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Informationen gällande dilatationsfogar är i dagsläget otydlig ochkonstruktörer ifrågasätter användandet av dem. Avsaknaden aven tydlig standard medför att användandet blir inkonsekvent.Behovet av att standardisera eller utförligt beskriva de viktigafaktorerna som spelar in är efterfrågat. Den främstaproblematiken ligger i avståndet mellan dilatationsfogar och när,eller om de är nödvändiga.Detta examensarbete har utförts i samarbete med avdelningenProperty & Buildings på WSP Uppsala i syfte om att spridakunskap om användandet av dilatationsfog inom konstruktion.Målet med arbetet är att effektivisera byggbranschensanvändande av dilatationsfogar. Studien framför ett antal nugällande rekommendationer från olika källor i litteraturstudiensamt tre intervjuer med erfarna konstruktörer. Denna informationsammanställs sedan i resultatet och slutsatsen, där en egen teoriframförts i förhoppning om att klargöra otydligheter inom ämnetsamt inspirera till vidare studier.Studien visar att sprickbildning är den främsta anledningen tillbehovet av en dilatationsfog och att många olika faktorer påverkaruppkomsten av sprickor. De faktorer som påverkar mest ärbyggnadens underlag och geometrin på betongkonstruktionen dådessa kan leda till rörelser i betongen och tvång. Utöver dessatekniska faktorer inverkar projektets ekonomi på användandet avdilatationsfogen. Detta leder till att varje enskilt fall börundersökas för att använda fogen effektivt, men studien visar påatt ett avstånd på 30 meter kan anses säkert. / Today's information regarding expansion joints is lacking and construction engineersare questioning the use of them. The absence of a distinct standard results ininconsistent usage.A standardization or a thorough description of the important factors taking place in thesubject is requested. The main issue regards the distance between expansion joints andwhen or if they are necessary.The purpose of this study is to spread knowledge regarding the use of expansion jointswithin construction and the work has been done in cooperation with the Property &Buildings department at WSP Uppsala. The end goal is to increase efficiency of the usageof expansion joints within construction. This study features several presentrecommendations from different written sources as well as three interviews withknowledgeable construction engineers. The information gathered is concluded andpresented in the results and conclusion parts of the report. To clarify the ambiguitiesregarding the subject and to inspire further research a theory has been presented aswell.The study shows that cracking is the main reason for usage of expansion joints and theorigin of cracks depends on many different elements. Mainly it is the buildingsgroundwork and the geometry of the different concrete construction units that lead tovarious movement and constrain damage. Alongside these elements the project's budgetdirectly affects usage of expansion joints. These factors all indicate that every uniquecase should be studied to assess the necessity and effective usage of expansion joints,however the study has shown that 30 meters between joints can be considered safe.

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Gasification is a process used to convert any carbonaceous species through heterogeneous reaction to obtain the desired gaseous products of H2 and CO which are used to make chemicals, liquid transportation fuels, and power. Both pyrolysis and heterogeneous gasification occur in commercial entrained-flow gasifiers at pressures from 4 to 65 atm with local gas temperatures as high as 2000 °C. Many gasification studies have been performed at moderate temperatures, heating rates, and pressures. In this work, both pyrolysis and char gasification experiments were performed on coal, petroleum coke, and biomass at conditions pertinent to commercial entrained-flow gasifiers. Rapid biomass pyrolysis experiments were performed at atmospheric pressure in an entrained-flow reactor for sawdust, switchgrass, corn stover, and straw mostly using a peak gas temperature of 1163 K at particle residence times ranging from 34 to 113 ms. Biomass pyrolysis was modeled using the Chemical Percolation Devolatilization model assuming that biomass pyrolysis occurs as a weighted average of its individual components (cellulose, hemicellulose, and lignin). Thermal cracking of biomass tar into light gas was included using a first-order model with kinetic parameters regressed in the current study. Char gasification rates were measured for biomass, petroleum coke, and coal in a pressurized entrained-flow reactor at high heating-rate conditions at total pressures between 10 and 15 atm. Peak centerline gas temperatures were between 1611 and 1879 K. The range of particle residence times used in the gasification experiments was 42 to 275 ms. The CO2 gasification rates of biomass and petroleum coke chars were measured at conditions where the reaction environment consisted of approximately 40 and 90 mol% CO2. Steam gasification rates of coal char were measured at conditions where the maximum H2O concentration was 8.6 mol%. Measured data was used to regress apparent kinetic parameters for a first-order model that describes char conversion. The measured char gasification rates were far from the film-diffusion limit, and are pertinent for pulverized particles where no internal particle temperature gradients are important. The modeling and measured data of char gasification rates in this research will aid in the design and efficient operation of commercial entrained-flow gasifiers, as well as provide validation for both existing and future models at a wide range of temperatures and pressures at high heating-rate conditions.

In Sweden, it is Eurocode 2 which forms the basis for performing a design of concrete structures, in which methods can be found treating the subject of restrained concrete members and cracking in the serviceability limit state. In the code, both detailed hand calculations procedures as well as simplified methods are described. Several proposal of how to treat base restrained structures can be found in other codes and reports. Some state that the procedure given in Eurocode 2 is on the unsafe side as the method relies on stabilized cracking, while some say that the method is over conservative as the restraining actions will prevent the cracks from opening. As these methods are analysed closer and further tested, it is obtained that they all yield different results under the same assumptions. Most of them are within a similar span, and the deviation arises as the various methods takes different aspect into consideration. One method yields a result which is considerably higher than all other, denoted the Chalmers method. As this method is taught at the technical institute of Gothenburg (Chalmers), the large deviation have caused some confusion among Swedish engineers. As the methods are compared to numerical analyses, it is found that the detailed calculation procedure stated in Eurocode 2 yields fairly good prediction of crack widths for lower levels of strain, while for high levels of strain it is over conservative. The Chalmers method seems to underestimate the number of cracks which occur, and thus give rise to the deviating results. It is further found that in relation to more detailed hand calculations, the simplified procedure stated in Eurocode 2 may not always be on the safe side. The procedure is only valid within a certain range which may be exceeded depending on the magnitude of the load and choice of various design parameters. The effect creep have on base restrained structures subjected to long term loads such as shrinkage is further discussed and analysed numerically. Various hand calculation methods suggest that creep have a positive influence on base restrained structures in the sense that the crack width become smaller. The numerical results indicates that this is indeed the case, however, uncertainties of these analyses are considered to be large in relation to the short term analyses. / I Sverige är det Eurokod 2 som används som basis för dimensionering av betongkonstruktioner, i vilken metoder som beskriver sprickkontroll i bruksgränsstadiet för betong utsatt för tvångskrafter återfinns. Både detaljerade handberäkningsmetoder och förenklade metoder beskrivs. I olika koder och rapporter återfinns ett flertal förslag till hur detta problem ska hanteras. Vissa påstår att metoderna som anges i Eurokod 2 är på osäkra sidan då dessa förlitar sig på stabiliserad sprickbildning, medan andra menar att Eurokod 2 är för konservativ då inspänningen kommer förhindra att sprickorna öppnar sig. Då metoderna analyseras noggrannare och testas framgår det att alla genererar olika resultat under samma antaganden. De flesta ligger inom samma spann och skillnaderna uppkommer då de olika metoderna beaktar olika aspekter. En metod genererar dock ett resultat som är högre än alla andra, som i denna rapport benämns som Chalmersmetoden. Då denna metod lärs ut på Göteborgs tekniska universitet (Chalmers) så har de utstickande resultatet skapat en viss förvirring bland konstruktörer i Sverige. Då metoderna jämförs med numeriska analyser framgår det att Eurokod 2 förutspår en rimlig sprickvidd för låga töjningsgrader, medan den verkar vara överkonservativ för höga töjningsgrader. Chalmersmetoden verkar underestimera antalet sprickor som uppkommer i konstruktionen, vilket resulterar i de utstickande resultaten. Fortsättningsvis fastslås det att i relation till en mer detaljerad handberäkning så är den förenklade metoden i Eurokod 2 inte alltid på säkra sidan. Metoden är endast giltig inom ett visst spann, vilket kan överskridas beroende på den egentliga töjningens storlek och valet av dimensioneringsparametrar. Krypningens effekt på fastinspända betongkonstruktioner då de utsätts för långtidslaster så som krympning har också diskuterats och analyserats numeriskt. Olika handberäkningsmetoder antyder att krypningen har en positiv effekt på så sätt att sprickvidden minskar. Även de numeriska resultaten indikeratar att så är fallet, dock anses osäkerheten i dessa analyser vara stor i förhållande till analyser av korttidslaster.

Today, in the automotive industry, many of the interior parts in the car are made of ABS and PC/ABS polymeric blend. These materials are used in the areas for example: instrument panels, tunnel consoles and door panels. The extensive use of these materials means that it is important to gain in-depth knowledge about the materials,their properties; and also their behaviour when in contact with different chemicals andat different conditions.This study aims to address the potential problem of the polymers used in the interiorof the car - ABS and PC/ABS cracking due to environmental factors. This study proposes to introduce a low-cost test method to compare the polymeric materials and choose the best one for future purposes with the environmental circumstances in mind for materials to have a good service life.During the thesis project, ABS and PC/ABS samples were tested for environmental stress cracking to compare the strained materials against PEG 400 and an assemblyfluid chemical. These tests were conducted at three different temperature levels.Differential Scanning Calorimetry (DSC) was used to verify the polymeric materialsthat the samples were made of. Optical microscope and FTIR were employed to analyzethe samples for crazes / cracks and degradation of material, respectively.This thesis helped in establishing a good starting point for ESC testing of different materials for the organization. The test method was used to test the failure of material sin ESC. It was observed that the chemicals used for the testing were aggressive and accelerated the cracking process in the materials rapidly. Another observation of the tests was that high strain also caused the materials to fail quickly. While comparing the materials, PC/ABS polymer blend was more resistant than ABS materials to cracking when exposed to same strain level during the creep rupture test (test in absence ofchemicals acting as a reference test for ESC).

Creep is defined as deformation that takes place under constant load after an initial elastic response. This thesis focuses on a material property problem area that concerns stress analysis. Focus is on stress development considering creep deformations occurring when a concrete structure is under load, i.e. stress analysis with viscoelastic properties of the material.From laboratory tests, both elastic modulus and deformations over time are estimated in an evaluation process. Usually, deformations of moist sealed samples are denoted basic creep. At Luleå Technical University creep measurements are evaluated according to the theory and methodology in Larson and Jonasson (2003a, 2003b). The model is denoted Linear Logarithmic Model, used for moist sealed concrete samples. This thesis involves an investigation of the evaluation procedure for basic creep performed in Thysell laboratory at LTU, to examine how sensitive the evaluation process is for the outcome from stress calculations. The calculations are performed in the Finite Element Method software ConTeSt Pro.The aim of the thesis is to analyze the sensitivity of evaluation of basic creep and of the Linear Logarithmic Model (LLM) by making changes in the evaluation process to see how different parameters sets effect calculated stresses/strains during through crack analysis. The changes are solely done in the relaxation spectra.The purpose is also to analyze how sensitive the changes made in the evaluation process are when typical cases are studied. The typical cases are defined with a structure of a newly cast wall on a mature slab, where various thickness of the wall during different temperature conditions are analyzed. The temperature conditions are named standard, winter and summer. With this, concrete is tested and evaluated to yield two material parameter sets useful for temperature - and stress calculations for young concrete.The material parameter sets were analyzed and their creep values were converted into relaxation values, i.e. relaxation spectra, according to Maxwell-chain formulation for LLM. ConTeSt calculations generate temperature development for the walls and slabs. Colour maps and values of the strain ratio for each studied case are also obtained.It can be established that the evaluation process of basic creep is sensitive. A conclusion to be drawn is that small changes in the relaxation spectra, gives changes in the results of stress calculations for the typical cases. As soon as we deviate from the temperature development for the test performed in the laboratory, either by changing the thickness of the wall or by testing different temperature conditions we get a different temperature development than the tested one. With the deviation in the calculated temperature development compared to the measured one, a difference in the calculated strain ratios for the two different material parameter sets created are found.The main discovery in this work is that when a geometry of the wall that is identical to the geometry of the concrete tested at the laboratory is analyzed, a small deviation in the calculations of strain is obtained. This is expected since the temperature development in the created wall will follow the temperature development of the tested concrete. When differing from this geometry and temperature case, differences in calculated strain ratios are observed. / Krypning är deformation som sker under en konstant belastning och i detta examensarbete är det fokus på deformationer av fuktförseglade betongprover. Detta examensarbete är inriktat på olika materialparametersuppsättningar som berör spänningsanalyser. Det är fokus på spänningsutveckling med avseende på krypdeformationer som uppstår när en betongstruktur är under belastning. Detta gällande spänningsanalyser med viskoelastiska egenskaper hos betongmaterialet. Från laboratorietester bestäms både elasticitetsmodulen och deformationer över tid i en utvärderingsprocess. På Luleå tekniska universitet, utvärderas krypningsmätningarna enligt teorin och metodiken som finns beskriven i Larson och Jonasson (2003a, 2003b). Modellen är benämnd Linjär Logaritmisk Modell (LLM), som används för fuktförseglade betongprover. Examensarbetet innehåller en undersökning av utvärderingsprocessen för krypning utförda i Thysell laboratoriet vid LTU. Detta för att undersöka hur känslig utvärderingsprocessen är för resultatet av spänningsberäkningar. Beräkningarna utförs i Finita Elementprogrammet ConTeSt. Syftet med detta arbete är att analysera känsligheten i utvärderingen av krypning för fuktförseglade betongprover och för den Linjära Logaritmiska modellen genom att göra ändringar i utvärderingsprocessen för att se hur olika materialparametersuppsättningar påverkar beräknade spänningar under analys av genomgående sprickor. Ändringar görs endast i relaxationsspektra. Syftet är också att analysera hur känsliga förändringarna i utvärderingsprocessen är när olika typfall studeras. Typfallen definieras av ny gjuten vägg på en mogen betongplatta, där olika väggtjocklekar under olika temperaturförhållanden analyseras. Temperaturförhållandena benämns standard, vinter och sommar. Därvid testas och utvärderas betongen för att ge två materialparameteruppsättningar som är användbara för temperatur- och spänningsberäkningar för ung betong.Materialparameteruppsättningarna analyserades och deras krypvärden konverterades till relaxationsvärden, så kallade relaxations spektra, genom att använda Maxwell element för LLM. Från ConTeSt beräkningar erhålls värden för temperaturutveckling i vägg samt platta. Värmeutvecklingskarta tillsammans med värden på töjningskvoten för väggarna under varje studerat temperaturfall erhålls också från ConTeSt programmet. Det kan fastställas att den studerade utvärderingsprocessen för krypning är känslig. Små ändringar i relaxationsspektra ger variationer i resultatet av spänningsberäkningar för de olika typfallen. Så fort vi varierar den beräknade väggens temperaturutveckling från temperaturutvecklingen för testet som utförts i laboratoriet, antingen genom att ändra väggtjocklek eller genom att testa olika temperaturförhållanden, så erhålls en annorlunda temperaturutveckling än den som togs fram från laboratoriet. Med avvikelser i de beräknade temperaturutvecklingarna jämfört med den erhållna temperaturutvecklingen från den testade betongen i laboratoriet beräknas och analyseras skillnaden i töjningskvot. Den huvudsakliga upptäckten i detta arbete är att när den beräknade geometrin på väggen är identisk med den geometri som används för testriggen i laboratoriet, erhålls små variationer i de beräknade töjningskvoten. Detta är förväntat eftersom temperaturutvecklingen i den beräknade väggen är densamma som för betongen i testriggen i laboratoriet. När man avviker från den geometri eller de temperaturförhållandena som är identiska till dem i laboratoriet så erhålls större avvikelser i värden för den beräknade töjningskvoten.

In this work, Slow Strain Rate Test (SSRT) testing, Light Optical Microscopy (LOM) and Scanning Electron Microscopy (SEM) were used to study the effect of microstructure, corrosive environments and cathodic polarisation on stress corrosion cracking (SCC) of two grades of high strength steels, Type A and Type B. Type A is manufactured by quench and tempered (Q&T) method. Type B, a normalize steel was used as reference. This study also supports electrochemical polarisation resistance method as an effective testing technique for measuring the uniform corrosion rate. SSRT samples were chosen from base metal, weld metal and Heat Affected Zone (HAZ). SSRT tests were performed at room temperature under Open Circuit Potential (OCP) and cathodic polarisation using 4 mA/cm2 in 1 wt% and 3.5 wt% NaCl solutions. From the obtained corrosion rate measurements performed in 1 wt% and 3.5 wt% NaCl solutions it was observed that increased chloride concentration and dissolved oxygen content enhanced the uniform corrosion for all tested materials. Moreover, the obtained results from SSRT tests demonstrate that both Q&T and normalized steels were not susceptible to SCC in certain strain rate (1×10-6 s-1) in 1 wt% and 3.5 wt% NaCl solutions under OCP condition. It was confirmed by a ductile fracture mode and high reduction in area. The weld metal of Type A with acicular ferrite (AF), pro-eutectoid (PF) and bainite microstructure showed higher susceptibility to hydrogen assisted stress corrosion cracking compared to base metal and HAZ. In addition, typical brittle intergranular cracking with small reduction in area was observed on the fracture surface of the Type A due to hydrogen charging.