Yes / Adsorbents are developing in the various separation industries; these adsorbents can use to sweeten natural gas and remove hydrogen sulfide. Many commercial adsorbents are not regenerable when exposed to hydrogen sulfide because hydrogen sulfide is highly reactive. For removal, the main challenge when using surface adsorbent, is the dissociation adsorption of and non-regenerability of adsorbent. In this study, ultra-stable Y (USY) zeolite, was chosen to adsorb hydrogen sulfide due to its unique physical and chemical properties. To accurately model the adsorption isotherms, experimental adsorption data were measured in high pressure up to 12 bar for hydrogen sulfide and 21 bar for carbon dioxide, methane, and nitrogen as other natural gas components. The experiments were performed at three temperatures of 283, 293 and 303 K. Toth model fitted the experimental data very well, and the capacity of hydrogen sulfide adsorption on USY at the temperature of 283 K and pressure of 12 bar is 4.47 mmol/g that is noticeable. By performing ten cycles of adsorption and regeneration of hydrogen sulfide on USY, the regenerability of the adsorbent was investigated and compared by conducting a similar test on commercial 13X adsorbent. USY is found to be completely regenerable when exposed to hydrogen sulfide. The Isosteric adsorption heat of hydrogen sulfide on the adsorbent is 18.1 kJ/mol, which indicates physical adsorption, and the order of adsorption capacity of tested compounds on USY is H2S > CO2≫CH4 > N2.

The aim is to produce aliphatic liquid hydrocarbons using heterogeneous ethylene oligomerization. Thiscould potentially produce renewable synthetic fuels. Heterogeneous catalysis has some advantages overhomogeneous catalysis regarding some sustainability aspects. To achieve this, a setup was built using a heatedfixed bed reactor with an in-situ has chromatography to study conversion and gaseous products, and ex-situGC as well as NMR for analyzing liquid products. Ethylene was oligomerized on a commercial ZSM-5 zeoliteunder varying temperature conditions and feed gas dilution with hydrogen or helium. The gas and liquidproducts were analyzed and evaluated. Additionally, the ZSM-5 was studied at different silica to alumina ratios. The thesis discusses how conversion, liquid yield and selectivity of gas products using GC together withanalysis of liquid products using H-NMR can be used as a simple and quick evaluation. The liquid product isevaluated by the distribution of olefinic and aromatic hydrocarbon species using the hydrogen signal area inthe characteristic chemical shifts of olefinic and aromatic hydrogen. At 250-400oC, 6 bar of ethylene, with andwithout feed dilution, and WHSV of 204 h-1, conversion was consistently above 95% for the diluted 400oCruns. Though the liquid yield fell to around 6%, compared to the best yield at 18% for the pure 300oC run.Diluting the feed had a positive effect on increasing olefinic hydrogen signal while decreasing aromatichydrogen signal. The difference between diluting with H2 or helium had a surprisingly small effect. Decreasingthe Si/Al ratio had no significant effect on performance, while increasing the Si/Al ratio made the zeolite loseits catalytic ability. With a pure ethylene feed the lowest aromatic hydrogen signal was found at 350oC, whilethe olefinic signal did not vary too much with temperature. With diluted feed the higher temperature did leadto a lower olefinic hydrogen signal and higher aromatic hydrogen signal.

High concentrations of heavy metals in the soils have potential long-term environmental and health concerns because of their persistence and accumulation tendency in the environment and along the food chain. This study was aimed at studying the feasibility of heavy metals removal from the soil using plants naturally growing in the surroundings of selected polluted sites in Tanzania and soil application of the sorbent materials zeolite and autoclaved aerated concrete (AAC). The results showed that Sporobolus sp. is a hyperaccumulator of Cu. Four other species, Launea cornuta (Oliv &amp; Hiern) O. Jeffrey, Tagetes minuta (L.), Sporobolus sp. and Blotiella glabra (Bory) Tryon showed high potential for phytoextraction of Cu. No hyperaccumulators of Pb and Zn were identified in the area, but Tephrosia candida and Tagetes minuta (L.) were identified as potential plants for phytoextraction of Pb, while Conyza bonariensis (L.) Cronquist, Launea cornuta (Oliv &amp; Hiern) O. Jeffrey, Tagetes minuta (L.), Blotiella glabra (Bory) Tryon, Pteridium aquilinum (L.) Kulm and Polygonum setogulum A. Rich were identified as potential plants for phytoextraction of Zn. The result from sorbent experiments showed that both materials had a potential for remediating metal polluted soils. The AAC had a higher removal capacity for both Zn and Pb than zeolite. The removal capacity of zeolite and AAC in a mixed metal experiment (Pb and Zn) showed a little difference in the sorption capacity of AAC and Zeolite for Pb and Zn respectively. Speciation of the metal in soil shows that the major part of the metal was associated with firmly attached component of the metal in the soil. Compared with the total metal concentration analysed, the available component accounted for 13-39% for Zn and 31-39% for Pb. It can be suggested to co-remediate polluted soils using reactive sorbent nodules and hyper-accumulating plant species. Identification of the best combinations and designs remains the subject of future research. / <p>QC 20121130</p>

Treating ammonium pollution in ground water by natural zeolite after being modificated to the Naform (Z-Na) is the new way of research that scientists interested in. The experiment results showed that, at pH 6, the efficient of treating ammonium in ground water is the highest. The efficient of treating increase rapidly in the first 5 minutes and remain stable after that. Higher concentration of the Z-Na will increase the treating coefficient of the process. With a water sample that has CNNH4+= 27 mg/L at first, using CZ-Na=13g/L and after 5 minutes, the concentration of ammonium in water was declined to 1mg/L, passed the Vietnamese standard for ground water (QCVN 09:2015- MT/BTNMT). The treating coefficient is 96.30%, the adsorption capacity is 2.07 mg N-NH4 +/1g ZNa. The loaded Z-Na was regenerated using 2g/L NaOH solution, the ammonium recovery ratio exceeded 92%. This means the reuse of Z-Na for ammonium adsorption is very high. The results of the experiment with groundwater samples in Phu Xuyen district, Ha Noi have a concentration of 53 mg/L. In conclusion, Z-Na material is perfectly fit for purpose of treating ammonium in ground water because of it low price, safety, easily to imitate and high efficiency. / Xử lí ô nhiễm amoni trong nước ngầm bằng vật liệu zeolite tự nhiên được biến tính bằng muối ăn (Z-Na) là một hướng nghiên cứu mới, được các nhà khoa học rất quan tâm. Kết quả thí nghiệm cho thấy, tại pH 6 thì hiệu quả xử lí amoni trong nước là tốt nhất. Hiệu quả xử lí amoni trong nước tăng rất nhanh trong 5 phút đầu tiên xử lý. Càng tăng nồng độ Z-Na thì hiệu quả xử lí amoni càng cao. Với dung dịch nước ban đầu có nồng độ amoni tính theo nitơ (N-NH4 +) nhỏ hơn 27 mg/L và nồng độ vật liệu Z-Na sử dụng là 13g/L thì nước sau xử lí có nồng độ nhỏ hơn 1mg N-NH4 +/L, đạt QCVN 09-MT:2015/BTNMT, hiệu suất xử lí đạt 96,30%, dung lượng hấp phụ cực đại đạt 2,07 mg NNH4 +/1g Z-Na. Vật liệu Z-Na sau khi xử lý được nghiên cứu giải hấp bằng dung dịch NaOH với nồng độ 2g/L cho thấy hiệu quả giải hấp đạt 92% lượng amoni được hấp phụ. Điều này chứng tỏ khả năng tái sử dụng của vật liệu Z-Na cho hấp phụ amoni là khá cao. Kết quả nghiên cứu đã được thử nghiệm xử lý với mẫu nước ngầm tại huyện Phú Xuyên, Hà Nội có nồng độ N-NH4 + là 53 mg/L. Vì vậy, vật liệu Z-Na hoàn toàn có thể ứng dụng vào thực tiễn để xử lý amoni trong nước ngầm rất an toàn, dễ thực hiện và hiệu quả cao.

No description available.

No description available.

No description available.

No description available.

No description available.

No description available.