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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
21

Study on Ammonia Utilization and Alternative Anode Materials for Solid Oxide Fuel Cells / 固体酸化物形燃料電池におけるアンモニアの利用とアノード代替材料に関する研究

Ahmed, Fathi Salem Molouk 23 March 2016 (has links)
京都大学 / 0048 / 新制・課程博士 / 博士(工学) / 甲第19729号 / 工博第4184号 / 新制||工||1645(附属図書館) / 32765 / 京都大学大学院工学研究科物質エネルギー化学専攻 / (主査)教授 江口 浩一, 教授 安部 武志, 教授 陰山 洋 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DFAM
22

Dry Reforming of Methane by Ni-In-Ce Supported Catalysts

Alharbi, Abdulrahman 08 1900 (has links)
In light of global warming’s environmental implications, research is shifted towards potential processes that can utilize CO2 and reduce its emissions in the industrial sector. One of the promising processes is dry reforming of methane (DRM), which is capable of utilizing CO2 and producing valuable syngas (H2 and CO). The main challenge of DRM is the deactivation of catalysts under the reaction temperatures (above 700 °C) due to sintering of the active metal and coke formation. Ni-based catalysts are the most widely investigated catalysts in literature for DRM due to their cost efficiency and availability. This study is an extension of the work done by Saudi Basic Industries Corporation (SABIC) devoted to investigating Ni-Ce-In system for DRM reaction. Five catalysts were synthesized by dry impregnation method according to SABIC synthesis procedure (Ni/Al2O3, Ni-In/Al2O3, Ni/CeO2/Al2O3, Ni/In-CeO2/Al2O3, and Ni-In/CeO2/Al2O3). The metallic loading targets were 7.5 wt.%, 10 wt.%, and 0.8 wt.% for nickel, cerium, and indium, respectively. The addition of indium in combination with cerium resulted in the highest catalytic activity. Additionally, the co-impregnation of indium and cerium resulted in enhancing the catalytic activity more than subsequential impregnation (Ni/In-CeO2/Al2O3 compared to Ni-In/CeO2/Al2O3). The addition of cerium or indium separately with nickel did not seem to affect activity since Ni/Al2O3, Ni-In/Al2O3, and Ni/CeO2/Al2O3 exhibited similar conversion values. All catalysts were stable for more than two days under DRM conditions without deactivating. Therefore, deactivation behaviors of the catalysts were not covered in this study.
23

The design and manufacturing of scandia-ceria stabilized zirconia ceramics for use as electrolyte material in solid oxide fuel cells

Bean, Glenn E. 01 January 2009 (has links)
In order to increase the efficiency and economic viability of solid oxide fuel cells (SOFCs), new materials for the cathode, anode, and electrolyte of the cells must be found. SOFCs have a ceramic electrolyte, which is commonly made of fully stabilized zirconia. Due to increased material degradation rates at elevated temperatures ( ~ 1000°C) of current SOFCs, materials for the manufacture of intermediate temperature SOFCs, which operate in the range of 700-800°C, are currently under study. In this study, the manufacturing process for scandia-ceria stabilized zirconia powder (1 0mol¾ Sc2O3, lmol¾ CeO2, 89mol% ZrO2), from Daiichi Kigenso Kagaku Kogyo (DKKK) is developed, including tape casting and sintering procedures to result in pellets of high enough quality to produce single button cells. It is found that a slip prepared with about 44 wt% zirconia powder and increased proportions of solvents, dispersant, binder and plasticizers produces a favorable viscosity of about 7 40cP after deairing, and will produce tapes that are reasonably smooth and of stable thickness. Since the single cell will be structurally based upon this electrolyte material, the physical properties of the pellets are important, in addition to the electrochemical properties of the constituent materials. Tapes cast at 500µm, at 50% feed rate with a 50°C drying temperature, laminated and sintered at 1500°C on setter plates will produce flat, smooth, stiff pellets for the production of single buttons for use as the electrolyte. Cathode (50-50 mixture of La0.6Sr0_4Fe0_8Co0.2O3 + 20mol% Gd2O3 80mol% CeO2) and Anode (35 wt% DKKK powder, 65 wt% NiO) materials were hand-painted on to either side of the electrolyte and sintered to create a complete SOFC cell consisting of cathode, electrolyte, and anode.
24

Synthesis Of Biocompatible Antioixidant Polymer Coated Cerium Oxide Nanoparticles, Its Oxidase Like Behavior And Cellular Uptake

Asati, Atul 01 January 2009 (has links)
Cerium oxide nanoparticles have been widely used for various applications such as catalytic converters for automobile exhaust, ultraviolet absorber, and electrolyte in fuel cells. Most recently, cerium oxide nanoparticles (nanoceria) have been employed as potent free-radical scavengers with neuroprotective, radioprotective, and anti-inflammatory properties. These properties of cerium oxide nanoparticles can open new vistas in medicine and biotechnology. The present study utilizes the water-based-wet-chemical method to synthesize biocompatible,stable and highly monodisperse polymer coated cerium oxide nanoparticles. Polymer coated cerium oxide nanoparticles possess all the characteristics of the uncoated cerium oxide nanoparticles. These nanoparticles were found to be effective as pH-dependent antioxidant giving cytoprotection to normal cell lines against hydrogen peroxide and nitric oxide radical but not to cancer cells. Moreover, cerium oxide nanoparticle also exhibits unique oxidase-like activity at acidic pH oxidizing a series of organic compound without the need of hydrogen peroxide. Based on these results, we have designed an immunoassay in which folate-conjugated cerium oxide nanoparticles provide dual functionality by binding to folate expressing cancer cells and facilitating detection by catalytic oxidation of sensitive colorimetric substrates (dyes). Finally, we have shown that the polymer coated cerium oxide nanoparticles shows distinct toxicity depending upon their subcellular localization based on uptake studies using DiI loaded cerium oxide nanoparticles. In these results, we have found that cerium oxide nanoparticles entrapped into lysosomes are more toxic as opposed to when they are localized in the cytoplasm.Overall we propose that the polymer coated cerium oxide nanoparticles displays selective antioxidant property, oxidase-like activity, and cytotoxicity to biological systems depending upon its pH environment.
25

Synthesis of Ethanol from High Pressure Syngas over Rhodium-Based Catalysts

Sheerin, Ephraim A. 27 October 2014 (has links)
No description available.
26

Sol-Gel Synthesis and Characterization of Mesoporous Ceria Membranes

Rane, Neelesh Janardan 17 April 2003 (has links)
No description available.
27

Synthesis and characterisation of ordered mesoporous materials

Dougherty, Troy Allen January 2010 (has links)
Ordered mesoporous materials have attracted much attention recently for use in a wide range of applications. The oxidising materials, ceria (CeO₂) and CGO (Ce₀.₉Gd₀.₁O[subscript(2-δ)]) have both been synthesised with ordered mesopores, but a method for the simple fabrication of these materials in high yields with crystalline pore walls has not yet been reported in the literature. This thesis details the development of the vacuum impregnation method for the synthesis of ordered mesoporous materials with emphasis on ceria and CGO. Using the vacuum impregnation method both materials were successfully prepared. The materials exhibited the porous single crystal morphology in high yields, with unusual crystallographic features. Nitrogen physisorption, transmission electron microscopy (TEM), TEM tomography and temperature programmed studies were employed. Temperature programmed studies showed the materials to be catalytically active at lower temperatures than traditionally-prepared ceria. Photovoltaic studies showed that the materials exhibited efficient exciton quenching. The observation of nanowire extrusion during the synthetic procedure assisted in the postulation of a mechanism for product formation in the vacuum impregnation method. The vacuum impregnation method was subsequently shown to be applicable to the synthesis of other materials, with encouraging results presented for ordered mesoporous carbon and Zr₀.₈₄Y₀.₁₆O[subscript(2-δ)]. The syntheses of ordered mesoporous La₀.₈₅Sr₀.₁₅GaO[subscript(3-δ)] and La₀.₇₆Sr₀.₁₉CoO[subscript(3-δ)] were unsuccessful.
28

Estudos ab initio das propriedades estruturais, energéticas e eletrônicas de clusters de óxidos mistos de Ce15-nZrnO30,(n=0-15) / Ab initio study of the structural, energetic and electronic properties of mixed oxides clusters Ce15-nZrnO30, (n = 0-15)

Sousa, Priscilla Felício 10 October 2017 (has links)
Partículas nanométricas de óxidos têm despertado um grande interesse devido a ampla gama de aplicações, por exemplo em catálise, óptica, sensores de gases, semicondutores, entre outros. Por isso, há vários estudos para uma grande variedade de óxidos com composição MO2, em função do tamanho e terminação da superfície. Também existe um grande interesse no estudo de óxidos mistos devido a possibilidade de combinar dois ou mais óxidos em escala nanométrica, com objetivo de controlar as propriedades físicas e químicas em função da composição. Neste trabalho, utilizou-se os metais Ce e Zr, uma vez que os óxidos desses elementos têm um grande potencial de aplicação na indústria como em células combustíveis, reações catalíticas entre outros. Os óxidos mistos Cem-nZrnO2mpossuem a capacidade de armazenar ou liberar oxigênio ao longo de reações químicas, e portanto, são largamente empregados em catalisadores de três-vias na indústria automobilística. Neste estudo foi empregada a teoria do funcional da densidade (DFT) com o funcional de troca-correlação proposto por Perdew, Burke e Ernzerhof (PBE). Investigou-se as propriedades estruturais, energéticas e eletrônicas dos clusters puros e então, selecionou-se quatro estruturas, as quais foram aplicadas na construção dos clusters de óxidos mistos de céria-zircônia. Por meio dos estudos de eletronegatividade de Mulliken, verificou-se que os clusters de zircônia apresentam uma tendência maior em atrair elétrons, quando comparados aos clusters de céria. Observou-se também que as estruturas de mais baixa energia de céria e zircônia apresentam diferentes números de coordenação (CN), no caso 4 e 3 NNN (vizinhos mais próximos), respectivamente. Isso se deve ao fato de tais estruturas não serem esféricas e também aos diferentes tamanhos atômicos de Ce e Zr. Além disso, notou-se que há uma maior compactação dos clusters de menor energia se comparados aos de maior energia, tanto para o céria quanto para zircônia, obteve-se os seguintes valores de diâmetro 1 nm e 2 nm para essa variação da energia relativa. Com esses resultados tem-se que há uma propensão dos clusters mistos, manterem propriedades semelhantes dos cluster puros, devido a similaridade entre o comportamento das estruturas de céria e da zircônia, os quais foram os agentes geradores dos clusters mistos. Observou-se que as propriedades estruturais dos cluster puros como CN, dav, σ e raio, mantiveram-se com a mesmas tendências nos clusters mistos. Para a obtenção do cluster mais estável analisou-se a energia de formação dos sistemas, sendo que a configuração mais favorável de ser formada é a Ce0,27Zr0,73O2, a qual considerou-se a estrutura pGMC representativa das configurações estudadas. Levando-se em consideração os resultados obtidos, na análise de formação dos clusters mistos delimitou-se a região de maior probabilidade de formação de clusters mistos estáveis entre 25% a 60%, de cério na composição. / Oxide nanomaterials have aroused great interest due to their application in several fields, such as in catalysis, optics, gas sensors, semiconductors, among others. Therefore, there are several studies for a wide variety of oxides with composition, and MO2, depending on the size and surface termination. There is also great interest in the study of mixed oxides due to the possibility of combining two or more oxides on a nanometric scale, in order to control their physical and chemical properties. In this work the metals Ce and Zr were used, since the oxides of these elements have a promising application in the industry as in fuel cells, catalytic reactions among others. The mixed oxides Cem-nZrnO2m present the ability to store or release oxygen during chemical reactions and therefore are widely used in three-way catalysts in the automotive industry. In this study, we used density functional theory (DFT) with PBE for the exchange-correlation functional. To investigate the structural, electronic and energetic properties of clusters, four selected structures were applied to build up the mixed ceria-zirconia oxides. Through the Mulliken electronegativity studies, it was found that zirconia clusters have a greater tendency to attract electrons, than the ceria clusters. Also observed that the lowest energy structures of ceria and zirconia have different coordination numbers, 4 and 3 NNN (Number of Nearest Neighbours), respectively. This is due to the fact that such structures are not spherical and have different atomic sizes. In addition, it was noted that there is a higher compaction of the clusters of lower energy compared to higher energy, for both ceria and zirconia, it was obtained the following values of diameter 1 nm and 2 nm for this variation of relative energy change. These results show that there is a trend in which mixed clusters have similar properties of the pure cluster, due to the similarity between the behavior of the structures of ceria and zirconia, which were the generating agents of the mixed clusters. It was observed that the structural properties of the pure clusters like CN, dav, σ and cluster radii, remained with the same trends in the mixed clusters. To obtain the most stable clusters we analyzed the formation energy of the systems, the most favorable configuration to be obtained is Ce0,27Zr0,73O2, which was considered the representative pGMC structure of the studied configurations. Taking into consideration the results, obtained in the analysis of the formation of the mixed clusters, delimited the higher probability of formation of mixed stable clusters between 25% to 60%, of cerium in composition.
29

Estudos ab initio das propriedades estruturais, energéticas e eletrônicas de clusters de óxidos mistos de Ce15-nZrnO30,(n=0-15) / Ab initio study of the structural, energetic and electronic properties of mixed oxides clusters Ce15-nZrnO30, (n = 0-15)

Priscilla Felício Sousa 10 October 2017 (has links)
Partículas nanométricas de óxidos têm despertado um grande interesse devido a ampla gama de aplicações, por exemplo em catálise, óptica, sensores de gases, semicondutores, entre outros. Por isso, há vários estudos para uma grande variedade de óxidos com composição MO2, em função do tamanho e terminação da superfície. Também existe um grande interesse no estudo de óxidos mistos devido a possibilidade de combinar dois ou mais óxidos em escala nanométrica, com objetivo de controlar as propriedades físicas e químicas em função da composição. Neste trabalho, utilizou-se os metais Ce e Zr, uma vez que os óxidos desses elementos têm um grande potencial de aplicação na indústria como em células combustíveis, reações catalíticas entre outros. Os óxidos mistos Cem-nZrnO2mpossuem a capacidade de armazenar ou liberar oxigênio ao longo de reações químicas, e portanto, são largamente empregados em catalisadores de três-vias na indústria automobilística. Neste estudo foi empregada a teoria do funcional da densidade (DFT) com o funcional de troca-correlação proposto por Perdew, Burke e Ernzerhof (PBE). Investigou-se as propriedades estruturais, energéticas e eletrônicas dos clusters puros e então, selecionou-se quatro estruturas, as quais foram aplicadas na construção dos clusters de óxidos mistos de céria-zircônia. Por meio dos estudos de eletronegatividade de Mulliken, verificou-se que os clusters de zircônia apresentam uma tendência maior em atrair elétrons, quando comparados aos clusters de céria. Observou-se também que as estruturas de mais baixa energia de céria e zircônia apresentam diferentes números de coordenação (CN), no caso 4 e 3 NNN (vizinhos mais próximos), respectivamente. Isso se deve ao fato de tais estruturas não serem esféricas e também aos diferentes tamanhos atômicos de Ce e Zr. Além disso, notou-se que há uma maior compactação dos clusters de menor energia se comparados aos de maior energia, tanto para o céria quanto para zircônia, obteve-se os seguintes valores de diâmetro 1 nm e 2 nm para essa variação da energia relativa. Com esses resultados tem-se que há uma propensão dos clusters mistos, manterem propriedades semelhantes dos cluster puros, devido a similaridade entre o comportamento das estruturas de céria e da zircônia, os quais foram os agentes geradores dos clusters mistos. Observou-se que as propriedades estruturais dos cluster puros como CN, dav, σ e raio, mantiveram-se com a mesmas tendências nos clusters mistos. Para a obtenção do cluster mais estável analisou-se a energia de formação dos sistemas, sendo que a configuração mais favorável de ser formada é a Ce0,27Zr0,73O2, a qual considerou-se a estrutura pGMC representativa das configurações estudadas. Levando-se em consideração os resultados obtidos, na análise de formação dos clusters mistos delimitou-se a região de maior probabilidade de formação de clusters mistos estáveis entre 25% a 60%, de cério na composição. / Oxide nanomaterials have aroused great interest due to their application in several fields, such as in catalysis, optics, gas sensors, semiconductors, among others. Therefore, there are several studies for a wide variety of oxides with composition, and MO2, depending on the size and surface termination. There is also great interest in the study of mixed oxides due to the possibility of combining two or more oxides on a nanometric scale, in order to control their physical and chemical properties. In this work the metals Ce and Zr were used, since the oxides of these elements have a promising application in the industry as in fuel cells, catalytic reactions among others. The mixed oxides Cem-nZrnO2m present the ability to store or release oxygen during chemical reactions and therefore are widely used in three-way catalysts in the automotive industry. In this study, we used density functional theory (DFT) with PBE for the exchange-correlation functional. To investigate the structural, electronic and energetic properties of clusters, four selected structures were applied to build up the mixed ceria-zirconia oxides. Through the Mulliken electronegativity studies, it was found that zirconia clusters have a greater tendency to attract electrons, than the ceria clusters. Also observed that the lowest energy structures of ceria and zirconia have different coordination numbers, 4 and 3 NNN (Number of Nearest Neighbours), respectively. This is due to the fact that such structures are not spherical and have different atomic sizes. In addition, it was noted that there is a higher compaction of the clusters of lower energy compared to higher energy, for both ceria and zirconia, it was obtained the following values of diameter 1 nm and 2 nm for this variation of relative energy change. These results show that there is a trend in which mixed clusters have similar properties of the pure cluster, due to the similarity between the behavior of the structures of ceria and zirconia, which were the generating agents of the mixed clusters. It was observed that the structural properties of the pure clusters like CN, dav, σ and cluster radii, remained with the same trends in the mixed clusters. To obtain the most stable clusters we analyzed the formation energy of the systems, the most favorable configuration to be obtained is Ce0,27Zr0,73O2, which was considered the representative pGMC structure of the studied configurations. Taking into consideration the results, obtained in the analysis of the formation of the mixed clusters, delimited the higher probability of formation of mixed stable clusters between 25% to 60%, of cerium in composition.
30

Synthesis and characterisation of CeO?, Sm?O? and Sm-doped CeO? nanoparticles with unique morphologies

Bugayeva, Natalia January 2006 (has links)
[Truncated abstract] This work was concerned with investigations into the synthesis of Ce(OH)4, Sm(OH)3 and hydrated Ce-Sm mixed oxide nanoparticles with anisotropic morphologies via a chemical precipitation technique. The effect of various experimental parameters including temperature, aging time, ionic environment and thermal treatment on the morphology, structure of nanoparticles as well as elemental homogeneity of the mixed oxide nanoparticles was emphasised. It was shown that different experimental conditions resulted in different particle morphologies. This suggested that by tuning experimental parameters an ultimate goal of nanotechnology, the formation of nanoparticles with desired morphologies and sizes, may be achieved. It was found that by modifying experimental parameters it was possible to influence the development of various morphological and structural characteristics of Ce(OH)4 nanoparticles. The resulting morphologies were fibrous needle-like, rod-like and nanowire particles of various sizes. Characterisation of the nanoparticles was conducted through analysis by X-ray diffraction, surface area analysis and transmission electron microscopy techniques. Investigations into the structure of the hydrated CeO2 nanoparticles were undertaken since it is considered to be a key to the relevant properties of the material. The structure was found to exhibit multiple twinning phenomenon with 5-fold symmetry, with a consequence that atomic planes formed the particle surface. However, upon thermal treatment of needle-like particles, structural transformation was observed that possibly led to the development of more reactive and particle circumferential facets. A structural model and formation mechanism of such structures was proposed. ... A preliminary study into suitability of particle anisotropic morphology for compaction and densification processes was undertaken. Investigations into the sintering behaviour of the particles with anisotropic morphology were conducted on ceria nanoneedles. It was found that these particles displayed favourable sintering characteristics. The final densities of the hydrated ceria needle-like particle samples were achieved as high as 94.1% of the theoretical density after sintering at 1100°C for 5 hours.

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