects from Twilight Cove (126oE) to Cape Leeuwin (115oE) and was augmented by shipborne ADCP data. The field data set provided a detailed understanding of three major current systems: Leeuwin Current (LC), Leeuwin Undercurrent (LU) and Flinders Current (FC). The LC along the south coast exhibits different characteristics when compared to that along the west coast. The LC flows into the colder and lower salinity subantarctic environment of the south coast. This is evident in a strong geopotential gradient off the south-west corner of Australia (Cape Leeuwin) resulting in rapid acceleration of the LC as it reaches a maximum velocity in this region. Numerical modelling studies, using the Regional Ocean Modelling System (ROMS) indicated that wind stress is an important component of the dynamics in this region. This was identified when comparing summer and winter conditions when the winds act in opposite directions, from north-westerly to southeasterly respectively. Along the shelf break and slope, the Flinders Current (FC) interacts with LC. As the dominant current, the FC serves both as a surface and as an undercurrent, transporting sub Antarctic mode water (SAMW). This interconnection the FC and LU can be seen clearly from the salinity, temperature and velocities within the depth range 200-700m postulating a connection between subsurface waters off Tasmania (origin of the Flinders Current) and the tropical Indian Ocean through the Flinders and Leeuwin Undercurrents.
239

The interplay between physical and chemical processes in the formation of world-class orogenic gold deposits in the Eastern Goldfields Province, Western Australia

Hodkiewicz, Paul January 2003 (has links)
[Formulae and special characters can only be approximated here. Please see the pdf version of the abstract for an accurate reproduction.] The formation of world-class Archean orogenic gold deposits in the Eastern Goldfields Province of Western Australia was the result of a critical combination of physical and chemical processes that modified a single and widespread ore-fluid along fluid pathways and at the sites of gold deposition. Increased gold endowment in these deposits is associated with efficient regional-scale fluid focusing mechanisms and the influence of multiple ore-depositional processes at the deposit-scale. Measurement of the complexity of geologic features, as displayed in high-quality geologic maps of uniform data density, can be used to highlight areas that influence regional-scale hydrothermal fluid flow. Useful measurements of geological complexity include fractal dimensions of map patterns, density and orientation of faults and lithologic contacts, and proportions of rock types. Fractal dimensions of map patterns of lithologic contacts and faults highlight complexity gradients. Steep complexity gradients, between domains of high and low fractal dimensions within a greenstone belt, correspond to district-scale regions that have the potential to focus the flow of large volumes of hydrothermal fluid, which is critical for the formation of significant orogenic gold mineralization. Steep complexity gradients commonly occur in greenstone belts where thick sedimentary units overly more complex patterns of lithologic contacts, associated with mafic intrusive and mafic volcanic units. The sedimentary units in these areas potentially acted as seals to the hydrothermal Mineral Systems, which resulted in fluid-pressure gradients and increased fluid flow. The largest gold deposits in the Kalgoorlie Terrane and the Laverton Tectonic Zone occur at steep complexity gradients adjacent to thick sedimentary units, indicating the significance of these structural settings to gold endowment. Complexity gradients, as displayed in surface map patterns, are an indication of three-dimensional connectivity along fluid pathways, between fluid source areas and deposit locations. Systematic changes in the orientation of crustal-scale shear zones are also significant and measurable map features. The largest gold deposits along the Bardoc Tectonic Zone and Boulder-Lefroy Shear Zone, in the Eastern Goldfields Province, occur where there are counter-clockwise changes in shear zone orientation, compared to the average orientation of the shear zone along its entire length. Sinistral movement along these shear zones resulted in the formation of district-scale dilational jogs and focused hydrothermal fluid-flow at the Golden Mile, New Celebration and Victory-Defiance deposits. Faults and lithologic contacts are the dominant fluid pathways in orogenic gold Mineral Systems, and measurements of the density of faults and contacts are also a method of quantifying the complexity of geologic map patterns on high-quality maps. Significantly higher densities of pathways in areas surrounding larger gold deposits are measurable within 20- and 5-kilometer search radii around them. Large variations in the sulfur isotopic composition of ore-related pyrites in orogenic gold deposits in the Eastern Goldfields Province are the result of different golddepositional mechanisms and the in-situ oxidation of a primary ore fluid in specific structural settings. Phase separation and wall-rock carbonation are potentially the most common mechanisms of ore-fluid oxidation and gold precipitation. The influence of multiple gold-depositional mechanisms increases the potential for significant ore-fluid oxidation, and more importantly, provides an effective means of increasing gold endowment. This explains the occurrence of negative δ34S values in ore-related pyrites in some world-class orogenic gold deposits. Sulfur isotopic compositions alone cannot uniquely define potential gold endowment. However, in combination with structural, hydrothermal alteration and fluid inclusion studies that also seek to identify multiple ore-forming processes, they can be a useful indicator. The structural setting of a deposit is also a potentially important factor controlling ore-fluid oxidation and the distribution of δ34S values in ore-related pyrites. At Victory-Defiance, the occurrence of negative δ34S(py) values in gently-dipping dilational structures, compared to more positive δ34S(py) values in steeply-dipping compressional structures, is potentially associated with different gold-depositional mechanisms that developed as a result of fluid-pressure fluctuations during different stages of the fault-valve cycle. During the pre-failure stage, when fluids are discharging from faults, fluid-rock interaction is the dominant gold-depositional mechanism. Phase separation and back-mixing of modified ore-fluid components are dominant during and immediately after faulting. Under appropriate conditions, any, or all, of these three mechanisms can oxidize orogenic gold fluids and cause gold deposition. The influence of multiple gold-depositional mechanisms during fault-valve cycles at dilational jogs, where fluid pressure fluctuations are interpreted to be most severe, can potentially explain both the large gold endowment of the giant to world-class Golden Mile, New Celebration and Victory-Defiance deposits along the Boulder-Lefroy Shear Zone, and the presence of gold-related pyrites with negative δ34S values in these deposits. This study highlights the interplay that exists between physical and chemical processes in orogenic gold Mineral Systems, during the transport of ore fluids in pathways from original fluid reservoirs to deposit sites. Potentially, a single and widespread orogenic ore-fluid could become oxidized, and lead to the formation of ore-related sulfides with variable sulfur isotopic compositions, depending on the nature and orientation of major fluid pathways, the nature of wall-rocks through which it circulates, and the precise ore-depositional processes that develop during fault-valve cycles.
240

Effects of land-use change on phosphorus forms in South-West Australian soils

George, Suman Jacob January 2004 (has links)
[Truncated abstract] Eleven sites, each with the trio of land uses: Eucalyptus globulus plantation, pasture and natural vegetation, representing from the Mediterranean climate, high rainfall region (<550 mm annually) of south-western Australia were investigated to assess medium-term changes in the P-supplying capacity of soils in eucalypt plantations growing on agricultural land. The natural vegetation soils were a benchmark for comparing soil P change since land clearing and development for agriculture. The experimental framework provided an ideal basis for studying changes in P forms since land clearing and fertilization for agriculture and the ensuing conversion to plantations (on an average 9 years ago). Conventional soil P indices measure plant available P that is more relevant to short duration annual crops and pastures. To predict medium-term P availability, P forms were determined using Hedley et al.’s (1982) fractionation scheme and fractions were grouped using the Guo and Youst (1998) criteria into readily, moderately and sparingly available P. The P species were also determined by 31P NMR spectroscopy of 0.5M NaOH-0.1M EDTA extracts. Hedley et al.’s (1982) inorganic P extracted by anion exchange resin and by NaHCO3 are widely considered to be approximations to the actual plant available P. The availability to plants of other P fractions is less certain and this is examined in an experiment to compare the plant availability of various P fractions in soils from fertilized and unfertilized land uses following exhaustive cropping in the glasshouse. The soil texture for the sites studied included coarse sand, loamy sand, clayey sand, and sandy loam. Surface soils (0-10 cm) have pH(CaCl2) in the acidic range (mean 4.4) and there is no significant difference due to differences in land use (P<0.05). The soils are of low EC (1:5 H2O) - 6 mS m-1. There is an almost 5-fold variation in organic C among sites (from 1.4% to 8%) but organic C values did not show any significant effect (P<0.05) of changes in land use. To evaluate the degree of similarity of soils within each triplet set at a site principal component analysis was carried out on those soil chemical⁄mineralogical characteristics that were least likely to be affected by changes in land use practices. This analysis showed good matching of the triplet of sub-sites on the whole, especially for the duo of pasture and plantation land uses. This degree of matching of the trio of land uses was considered while interpreting the effects of land use on the forms and behaviour of soil P, and variations due to various extents of mismatch were mostly addressed using statistical techniques including regression analysis to interpret sub-site difference

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