This master thesis summarizes the current knowledge about non-commercial 3D printing FDM technology. The goal of this thesis is to demonstrate the gained knowledge by building a 3D printer which can partially replicate itself, and to evaluate its technological parameters. The experimental part of this work is focused on the impact of the changes in technological parameters of printing on mechanical properties of printed parts.

The master´s thesis is focused on the characterization of degradation process of polypropylene and polypropylene with statistic copolymer into which manganese (II) stearate and cobalt (II) stearates were added at 0.05, 0.10 and 0.20 wt.% loadings. The aim of the thesis was to prepare the controlled life-time polypropylene. The degradation was studied at varying temperatures and prodegradant loadings. The prodegradants were synthetized and characterized using the FTIR and DSC techniques. Thermooxidation of the tested samples induced the changes in crystallinity, melting points and melt-flow indexes. Tensile strength and other mechanical properties were determined by means of the tensile test. The carbonyl index was determined using FTIR, the thermooxidation stability test was used to determine the activation energies of reactions. The changes in morphology of degraded samples were observed by SEM analysis.

Bioactive glasses exhibit unique characteristics as a material for bone tissue engineering. Unfortunately, their extensive application for the repair of load-bearing bone defects is still limited by low mechanical strength and fracture toughness. The main aim of this work was two-fold: the reinforcement of brittle Bioglass®-based porous scaffolds and the production of bulk Bioglass® samples exhibiting enhanced mechanical properties. For the first task, scaffolds were coated by composite coating constituted by polyvinyl alcohol (PVA) and microfibrillated cellulose (MFC). The addition of PVA/MFC coating led to a 10 fold increase of compressive strength and a 20 fold increase of tensile strength in comparison with non-coated scaffolds. SEM observations of broken struts surfaces proved the reinforcing and toughening mechanism of the composite coating which was ascribed to crack bridging and fracture of cellulose fibrils. The mechanical properties of the coating material were investigated by tensile testing of PVA/MFC stand–alone specimens. The stirring time of the PVA/MFC solution came out as a crucial parameter in order to achieve a more homogeneous dispersion of the fibres and consequently enhanced strength and stiffness. Numerical simulation of a PVA coated Bioglass® strut revealed the infiltration depth of the coating until the crack tip as the most effective criterion for the struts strengthening. Contact angle and linear viscosity measurements of PVA/MFC solutions showed that MFC causes a reduction in contact angle and a drastic increase in viscosity, indicating that a balance between these opposing effects must be achieved. Concerning the production of bulk samples, conventional furnace and spark plasma sintering technique was used. Spark plasma sintering performed without the assistance of mechanical pressure and at heating rates ranging from 100 to 300°C /min led to a material having density close to theoretical one and fracture toughness nearly 4 times higher in comparison with conventional sintering. Fractographic analysis revealed the crack deflection as the main toughening mechanisms acting in the bulk Bioglass®. Time–dependent crack healing process was also observed. The further investigation on the non-equilibrium phases crystallized is required. All obtained results are discussed in detail and general recommendations for scaffolds with enhanced mechanical resistance are served.

Moisture damage in asphalt pavement has always been a problem for drivers, bicyclists, and pedestrians. The primary objective of this study is to evaluate moisture susceptibility of Hot-Mix Asphalt (HMA) and to investigate mitigation techniques using different antistripping agents. Three types of antistripping agents were used in this research investigation. Two of which are chemical based and the other is hydrated lime. The two types of liquid antistripping agents used in this study include Arr Maz CC LOF-6500 and Arr Maz CC XL-9000. These two liquid antistripping agents were tested at 0.25%, 0.50%, and 0.75%. Hydrated Lime was tested at 1.0%, 1.5%, and 2.0%. The binder used in this study is Asphalt Performance Grade (PG) 64-16 provided by Oxnard Refinery. The crushed stone aggregate used in this study was provided by Cal Portland. This study follows the guidelines of standardized AASHTO, ASTM, and SuperPave mix design for all preparation and test procedures. A total of 120 4-inch by 2.83-inch core specimens with void ratios between 6 to 8 percent were created to test for moisture susceptibility in accordance with the Modified Lottman Test, which tested for Indirect Tensile Strength and Immersion Compression Test, which tested for Compression Strength and Elasticity. During the test, half of these specimens were placed in a hot water bath for 24 hours to condition the sample to represent field performance and the other half were unconditioned. Based on the results, the best liquid antistripping agent is XL-9000 at 0.50% and hydrated lime is most efficient at a dosage rate of 1.5%. The best performing antistripping additive for the value is hydrated lime at 1.5%.

Sprains are the most common injuries to ligamentous tissues. They are classified as first-degree, second-degree, or third-degree sprains depending upon their severity. First-degree sprains are the result of over-stretching of ligaments. Second-degree sprains involve partial tears of the ligaments. In third-degree sprains, the ligaments are completely torn. Although first- and second-degree sprains are not as severe as third-degree sprains, they occur more frequently. The mechanisms leading to sprains are still not well understood. Therefore, histo-mechanical experiments and theoretical studies are needed to advance our current knowledge on the etiology of sprains. In the first part of this study, a structurally-based constitutive equation is proposed to simulate the damage evolution process in ligaments. The ligament is modeled as a bundle of crimped collagen fibers that are assumed to be oriented along one direction, the physiological loading direction. The gradual straightening of collagen fibers determines the nonlinearity in the toe region of the tensile axial stress-strain curve. Straight collagen fibers behave as a linear elastic material. The gradual damage of collagen fibers determines the nonlinearity in the failure region of the tensile axial stress-strain curve. The parameters in the constitutive equation are estimated by curve fitting experimental data on rat medial collateral ligaments (MCLs) published in the biomechanics literature. In the second part of this study, mechanical experiments are performed in order to identify and quantify damage in ligamentous tissues. MCLs, which are harvested from Sprague-Dawley (SD) rats, are subjected to displacement controlled tensile tests. Specifically, the ligaments are stretched to consecutively increasing stretch values until their complete failure occurs. The elongation of the toe region and decrease in tangent modulus of the linear region of the collected stress-strain data are analyzed and two significantly different damage threshold strains are determined. The effect of age and skeletal maturation on the damage evolution process is also investigated by performing mechanical tests on MCLs isolated from two age groups of SD rats. In the third part of this study, scanning electron microscopy (SEM) is used to determine variations in the microstructure of ligaments that are associated with the elongation of the toe region and decrease in tangent modulus of the linear region of the stress-strain curve. MCLs from SD rats are subjected to different threshold strains that produce damage and, subsequently, examined using SEM. By comparing the morphology of collagen fibers and fibrils in undamaged and damaged MCLs, the microscopic variations induced by strain are determined and correlated to the observed macroscopic mechanical damage. / Ph. D.

Für die Ermittlung der Ermüdungsfunktion sowie der E-Modul-Funktion sind in den europäischen Normen verschiedene Versuchsarten vorgesehen. In Deutschland werden bisher der Einaxiale Zugschwellversuch und der Spaltzugschwellversuch angewandt. Diese vergleichsweise einfachen Versuche können das Ermüdungsverhalten eines Asphaltgemisches in situ nur mit Einschränkungen (z.B. hinsichtlich des vorherrschenden Spannungszustandes) wiedergeben. Der Triaxialversuch mit Zug-/Druckschwellbelastung kann zur realitätsnahen Untersuchung des Ermüdungsverhaltens (Ermüdungsfunktion in Verbindung mit der E-Modul-Funktion) angewandt werden, da neben der frei wählbaren Zugbeanspruchung zusätzlich beliebige Druckbeanspruchungen normal zur Zugspannung auf den Probekörper aufgegeben werden können. Aufgrund der aufwändigen Versuchsdurchführung findet der Versuch bisher nur in der Forschung Anwendung. Die für die Dissertation ausgewerteten Daten umfassen die Ergebnisse von Einaxialen Zugschwellversuchen, Spaltzugschwellversuchen und Triaxialversuchen mit Zug-/Druckschwellbelastung an insgesamt sechs verschiedenen Asphaltgemischen. Die Einflüsse aus dem Hohlraumgehalt, der Belastungsfrequenz sowie der Mischgutart und -sorte auf das Ermüdungsverhalten konnten herausgearbeitet werden. Weiterhin gelang aus den Ergebnissen aller Versuchsarten die Aufstellung von Ermüdungsflächenfunktionen in Abhängigkeit von Dehnungsanteilen infolge verschiedener Spannungskomponenten (mehraxialer Spannungszustand) unter Berücksichtigung der in den Probekörpern der verschiedenen Ermüdungsversuche auftretenden Spannungskombinationen Zug- zu Druckspannung. Die Gültigkeit der ermittelten Ermüdungsflächenfunktion für andere, über die in den angewendeten Versuchsarten hinausgehende Spannungskombinationen muss mit Hilfe geeigneter (noch zu entwickelnder) Versuche überprüft werden.

Für die Ermittlung der Ermüdungsfunktion sowie der E-Modul-Funktion sind in den europäischen Normen verschiedene Versuchsarten vorgesehen. In Deutschland werden bisher der Einaxiale Zugschwellversuch und der Spaltzugschwellversuch angewandt. Diese vergleichsweise einfachen Versuche können das Ermüdungsverhalten eines Asphaltgemisches in situ nur mit Einschränkungen (z.B. hinsichtlich des vorherrschenden Spannungszustandes) wiedergeben. Der Triaxialversuch mit Zug-/Druckschwellbelastung kann zur realitätsnahen Untersuchung des Ermüdungsverhaltens (Ermüdungsfunktion in Verbindung mit der E-Modul-Funktion) angewandt werden, da neben der frei wählbaren Zugbeanspruchung zusätzlich beliebige Druckbeanspruchungen normal zur Zugspannung auf den Probekörper aufgegeben werden können. Aufgrund der aufwändigen Versuchsdurchführung findet der Versuch bisher nur in der Forschung Anwendung. Die für die Dissertation ausgewerteten Daten umfassen die Ergebnisse von Einaxialen Zugschwellversuchen, Spaltzugschwellversuchen und Triaxialversuchen mit Zug-/Druckschwellbelastung an insgesamt sechs verschiedenen Asphaltgemischen. Die Einflüsse aus dem Hohlraumgehalt, der Belastungsfrequenz sowie der Mischgutart und -sorte auf das Ermüdungsverhalten konnten herausgearbeitet werden. Weiterhin gelang aus den Ergebnissen aller Versuchsarten die Aufstellung von Ermüdungsflächenfunktionen in Abhängigkeit von Dehnungsanteilen infolge verschiedener Spannungskomponenten (mehraxialer Spannungszustand) unter Berücksichtigung der in den Probekörpern der verschiedenen Ermüdungsversuche auftretenden Spannungskombinationen Zug- zu Druckspannung. Die Gültigkeit der ermittelten Ermüdungsflächenfunktion für andere, über die in den angewendeten Versuchsarten hinausgehende Spannungskombinationen muss mit Hilfe geeigneter (noch zu entwickelnder) Versuche überprüft werden.

This report aims to increase the scientific knowledge about long-term prospects for the adhesive and adhesive joints for bonding of stainless steels. The effects of water, temperature and chemicals on the adhesive and adhesive joints are investigated. Stainless steel plates are pretreated with a primer and isopropanol, there after joined together with single lap modeling. The strength of the joint is tested with a tensile test and additionally a watertightness test is performed to determine if the joints are watertight. For this project three versions of stainless steels is used and two different technologies of two- part adhesives, silicone and silane-modified polymer and one technology of tape, a double coated acrylic foam tape are tested. The result shows that all the adhesives fails cohesively and that tape fails partly adhesively. Result shows that all tests are affected by water, temperature and chemicals on different levels but tape is affected the most with a minimum of 40% loss in shear strength. Watertightness test shows that aged tape joints are not watertight. The polymer shows no signs of decreasing in shear strength and is watertight, but does become more viscous by aging. The report shows that a possible combination of adhesive and pretreatment that can withstand the effects of water, temperature and chemicals is found. The polymer presents a possibility to bond stainless steel with a simple pretreatment. Tape didn’t pass the test in a suitable way but presents opportunities if a sufficient pretreatment can be found.

Due to the findings of extensive damage on geogrids used in a road embankment in northern Sweden, the Swedish Transport Administration (TRV) started to investigate the reason of these damages. Since the geogrids were installed at low temperature, below 0°C, it was suspected that the damages were connected the low temperature. To analyse whether low temperatures have an influence on the extent of installation damages, both a half-scale setup and temperature controlled tensile tests have been carried out on geogrids. In total five different types of geogrids have been tested; 3 extruded polypropylene geogrids, 1 woven PET geogrid, and 1 welded PET geogrid. All geogrids had an aperture size of approximately 35 mm and specified tensile strength of approximately 40 kN/m. The Half-scale tests was conducted by building a small road embankment inside a freeze container, at the Luleå University of Technology (LTU). The embankment contained crushed aggregate, type 0-70 mm, and geogrids. The purpose of the half-scale test was to simulate installation of geogrids at different temperatures and thereby investigate whether low temperatures have an influence on the rate of installation damages. The half-scale test was done for each type of geogrid at the temperatures: +20°C, -20°C and -30°C. First, the geogrid was covered by 150 mm of crushed aggregate. Then a vibratory plate (160 kg) was used to compact the crushed aggregate. After each installation, the crushed aggregate was removed carefully by vacuum suction. The geogrid was removed and then analysed by visual control and tensile tests conducted according to ISO 10319:2008 (wide width tensile test). Results from the half-scale tests indicate that 2 out of 5 of the tested geogrids were affected by the testing procedure. The results indicate that: -        one of the geogrids of polyprophylene (here referred to as G2) was more damaged at lower temperatures compared to installation at +20° C. -        the geogrid of woven PET (here referred to as G5) was less damaged at lower temperatures compared to installation at +20° C. Results for the other geogrids are either inconsistent or shows no significant variation of the measured parameters as function of temperature. Hence, these results cannot be interpreted as damage during installation. Temperature controlled tensile tests were done by tensile testing single strands from the geogrids to failure, inside a temperature controlled chamber. The purpose of these tests was to investigate how the strength properties of the geogrids are affected by low temperature. The test was repeated 5 times for each geogrid and temperature (+20°C, 0°C, -10°C and -20°C). Force and strain was measured during the tests. The results from the temperature controlled tensile tests show that the maximum strain decreases with lower temperature for all tested geogrids. The maximum strain decreased by 16% - 49% when the temperature dropped from +20°C to -20°C. The results show that the tensile strength increases with lower temperature for all tested geogrids except for the welded PET geogrid (here referred to as G1). For G1 the tensile strength decreased by approximately 7% at a temperature drop from +20°C to -20°C. For the woven PET geogrid (G5) and the polypropylene geogrids (G2-G3) the tensile strength increased between 13%-45% at a temperature drop from +20°C to -20°C. The E-modulus increased at lower temperature for all tested geogrids. The secant E-modulus at 2% strain increased by 13%-71% at a temperature drop from +20°C to -20°C. Summarized conclusions from the tests: Strength properties changed for all tested geogrids as the temperature decreased. All tested geogrids got stiffer at lower temperatures. The magnitude of the effects is different for different geogrids. The tensile strength increased with lower temperature for all tested geogrids except for the welded PET geogrid, which got lower tensile strength at lower temperature. The half-scale test indicates that the amount of installation damages at geogrids can be dependent of the temperature at installation. However, these indications can only be seen at two out of five tested geogrids. The effect cannot be connected to a specific step in the installation procedure and cannot be explained by the results from the temperature controlled tensile tests. The results from the half-scale test have a statistically low reliability since only one installation for each temperature and geogrid type was done. The compaction equipment used during the test was small, and had low compaction energy compared to a vibratory roller compactor commonly used in construction work. With respect to the discussion above, further studies should be focusing on developing the half-scale test. It is suggested that the test is scaled up to a full-scale test in order to simulate a real installation as close as possible. The test should also be conducted several times for each geogrid at each temperature in order to enable statistical analyses.

Abstract The purpose of this research is to investigate the influence of Manganese (Mn) on cast aluminum alloys where a substantial amount of Iron (Fe) is included. Ductility and tensile strength need to be improved in recycled aluminum alloys where greater amounts of Fe are found. Fe is a common impurity and is known to be detrimental to mechanical properties and in order to neutralize the effects of Fe; modifiers such as Mn are added. In this investigation, attempts will be carried out aiming to find the optimal amount of Mn. Other related topics that will be discussed are whether there exists a Mn/Fe ratio which clearly modifies the harmful iron- rich phases and improves the properties for a certain alloy or not. Also, will the heat treatment have a significant effect on mechanical properties? These are some of the questions that will be answered in this paper. It is hard to find research articles that focus only on the influence of Mn on the microstructure and mechanical properties of Al-Si cast alloys. Much of the work that is already published concerns only a specific alloy and casting method. In this work three different casting processes, sand-, die- and high pressure die-casting, will be simulated by using gradient solidification equipment. Furthermore, the influence of heat treatment on the mechanical properties will be examined. The results showed that the solidification rate had the biggest impact on the microstructure and mechanical properties of the alloys, where the fastest cooling rate gave the best results. The effect of Mn seems to influence the samples with coarser microstructures significantly where it had time to modify the Iron-rich needles, also called the β-phase. At higher cooling rates the impact of Mn was impeded. It has been observed that a high content of Mn (around 0.6%) needs to be added before the properties start to improve. UTS (Ultimate Tensile Strength) and YS (Yield Strength) are improved while ductility is lowered. Heat treatment did not seem to have any influence on the effects of Mn.