While photocatalysis is considered a promising sustainable technology in the field of heterogeneous catalysis as well as biocatalysis, figures of merit (FOM) for comparing catalytic performance, especially between disciplines, are not well established. Here, photocatalytic water splitting was conducted using a semiconductor (NiO/La-NaTaO3) and a bio-photocatalyst (Synechocystis sp. PCC 6803) in the same setup under similar reaction conditions, eliminating the often ill-defined influence of the setup on the FOMs obtained. Comparing the results enables the critical evaluation of existing FOMs and a quantitative comparison of both photocatalytic systems. A single FOM is insufficient to compare the photocatalysts, instead a combination of multiple FOMs (reaction rate, photocatalytic space time yield and a redefined apparent quantum yield) is superior for assessing a variety of photocatalytic systems.

Fastighetsbildning i Sverige är en process som innebär förändringar i fastighetsindelningengenom både nybildning och ombildning av fastigheter. Genom dessa åtgärder anpassasfastigheterna till förändrade behov och markanvändningen effektiveras. Avstyckning ochklyvning är två olika fastighetsbildningsåtgärder som regleras i fastighetsbildningslagen.Genom dessa åtgärder nybildas nya fastigheter. Ur ett fastighetsbildningsperspektivhandläggs klyvning och avstyckning på liknande sätt. Studien syftar till att undersöka i vilken mån dessa bildningsåtgärder kan sammanföras ifastighetsbildningslagen. Studien syftar även på att undersöka vad konsekvenserna blir omdessa åtgärder skulle sammanföras. Dessutom vad det skulle innebära för de berördaaktörerna som till exempel det Statliga Lantmäteriet (SLM) och den kommunalalantmäterimyndigheten (KLM). Målet med examensarbetet är att öka kunskapen om dessa två fastighetsbildningsåtgärderoch redovisa hur detta skulle påverka de berörda aktörerna om åtgärderna skullesammanföras i fastighetsbildningslagen. Förhoppningsvis leder detta arbete till att nå enlösning om en förbättring i fastighetsbildningslagen. För att besvara arbetets frågeställningar har intervjuer med förrättningslantmätare från detStatliga och kommunala Lantmäteriet genomförts. Den kvalitativa metoden i form avintervjuer har kompletterats med den kvantitativa metoden i form av data som harinhämtats från det Statliga Lantmäteriet. Inhämtat data behandlar inkomna och beslutfattade ärenden i avstyckning och klyvning. En juridisk metod genom dagens regelverkkring åtgärderna har studerats för att få en förståelse på hur lagstiftningen i dag är. Av arbetets resultat framgår det att avstyckning är den vanligaste nybildningsåtgärden tillskillnad från klyvning som förekommer väldigt sällan. Trots det resultatet är det intemöjligt i dag att sammanföra samtliga åtgärder i fastighetsbildningslagen då varje åtgärduppfyller sin funktion i respektive kapitel i lagstiftningen. Vidare drar slutsatsen att SLMoch KLM påverkas på samma sätt om en eventuell lagändring skulle ske. Lagstiftningengällande klyvning i dag gör det svårt för det Statliga lantmäteriet (SLM) och denkommunala lantmäterimyndigheten (KLM) att handlägga klyvningar på ett effektivt sättutan tvister. / Real estate formation in Sweden involves changes in property divisions through both thecreation of new properties and the reorganization of existing ones. These measures aim toadapt properties to changing needs and improve land use efficiency. Subdivision anddivision are two distinct procedures regulated by the Real Estate Formation Act that resultin the creation of new properties. From a real estate formation perspective, subdivisionand division are handled in similar way. This study aims to investigate the extent to which these formation procedures can beintegrated into the real estate formation legislation. The study also examines theconsequences of merging these procedures and the implications for stakeholders, such asthe State Land Survey and the Municipal Land Survey. The objective of this thesis is to increase knowledge about these two real estate formationprocedures and to elucidate how their integration into the legislation would impact theinvolved stakeholders. The hope is that this work will contribute to finding a solution forimproving the real estate formation legislation. To answer the research questions,interviews were conducted with cadastral surveyors from both the State and MunicipalLand Survey offices. The qualitative method of interviews was completed by thequantitative method using data obtained from the State Land Survey. The collected datapertains to incoming cases and decisions made in subdivision and division procedures.Additionally, a legal analysis of the current regulations governing these procedures wasconducted to gain an understanding of the existing legislation. The results of the study indicate that subdivision is the most common procedure forcreating new properties, whereas division occurs very rarely. Despite this finding, it iscurrently not possible to merge all the procedure serves its purpose within its respectivechapter of this legislation. Furthermore, the study concludes that both the State LandSurvey and the Municipal Land Survey would be similarly affected if a potential legalamendment were to take place. The existing legislation concerning division poseschallenges for the State Land Survey and the Municipal Land Survey in effectively handlingdivision procedures without disputes.

This paper presents an investigation of seven different flux splitting algorithms for the discretization of inviscid fluxes, which are the primary source for the non-linear behavior (eg. shocks, contact discontinuities). The aim of the present work is to enhance the accuracy and robustness of CHEM, a three-dimensional flow solver, which is capable of simulating a wide range of flow conditions, including chemical non-equilibrium. Five different test cases cases are considered and thoroughly analyzed. The overall goal is to find a numerical scheme that can meet some stringent specifications of efficiency, accuracy and robustness on the widest possible spectrum of flow conditions.

No description available.

No description available.

When multiple autonomous vehicles drive closelytogether behind each other, it is called a platoon. Platooningprovides several benefits, such as decreased congestion andreduced fuel consumption. In order for more vehicles to takeadvantage of these benefits, the platoon should be able to openup a space for other vehicles to merge into. Thus, our goal withthe project was to develop a system that can split a platoon.To achieve this, we are using model predictive control (MPC) tocontrol the system because it can handle constraints and controlsystems with multiple variables. To test the implemented system,we created a simulation environment in Python. We createdseveral plots to analyze and show the results of the simulations.To make the simulation more realistic, we introduced air drag tothe system. To counteract this effect, we added linearized air dragto the MPC. We showed that the constructed system could splitbetween any two adjacent vehicles in a platoon up to 50 meters.Another significant result was that the MPC could compensatefor the air drag without adding linearized air drag to the MPC. / När flera autonoma fordon kör nära varandra kallas det för en platoon. Det finns flera fördelar med platooning som minskad trafik samt minskad bränsleförbrukning. För att fler fordon ska kunna dra nytta av dessa fördelar bör nya fordon kunna sammansluta till en platoon och på grund av detta bör fordonen i platoonen kunna öppna ett utrymme för det nya fordonet. Därför är vårt mål med detta projekt att utveckla ett system som kan styra och dela på en platoon. För att åstadkomma detta använder vi model prediktiv reglering (MPC) eftersom den är bra på att hanterar bivilkor och styra system med många variabler. Vi implementerade systemet i Python, där en simuleringsmiljö skapades. För att se och analysera resultaten av simuleringen skapades grafer som visade hur fordonen hade färdats under simuleringen. Vi lade till luftmotstånd i simuleringen för att göra den mer realistisk. För att motverka luftmotståndet lade vi även till ett linjäriserat luftmotstånd till i MPC:n. I slutet av projektet kunde systemet dela platoonen mellan två fordon med ett avstånd upp till 50 meter. Vi observerade att MPC:n kunde kompensera motståndet utan implementationen av det linjäriserade luftmotståndet. / Kandidatexjobb i elektroteknik 2021, KTH, Stockholm

As the Army transitions to the Army Force Generation (ARFORGEN) deployment cycle, it must adjust its many operations in support of ARFORGEN. Specifically, the Initial Military Training (IMT) must be able to adjust the scheduling of its classes for newly enlisted service members to finish training such that they fulfill Brigade Combat Team (BCT) requirements within their common due windows. We formulate this problem as a lot streaming problem. Lot streaming splits a batch of jobs into sublots,which are then processed over the machines in an overlapping fashion. To schedule classes for the IMT, there are two stages that must be coordinated: Basic Training (BT) and Advanced Individual Training (AIT). For the Army Force Generation problem, the classes are considered as sublots that are streamed from one stage to the next. For this process, the model formulation must address determination of class sizes and scheduling of soldiers and classes at the two stages such that (1) the start times of the soldiers at Stage 2 are greater than their completion times at Stage 1, and (2) the assignment of requisite number of soldiers is made to each BCT, so as to minimize the total flow time. We propose a decomposition-based approach for the solution of this problem. In an effort to decompose the problem, the original lot streaming problem is reformulated such that the master problem selects an optimal combination of schedules for training classes and assigning soldiers to BCTs. A complete schedule selected in the master problem includes the assignments of soldiers to classes in BT, AIT, and their assignments to the BCTs, so as to minimize the total flow time as well as earliness and tardiness for regular Army units. Earliness and Tardiness are defined as the length of the time a soldier waits before and after the due date, respectively, of the BCT to which he or she is assigned. Our decomposition-based method enables solution of larger problem instances without running out of memory, and it affords CPU time reductions when compared with the CPU times required for these problem instances obtained via direct application of CPLEX 12.1. Our investigation into the structure of the problem has enabled further improvement of the proposed decomposition-based method. This improvement is achieved because of a result, which we show, that the first and second-stage scheduling problems need not be solved as one combined subproblem, but rather, they can be solved sequentially, the first stage problem followed by the second stage problem. The combination of Stage 1 and Stage 2 problems as one subproblem creates several additional enumerations of possible schedules the model must generate. By reducing this number of enumerations, the computational effort involved in solving the model reduces significantly, thereby allowing reductions in CPU time. In the Sequential approach, the completion times of soldiers determined at Stage 1 are passed to Stage 2 as bounds on their completion times at Stage 2. We prove that solving the combined subproblem sequentially as two subproblems is optimal when the first stage has no limit on the batch size and the ready times of the soldiers at Stage 1 are the same. For the Army Force Generation problem, we use unequal ready times, and therefore, solving the scheduling problems for the first two stages as sequential subproblems can lead to suboptimal solutions. Our experimental investigation shows efficacy of solving larger-sized problem instances with this method. We also recommend various potential additions to improve the Sequential approach for application to the overall Army problem. We have also demonstrated the use of our methodology to a real-life problem instance. Our methodology results in schedules for IMT with an estimated 28% reduction in mean flow time for soldiers over what is currently experienced in practice. We apply this Sequential approach to various extensions of the problem on hand that pertain to hybrid flow shop and agile manufacturing environments. Results of our computational investigation show the effectiveness of using the Sequential approach over direct solution by CPLEX from the viewpoint of both optimality gap and the CPU time required. In particular, we consider two different model configurations for a hybrid flow shop and three different model configurations for an agile manufacturing facility. / Ph. D.

The goal of this research was to develop a series of mixed-metal supramolecular complexes with specialized light absorbing units to probe perturbation of excited-state properties by ligand deuteration and long-term complex stability via racemization of initially enantiopure light absorbing subunits. Varying bidentate polypyridyl terminal ligands (TL), bridging ligands (BL), reactive metal center (RM), or number of Ru(II) light absorbers (LA) tunes the electrochemical, spectroscopic, photophysical, and photochemical properties within the supramolecular architecture. Ru(II) monometallics of the design [(bpy)2Ru(prolinate)](PF6) utilize prolinate as a chiral directing ligand to impart chirality to the Ru(II) LAs in the synthesis of more sophisticated supramolecular complexes. Ru(II) monometallics of the design [(TL)2Ru(BL)](PF6)2 (TL = bpy or d8-bpy; BL = dpp or d10-dpp; bpy = 2,2′-bipyridine; dpp = 2,3-bis(2-pyridyl)pyrazine) covalently couple two TLs and one BL to a central Ru(II) metal center forming a LA subunit. Larger bi- and trimetallic complexes are formed by coupling an additional Ru(II), Rh(III), or Pt(II) metal center to an existing Ru(II) LA through a BL. Ru(II),Ru(II), Ru(II),Rh(III), and Ru(II),Pt(II) bimetallics of the design [(TL)2Ru(BL)Ru(TL)2](PF6)4, [(TL)2Ru(BL)RhCl2(TL′)](PF6)3, and [(TL)2Ru(BL)PtCl2](PF6)2 (TL/TL′ = bpy or d8-bpy; BL = dpp or d10-dpp) couple only one Ru(II) LA to a Ru(II), Rh(III), or Pt(II) metal center through the BL. Ru(II),Rh(III),Ru(II) trimetallics of the design [{(TL)2Ru(BL)}2RhCl2](PF6)5 (TL = bpy or d8-bpy; BL = dpp or d10-dpp) covalently couple two Ru(II) LAs to a central Rh(III) RM through polyazine BLs. The complexes discussed herein are synthesized using a building block approach, permitting modification of the supramolecular architecture through multiple synthetic steps. Electrochemical analysis of the mono-, bi-, and trimetallic complexes displays several common features: a Ru-based HOMO and either a bridging ligand or Rh-based LUMO. TL and BL modification by ligand deuteration does not affect the electrochemistry of the Ru(II), Ru(II),Ru(II), Ru(II),Rh(III), or Ru(II),Rh(III),Ru(II) complexes. Likewise, utilizing a single enantiomer of the LA subunit does not modify the redox behavior of Ru(II), Ru(II),Pt(II), or Ru(II),Rh(III),Ru(II) complexes. All of the mono-, bi-, and trimetallic complexes are efficient light absorbers throughout the UV and visible with π→π* intraligand (IL) transitions in the UV and Ru(dπ)→ligand(π*) metal-to-ligand charge transfer (MLCT) transitions in the visible. Ligand deuteration does not affect the light absorbing properties of the complexes, while incorporation of chiral LA subunits imparts a preference for circularly polarized light (CPL) absorbance into supramolecular complexes. Photoexcitation of the Ru(dπ)→dpp(π*) 1MLCT results in near unity population of short-lived, weakly emissive Ru(dπ)→dpp(π*) ³MLCT excited state. In the Ru(II), Ru(II),Ru(II), and Ru(II),Pt(II) complexes, the 3MLCT excited state relaxes to the ground state by emission of a photon or vibrational relaxation processes. In the Ru(II),Rh(III) and Ru(II),Rh(III),Ru(II) complexes, the 3MLCT excited state is efficiently quenched by intramolecular electron transfer to populate a non-emissive Ru(dπ)→'Rh(dσ*) metal-to-metal charge transfer (3MMCT) excited state. Utilizing a deuterated BL, the excited-state lifetimes and quantum yield of emission (Φem) are increased for Ru(II), Ru(II),Ru(II), Ru(II),Rh(III) and Ru(II),Rh(III),Ru(II) complexes. The Ru(II),Rh(III) and Ru(II),Rh(III),Ru(II) complexes have previously been shown to be exceptional photochemical molecular devices (PMD) for photoinitiated electron collection (PEC). The ability of these complexes to undergo multiple redox cycles, efficiently absorb light, populate reactive excited states, and collect electrons at a reactive Rh metal center fulfills the requirements for H2O reduction photocatalysts. Photolysis of the Ru(II),Rh(III) and Ru(II),Rh(III),Ru(II) complexes with 470 nm light in the presence of a sacrificial electron donor and H2O substrate yields photocatalytic H2 production. Varying the BL from dpp to d10-dpp in the bimetallic architecture results in enhanced, although relatively low, catalyst efficiency producing 40 ± 10 μL H2 with dpp and 80 ± 10 μL H2 with d10-dpp in a CH3CN solvent system after 48 h photolysis. The trimetallic architecture showed no enhancement in photocatalytic efficiency and produced 210 ± 20 μL H2 with dpp and 180 ± 20 μL H2 with d10-dpp in a DMF solvent system after 20 h photolysis. The Ru(II),Rh(III) and Ru(II),Rh(III),Ru(II) complexes' behavior differs in that the excited state lifetime is the most important factor for bimetallic catalyst functioning, but intramolecular electron transfer is the most important factor for the trimetallic photocatalysts. Another important property to understand with these catalysts is their long-term stability in solution. In order for these mixed-metal complexes to be industrially useful, they must perform for long periods of time without degradation in the presence of H2O substrate and electron donors in solution. Previous examinations of Ru(II),Rh(III),Ru(II) photocatalysts have found that they can perform for ca. 50 h of photolysis, but are not as effective as the initial few hours. Special care was taken to synthesize enantiopure LA subunits and incorporate them into Ru(II),Pt(II) and Ru(II),Rh(III),Ru(II) architectures to study their photolytic stability by monitoring how long the complexes retained their chirality using electronic circular dichroism (ECD) spectroscopy. After photolyzing for longer than 200 hours with an LED light source, the quantum yield for racemization (Φrac) for the Ru(II),Pt(II) and Ru(II),Rh(III),Ru(II) architectures is 2.6 ⨉ 10⁻⁸ and 0.72 ⨉ 10⁻⁸ respectively. Also, by photolyzing in the presence of free bpy, the bi- and trimetallic complexes racemize via a non-dissociative trigonal twist mechanism. This dissertation reports the detailed analysis of the electrochemical, spectroscopic, photophysical, and photochemical properties of a series of selectively deuterated [(TL)2Ru(BL)](PF6)2, [(TL)2Ru(BL)Ru(TL)2](PF6)4, [(TL)2Ru(BL)RhCl2(TL′)](PF6)3, and [{(TL)2Ru(BL)}2RhCl2](PF6)5 (TL = bpy or d8-bpy; BL = dpp or d10-dpp; bpy = 2,2′-bipyridine; dpp = 2,3-bis(2-pyridyl)pyrazine) supramolecular complexes and a series of [(bpy)2Ru(prolinate)](PF6), [(bpy)2Ru(dpp)](PF6)2, [(bpy)2Ru(dpp)PtCl2](PF6)2, and [{(bpy)2Ru(dpp)}2RhCl2](PF6)5 supramolecular complexes with enantiopure light absorbing subunits. The design of the supramolecular architecture and intrinsic properties of each subunit contribute to the function of these systems. The careful design, synthesis and purification, thorough characterizations, and experimentation have led to deeper understanding of the molecular properties required for efficient H2O reduction. / Ph. D.

This thesis is devoted to optical properties of Aharonov-Bohm quantum rings in external electromagnetic fields. It contains two problems. The first problem deals with a single-electron Aharonov-Bohm quantum ring pierced by a magnetic flux and subjected to an in-plane (lateral) electric field. We predict magneto-oscillations of the ring electric dipole moment. These oscillations are accompanied by periodic changes in the selection rules for inter-level optical transitions in the ring allowing control of polarization properties of the associated terahertz radiation. The second problem treats a single-mode microcavity with an embedded Aharonov-Bohm quantum ring, which is pierced by a magnetic flux and subjected to a lateral electric field. We show that external electric and magnetic fields provide additional means of control of the emission spectrum of the system. In particular, when the magnetic flux through the quantum ring is equal to a half-integer number of the magnetic flux quantum, a small change in the lateral electric field allows tuning of the energy levels of the quantum ring into resonance with the microcavity mode, providing an efficient way to control the quantum ring-microcavity coupling strength. Emission spectra of the system are calculated for several combinations of the applied magnetic and electric fields.

In this thesis, we present and analyze three algorithms that are designed to make computer simulation more efficient, valid, and/or applicable. The first algorithm uses simulation cloning to enhance efficiency in transient simulation. Traditional simulation cloning is a technique that shares some parts of the simulation results when simulating different scenarios. We apply this idea to transient simulation, where multiple replications are required to achieve statistical validity. Computational savings are achieved by sharing some parts of the simulation results among several replications. We improve the algorithm by inducing negative correlation to compensate for the (undesirable) positive correlation introduced by sharing some parts of the simulation. Then we identify how many replications should share the same data, and provide numerical results to analyze the performance of our approach. The second algorithm chooses a set of best systems when there are multiple candidate systems and multiple objectives. We provide three different formulations of correct selection of the Pareto optimal set, where a system is Pareto optimal if it is not inferior in all objectives compared to other competing systems. Then we present our Pareto selection algorithm and prove its validity for all three formulations. Finally, we provide numerical results aimed at understanding how well our algorithm performs in various settings. Finally, we discuss the estimation of input distributions when theoretical distributions do not provide a good fit to existing data. Our approach is to use a quasi-empirical distribution, which is a mixture of an empirical distribution and a distribution for the right tail. We describe an existing approach that involves an exponential tail distribution, and adapt the approach to incorporate a Pareto tail distribution and to use a different cutoff point between the empirical and tail distributions. Then, to measure the impact, we simulate a stable M/G/1 queue with a known inter-arrival and unknown service time distributions, and estimate the mean and tail probabilities of the waiting time in queue using the different approaches. The results suggest that if we know that the system is stable, and suspect that the tail of the service time distribution is not exponential, then a quasi-empirical distribution with a Pareto tail works well, but with a lower bound imposed on the tail index.