In this thesis biomimetic design is applied to the redesign of a PEM fuel cell flow field. A number of designs inspired by biological phenomena were developed to address the problem of attaining a uniform current density distribution across a PEM fuel cell. These designs are evaluated using a numerical model. One design, inspired by Murray’s law of branching in plants and animals, is further evaluated using and a physical model and comparing it to a commercial triple serpentine flow field. Improvements in pressure drop were seen for the Murray’s law inspired flow field, however, it was found to be prone to flooding. If this flow field design were to be applied to high temperature membrane materials, materials that can operate above 100 °C where water is always in the vapor state, the mass transfer and reduced pressure drop advantages of the Murray flow field could be fully achieved.

The development of improved water management strategies for the polymer electrolyte membrane fuel cell (PEMFC) could stand to benefit from an improved understanding of the surface and internal structure of the gas diffusion layer (GDL). The GDL is a fibrous porous material enabling mass transport between the PEMFC catalyst layer and flow fields. Fluorescence-based visualizations of liquid water droplet evaporation on GDL surfaces were performed to investigate water droplet pinning behaviours. The heterogeneous in-plane and through-plane porosity distributions of untreated GDLs were studied using computed tomography visualizations. The through-plane porosity distributions were utilized to calculate heterogeneous local tortuosity, relative diffusivity, and permeability distributions. Finally, the heterogeneous through-plane porosity distributions of GDLs treated for increased hydrophobicity were investigated. This work provides new insight into GDL material properties to better inform future PEMFC models.

Urban Search and Rescue (USAR) is the emergency response function that deals with the collapse of man-made structures. USAR environments contain concrete rubble, dust and debris, and provide poor lighting conditions. Due to the dangers that USAR rescue workers and their canines face, robots have become of interest in aiding rescue workers in searching. Experiences with robots in USAR missions have shown that a compact 3D sensor for 3D mapping of the environment is beneficial in providing the robot and identified victims’ locations within the structurally unstable environment. This thesis presents the developments of a novel 3D sensory system that provides both 3D and 2D texture information for mapping of cluttered unknown USAR environments. The sensor has been integrated into a robot platform, and experiments conducted to validate its usability in such applications. The experimental results show the potential for using this sensor in USAR robot mission.

Time of Flight Diffraction (TOFD) is one of the most accurate ultrasonic methods for crack detection and sizing in pipeline girth welds. Its performance, however, is limited by the temporal resolution of the signal. In this thesis, we develop a signal processing method based on autoregressive spectral extrapolation to improve the temporal resolution of ultrasonic signals. The original method cannot be used in industrial applications since its performance is highly dependent on selection of a number of free parameters. This method is modified by optimizing its various steps and limiting the number of free parameters, and an automated algorithm for selection of values for the remaining free parameters is proposed based on the analysis of a large set of synthetic signals. The performance of the final algorithm is evaluated using experimental data; it is shown that the uncertainty in crack sizing accuracy can be reduced by as much as 80%. Furthermore, the proposed method is shown to be capable of resolving overlapping echoes; therefore, smaller cracks that have echoes that are not clearly resolved in the raw signal, can be detected and sized in the enhanced signal.

Two on-line task re-allocation methodologies capable of re-allocating agents to tasks on-line for minimum task completion time in dynamic environments are presented herein. The first methodology, the Dynamic Nearest Neighbour (DNN) Policy, is proposed for the operation of a fleet of vehicles in a city-like application of the dial-a-ride problem. The second methodology, the Dynamic Re-Pairing Methodology (DRPM) is proposed for the interception of a group of mobile targets by a dynamic team of robotic pursuers, where the targets are assumed to be highly maneuverable with a priori unknown, but real-time trackable, motion trajectories. Extensive simulations and experiments have verified the DNN policy to be tangibly superior to the first-come-first-served and nearest neighbour policies in minimizing customer mean system time, and the DRPM to be tangibly efficient in the optimal dynamic re-pairing of multiple mobile pursuers to multiple mobile targets for minimum total interception time.

The impact dynamics and drying of paint films sprayed on steel were experimentally investigated. The rupture of sprayed liquid films was first photographed on different substrates. The critical film thickness, below which a film would break, was observed to increase with increasing advancing liquid-solid contact angle, and was unaffected by liquid viscosity for a given substrate. For viscous paint, it was observed that there is no rupture or splashing from a paint droplet impacting a solid substrate or another paint drop or film. For paint films drying at room temperature, mass fluxes were measured and correlated with a simple analytical model based on transient diffusion, and showed good agreement. The mass flux of sprayed paint films decreased slightly with time, and the volatile concentration decreased appreciably. For sprayed paint films cured with heat, there is a minimum stand-time in order to cure a film without any entrapped bubbles.

Dental secondary caries is the carious lesion developed around existing restoration margins. Many new technologies have been developed for caries detection purposes, but their performance is unsatisfactory for the specific purpose of secondary caries diagnosis. Therefore, the development of a novel technology to detect secondary caries has been highly necessary. The objective of this research was to investigate the ability of photothermal radiometry and modulated luminescence to detect secondary caries: wall lesions and outer lesions. Changes in experimental PTR-LUM signals due to sequential demineralization on vertical walls of sectioned tooth samples were investigated. Another study was conducted to investigate how two different types of secondary caries, wall lesions and outer lesions, affect the PTR-LUM signals. The studies demonstrated that PTR-LUM is sensitive to progressive demineralization and remineralization on vertical walls of sectioned tooth samples, as well as to the presence of wall lesions and outer lesions developed around composite restorations.

In this thesis, I present a microfluidic platform that enables automated image-based assessment of biological structure and function. My work focuses on assessing intact resistance arteries from the mouse cerebral vascular bed with a diameter of approximately 120µm in vitro. The experimental platform consists of a microfluidic device and a world-to-chip fluidic interconnect that minimizes unwanted dead volumes and eliminates the need for any liquid-filled peripheral equipment. The integrated platform is computer controlled and capable of fully automated operation once a small blood vessel segment is loaded onto the chip. Robust operation of the platform was demonstrated through a series of case studies that assessed small artery function and changes therein induced by incubation with the drug nifedipine, a dihydropyridine calcium channel blocker. In addition artery segments were stained for L-type calcium channels, F-actin and nuclei, from which structural information about cell alignment and shape was quantified.

Aircraft manufacturer Aquavion Systems is currently designing and constructing prototypes for its revolutionary new fleet of aircraft called the SeaStryder. During the prototyping phase, it was discovered that the center-of-gravity of the SeaStryder600 was too far aft and outside of the acceptable range. To solve this design issue, it was hypothesized that the weight of the horizontal stabilizer may be reduced without compromising its structural integrity. The following document analyzes this hypothesis and provides two alternative designs. Each design exceeds the design requirements, meets additional requirements requested by industry, and provides a significant degree of weight savings. The first design provides a 25% weight reduction. The second design provides an 18% weight reduction as well as a 160% increase in loading capacity. The designs proposed have both been verified through the use of Finite Element Analysis as well as by means of experimentation where two prototype wings were constructed and tested to failure confirming the analytical results.

The effects of changing nozzle hole patterns and hole geometry in a direct injection natural gas optically accessible engine was investigated. Six nozzles were studied having a 1 hole, 3 hole, and 9 hole pattern; each having either elliptical or circular hole geometries. Combustion images were taken with a high speed camera and the nozzles were compared on the basis of their ignition delay time, rate of heat release, net heat release, fuel utilization, gross indicated thermal efficiency, and particulate emissions. The best performance in all categories was achieved by the 9 hole nozzles which was largely attributed to better fuel mixing as a result of its hole distribution. The elliptical hole geometry exhibited characteristics of improved mixing mainly through reduced ignition delay time and reduced elemental carbon emissions.