<p>Interrogating the concept of power is ethical social work practice. This research aims to investigate the manner in which visible minority women social service providers perceive the concept of power as non-managerial employees in the women’s shelter system. Therefore, the necessity to delineate the ongoing challenges and contradictions that shape the work experiences of visible minority women social service providers contributes and furthers our understanding of social justice, critical social work practice, and strategies to enhance workplace equity. In addressing the phenomenon of power from the viewpoint of those affected, this ultimately helps to broaden the understanding how as social workers it remains pivotal to raise awareness about the ongoing power imbalances in social services settings. Semi-structured, in-depth interviews with visible minority women employed in the women’s shelter system in southern, Ontario were conducted and complement the author’s own personal reflections as a visible minority woman previously employed in the Violence Against Women’s shelter system. This research suggests that due to ongoing power differentials, neoliberal restructuring and discriminatory incidents, continued attention is required in order to address social inequality and enhance workplace equity.</p> / Master of Social Work (MSW)

ABSTRACT Why do we design architecture? How we design it? Why do we design architecture in this way, not in that way? What‘s the most important characteristic for architecture? How we can identity if architecture has realized all ideas we proposed before? With these questions, with the help from kind professors, I found one interesting place - Cao changdi, Beijing, China. Luckily, I found one interesting street and noticed there are some problems here. I needed to figure out what exactly are the problems and try to solve the problems with architecture. I found that relations and connections are missing at this street. They are supposed to be there, but they are invisible. Why not make them visible? I tried to direct this design based on the user’s stories or experiences. My approach was to visualize peoples’ experience in a new architecture through story boards, or ‘frame’ of applying the film director’s skills and design minds to approach architecture. Let peoples’ experience in an architecture become a movie. Applying the film director’s skills and minds to the design of architecture. Space plays an important role in architecture design. What happened in that space is what is important. Of course, stories would happen in that space. Then what’s the story? My thesis project would illustrate how three stories - visitor, villager and artist‘s experience help to direct the design.

Doctor of Philosophy / Department of Chemistry / Kenneth J. Klabunde / For solar environmental remediation, a new generation of nanosized (< 10 nm) titanium dioxide photocatalysts codoped with metals and nonmetals, or metals only were prepared by the xero-gel and aero-gel methods. For silver or cobalt-based xero-gel titanium dioxide photocatalysts, photoactivities tests revealed that codoping of titanium dioxide with a metal (1% Ag or 2% Co) and nonmetals (carbon and sulfur) is necessary to achieve high-activities for acetaldehyde degradation under visible light (wavelength > 420 nm). It was concluded that high visible-light-activities for acetaldehyde degradation over codoped titanium dioxide were attributed to an interplay of anatase crystallinity, high-surface area, reduced band-gap (< 3.0 eV), uniform dispersion of doped metal ions, and suppressed recombination rate of photogenerated electron-hole pairs. Moreover, the nature and amount of codoped metals play a significant role in visible-light-induced photocatalysis. Metals (Al, Ga, and In) doped/codoped titanium dioxide photocatalysts were prepared by the aero-gel method. The photocatalytic studies showed that activities of metal doped/codoped photocatalysts under UV light (wavelength < 400 nm) were found to be dependent on pollutants. Indium demonstrated beneficial effects in both textural and photocatalytic properties. Gallium and indium codoped titanium dioxide photocatalysts displayed even better performance in the CO oxidation reaction under UV light. Notably, titanium dioxide codoped with Ga, In, and Pt, exhibited unique photoactivities for the CO oxidation under both UV and visible light irradiation, indicating that this system could have promise for the water-gas shift reaction for hydrogen production. Silver-based nanostructured titanium dioxide samples were developed for killing human pathogens (Escherichia coli cells and Bacillus subtilis spores). Biocidal tests revealed that silver, carbon, and sulfur codoped titanium dioxide nanoparticles (< 10 nm) possess very strong antimicrobial actions on both E. coli (logarithmic kill > 8) and B. subtilis spores (logarithmic kill > 5) for 30 minute exposures in dark conditions compared with Degussa P25. It was believed that the carbon and sulfur codoped titanium dioxide support and Ag species acted synergistically during deactivation of both E. coli and B. subtilis spores. Thus, titanium dioxide codoped with silver, carbon, sulfur can serve as a multifunctional generic biocide and a visible- light-active photocatalyst.

This dissertation is about pastoral care and counselling to elderly people to keep them visible within our faith communities. The research is a reflection and a re-telling of the lives of five elderly people who shared their stories with me. I heard them talk about ageing as an ongoing journey that is not always smooth. To grow older includes a lot of changes and a reassessment of lifestyles and goals as well as the danger of becoming invisible to others. Visibility cannot be maintained without communities of support, and care within communities of shared prophetic mission. A pastoral therapist must convey the Christian message of care by healing and caring solidarity, co-constructing new narratives of hope, and bringing back visibility to the elderly. / Practical Theology / M.Th. (Specialisation in Pastoral Therapy)

Beta Pictoris est jusqu'à présent la seule étoile autour de laquelle un disque de matière a été image. Ce disque pourrait constituer un système protoplanétaire dans un état d'évolution encore indéterminé. Nous présentons les observations en spectroscopie haute résolution (visible et uv) de la partie gazeuse de ce disque et un modèle de disque proposé pour en rendre compte. Ce modèle est discuté et comparé à ceux dérivés des observations en imagerie de la poussière. D'importantes variations sont observées dans la partie rouge des raies circumstellaires des éléments métalliques ionisés. Ces variations sont analysées en detail. Nous montrons qu'elles peuvent s'expliquer par l'évaporation de gros corps solides (environ 1 km) en chute vers l'étoile. Nous présentons enfin une approche possible dans la recherche d'autres systèmes semblables à celui de beta Pictoris et les premiers résultats dans ce domaine

L'adsorption de l'anthracène et de molécules de type Diphényl-polyènes (trans-Stilbene, 1,4-Diphenyl-1,3 butadiene, 1,6-Diphenyl-1,3,5-hexatriene) a été étudiée par simulations Monte Carlo, absorption UV-visible par réflexion diffuse, diffusion Raman multiexcitation et Résonance Paramagnétique Electronique (RPE) dans des zéolithes (aluminosilicates) à canaux de type Ferrierite (M-FER), ZSM-5 (MnZSM-5) et Mordenite (M-MOR).<br />Les résultats mettent en évidence l'insertion des molécules dans les canaux. Dans le cas de cations polarisants (M = H+ et Li+) une ionisation spontanée produit la formation de paires radical cation – électron de longue durée. Au cours de la recombinaison de charges, des paires électron-trou sont mises en évidence par des techniques impulsionnelles de RPE. Dans le cas des molécules insérées sans modification chimique (M = Na+, K+, Rb+, Cs+), la photolyse UV induit des paires de radicaux dont la lente recombinaison implique des phénomènes de transferts d'électrons régis par la théorie de Marcus. L'exceptionnelle stabilité des paires de radicaux est attribuée au confinement des molécules dans les canaux, à la teneur en aluminium et à la nature des cations de la zéolithe. Ces paires de radicaux sont des intermédiaires réactionnels mis en jeu dans les processus catalytiques et de photodégradation d'hydrocarbures. Ils sont aussi impliqués dans le processus primordial de l'effet photovoltaïque.

L'intérêt philosophique pour la " visibilité " - Sichtbarkeit -, à la fin du XIXe siècle, participe d'une interaction nouvelle entre art, science et technique. Le dessin réunit les arts graphiques comme science du " visible ". Vitruve établit déjà que la " science de l'architecte " - Architecti scientia - prend valeur et se renforce par la " science du dessin " - Graphidis scientia. La recherche porte sur l'analyse du dessin que l'architecte utilise et produit lorsqu'il travaille à s'instruire selon son propre arbitre et ses propres moyens, hors les murs des écoles et des ateliers, au tournant du XIXe au XXe siècle. Charles-Édouard Jeanneret (1887-1965), Paul Tournon (1881-1964) et Jean-Charles Moreux (1889-1956) voyagent pour leur apprentissage. Ils regardent le monde et transcrivent leur étonnement activé au contact de la réalité. De la même manière, pour se former, alors que leur production architecturale sera très différente, ils notent en dessin. Nous interrogeons la réduction intellectuelle et graphique de la note comme une forme courte de représentation. La forme courte est le travail conscient d'analyse et de recherche synthétique. Chaque trait est pensé et pensé comme matérialité. C'est un acte conceptuel d'abstraction. Comment cette forme courte, que nous interprétons dans sa vocation théorique, participe-t-elle de l'acquisition du " regard instruit " de l'architecte ?

Natural archives such as lake sediments allow us to assess contemporary ecosystem responses to climate and environmental changes in a long-term context beyond the few decades to at most few centuries covered by monitoring or historical data. To achieve a comprehensive view of the changes preserved in sediment records, multi-proxy studies – ideally in high resolution – are necessary. However, this combination of including a range of analyses and high resolution constrains the amount of material available for analyses and increases the analytical costs. Infrared spectroscopic methods are a cost-efficient alternative to conventional methods because they offer a) a simple sample pre-treatment, b) a rapid measurement time, c) the non- or minimal consumption of sample material, and d) the potential to extract quantitative and qualitative information about organic and inorganic sediment components from a single measurement. The main objective of this doctoral thesis was twofold. The first part was to further explore the potential of Fourier transform infrared (FTIR) and visible-near infrared (VNIR) spectroscopy in paleolimnological studies as a) an alternative tool to conventional methods for quantifying biogenic silica (bSi) – a common proxy of paleoproductivity in lakes – in sediments and b) as a tool to infer past lake-water total organic carbon (TOC) levels from sediments. In a methodological study, I developed an independent application of FTIR spectroscopy and PLS modeling for determining bSi in sediments by using synthetic sediment mixtures with known bSi content. In contrast to previous models, this model is independent from conventional wet-chemical techniques, which had thus far been used as the calibration reference, and their inherent measurement uncertainties. The second part of the research was to apply these techniques as part of three multi-proxy studies aiming to a) improve our understanding of long-term element cycling in boreal and arctic landscapes in response to climatic and environmental changes, and b) to assess ongoing changes, particularly in lake-water TOC, on a centennial to millennial time scale. In the first applied study, high-resolution FTIR measurements of the 318-m long sediment record of Lake El’gygytgyn provided a detailed insight into long-term climate variability in the Siberian Arctic over the past 3.6 million years. Highest bSi accumulation occurred during the warm middle Pliocene (3.6-3.3 Ma), followed by a gradual but variable decline, which reflects the first onset of glacial periods and then the finally full establishment of glacial–interglacial cycles during the Quaternary. The second applied study investigated the sediment record of Torneträsk in subarctic northern Sweden also in relation to climate change, but only over the recent post-glacial period (~10 ka). By comparing responses to past climatic and environmental forcings that were recorded in this large-lake system with those recorded in small lakes from its catchment, I determined the significance and magnitude of larger-scale changes across the study region. Three different types of response were identified over the Holocene: i) a gradual response to the early landscape development following deglaciation (~10000-5300 cal yr BP); ii) an abrupt but delayed response following climate cooling during the late Holocene, which occurred c. 1300 cal yr BP – about 1000-2000 years later than in smaller lakes from the area; and iii) an immediate response to the ongoing climate change during the past century. The rapid, recent response in a previously rather insensitive lake-ecosystem emphasizes the unprecedented scale of ongoing climate change in northern Fennoscandia. In the third applied study, VNIR-inferred lake-water TOC concentrations from lakes across central Sweden showed that the ongoing, observed increase in surface water TOC in this region was in fact preceded by a long-term decline beginning already AD 1450-1600. These dynamics coincided with early human land use activities in the form of widespread summer forest grazing and farming that ceased over the past century. The results of this study show the strong impact of past human activities on past as well as ongoing TOC levels in surface waters, which has thus far been underestimated. The research in this thesis demonstrates that infrared spectroscopic methods can be an essential component in high-resolution, multi-proxy studies of past environmental and climate changes.

This thesis explores the use of single-photon avalanche diodes (SPADs) for visible light communications (VLC). The high sensitivity of SPADs can potentially enhance the performance of VLC receivers. However, a SPAD-based system has challenges that need to be addressed before it can be considered as a viable option for VLC. The first challenge is the susceptibility of SPAD-based receivers to variations in ambient light. The high sensitivity of SPADs is advantageous for signal detection, but also makes SPADs vulnerable to variations in ambient light. In this thesis, the performance of a SPAD-based receiver is investigated under changing lighting conditions. Analytical expressions to quantify performance are derived, and an experiment is conducted to gain further understanding of system performance. It is shown that a SPAD-based receiver is highly sensitive to illumination changes when on-off keying (OOK) is employed, and that pulse-position modulation (PPM) is a preferred modulation scheme as it is more robust. The second challenge is broadcasting to SPAD-based receivers with different capabilities. A traditional broadcasting scheme is time-sharing, whereby a transmitter sends data to receivers in an alternating manner. Broadcasting to SPAD-based receivers is challenging as receivers may have diverse capabilities. In this thesis, a new multiresolution modulation scheme is proposed, which can potentially improve system performance over the traditional timesharing approach. The performance of the proposed scheme is analyzed, and a proof-of-concept experiment is performed to demonstrate its viability.

HPLC has been used and can quickly determine several ions simultaneously. The method of determination described for transition metals [Cr(III), Fe(III), Ni(II), Co(II), Cu(II), Zn(II), Cd(II), Mn(II)] and [Ca(II), Pb(II)] using HPLC with UV-VIS detection is better than the PAR complexation method commonly used. The effects of both eluent pH and detector wavelength were investigated. Results from using different pHs and wavelengths, optional analytical conditions for the separation of [Ni(II), Co(II), Cu(II)], [Cr(III), Fe(III), Ca(II), Ni(II), Cu(II)], and [Ca(II), Zn(II), Pb(II)] in one injection, respectively, are described. The influence of adding different concentrations of Na_2EDTA solvent to the sample is shown. Detection limits, linear range, and the comparisons between this study and a post-column PAR method are given.