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PRECIPITATION, ORIENTATION AND COMPOSITION EFFECTS ON THE SHAPE MEMORY PROPERTIES OF HIGH STRENGTH NiTiHfPd ALLOYSAcar, Emre 01 January 2014 (has links)
NiTiHf high temperature shape memory alloys are attractive due to their high operating temperatures (>100 oC) and acceptable transformation strain compared to NiTi. However, NiTiHf has limitations due to their lack of ductility and low strength, resulting in poor shape memory properties. In this study, Pd has been added to NiTiHf alloys in an attempt to improve their shape memory behavior. A combined approach of quaternary alloying and precipitation strengthening was used.
The characterization of a Ni45.3Ti29.7Hf20Pd5 (at. %) polycrystalline alloy was performed in compression after selected aging treatments. Transmission electron microscopy was used to reveal the precipitation characteristics. Differential scanning calorimetry, load-biased (constant stress) thermal cycling experiments and isothermal stress cycling (superelasticity) tests were utilized to investigate the effects of aging temperature and time. The crystal structure and lattice parameters were determined from X-ray diffraction analysis. Significant improvement in the shape memory properties of Ni45.3Ti29.7Hf20Pd5 was obtained through precipitation strengthening. The effects of chemical composition (effects of Hf content replacing with Ti) on the shape memory properties of NiTiHfPd alloys were also revealed.
Orientation dependence of the shape memory properties in aged Ni45.3Ti29.7Hf20Pd5 single crystals were investigated along the [111], [011] and [-117] orientations. The shape memory properties were determined to be strong functions of orientation and aging condition. A perfect superelastic behavior (with no irrecoverable strain) with 4.2 % recoverable compressive strain was obtained in the solutionized condition at stress levels as high as 2.5 GPa while 2 % shape memory strain under a bias stress of 1500 MPa was possible in an aged [111] oriented single crystal. A mechanical hysteresis of 1270 MPa at -30 oC, which is the largest mechanical hysteresis that the authors are aware of in the SMA literature, was observed along the [111] orientation.
Finally, thermodynamic analyses were conducted to reveal the relationships between microstructure (e.g. precipitate size and interparticle distances) and martensitic transformations in Ni45.3Ti29.7Hf20Pd5 SMAs. Precipitate characteristics were found to be effective on the elastic energies for nucleation, propagation with dissipation energy and these energies influenced the TTs and the constant stress shape memory properties in Ni45.3Ti29.7Hf20Pd5 alloys.
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Thermomechanical response of laser processed nickel-titanium shape memory alloyDaly, Matthew January 2012 (has links)
The exciting thermomechanical properties of nickel-titanium shape memory alloys have sparked significant research efforts seeking to exploit their exotic capabilities. Until recently, the performance capabilities of nickel-titanium devices have been inhibited by the retention of only one thermomechanical characteristic. However, laser processing technology promises to deliver enhanced material offerings which are capable of multiple functional responses. Presented in this thesis, is an investigation of the effects of laser processing on the thermomechanical behaviour of nickel-titanium shape memory alloys. In the context of this work, laser processing refers to removal of alloy constituents, as in the case of laser ablation, or alternatively, addition of elements through laser alloying.
The effects of laser ablation on the composition, crystallography and phase transformation temperatures of a nickel-titanium strip have been studied. Application of laser energy was shown to ablate nickel constituents, induce an austenite-martensite phase change and cause an increase in phase transformation onset temperatures, which correlated well with reported findings. Laser processing of a nickel-titanium wire was shown to locally embed an additional thermomechanical response which manifested as unique shape memory and pseudoelastic properties.
Localized alloying of ternary species via laser processing of nickel-titanium strip was investigated. Synthesis of a ternary shape memory intermetallic within the laser processing region was achieved through melting of copper foils. Results from thermoanalytical testing indicated that the ternary compound possessed a higher phase transformation temperature and reduced transformation hysteresis in comparison to the reference alloy. Indentation testing was used to demonstrate the augmented thermomechanical characteristics of the laser processed shape memory alloy.
In order to demonstrate the enhanced functionality of laser processed nickel-titanium shape memory alloys, a self-positioning nickel-titanium microgripper was fabricated. The microgripper was designed to actuate through four different positions, corresponding to activation of three embedded shape memory characteristics. Thermoanalytical and tensile testing instrumentations were used to characterize the thermomechanical performance of the laser processed nickel-titanium microgripper. Results indicated that each of the laser processed microgripper components possessed unique mechanical and shape memory recovery properties.
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Thermomechanical Cyclic Response of TiNiPd High-Temperature Shape Memory AlloysAtli, Kadri 2011 August 1900 (has links)
TiNiPd high-temperature shape memory alloys (HTSMAs) have attracted considerable attention as potential solid-state actuators capable of operating at temperatures up to 500 °C, exhibiting excellent corrosion resistance, adequate ductility levels and significant strain recovery under both constrained and unconstrained thermomechanical conditions. During operation, these actuators may be subjected to multiple cycles and from an application point of view, the functional stability, i.e. conservation of original actuator dimensions and transformation temperatures during repeated employment, is of considerable importance.
This study addresses the issue of functional stability in a model HTSMA, Ti50.5Ni24.5Pd25, for its use as a compact solid-state actuator. Since the primary reason for functional instability is the creation of lattice defects (dislocations, vacancies, etc.) during repeated transformation cycles, several methods were successfully undertaken to improve the functional stability through inhibiting the generation of these defects. Solid-solution strengthening through Sc microalloying and thermomechanical treatments via severe plastic deformation were the two approaches used to strengthen the HTSMA against defect generation. Thermal cycling the HTSMA under stress was the third method to voluntarily introduce defects into the microstructure such that further defect generation during application would be impeded. Overall, severe plastic deformation was found to be more efficient than other strengthening methods in improving the functional stability of TiNiPd HTSMA, yet it brought about disadvantages such as reduction in transformation strain and transformation temperatures.
While functional instability is due to the creation of lattice defects, the generation of these defects is mainly controlled by the crystallographic incompatibility between martensitically transforming phases and the strength levels for plastic deformation. It was shown that TiNiPd HTSMAs, which exhibited martensitic transformation from a cubic (B2) to orthorhombic (B19) symmetry, illustrated better compatibility and thus better functional stability levels compared to TiNi SMAs, which had a B2 to monoclinic (B19’) transition. Although crystallographic incompatibility seems to be the governing factor for the functional stability of the TiNiPd HTSMA, the strength differential between the onset of plastic deformation and local constraint due to the martensitic transformation was also found to be an influential factor determining the overall stable behavior.
Functional stability was also investigated for the two-way shape memory effect (TWSME) in TiNiPd HTSMAs. Better strength and compatibility levels compared to TiNi SMAs were also reflected in the TWSME characteristics in the form of enhanced stability under stress-free thermal cycling. The stability during constrained thermal cycling was not as good and TWSME degraded rapidly while doing work against an opposing stress. Nevertheless, work output levels were much higher as compared to those obtained from conventional TiNi and Cu-based SMAs.
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Precision Pointing in Space Using Arrays of Shape Memory Based Linear ActuatorsJanuary 2016 (has links)
abstract: Space systems such as communication satellites, earth observation satellites and telescope require accurate pointing to observe fixed targets over prolonged time. These systems typically use reaction wheels to slew the spacecraft and gimballing systems containing motors to achieve precise pointing. Motor based actuators have limited life as they contain moving parts that require lubrication in space. Alternate methods have utilized piezoelectric actuators. This paper presents Shape memory alloys (SMA) actuators for control of a deployable antenna placed on a satellite. The SMAs are operated as a series of distributed linear actuators. These distributed linear actuators are not prone to single point failures and although each individual actuator is imprecise due to hysteresis and temperature variation, the system as a whole achieves reliable results. The SMAs can be programmed to perform a series of periodic motion and operate as a mechanical guidance system that is not prone to damage from radiation or space weather. Efforts are focused on developing a system that can achieve 1 degree pointing accuracy at first, with an ultimate goal of achieving a few arc seconds accuracy. Bench top model of the actuator system has been developed and working towards testing the system under vacuum. A demonstration flight of the technology is planned aboard a CubeSat. / Dissertation/Thesis / Masters Thesis Mechanical Engineering 2016
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Aging Response And Its Effect On Mechanical Properties Of Cu-Al-Ni Single Crystal Shape Memory AlloySuresh, N 02 1900 (has links) (PDF)
No description available.
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Prestressing RC Beams with Near Surface Mounting (NSM) Fiber Reinforced Polymers (FRP) and/or Iron-Based Shape Memory Alloy (Fe-SMA) RodsRaad, Janet January 2018 (has links)
No description available.
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Shape Memory Polymer Composites For Actively-Switched Thermal Management MaterialsPeswani, Mohnish 01 February 2019 (has links)
No description available.
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Deposition Kinetics of Titanium and Zirconium Diffusion Coatings on Nickel Microwires via Pack CementationAchuthankutty, Ajith 16 June 2020 (has links)
No description available.
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IONOMERS AND THEIR COMPOSITES AS SHAPE MEMORY POLYMERS IN FILMS AND 3D PRINTINGZhao, Zhiyang 26 September 2018 (has links)
No description available.
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Coupled Thermal and Electrical Transport in Unconventional Metals for Applications in Solid-State CoolingSaini, Abhishek 23 August 2022 (has links)
No description available.
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