Submitted by Fabio Sobreira Campos da Costa (fabio.sobreira@ufpe.br) on 2017-02-13T15:32:26Z No. of bitstreams: 2 license_rdf: 1232 bytes, checksum: 66e71c371cc565284e70f40736c94386 (MD5) TeseDoutorado_MarcelaSeixas.pdf: 6064842 bytes, checksum: 5d148170b369d14be988b9c57683862a (MD5) / Made available in DSpace on 2017-02-13T15:32:26Z (GMT). No. of bitstreams: 2 license_rdf: 1232 bytes, checksum: 66e71c371cc565284e70f40736c94386 (MD5) TeseDoutorado_MarcelaSeixas.pdf: 6064842 bytes, checksum: 5d148170b369d14be988b9c57683862a (MD5) Previous issue date: 2015-08-31 / CNPq / O interesse em estudos relacionados ao processo de fraturamento hidráulico vem aumentando, principalmente devido à exploração de reservatórios não convencionais, que se torna cada vez mais importante para a demanda de energia atual, com estimativas de grandes reservas distribuídas por vários países. A modelagem numérica de tal processo é um desafio, devido à complexidade da física envolvida. A interação entre propriedades mecânicas da rocha, tensões in situ, e heterogeneidades como fraturas naturais e planos de fraqueza é determinante na geometria da fratura induzida. Para resolver este tipo de problema acoplado, o método dos elementos finitos é amplamente utilizado e um dos mais versáteis. O presente estudo propõe uma técnica numérica denominada Fragmentação de Malha, que usa elementos finitos com elevada razão de aspecto (ou elementos especiais de interface), combinados com um modelo constitutivo baseado na mecânica do dano para reproduzir os efeitos do processo de formação de fraturas. Esta metodologia, com base na Aproximação Contínua de Descontinuidades Fortes, consiste em introduzir estes elementos de interface entre elementos regulares de uma malha de elementos finitos. Dentre as vantagens dessa técnica estão a sua facilidade de adaptação a programas convencionais de elementos finitos e o fato de não ser necessário o uso de algoritmos de construção de trajetória da descontinuidade. As aplicações apresentados neste trabalho mostram a capacidade da técnica proposta na modelagem do fraturamento hidráulico em reservatórios não convencionais. / The interest in studies related to the hydraulic fracturing process has increased over the last decade, mainly due to the exploitation of unconventional reservoirs, which is growing and becoming more important to the current energy demand, with the estimation of the existence of large reserves spread over several countries. Numerical modelling of such processes is a challenging task because of the complexity of the physics involved, and because of the structurally complicated geometry of the reservoir. The interaction between rock’s mechanical properties, insitu stresses, and heterogeneities such as natural fractures and weak bedding planes is determinant of the induced fracture geometry. To solve this kind of coupled hydromechanical problem, the Finite Elements Method is one of the most versatile and widely used. The present study propose a numerical technique called mesh fragmentation, that uses solid finite elements with high aspect ratio combining with a proper strain softening constitutive model to reproduce the effects of fractures formation process. This methodology, based on the Continuous Strong Discontinuous Approach, consists in introducing these high aspect ratio elements between regular elements of a finite element mesh. Some advantages of this technique are that it can be easily adapted to standard finite elements programs and no tracking algorithms are necessary to follow the evolution of the fracture. The case studies presented in this paper show the ability of the proposed technique to model hydraulic fracturing propagation in unconventional reservoirs.

On a large class of two-dimensional anisotropic meshes, the inf-sup condition (stability) is proved for the triangular and quadrilateral finite element pairs suggested by Bernardi/Raugel and Fortin. As a consequence the pairs ${\cal P}_2-{\cal P}_0$, ${\cal Q}_2-{\cal P}_0$, and ${\cal Q}_2^\prime-{\cal P}_0$ turn out to be stable independent of the aspect ratio of the elements.

A large aspect ratio leads to higher ion capacity in miniaturized ion trap mass spectrometers. The aspect ratio (AR) of an ion trap represents the ratio between an extended trapping dimension and the characteristic trapping dimension. In contrast to linear and rectilinear traps, changing the AR of a toroidal ion trap (TorIT) results in changes to the degree of curvature and shape of the trapping potential, and hence, on performance as a mass analyzer. SIMION simulations show that higher-order terms in the trapping potential vary strongly for small and moderate AR values (below ~10), with the effects asymptotically flattening for larger AR values. Because of the asymmetry in electrode geometry, the trapping center does not coincide with the geometric center of the trap, and this displacement also varies with AR. For instance, in the asymmetric TorIT, the saddle point in the trapping potential and the geometric trap center differ from +0.6 to -0.4 mm depending on AR. Ion secular frequencies also change with the AR. Whereas ions in the simplified TorIT have stable trajectories for any value of AR, ions in the asymmetric TorIT become unstable at large AR values. Variations in high-order terms, the trapping center, and secular frequencies with AR are a unique feature of toroidal traps, and require significant changes in trap design and operation as the aspect ratio is changed.

Android-applikationers användargränssnitt kan se annorlunda ut på olika Android-enheteroch det är svårt att anpassa en applikation efter alla enheter då det finns så många unikamodeller. Målet med arbetet var att framställa ett verktyg som kunde med hjälp av ett korrektdefinierat gränssnitt, upptäcka skillnader i gränssnittet mellan olika Android-enheter.Ett egenutvecklat verktyg framställdes och hade en hög precision. Verktyget kunde bådaupptäcka skillnader och rapportera hur stor skillnaden var mellan gränssnitten. / User interfaces can look different on different Android devices and it is difficult to tailor anapplication to all Android devices. The goal with this project was to develop a tool that canuse a correct image of a user-interface and find differences in other images taken from otherAndroid devices. A tool was developed from scratch and it proved accurate in most cases.The tool could both find differences and report how large the difference was.

Metal-organic frameworks (MOFs) are an emerging class of materials exhibiting desirable properties and functionalities for a variety of applications, including catalysis, molecular separation, gas storage, and mechanical reinforcement. However, the majority of MOFs exist as particulate powders, limiting their transportability and applicability in practical fields. Polymers, on the other hand, are one of the most widely used materials in the world owing to their facile processability and low production cost. Combining MOFs and polymers to form MOF-polymer composites can potentially maintain the merits of both materials while overcoming drawbacks of each individual component. Specifically, MOFs are promising candidates as mechanical reinforcers for polymers because of their low density, high specific modulus, and controllable dimensions. Herein, we aim to provide a comprehensive investigation into the chemistry and mechanical properties of MOF-polymer composites. Various governing parameters, including particle aspect ratio (AR), MOF-particle interface, and intrinsic mechanical properties of MOFs, were thoroughly studied to construct an optimal pathway for fabricating mechanically reinforced MOF-polymer composites. Chapter 1 presents an introduction to MOFs, polymer composites, and mechanical properties and characterizations of polymeric materials. It serves as a foundation of this dissertation and outlines essential concepts for the scientific background. The primary factors that impact the mechanical properties of polymer composite are highlighted, leading to the following three research chapters. Comprehensive background on various characterization techniques that aim at mechanical properties is covered in detail. Chapter 2 focuses on the role of MOF AR on the mechanical properties of MOF-polymer composites. PCN-222, a Zr-MOF with porphyrin linkers, was synthesized with AR ranging from 3.4 to 54. The crystallinity and chemical structure of the MOFs remained consistent for different ARs, ensuring that the AR was the only variable in determining the mechanical reinforcement. Fabricated through the doctor-blade technique, the MOF-PMMA composite films showed homogeneous MOF distribution and alignment. Tensile tests revealed that Young's modulus of the composites increased with MOF AR, exhibiting a good agreement with a modified Halpin-Tsai model. Both storage and loss moduli were also enhanced following increased MOF AR. In addition, the thermal stability was also improved with the addition of MOF particles. In Chapter 3, the authors extend the understanding of mechanical properties of MOF-polymer composites to the interfacial properties between the two materials. Pristine MOFs often lack strong interactions with a polymer matrix due to the difference in chemical/physical properties. The authors developed a three-step synthetic route to grow PMMA on the surface of PCN-222. Owing to an efficient surface-initiated polymerization technique, the PMMA was successfully grafted with high molecular weight and grafting density. The molecular weight of PMMA could be controlled by simply varying polymerization time. The PMMA-grafted PCN-222 was manufactured along with PMMA matrix to form composite films. Mechanical analysis proved that the mechanical reinforcement was improved with increasing grafted molecular weight. Chapter 4 presents an experimental approach to unveil the structure-mechanical property of MOF single crystals, which provides insights on designing MOFs with desired mechanical strength. Zeolitic imidazolate frameworks (ZIFs), a subdivision of MOFs, were chosen as the template owing to their facile synthesis, structural diversity, and high crystallinity. Two types of micron-sized ZIFs, ZIF-8 with Zn2+ node and ZIF-67 with Co2+ node, were synthesized to compare the effect of metal-linker bond. Moreover, the linker composition was varied to examine the difference in crystal structure and defect level. The mechanical properties of these ZIF samples were revealed by nanoindentation on single particles. Overall, the stronger metal-linker bond and high crystallinity were able to yield the highest elastic modulus and hardness. Finally, Chapter 5 offers a comprehensive review on polymer-grafted MOF particles regarding the synthesis and applications associated with surface-anchored polymers. Various polymerization techniques were summarized, and their adjustment and limitations with respect to MOFs were highlighted. The novel and unique applications arisen from polymer-grafted MOFs and Mixed Matrix Membranes were thoroughly discussed. / Doctor of Philosophy / Polymer composites, a combination of polymer matrix and particle fillers, have shown great applicability in nearly every aspect of our daily lives. For example, rubber tires, composed of synthetic polymeric rubber and inorganic particle fillers (e.g., carbon black and glass fiber), have been a great booster for modern society owing to their durability and mechanical strength. Aircraft are also made of roughly 50% composite materials, because of their lightweight and high mechanical strength. Herein, we present a novel type of polymer composite using metal-organic frameworks (MOFs) as mechanical reinforcers. Thanks to the low density, high modulus, and tunable geometry, MOFs can be ideal candidates for mechanically reinforced polymer composites. In this dissertation, several fundamental parameters that impact the mechanical properties of MOF-polymer composites are discussed. The intent of this work is to provide mechanistic insights on the development of outstanding lightweight composites with efficient mechanical reinforcement.

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In the thesis, a lifting body has been designed aiming to generate lift force for the pentacopter,called TILT LR (Long Range), at higher velocities during flights to improve the aerodynamicperformances. The configuration, which is used as the skeleton of the long range drone for upto 75 kilometers flights, is based upon a tilting system allowing the rotors to rotate around theirown axis in both pitch and roll angles. This offers the possibility to the TILT LR flying withoutany vertical excess thrust at a proper angle of attack and velocity. This new drone can be directlyapplied to missions require long flight time or cover long distance, such as Search & Rescue(SAR), power lines and off-shore structures inspection, fire monitoring or surveillance.Several main CAD models have been created during the process of design and presented in thereport together with the final design. For each model in the process, CFD simulations have beenapplied to observe the behaviors of the flows around the surfaces of the body during steadyflights, followed by a brief analysis for further modification. A series of simulations withvarying velocities and angle of attack have been performed for the final design, analyzing itsperformances under different air conditions. Flight envelope of the design has been presentedalso, together with some ideas of possible further studies on the pentacopter.

Precise manipulation of heterogeneous droplets on an open droplet microfluidic platform could have numerous practical advantages in a broad range of applications, from proton exchange membrane (PEM) fuel cells and microreactors, to medical diagnostic platforms capable of assaying complex biological analytes. Toward the aim of developing electrically controllable micropost arrays for use in open droplet manipulation, custom-designed titanium dioxide (TiO2)- loaded poly(dimethylsiloxane) (PDMS) micropost arrays were developed in this work and indirectly mechanically actuated by applying an electric field. Initial experiments explored the bulk properties of TiO2-loaded PDMS films, with scanning electron microscopy (SEM) confirming a uniform TiO2 particle distribution in the PDMS, and tensile testing of bulk films showing an inverse relationship between TiO2 % (w/w) and Young’s Modulus with the Young’s Moduli quantified as 4.22 ± 0.51 MPa for unloaded PDMS, 2.27 ± 0.18 MPa for 10 % (w/w) TiO2, and 1.39 ± 0.20 MPa for 20 % (w/w) TiO2. Following bulk material evaluation, soft lithography methods were developed to fabricate TiO2- loaded PDMS micropost arrays. Mathematical predictions were applied to design microposts of varying shape, length, and gap spacing to yield super-hydrophobic surfaces actuatable by an electric field. Visual inspection and optical microscopy of the resulting arrays confirmed a non- collapsed micropost geometry. Overall, round microposts that were 100, 200, and 300 μm in length, 15 μm in diameter, and spaced 50 μm apart were produced largely free of defects, and used in contact angle measurements and micropost deflection experiments. Droplet contact angles measured on the arrays remained above 120° indicating the arrays successfully provided super- hydrophobic surfaces. Individual microposts deflected most notably above an electric field strength of 520 kV/m (12.5 kV nominal voltage). The ability to mechanically deflect customized microposts using an electric field demonstrated by this work is promising for translating this technology to precise droplet manipulation applications. Indirect actuation of droplets could enable the manipulation of liquids with varying electrical properties, which is a limitation of current micropumping technologies. Once optimized, electrically actuated micropost arrays could significantly contribute to the micro- handling of heterogeneous, highly ionic, and/or deionized fluids. / Thesis (Master, Chemical Engineering) -- Queen's University, 2013-03-03 17:25:49.785

Microelectromechanical systems (MEMS) devices have been increasing in popularity for radio frequency (RF) and microwave communication systems due to the ability of MEMS devices to improve the performance of these circuits and systems. This interdisciplinary field combines the aspects of lithographic fabrication, mechanics, materials science, and RF/microwave circuit technology to produce moving structures with feature dimensions on the micron scale (micro-structures). MEMS technology has been used to improve switches, varactors, and inductors to name a few specific examples. Most MEMS devices have been fabricated using planar micro fabrication techniques that are similar to current integrated circuit (IC) fabrication techniques. These techniques limit the thickness of individual layers to a few microns, and restrict the structures to have planar and not vertical features. One micro fabrication technology that has not seen much application to microwave MEMS devices is LIGA, a German acronym for X-ray lithography, electroforming, and moulding. LIGA uses X-ray lithography to produce very tall structures (hundreds of microns) with excellent structural quality, and with lateral feature sizes smaller than a micron. These unique properties have led to an increased interest in LIGA for the development of high performance microwave devices, particularly as operating frequencies increase and physical device size decreases. Existing work using LIGA for microwave devices has concentrated on statically operating structures such as transmission lines, filters, couplers, and antennas. This research uses these unique fabrication capabilities to develop dynamically operating microwave devices with high frequency performance. This thesis documents the design, fabrication and testing of LIGA-MEMS variable capacitors that exploit the vertical dimension. Also included are methods to improve both the reliable fabrication and operation of these devices as well as material property characterization. Variable capacitors can be found in systems such as voltage-controlled oscillators, filters, impedance matching networks and phase shifters. Important figures-of-merit for these devices include the quality factor (Q), tuning range and tuning voltage. Two different types of variable capacitors are presented, a pull-away design and a design based on the principle of leveraged bending. The pull-away style variable capacitors were found to have high Q-factors, especially the devices fabricated using a thick gold device layer. As an example, the small gold half capacitance electrode design features a Q-factor of 95 at an operating frequency of 5.6 GHz and a tuning ratio of 1.36:1 with a tuning voltage range of 0 to 7.8 V. The design based on leveraged bending significantly improves the tuning ratio to a value of 1.9:1 while still maintaining a high Q-factor similar to those found in the pull-away style designs. A further increase in tuning ratio to a value of approximately 2.7:1 would be possible, based on simulated results, by simply changing the angle of the capacitance electrode in the layout. To improve device performance and fabrication reliability, modifications were made to both the fabrication process and the device layout. In the fabrication process the exposure step, electroplating step, and the etching process were modified to improve the quality of the resulting devices. In the layout, anti-stiction measures were introduced that reduce the contact area during collapse. To improve device characterization as well as the feedback link between simulation and fabrication, a set of test structures called VM-TEST was developed to accurately determine the important mechanical material properties of thick electroplated layers. These structures utilize the measurement of the pull-in voltage in cantilever and fixed-fixed beams, along with measured structure dimensions, to accurately extract the mechanical properties. Both nickel and gold test structures were analyzed with extracted Young’s modulus values of 186.2 and 60.8 GPa respectively. Also presented is a study of the gap shape in cantilever and fixed-fixed beams that significantly reduces the pull-in voltage while still maintaining a required maximum actuator displacement. It was shown that in the case of cantilever beam actuators, an approximately 40% reduction in pull-in voltage is possible, and in the case of fixed-fixed beam actuators, an approximately 30% reduction is possible by simply varying the shape of the gap between the beam and actuator electrode. These results can be used to significantly reduce the pull-in voltage of future designs. These promising results show that the LIGA fabrication process is capable of producing high performance dynamically operating RF MEMS devices, by exploiting the vertical dimension, not typically performed in most existing RF MEMS designs.

When an aircraft is aerodynamically or structurally damaged in battle, it may not able to complete the mission and the damage may cause its loss. The subject of aircraft battle survivability is one of critical concern to many disciplines, whether military or civil. This thesis considered and focused on Computational Fluid Dynamics [CFD] predictions and experimental investigations into the effects of simulated battle damage on the low-speed aerodynamics of a fmite aspect ratio wing. Results showed that in two-dimensional [2d] and three-dimensional [3D] CFD simulations, Fluent's® models work reasonably well in predicting jets flow structures, pressure distributions, and pressure-coefficient Cp's contours but not for aerodynamic coefficients. The consequences were therefore that CFD prediction was poor on aerodynamic-coefficients increments. The prediction of Cp's achieved good agreement upstream and near the damage hole, but showed poor agreement at downstream of the hole. For the flow structure visualisation, at both weak and strong jet incidences, the solver always predicted pressure-distribution-coefficient lower at upstream and higher at downstream. The results showed relatively good agreement for the case of transitional and strong jet incidences but slightly poor for weak jet incidences. From the experimental results of Finite Wing, the increments for Aspect-ratio, AR6, AR8 and ARIO showed that as damage moves out towards the tip, aerodynamic-coefficients increments i.e. lift-loss and drag-rise decreased, and pitching-moment-coefficient increment indicated a more positive value at all incidence ranges and at all aspect ratios. Increasing the incidence resulted in greater magnitudes of lift-loss and drag-rise for all damage locations and aspect ratios. At the weak jet incidence 4° for AR8 and in all of the three damage locations, the main characteristics of the weak-jet were illustrated clearly. The increments were relatively small. Whilst at 8°, the flow structure was characterised as transitional to stronger-jet. In Finite Wing tests and for all damage locations, there was always a flow structure asymmetry. This was believed to be due to gravity, surface imperfection, and or genuine feature. An 'early strong jet' that indicated in Finite Wing-AR8 at 'transitional' incidence of 8°, also indicated in twodimensional results but at the weak-jet incidence of 4°. For the application of 2d data to AR6, AR8, and ARIO, an assessment of 2d force results led to the analysis that the tests in the AAE's Low Turbulence Tunnel for 2d were under-predicting the damage effects at low incidence, and over-predicting at high incidences. This suggested therefore that Irwin's 2d results could not be used immediately to predict three-dimensional.