Three models have been developed and applied in the performance assessment of a final repository. They are based on accepted theories and experimental results for known and possible mechanisms that may dominate in the oxidative dissolution of spent fuel and the release of nuclides from a canister. Assuming that the canister is breached at an early stage after disposal, the three models describe three sub-systems in the near field of the repository, in which the governing processes and mechanisms are quite different. In the model for the oxidative dissolution of the fuel matrix, a set of kinetic descriptions is provided that describes the oxidative dissolution of the fuel matrix and the release of the embedded nuclides. In particular, the effect of autocatalytic reduction of hexavalent uranium by dissolved H2, using UO2 (s) on the fuel pellets as a catalyst, is taken into account. The simulation results suggest that most of the radiolytic oxidants will be consumed by the oxidation of the fuel matrix, and that much less will be depleted by dissolved ferrous iron. Most of the radiolytically produced hexavalent uranium will be reduced by the autocatalytic reaction with H2 on the fuel surface. It will reprecipitate as UO2 (s) on the fuel surface, and thus very little net oxidation of the fuel will take place. In the reactive transport model, the interactions of multiple processes within a defective canister are described, in which numerous redox reactions take place as multiple species diffuse. The effect of corrosion of the cast iron insert of the canister and the reduction of dissolved hexavalent uranium by ferrous iron sorbed onto iron corrosion products and by dissolved H2 are particularly included. Scoping calculations suggest that corrosion of the iron insert will occur primarily under anaerobic conditions. The escaping oxidants from the fuel rods will migrate toward the iron insert. Much of these oxidants will, however, be consumed by ferrous iron that comes from the corrosion of iron. The nonscavenged hexavalent uranium will be reduced by ferrous iron sorbed onto the iron corrosion products and by dissolved hydrogen. In the transport resistance network model, the transport of reactive actinides in the near field is simulated. The model describes the transport resistance in terms of coupled resistors by a coarse compartmentalisation of the repository, based on the concept that various ligands first come into the canister and then diffuse out to the surroundings in the form of nuclide complexes. The simulation results suggest that carbonate accelerates the oxidative dissolution of the fuel matrix by stabilizing uranyl ions, and that phosphate and silicate tend to limit the dissolution by the formation of insoluble secondary phases. The three models provide powerful tools to evaluate "what if" situations and alternative scenarios involving various interpretations of the repository system. They can be used to predict the rate of release of actinides from the fuel, to test alternative hypotheses and to study the response of the system to various parameters and conditions imposed upon it. / QC 20100521

Capacitive communication using human body as a electrical channel has attracted much attention in the area of personal area networks (PANs) since its introduction by Zimmerman in 1995. The reason being that the personal information and communication appliances are becoming an integral part of our daily lives. The advancement in technology is also helping a great deal in making them interesting,useful and very much affordable. If we interconnect these body-based devices with capacitive communication approach in a manner appropriate to the power, size, cost and functionality, it lessens the burden of supporting a communication channel by existing wired and wireless technologies. More than that, using body as physical communication channel for a PAN device compared to traditional radio transmission seems to have a lot of inherent advantages in terms of power and security etc. But still a lot of feasibility and reliability issues have to be addressed before it is ready for prime time. This promising technology is recently sub-classified into body area networks (BAN) and is currently under discussion in the IEEE 802.15.6 Task Group for addressing the technical requirements to unleash its full potential for BANs. This could play a part in Ericsson's envision of  50 billion connections by 2020. This thesis work is part of the main project to investigate the models, interface and derive requirements on the analog-front-end (AFE) required for the system. Also to suggest a first order model of the AFE that suits this communication system.In this thesis work the human body is modeled along with interfaces and transceiver to reflect the true condition of the system functioning. Various requirements like sensitivity, dynamic range, noise figure and signal-to-noise ratio (SNR) requirements are derived based on the system model. An AFE model based on discrete components is simulated, which was later used for proof of concept. Also a first order AFE model is developed based on the requirements derived. The AFE model is simulated under the assumed interference and noise conditions. The first order requirements for the submodules of the AFE are also derived. Future work and challenges are discussed.

This thesis proposed a near-field electromagnetic interference measurement framework to obtain sensitivity and spatial resolution of the characteristic parameters of magnetic probe based on International Electrotechnical Commission proposed for integrated circuits electromagnetic radiation measurement standards IEC 61967-6 : magnetic probe method. Using cross-coupled planar microwave bandpass filter which is realized by glass fiber board (FR4) for near-field measurement and electromagnetic simulation in comparsion. Nowadays, integrated circuits has become an important source of energy of overall electromagnetic interference in electronic systems. Finally, do near-field scanning measurement for a 64-pin wire-bond quad flat nonlead (WB-QFN) package and the voltage-controlled oscillator chip in 0.18 £gm CMOS technology by using high scanning resolution of microprobe. Then observes the chip-level and package-level electromagnetic interference, and achieve chip-level of near-field electromagnetic interference measurement techniques.

This study presents near-field electrospinning (NFES) on flat and hollow cylindrical process to fabricate permanent piezoelectricity of polyvinylidene fluoride (PVDF)/ multi-walled carbon nanotube (MWCNT) piezoelectric nanofibers. Then the mechanical properties of fibers were measured. PVDF is a potential piezoelectric polymer material combining desirable mechanical, thermal, electrical properties with excellent chemical resistance. The existing researches mostly focused on piezoelectric thin film process. However, the research of characteristic about piezoelectric fiber is little. The methods of measurement of the mechanical properties (Young¡¦s modulus, hardness, and tensile strength¡Belongation) of the electrospun PVDF/MWCN composite nanofiber were carried out by using nano-indention test (MTS Nanoindenter Windows XP System) and tensile test (Microforce Testing System). By setting electric field (1¡Ñ107 V/m), rotating velocity (900 rpm) of the hollow cylindrical glass tube on a motion X-Y stage (2 mm/sec) and PVDF solution concentration (16 wt%), and MWCNT (0.03 wt%), in-situ electric poling, mechanical stretching and morphology of PVDF nanofiber were demonstrated. After the experiments of nano-indention test and tensile strength test, it is suggested that the good mechanical properties in NFES on cylindrical process. The results show that the mechanical properties of composite nanofiber are better than the conventional NFES process. The Young¡¦s modulus of 16% PVDF fiber prepared by cylindrical process is 0.89 GPa and hardness is 26.5 MPa. The mechanical properties were increased 56.2% and 49.4% after adding 0.03% of MWCNT, corresponding to 1.39 GPa and 39.6 MPa. The tensile strength was increased 32.7% and elongation at breaking point was increased 35% after adding 0.03% MWCNT.

Simplified methods of analysis described in codes and specifications for seismically isolated structures are always used either directly in special cases or for checking the results of nonlinear response history analysis (RHA). Important predictions for seismically isolated structures by simplified methods are the maximum displacements and base shears of the isolation system. In this study, the maximum isolator displacements and base shears determined by nonlinear RHA are compared with those determined by the equivalent lateral force (ELF) procedure in order to assess the accuracy of the simplified method in the case of bi-directional excitations with near-field characteristics. However, although there are currently many methods for ground motion selection and scaling, little guidance is available to classify which method is more appropriate than the others in any applications. Features of this study are that the ground motions used in analysis are selected and scaled using contemporary concepts and that the ground excitation is considered biv directional. The variations in response of isolated structures due to application of ground motions uni-directionally and bi-directionally are also studied by employing a scaling procedure that is appropriate for the bi-directional analysis. The proposed new scaling methodology is an amplitude scaling method that is capable of preserving the horizontal orthogonal components and it is developed especially for dynamic analysis of isolated structures. Analyses are conducted for two different symmetric reinforced concrete isolated structure for two different soil conditions in structural analysis program SAP2000. Effect of asymmetry in superstructure on isolator displacement is also investigated with further analyses considering 5% mass eccentricity at each floor level. Furthermore, once the significance of the orthogonal horizontal component on the response of isolation system is shown, the biaxial interaction of hysteretic behavior of lead rubber bearings is implemented in OpenSees by developing a subroutine which was not readily available.

Plasmons, i.e. collective oscillations of conduction electrons, have a strong influence on the optical properties of metal micro- and nanostructures and are of great interest for novel photonic devices. Here, plasmons on metal-dielectric interfaces are investigated using near-field optical microscopy and differential angular reflectance spectroscopy. Emphasis is placed on the study of plasmon interaction with individual nanostructures and on the nonlinear process of surface plasmon amplification. Specifically, plasmon transmission across single grooves in thin silver films is investigated with the help of a near-field optical microscope. It is found that plasmon transmittance as a function of groove width shows a non-monotonic behavior, exhibiting certain favorable groove widths with strongly decreased transmittance values. Additionally, evidence of groove-mediated plasmon mode coupling is observed. Spatial beating due to different plasmon wave vectors produces distinct interference features in near-field optical images. A theoretical approach explains these observations and gives estimated coupling effciencies deduced from visibility considerations. Furthermore, stimulated emission of surface plasmons induced by optical pumping using an organic dye solution is demonstrated for the first time. For this a novel twin-attenuated-total-reflection scheme is introduced. The experiment is described by a theoretical model which exhibits very good agreement. Together they provide clear evidence of the claimed process.

This dissertation presents subwavelength optics with focus on the theory and applications of subwavelength apertures in a metal film. Two main issues regarding the optics with subwavelength apertures are investigated. As the first issue, the extraordinary optical transmission (EOT) through a single hole in a metallic waveguide is presented. A total transmission through a single subwavelength aperture is theoretically predicted for a perfect electric conductor regardless of the aperture size, without relying on aperture arrays and surface corrugations as presented in previous works. The waveguide EOT is then applied to boost the optical throughput of an apertured near-field scanning optical microscope (NSOM) probe. Using a new structure for the apertured NSOM probe which allows for waveguide EOT, the optical throughput and the damage threshold are boosted by 100× and 40× as compared to a conventional structure, and the experimental findings are backed-up by comprehensive finite-difference time-domain (FDTD) simulations. Single fluorescent molecules are scanned using the EOT apertured NSOM probe, and a spatial resolution of 62 nm is achieved. As the second issue, subwavelength apertures are found useful for optical trapping. A small dielectric particle can significantly change the optical transmission through an aperture by dielectric loading, and subsequently, a large optical force is induced which favors trapping. A self-induced back-action (SIBA) optical trap is designed using a circular nanohole in a gold film. Trapping of 50 nm polystyrene particle is experimentally achieved, which is not possible using a conventional single beam optical tweezers. The circular nanohole SIBA trap works beyond the perturbative regime, as proven by FDTD simulations and a Maxwell stress tensor analysis. We further improve the nanohole trapping using a double-nanohole, which is more sensitive for small dielectric changes due to the intense local field enhancement between its two sharp tips. A single 12 nm silica sphere is experimentally trapped using the double-nanohole, as the smallest trapped dielectric particle reported. We also achieve the trapping of a single protein – a bovine serum albumin (BSA) protein with a hydrodynamic radius of 3.4 nm in the folded form. The trapped BSA is also unfolded by the large optical force, as confirmed by experiments with changing optical power and changing pH. The high signal-to-noise ratio of 33 in monitoring single protein trapping and unfolding shows a tremendous potential for using the double-nanohole as a sensor for protein binding events at a single molecule level. / Graduate

Acoustic noise pollution is an environmental aggressor in everyday life. Aero- dynamically generated noise annoys and was linked with health issues. It may be caused by high-speed turbulent free flows (e.g. aircraft jet exhausts), by airflow interacting with solid surfaces (e.g. fan noise, wind turbine noise), or it may arise within a confined flow environment (e.g. air ventilation systems, refrigeration systems). Hence, reducing the acoustic noise levels would result in a better life quality, where a systematic approach to decrease the acoustic noise radiation is required to guarantee optimal results. Computational predic- tion methods able to provide all the required flow quantities with the desired temporal and spatial resolutions are perfectly suited in such application areas, when supplementing restricted experimental investigations. This thesis focuses on the use of numerical methodologies in compressible flow applications to understand aerodynamically noise generation mechanisms and to assess technologies used to suppress it. Robust and fast steady-state Reynolds Averaged Navier-Stokes (RANS) based formulations are employed for the optimal design process, while the high fidelity Large Eddy Simulation (LES) approach is utilized to reveal the detailed flow physics and to investigate the acoustic noise production mechanisms. The employment of fast methods on a wide range of cases represents a brute-force strategy used to scrutinize the optimization parameter space and to provide general behavioral trends. This in combination with accurate simulations performed for particular condi- tions of interest becomes a very powerful approach. Advance post-processing techniques (i.e. Proper Orthogonal Decomposition and Dynamic Mode Decomposition) have been employed to analyze the intricate, highly turbulent flows. The impact of using fluidic injection inside a convergent-divergent nozzle for acoustic noise suppression is analyzed, first using steady-state RANS simulations. More than 250 cases are investigated for the optimal injection location and angle, amount of injected flow and operating conditions. Based on a-priori established criteria, a few optimal candidate solutions are detected from which one geometrical configuration is selected for being thoroughly investigated by using detailed LES calculations. This allows analyzing the unsteady shock pattern movement and the flow structures resulting with fluidic injec- tion. When investigating external fluidic injection configurations, some lead to a high amplitude shock associated noise, so-called screech tones. Such unsteady phenomena can be captured and explained only by using unsteady simulations. Another complex flow scenario demonstrated using LES is that of a high ve- locity jet ejected into a confined convergent-divergent ejector (i.e. a jet pump). The standing wave pattern developed in the confined channel and captured by LES, significantly alters the acoustic noise production. Steady-state methods failed to predict such events. The unsteady highly resolved simulations proved to be essential for analyzing flow and acoustics phenomena in complex problems. This becomes a very powerful approach when is used together with steady-state, low time-consuming formulations and when complemented with experimental measurements. / <p>QC 20141202</p>

Most electromagnetic interference standards specify that measurements of radiated emissions must be performed in the far field (FF), e.g. at an open-area test site or in a semi-anechoic chamber. Since near field (NF) measurements are cheaper, quicker and more flexible compared to FF tests, establishing a correlation between NF and FF data is of great research interest. One strategy to achieve this goal is to find a set of basic radiators comprising electric and magnetic dipoles that generate the same NF as the original source at selected observation points. This set of dipoles, based on the uniqueness theorem, can then be used to predict the FF radiation patterns. The uniqueness theorem requires that electric or magnetic fields are matched on a closed surface with respect to the magnitude and phase. The focus of this thesis is the investigation of FF prediction based on NF magnitude-only data. In this thesis, a robust NF-FF conversion model based on Genetic Algorithms (GAs) is built up to predict the radiation of printed circuit boards (PCBs). This is done by introducing a dipole moment magnitude range pre-selection before the initialisation step of GAs, customising the processes of selection, crossover and mutation for anti-sticking and checking the correlation between NF and FF fitness values. Since the performance of GAs is tightly related to the number of dipoles in the GA model, FF characteristics of generic radiation sources (such as a long wire and a large loop) are analysed using both analytical calculation and source modelling by GAs. For structures with simple FF patterns, if more dipoles than necessary are used, the computational cost of GAs is unnecessarily high. On the other side, for structures with complicated FF patterns, the GA modelling may not be able to well approximate the FF radiation, due to the limitation for GAs to tackle too many unknowns. Therefore the scope of the model applicability is discussed, and a dipole number N, depending on the electrical size of the source, is recommended for GA modelling. By applying GAs to get the equivalent dipole set of a radiating PCB from the magnetic NF magnitudes, NF sampling approaches are investigated in detail, including where to locate NF sampling planes, what plane coverage angle to choose, how many points to observe, what type of data to collect, what dynamic range to allow for the data, and how many planes to choose. Two case studies are presented for predicting the FF radiation of PCBs from magnetic NF magnitude-only observations, and validate the NF sampling approaches in this thesis.

abstract: To detect and resolve sub-wavelength features at optical frequencies, beyond the diffraction limit, requires sensors that interact with the electromagnetic near-field of those features. Most instruments operating in this modality scan a single detector element across the surface under inspection because the scattered signals from a multiplicity of such elements would end up interfering with each other. However, an alternative massively parallelized configuration, consisting of a remotely interrogating array of dipoles, capable of interrogating multiple adjacent areas of the surface at the same time, was proposed in 2002. In the present work a remotely interrogating slot antenna inside a 60nm silver slab is designed which increases the signal to noise ratio of the original system. The antenna is tuned to resonance at 600nm range by taking advantage of the plasmon resonance properties of the metal’s negative permittivity and judicious shaping of the slot element. Full-physics simulations show the capability of detecting an 8nm particle using red light illumination. The sensitivity to the λ/78 particle is attained by detecting the change induced on the antenna’s far field signature by the proximate particle, a change that is 15dB greater than the scattering signature of the particle by itself. To verify the capabilities of this technology in a readily accessible experimental environment, a radiofrequency scale model is designed using a meta-material to mimic the optical properties of silver in the 2GHz to 5GHz range. Various approaches to the replication of the metal’s behavior are explored in a trade-off between fidelity to the metal’s natural plasmon response, desired bandwidth of the demonstration, and ii manufacturability of the meta-material. The simulation and experimental results successfully verify the capability of the proposed near-field sensor in sub-wavelength detection and imaging not only as a proof of concept for optical frequencies but also as a potential imaging device for radio frequencies. / Dissertation/Thesis / Doctoral Dissertation Electrical Engineering 2016