North American populations of white-winged scoters (<i>Melanitta fusca deglandi</i>) have declined markedly over the past several decades. The causes for decline are uncertain, but likely involve a complexity of events occurring on wintering and breeding areas. To gain insight into potential cross-seasonal effects, I delineated Atlantic and Pacific wintering scoter populations and linked them to a shared breeding area using stable isotope analysis of carbon (δ13C) and nitrogen (δ15N) ratios in feathers. By applying this methodology to a marked breeding population at Redberry Lake, Saskatchewan, I assigned females to putative wintering areas and determined: (1) population structure; (2) the extent of winter site philopatry; and, (3) differences in vital rates and other variates in relation to winter origin. Discriminant function analysis of isotopic ratios in feather samples from known wintering locations resulted in classification probabilities of 96% (<i>n</i> = 149) for Pacific and 78% (<i>n</i> = 32) for Atlantic wintering scoters. Using this methodology, I determined that the Redberry Lake breeding population is comprised of approximately 75% Pacific and 25% Atlantic wintering birds, and its members exhibit high degrees of winter region philopatry based on the classification of successive recaptures over three field seasons. Annual variations in population structure, as well as differences in nest initiation dates and blood contaminant loads in relation to winter area suggest seasonal interactions may influence survival and reproductive success of this population. To gain insight into potential seasonal interactions, I examined nest success and female survival in relation to winter area. No significant differences in nest success in relation to winter area were found, but nests that failed before mid-incubation were not sampled. Adult female survival rate for 2000-2004 was estimated as 0.85, with no significant difference detected between wintering areas. This study demonstrated that it is important to link breeding and wintering areas to better understand the factors influencing population dynamics and to effectively address conservation issues.

Varved (annually laminated) sediments are of great interest for inference of past environmental conditions, as they provide dated records with high time resolution. After deposition, the sediment varves are affected by diagenesis; i.e., chemical, physical and biological changes that occur within the sediment. An important premise when reconstructing past environmental conditions using lake sediments is that the signal of interest is preserved in the sediment. In this thesis I have used a unique collection of ten stored freeze cores of varved lake sediment from Nylandssjön in northern Sweden, collected from 1979 to 2007. The suite of cores made it possible to follow long-term (up to 27 years) changes in iron (Fe), sulfur (S), carbon (C), nitrogen (N), δ13C and δ15N in the sediment caused by processes that occur in the lake bottom as the sediment ages. The sediment geochemistry and resulting changes were followed in years for which there are surface varves in the core series. Fe and S concentrations analyzed by X-ray fluorescence spectroscopy showed no diagenetic front in the sediment and the data do not suggest a substantial vertical transport of Fe and S in the sediment. A model based on thermodynamic, limnological, and sediment data from the lake, showed that there are pe (redox) ranges within which either FeS (reduced specie) or Fe(OH)3/FeOOH oxidized species) is the only solid phase present and there are pe ranges within which the two solid phases co-exist. This supports the hypothesis that blackish and grey-brownish Fe-layers that occur in the varves were formed at the time of deposition. C and N analyzed with an elemental analyzer showed that within the first five years after deposition the C concentration of the sediment decreased by 20% and N by 30%, and after 27 yr in the sediment, there was a 23% loss of C and 35% loss of N. The C:N ratio increased with increasing age of the sediment; from ~ 10 in the surface varves to ~12 after 27 years of aging. δ13C and δ15N analyzed on a mass spectrometer showed that δ13C increased by 0.4-1.5‰ units during the first five years, after that only minor fluctuations in δ13C were recorded. Another pattern was seen for δ15N, with a gradual decrease of 0.3-0.7‰ units over the entire 27-year-period. The diagenetic changes in the stable isotope values that occur in Nylandssjön are minor, but they are of about the same magnitude as the variation in the isotopic signal in the varves deposited between 1950-2006. My results show that diagenesis does not change the visual appearance of the varves, except for varve thickness; the varves get thinner as the sediment ages. As the color of Fe in the varves likely reflects the environmental conditions at the time of deposition this creates possibilities for deciphering high-temporal-resolution information of past hypolimnetic oxygen conditions from varves. My findings on C, N, δ13C and δ15N will have implications for interpretations of paleolimnological data. The diagenetic effects should be carefully taken into consideration when C, N, δ13C and δ15N in sediment cores are used to study organic matter sources or paleoproductivity, in particular when dealing with relatively small and recent changes. In addition to the significance of diagenetic effects on sediment parameters, a comparison of the varves in Nylandssjön and the adjacent lake Koltjärnen, and the two deep basins of Nylandssjön show that subtle features in the lakes and their catchments affect the appearance of the varves, which make interpretation of varves complicated.

No description available.

L'évolution spatio-temporelle des populations d'Ophiocomina nigra et d'Ophiothrix fragilis (Ophiuridés, Echinodermes) a été étudiée dans deux écosystèmes contrastés de la pointe de Bretagne (France); la rade de Brest et la baie de Douarnenez. Entre la fin des années 80 et 2011, la population d'O. nigra s'est très largement étendue sur l'ensemble des zones d'études et a vu sa densité augmenter d'un facteur 5 en rade de Brest. Dans ce site, l'expansion d'O. nigra a généré de profonds changements qui se sont progressivement traduits entre autre par une exclusion spatiale d'O. fragilis du bassin central vers la partie sud de la zone d'étude où l'espèce colonise des coquilles vides de crépidules; Crepidula fornicata. L'expansion d'O. nigra a été mise en relation avec la combinaison de possible changements globaux du milieu et les traits biologiques de l'espèce. Les isotopes stables naturels (δ13C & δ15N) et les marqueurs d'acides gras ont été utilisés pour décrire l'écologie trophique des deux ophiures par un suivi in situ, sur des stations sélectionnées en raison de leurs situations contrastées (influence continentale vs influence océanique). Les facteurs de discrimination (∆δ13C et ∆δ15N) ont été calculés en expérimentation pour les deux espèces avec trois types de sources et ont montré principalement un effet de la qualité de la nourriture et de l'état reproducteur des espèces sur ces facteurs et des différences interspécifiques. Le suivi in situ a principalement révélé des différences interspécifiques dans l'alimentation des espèces. Le phytoplancton (diatomées) apparait en été comme une source majeure pour les deux espèces et plus importante pour O. fragilis. Des valeurs en δ15N plus élevées chez O. nigra par rapport à O. fragilis associées à une plus forte contribution de bactéries, de détritus et de matériel d'origine animal, indiquent que l'espèce exploite une grande diversité de sources de nourriture expliquant en partie son succès. Les macroalgues (Ulva sp) et les apports terrigènes semblent jouer un rôle trophique mineur pour les deux espèces, malgré une augmentation significative dans les sites plus confinés en fin d'étude.

Thesis (MSc (Forest and Wood Science))--University of Stellenbosch, 2011. / ENGLISH ABSTRACT: This study investigated the use of carbon isotopes as a potential measure for water availability and drought stress in Pinus radiata in the Western and Southern Cape, South Africa. An understanding of water availability and its variation in space is fundamental to the implementation of increasingly site-specific management regimes that have the potential to greatly improve productivity across sites in the region. Fifteen plantation compartments situated on water shedding sites were identified where good weather data existed and a water balance model could be run. In addition, late wood samples were analysed from four co-dominant trees in the same stand to determine the δ13C values of five tree rings, each representing a specific growth year before first thinning. Detailed water balances were constructed for each trial site and drought stress indicators (a) relative canopy conductance (after Granier et al., 2000) and (b) the ratio of actual to potential evapotranspiration (supply / demand ratio), were related to δ13C values in latewood. Maximum available soil water ranged from 52 to 313 mm across trial sites. The water balance model used adequately described soil water availability throughout each growing season and indicated that stand stress due to the lack of available soil water mainly occurred during the summer months of the study period (November to April). The supply / demand ratio for this period as well as the relative canopy conductance proved to be good measures of drought stress. The six-month supply demand ratio (calculated for the period November to April) ranged from 0.04 to nearly 1 (winter rainfall zone) and 0.35 to 1 (all-year rainfall zone) and were strongly related to δ13C values (p < 0.001; r2 = 0.7822). It appears that using δ13C values, it may be possible to classify sites into three water availability classes. This classification may assist in the implementation of intensive silvicultural operations on an increasingly site-specific basis. Where sites are enriched with water from lateral flow or upslope positions, δ13C may be the only reliable technique to quantify soil water availability. / AFRIKAANSE OPSOMMING: Hierdie studie ondersoek die gebruik van koolstof isotope as 'n moontlike maatstaf vir die beskikbaarheid van water en droogtestremming in Pinus radiata in die Wes-en Suid-Kaap, Suid-Afrika. 'n Begrip van die beskikbaarheid van water en die ruimtelike variasie daarvan is fundamenteel vir die implementering van groeiplek-spesifieke bestuur sisteem wat die potensiaal het om baie verbeterde produktiwiteit oor persele in die streek teweeg te bring. Vyftien plantasievakke, geleë op waterskeidingsterreine is geïdentifiseer waar goeie weer data bestaan en 'n water balans model uitgevoer kon word. Daarmee saam is laathout monsters vanuit vier ko-dominante bome in dieselfde kompartement geanaliseer en die δ13C waardes van laathout in vyf jaarringe bepaal wat elk 'n spesifieke jaar van groei voor die eerste dunning verteenwoordig. Gedetailleerde water balanse is vir elke proef perseel bereken en aanwysers van droogtestremming, nl.: (a) relatiewe kroon geleiding (na Granier et al., 2000) en (b) die verhouding van die werklike teenoor potensiële evapotranspirasie (vraag / aanbod verhouding) is gekorreleer met 13C waardes in laat hout. Die maksimum hoeveelheid water beskikbaar op die verskeie proefpersele wissel van 52 tot 313 mm. Die water balans model wat gebruik is beskryf die beskikbare grondwater met genoegsame akkuraatheid. vir die hele groeiseisoen. Die model dui ook aan dat die kompartemente droogtestremming as gevolg van die gebrek aan beskikbare grond water ervaar gedurende die somer maande van die studie tydperk (November tot April). Die vraag / aanbod verhouding vir hierdie tydperk, asook die relatiewe kroon geleiding is geskik om as maatstawwe van droogtestremming gebruik te word. Die vraag / aanbod verhouding (bereken vir die tydperk November tot April) het gewissel van 0,04 tot byna 1 (Winter reënval gebied) en 0,35 tot 1 (die heel jaar reënval sone) en is sterk verwant aan 13C waardes (p <0,001; r2 = 0,7822). Dit blyk dat met die gebruik van δ13C waardes, dit moontlik kan wees om kompartemente te klassifiseer in drie klasse van water beskikbaarheid. Hierdie klassifikasie kan help met die implementering van intensiewe boskultuur bedrywighede op 'n meer vak-spesifieke basis. Waar vakkeverryk is met water vanuit laterale vloei of hoër liggende posisies, mag δ13C dalk die enigste betroubare tegniek wees om die beskikbaarheid van water te kwantifiseer.

This study examined mercury and methylmercury concentrations in shark species in order to determine differences between shark species and between locations. Stable isotope ratios were determined to see if interaction existed between approximate trophic level and mercury concentrations. Sharks were sampled from Florida Bay where muscle tissue biopsies and blood samples were extracted upon capture. Stable isotope ratios for carbon-13 (δ13C) and nitrogen-15 (δ15N) from freezedried blood samples were compared with levels of organic and inorganic mercury species from tissue samples in seven different shark species, focusing on blacknose, blacktip, bull, and lemon sharks. Pre-caudal length (PCL) was strongly correlated to mercury concentration and δ13C but not with δ15N. Ratios of δ15N between shark species were in agreement with observed trophic-level behavior of blacktip sharks feeding on blacknose sharks, indicated by greater values for δ15N ratios in blacktip sharks. Calculated length-normalized stable isotope ratio values correlated strongly to values for mercury concentrations in blacktip sharks, indicating a potential method for forecasting inorganic or organic mercury concentrations without the use of more expensive mercury tests. This calculation also provided validity for a new metric involving the use of stable carbon isotope ratio divided by length (PCL) to be compared with other metrics. Correlations between δ15N values and mercury values indicate some level of interaction between trophic level and quantity of mercury contaminants in shark muscle tissue.

Les plages de sable sont des écosystèmes dynamiques couvrant 70% des côtes mondiales. Ces systèmes abritent un cortège spécifique unique et assurent des fonctions essentielles de nourricerie, de nurserie et d’épuration des eaux. Or à proximité des côtes, la population humaine est en développement constant ce qui accroît les multiples pressions d’origine anthropique sur les écosystèmes côtiers. L’apport en excès de nutriments constitue une menace majeure qui peut se traduire par le développement d’importantes biomasses de macroalgues opportunistes (eutrophisation). La fréquence et l’intensité de ces blooms, communément formés de chlorophycées à court cycle de vie (ulves) et appelés marées vertes (MV), s'amplifient sur les côtes françaises et dans le Monde menaçant le fonctionnement de systèmes prépondérants et uniques.La plupart des études visant à déterminer les effets des MV sur la structure et le fonctionnement d’écosystèmes sédimentaires ont été conduites dans des environnements abrités, micro- ou atidaux. Cette problématique est restée presqu’inexplorée dans des écosystèmes plus dynamiques (systèmes ouverts et macrotidaux) en raison des difficultés de mise en place d’échantillonnage et de détection des effets de stress d’origine anthropique, inhérentes à la variabilité de ces systèmes. Cette thèse a donc eu pour objectif principal de combler ce manque et produire des connaissances en étudiant les réponses in situ des communautés benthiques de plages de sable fin macrotidales en présence ou non de MV. Quatre études ont été menées à différentes échelles spatio-temporelles et en considérant différents compartiments biologiques pour répondre à cette question générale.Ce travail de thèse montre qu’à l’échelle de la région Bretagne (variabilité intégrée sur 2700km de côtes et 7 ans) les communautés benthiques d’écosystèmes dynamiques sont modifiées significativement et de manière conservative par la présence de MV. Ce travail démontre aussi que les marées vertes impactent différemment la faune benthique en fonction du type d’habitat (plages semi-exposées vs. exposées), de la profondeur (mediolittoral vs. infralittoral), et du compartiment biologique (macrofaune benthique vs. juvéniles de poissons plats). Ces comparaisons ont permis d’identifier la faune benthique de médiolittoral inférieur des plages exposées comme étant le système le plus affecté par les MV. L’étude des variations à fine échelle spatio-temporelle de ce dernier montre que les caractéristiques faunistiques (uni- et multi-variées) sont modifiées le long d’un gradient de couverture d’algues vertes. Par exemple, la β-diversité décroît significativement le long de ce gradient. Afin d’explorer les processus pouvant expliquer ces modifications, et déterminer si ces changements ont des répercussions sur le fonctionnement de l’écosystème « plage de sable », les effets de l’accumulation d’ulves sur le réseau trophique à différent(e)s niveaux/échelles ont été mesurés. Les résultats de cette étude montrent qu’une importante biomasse d’ulves induit un changement de la structure entière du réseau trophique et une modification importante du fonctionnement trophique des plages. Les expérimentations menées au cours de cette thèse montrent que les changements observés sont induits par des effets directs (consommation de débris d’ulves) et indirects (modifications d’autres sources de nourriture) de la présence des MV.Cette thèse propose un cadre de travail visant à mieux détecter les effets de stress anthropiques sur la structure et le fonctionnement d’écosystèmes dynamiques. Dans un contexte de changement global forçant les écosystèmes à faire face à de multiples stress, cette approche pourrait se révéler particulièrement utile pour démêler, comprendre et prédire les effets de perturbations induites par les activités humaines sur le fonctionnement des écosystèmes et constituer une aide à la gestion de ces environnements particuliers. / Highly dynamic systems, often considered as resilient systems, are characterised by abiotic and biotic processes under continuous and strong changes in space and time. Because of this variability, the detection of overlapping anthropogenic stress is challenging. Coastal areas harbour dynamic ecosystems in the for of open sandy beaches, which cover the vast majority of the world’s ice-free coastline. These ecosystems are currently threatened by increasing human-induced pressure, among which mass-development of opportunistic macroalgae (mainly composed of Chlorophyta, so called green tides), resulting from the eutrophication of coastal waters. The ecological impact of opportunistic macroalgal blooms (green tides, and blooms formed by other opportunistic taxa), has long been evaluated within sheltered and non-tidal ecosystems. Little is known, however, on how more dynamic ecosystems, such as open macrotidal sandy beaches, respond to such stress. This thesis assesses the effects of anthropogenic stress on the structure and the functioning of highly dynamic ecosystems using sandy beaches impacted by green tides as a study case. The thesis is based on four field studies, which analyse natural sandy sediment benthic community dynamics over several temporal (from month to multi-year) and spatial (from local to regional) scales. In this thesis, I report long-lasting responses of sandy beach benthic invertebrate communities to green tides, across thousands of kilometres and over seven years; and highlight more pronounced responses of zoobenthos living in exposed sandy beaches compared to semi-exposed sands. Within exposed sandy sediments, and across a vertical scale (from inshore to nearshore sandy habitats), I also demonstrate that the effects of the presence of algal mats on intertidal benthic invertebrate communities is more pronounced than that on subtidal benthic invertebrate assemblages, but also than on flatfish communities. Focussing on small-scale variations in the most affected faunal group (i.e. benthic invertebrates living at low shore), this thesis reveals a decrease in overall beta-diversity along a eutrophication-gradient manifested in the form of green tides, as well as the increasing importance of biological variables in explaining ecological variability of sandy beach macrobenthic assemblages along the same gradient. To illustrate the processes associated with the structural shifts observed where green tides occurred, I investigated the effects of high biomasses of opportunistic macroalgae (Ulva spp.) on the trophic structure and functioning of sandy beaches. This work reveals a progressive simplification of sandy beach food web structure and a modification of energy pathways over time, through direct and indirect effects of Ulva mats on several trophic levels. Through this thesis I demonstrate that highly dynamic systems respond differently (e.g. shift in δ13C, not in δ15N) and more subtly (e.g. no mass-mortality in benthos was found) to anthropogenic stress compared to what has been previously shown within more sheltered and non-tidal systems. Obtaining these results would not have been possible without the approach used through this work; I thus present a framework coupling field investigations with analytical approaches to describe shifts in highly variable ecosystems under human-induced stress.

No description available.

Isotope analyses on human and faunal skeletal remains from different Swedish Neolithic archaeological contexts are here applied as a means to reconstruct dietary strategies and mobility patterns. The chronological emphasis is on the Middle Neolithic period, and radiocarbon dating constitutes another central focus. The results reveal a food cultural diversity throughout the period in question, where dietary differences in part correspond to, but also transcend, the traditionally defined archaeological cultures in the Swedish Early to Middle Neolithic. Further, these differences, and the apparent continued utilisation of marine resources in several regions and cultural contexts, can only in part be explained by chronology or availability of resources depending on geographic location. Thus, the sometimes suggested sharp economic shift towards an agricultural way of life at the onset of the Neolithic is refuted. Taking the potential of isotope analyses a step further, aspects of Neolithic social relations and identities are discussed, partly from a food cultural perspective embarking from the obtained results. Relations between people and places, as well as to the past, are discussed. The apparent tenacity in the dietary strategies observed is understood in terms of their rootedness in the practices and social memory of the Neolithic societies in question. Food cultural practices are further argued to have given rise to different notions of identity, some of which can be related to the different archaeological cultures, although these cultures are not to be perceived as bounded entities or the sole basis of self-conceptualisation. Some of these identities have been focused around the dietary strategies of everyday life, whereas others emanate from practices, e.g. of ritualised character, whose dietary importance has been more marginal. Isotope analyses, when combined with other archaeological indices, have the potential to elucidate both these food cultural aspects. / At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 3: Submitted. Paper 4: Submitted. Paper 5: In press. Paper 6: Accepted.

Les spéléothèmes constituent une des rares archives continentales susceptibles de fournir des enregistrements à haute résolution de la variabilité climatique, datés de manière fiable. Cependant, ceux développés en contexte archéologique n'ont jamais fait l'objet d'études approfondies. L'objectif principal de ce travail est de tester leur potentiel informatif. Des spéléothèmes du stade isotopique 5, formés en entrée de cavités et intercalés dans des séquences archéologiques (Coudoulous et Bourgeois-Delaunay), ont fait l'objet d'analyses radiochronologiques, pétrographiques, chimiques et isotopiques. L'utilisation de la méthode de datation U-Th par TIMS a permis d'améliorer le calage chronologique des épisodes de concrétionnement et d'affiner la chronostratigraphie des gisements. Un continuum de structures cristallines a été identifié et mis en relation avec les conditions de précipitation de la calcite et avec le signal du δ13C. Les variations du δ13C et du δ18O enregistrées par les spéléothèmes ont été analysées à haute résolution et comparées avec les enregistrements d'autres archives climatiques. Elles ont été principalement influencées par la température. Des événements climatiques de courte durée ont été mis en évidence et un enregistrement très détaillé a été obtenu pour le SIO 5e. Cette étude démontre que les spéléothèmes d'entrées de grottes peuvent être exploités pour reconstituer les paléoenvironnements régionaux et pour préciser le cadre chronologique des occupations préhistoriques. Ils sont donc susceptibles de participer à la résolution des problèmes de corrélation de site à site et d'apporter des éléments de discussion aux thématiques traitant de l'influence de l'environnement sur les sociétés préhistoriques.