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The primary aim of this dissertation was to develop and validate a methodology for identifying spatial clusters (hotspots) of various paediatric cancers within South Africa by using GIS software. The Hotspot Analysis (Getis-Ord Gi*) Tool was used for this purpose. A series of spatial clusters (hotspots) were identified by the tool for each cancer type and these clusters were compared with the exiting literature regarding known environmental and other carcinogens. The quality of the cancer data used in the dissertation was however found to be questionable and significantly underreported. This caused the results of the tool to also be questionable. The dissertation therefore concluded that the tool could be successfully used to identify spatial clusters of cancer in principle. It was however found that the results of the tool needed to be viewed without caution in this dissertation due to the low quality of the cancer data used. / MSc (Geography and Environmental Management), North-West University, Potchefstroom Campus, 2014

The use of parallel computing is increasing with the need to solve ever more complex problems. Unfortunately, while the cost of parallel systems (including clusters and small-scale shared memory machines) has decreased, such machines are still not within the reach of many users. This is particularly true if large numbers of processors are needed. A largely untapped resource for doing some, simpler, types of parallel computing are temporarily idle machines in distributed environments. Such environments range from the simple (identical machines connected via a LAN) to the complex (heterogeneous machines connected via the Internet). In this thesis I describe a system for dynamically clustering together similar machines distributed across the Internet. This is done in a peer-to-peer (P2P) fashion with the goal of ultimately forming useful compute clusters without the need for a heavily centralized software system overseeing the process. In this sense my work builds on so-called "volunteer computing" efforts, such as SETI@Home but with the goal of supporting a #11;different class of compute problems. I #12;first consider the characteristics that are necessary to form good clusters of shared machines that can be used together effectively. Second, I exploit simple clustering algorithms to group together appropriate machines using the identified#12;ed characteristics. My system assembles workstations into clusters which are, in some sense, "close" in terms of bandwidth, latency and/or number of network hops and that are also computationally similar in terms of processor speed, memory capacity and available hard disk space. Finally, I assess the conditions under which my proposed system might be effective via simulation using generated network topologies that are intended to reflect real-world characteristics. The results of these simulations suggest that my system is tunable to different conditions and that the algorithms presented can #11;effectively group together appropriate machines to form clusters and can also manage those clusters #11;effectively as the constituent machines join and leave the system.

Clusters of atoms have remarkable optical properties that were exploited since the antiquity. It was only during the late 20th century though that their production was better controlled and opened the door to a better understanding of matter. Lasers are the tool of choice to study these nanoscopic objects so scientists have been blowing clusters with high intensities and short duration laser pulses to gain insights on the dynamics at the nanoscale. Clusters of atoms are an excellent first step in the study of bio-molecules imaging. New advancements in laser technology in the shape of Free Electron Lasers (FEL) made shorter and shorter wavelengths accessible from the infrared (IR) to the vacuum and extreme ultra-violet (VUV and XUV) to even X-rays. Experiments in these short wavelengths regimes revealed surprisingly high energy absorption that are yet to be fully explained. This thesis tries to increase the global knowledge of clusters of rare-gas atoms interacting with short duration and high intensity lasers in the VUV and XUV regime. Theoretical and numerical tools were developed and a novel model of energy transfer based on excited states will be presented. The first part describes the current knowledge of laser-cluster interaction in the short wavelength regime followed by the description of the new model. In the second part of the thesis the different tools and implementations used throughout this work are presented. Third, a series of journal articles (of which four are published and one to be submitted) are included where our models and tools were successfully used to explain experimental results.

Detailed chemical abundances of globular clusters in the Milky Way and M31 (the Andromeda Galaxy) are presented based on analyses of high resolution spectra. The unusual Milky Way cluster Palomar 1 (Pal 1) is studied through spectra of individual red giant branch stars; these abundances show that Pal 1 is not a classical globular cluster, and may have been accreted from a dwarf satellite of the Milky Way. The Milky Way globular clusters 47 Tuc, M3, M13, NGC 7006, and M15 are studied through their integrated light (i.e. a single spectrum is obtained for each cluster) in order to test high resolution integrated light analyses. The integrated abundances from these clusters reproduce the average abundances from individual stellar analyses for elements that do not vary within a cluster (e.g. Fe, Ca, and Ni). For elements that do vary within the clusters (e.g. Na and Mg) the integrated abundances fall within the observed ranges from individual stars. Certain abundance ratios are found to be extremely sensitive to uncertainties in the underlying stellar populations, such as input models, empirical relations to determine atmospheric parameters, interloping field stars, etc., while others (such as [Ca I/Fe I]) are largely insensitive to these effects. With these constraints on the accuracy and precision of high resolution integrated light analyses, detailed abundances are obtained for seven clusters in the outer halo of M31 that were recently discovered in the Pan-Andromeda Archaeological Survey (PAndAS) and are likely to have originated in dwarf galaxy satellites. Three clusters are relatively metal rich ([Fe/H] > −1.5) for their locations in the outer halo; their chemical abundances suggest that they likely originated in one or more fairly massive dwarf satellities. The other four are more metal-poor, and may have originated in less massive dwarf satellites. These results indicate that the Milky Way and M31 have both experienced some amount of accretion from dwarf satellites, though M31 may have had a more active accretion history. / Graduate

In this thesis, several theoretical concepts relating to the large-scale structure of the universe are presented. In particular, various aspects of the hierarchical scenario are investigated. The initial perturbation field and its early evolution are discussed in Chapter 3. Chapter 4 is concerned with two-point correlation functions for galaxies, clusters and super-clusters. In Chapter 5, some effects of using velocity as a distance measure are examined. In particular, it will be argued that caustics in redshift space are an almost inevitable feature of the hierarchical scenario. Chapter 6 concentrates on the possibity that quasar Ly-α absorption lines are redshift caustics.

An introduction is given to the fields of X-ray and cataclysmic binaries, low mass X-ray binaries (LMXBs) and globular clusters. New observations of the W Vir star AC5 (=V86) are used show that it is probably the source of Hα emission previous authors have found in core of the globular cluster M15. The first phase resolved optical spectroscopy of AC211, the optical counterpart of the X-ray source in M15, are presented, and its binary period discovered to be 9.l±0.5 hours. A re-analysis of archive ultraviolet (UV) spectra of M15, shows spectral features which are attributed to AC211. These observations are combined with those of other authors, to prove AC211 is probably an "accretion disc corona" (ADC) source. After reviewing the superoutbursts of the SU UMa class of dwarf novae, X-ray, UV, optical and infrared observations of the SU UMa star OY Car are used to show that during superoutburst there is extensive vertical structure in its accretion disc, similar to that in the ADC and "dipping" LMXBs. Archive UV data from the 1978 outburst of WZ Sge shows that it had similar vertical structure. UV observations presented of EX Hya during a bright outburst may have the same explanation. From the OY Car data, a temperature and area for the region which produces the "superhump" light are derived, of 8 OOOK and ^-10²⁰cm², respectively. It is found that during OY Car's superoutburst, the size of the 0-C variations of the eclipse timings are significantly smaller than was previously thought, and that it has an extended X-ray source whose size is comparable to the binary separation. The results are discussed with respect to models of the superhump phenomena in SU UMa stars, and possible causes of vertical disc structure in X-ray and cataclysmic binaries.

The vibrational energy levels of various rare gas trimers, Ar(_3), Ne(_3), He(_3), Ar(_2)Ne and Ne(_2)Ar, have been calculated using a coupled channel approach. We have compared results obtained with previous calculations. The existence of Efi-mov states in He(_3) has been investigated, and no evidence of their existence has been found. The affect of the Eckart conditions on embedding axis into a rotating-vibrating system has been investigated for several rare gas systems. A wide range of rare gas trimers have been studied, Ar(_3), He(_2)Ar, Ar(_2)He, Ar(_2)Ne and Ne(_2)Ar. For each trimer the full range of molecular motion is investigated. The low energy minima for the Ar(_n)N(_2) and Ne(_n)N(_2) systems have been found using simulated annealing search, and a gradient based minimisation technique, of a pairwise potential energy surface. Clusters with n ≥ 12 have been studied, and first solvation shells for both systems have been proposed. For each value of n, for n = 1 - 12, the first few low energy minima of the potential energy surface have been found. From these studies, we have gained a detailed understanding of the interplay of forces that determine the low energy structures for these systems. The affect of three-body interactions on the low energy minima both rare gas-N(_2) systems has been studied. In both system, rare gas-rare gas and rare gas- threebody interactions have been taken into account. This study has shown that the three-body forces have a small affect on the low energy structures of each system.

The understanding of nucleation and growth of metals on a planar support at the atomic level is critical for both surface science research and heterogeneous catalysis studies. In this dissertation, two planar substrates, including graphene and ultra-thin silica film were employed for supported model catalysts studies. The structure and stability of several catalytically important metals supported on these two substrates were thoroughly investigated using scanning tunneling microscopy (STM) coupled with other traditional surface science techniques. In the study of the graphene/Ru(0001) system, the key factors that govern the growth and distribution of metals on the graphene have been studied based on different behaviors of five transition metals, namely Pt, Rh, Pd, Co, and Au supported on the template of a graphene moire pattern formed on Ru(0001). Both metal-carbon (M-C) bond strength and metal cohesive energies play significant roles in the cluster formation process and the M-C bond strength is the most important factor that affects the morphology of clusters at the initial stages of growth. Interestingly, Au exhibits two-dimensional (2-D) structures that span several moire unit cells. Preliminary data obtained by dosing molecular oxygen onto CO pre-covered Au islands suggest that the 2-D Au islands catalyze the oxidation of CO. Moreover, graphene/Ru(0001) system was modified by introducing transition metals, oxygen or carbon at the interface between the graphene and Ru(0001). Our STM results reveal that the geometric and/or electronic structure of graphene can be adjusted correspondingly. In the study of the silica thin film system, the structure of silica was carefully investigated and our STM images favor for the [SiO4] cluster model rather than the network structure. The nucleation and adsorption of three metals, namely Rh, Pt and Pd show that the bond strength between the metal atom and Si is the key factor that determines the nucleation sites at the initial stages of metal deposition. The annealing effect studies reveal that Rh and Pt atoms diffuse beneath the silica film and form the 2-D islands that are covered with a silica thin film. In contrast, the formation of Pd silicide was observed upon annealing to high temperatures.

Typescript. / Thesis (Ph. D.)--University of Hawaii at Manoa, 1990. / Includes bibliographical references. / Microfiche. / xii, 178 leaves, bound ill. 29 cm