61 |
The dynamics of oxygen vacancies in zirconia : an analysis Of PAC dataAlves, Mauro A. 13 March 2003 (has links)
Nuclear techniques such as perturbed angular correlation (PAC) sample the
hyperfine interactions of a large number of probe atoms in specific crystallographic
sites. Real crystals contain static defects producing a distribution
of electric field gradients (EFGs) that add to the ideal EFG of the crystal at
any given probe site. Also, dynamic defects like moving vacancies and interstitial
atoms can be present in the crystal and contribute to the distribution
of EFGs. The distribution of EFGs leads to line broadening and a change in
the observed asymmetry parameter η since the total EFG no longer has the
symmetry of the perfect crystal. When both defects are present in a material,
obtaining quantitative information from the analysis of PAC spectra is usually very difficult since great care has to be taken to ensure that the source
of line broadening is identified correctly. In order to relate the relationship
between the static line broadening and changes in the asymmetry parameter
η, a uniform random distribution of point charges was used to simulate the
static defect EFG. PAC spectra collected on cubic niobium metal, cubic stabilized
zirconia and Nb-doped tetragonal zirconia were fitted with this model.
Although the quality of the fits is good, more work is needed to clarify the
relationship between the new model parameters and the line broadening and
asymmetry parameter derived from conventional model fits. The PAC spectra
of Nb-doped tetragonal zirconia were fitted with a conventional static model
to establish a reliable relationship between line broadening and the asymmetry
parameter when only static defects are present in a sample. To account for effects
of dynamic defects, a four state stochastic model for vacancy motion was
adapted in order to include the line broadening and changes in the asymmetry
produced by static defects. As a result, the activation energies corresponding
to the rates at which a oxygen vacancy is trapped by, detraps from, and hops
among equivalent sites about a PAC probe atom were calculated. The values
that were found are physically reasonable, indicating that the dynamics of an
oxygen vacancy around a PAC probe atom are satisfactorily described. / Graduation date: 2003
|
62 |
Asymmetric Correlations in Financial MarketsOzsoy, Sati Mehmet January 2013 (has links)
<p>This dissertation consists of three essays on asymmetric correlations in financial markets. In the first essay, I have two main contributions. First, I show that dividend growth rates have symmetric correlations. Second, I show that asymmetric correlations are different than correlations being counter-cyclical. The correlation asymmetry I study in this dissertation should not be confused with correlations being counter-cyclical, i.e. being higher during recessions than during booms. I show that while counter-cyclical correlations can simply be explained by counter-cyclical aggregate market volatility, the correlation asymmetry with respect to joint upside and downside movements of returns are not just due to the heightened market volatility during those times. </p><p>In the second essay I present a model in order to explain the correlation asymmetry observed in the data. This is the first paper to offer an explanation for observed correlation asymmetry. I formalize the explanation using an equilibrium model. The model is useful to understand both the cross-section and time-series of correlation asymmetry. By the means of my model, we can answer questions about why some stocks have higher correlation asymmetry, and why the correlation asymmetry was higher during 1990s? In the model asset prices respond the realization of dividends and news about the future. However, price responses to news are asymmetric and this asymmetry is endogenous. Price responses are endogenously stronger conditional on bad news than conditional on good news. This asymmetry also generates the observed correlation asymmetry. The price responses are asymmetric due to the ambiguity about the news quality. Information about the quality of the signal is incomplete in the sense that the exact precision of the signal is unknown; it is only known to be in an interval, which makes the representative agent treat news as ambiguous. To model ambiguity aversion, I use Gilboa and Schmeidler (1989)'s max-min expected utility representation. The agent has a set of beliefs about the quality of signals, and the ambiguity-averse agent behaves as if she maximizes expected utility under a worst-case scenario. This incomplete information about the news quality, together with ambiguity-averse agents, generates an asymmetric response to news. Endogenous worst-case scenarios differ depending on the realization of news. When observing ``bad" news, the worst-case scenario is that the news is reliable and the prices of trees decrease strongly. On the other hand, when ``good news" is observed, under the worst-case scenario the news is evaluated as less reliable, and thus the price increases are mild. Therefore, price responses are stronger conditional on a negative signal and this asymmetry creates a higher correlation conditional on a negative signal than conditional on a positive signal. I also show that the results are robust to the smooth ambiguity aversion representation.</p><p>Motivated by the model, I uncover a new empirical regularity that is unknown in the literature. I show that correlation asymmetry is related to idiosyncratic volatility: the higher the idiosyncratic volatility, the higher the correlation asymmetry. This novel empirical finding is also useful to understand the time-series and cross-sectional variation in correlation asymmetry. Stocks with smaller market capitalizations have greater correlation asymmetry compared to stocks with higher market capitalization. However, an explanation for this finding has been lacking. According to the explanation offered in this paper, smaller size stocks have greater correlation asymmetry compared to bigger size stocks because small size stocks tend to have higher idiosyncratic volatilities compared to bigger size stocks. In the time-series, correlation asymmetry shows quite significant variation as well. The average correlation asymmetry is especially high for the 1990s and decreases significantly at the beginning of the 2000s. This pattern in times-series can also be explained in terms of the time-series behavior of idiosyncratic volatilities. Several papers including Brandt et al. (2010), document higher idiosyncratic volatilities during 1990s while the aggregate volatility stays fairly stable. Basically, the high idiosyncratic volatilities during the 1990s also caused greater correlation asymmetry. </p><p>In the third essay, I study the correlation of returns in government bond markets. Similar to the findings in equity markets, I show that there is some evidence for asymmetric correlations in government bond markets. First, I show that the maturity structure matters for correlation asymmetry in bonds markets: Unlike long-maturity bonds, shorter-maturity bonds tend to have asymmetric correlations. Second, I show that the correlation asymmetry observed in European bond markets disappears with the formation of a common currency area. Lastly, I study the correlation between equity and bond returns in different countries. For long-maturity bonds, correlations with the domestic equity returns are asymmetric for half of the countries in the sample, including the U.S. These findings show that results on asymmetric correlations from equity markets can generalize, at least to some extent, to other financial markets.</p> / Dissertation
|
63 |
Design and architecture of an improved microcomputer-controlled perturbed angular correlation spectrometerStevens, Darren W. 25 February 1992 (has links)
Graduation date: 1992
|
64 |
Analysis of Financial Data using a Difference-Poisson Autoregressive ModelBaroud, Hiba January 2011 (has links)
Box and Jenkins methodologies have massively contributed to the analysis of time series data. However, the assumptions used in these methods impose constraints on the type of the data. As a result, difficulties arise when we apply those tools to a more generalized type of data (e.g. count, categorical or integer-valued data) rather than the classical continuous or more specifically Gaussian type. Papers in the literature proposed alternate methods to model discrete-valued time series data, among these methods is Pegram's operator (1980).
We use this operator to build an AR(p) model for integer-valued time series (including both positive and negative integers). The innovations follow the differenced Poisson distribution, or Skellam distribution. While the model includes the usual AR(p) correlation structure, it can be made more general. In fact, the operator can be extended in a way where it is possible to have components which contribute to positive correlation, while at the same time have components which contribute to negative correlation. As an illustration, the process is used to model the change in a stock’s price, where three variations are presented: Variation I, Variation II and Variation III. The first model disregards outliers; however, the second and third include large price changes associated with the effect of large volume trades and market openings.
Parameters of the model are estimated using Maximum Likelihood methods. We use several model selection criteria to select the best order for each variation of the model as well as to determine which is the best variation of the model. The most adequate order for all the variations of the model is $AR(3)$. While the best fit for the data is Variation II, residuals' diagnostic plots suggest that Variation III represents a better correlation structure for the model.
|
65 |
Boiling in Mini and Micro-ChannelsOlayiwola, Nurudeen Oladipupo 23 June 2005 (has links)
Cooling systems that consist of mini-channels (hydraulic diameters in the 0.5 mm to 2.0 mm range) and micro-channels (hydraulic diameters in the 100 m-500 m range) can dispose of extremely large volumetric thermal loads that are well beyond the feasible operating range of conventional cooling methods. Mini/micro-channel systems that utilize boiling fluids are particularly useful due to the superiority of boiling heat transfer mode over single-phase flow convection. Although forced flow boiling in mini and micro-channels has been investigated by several research groups in the past, a verified and reliable predictive method is not yet available.
In this study, the capability of a large number of forced flow boiling heat transfer correlations for application to mini channels is examined by comparing their predictions with three experimental data sets. The data all represent recently-published experiments with mini-channels The tested correlations include well-established methods for forced-flow boiling in conventional boiling systems, as well as correlations recently proposed for mini-channels.
Based on these comparisons, the most accurate existing predictive methods for mini-channel boiling are identified. The deficiencies of the predictive methods and the potential causes that underlie these deficiencies are also discussed.
|
66 |
Vector correlations in the photodissociation of ICN at 266 nmYang, Tsung-hang 03 August 2012 (has links)
The photodissociation dynamics of cyanogen iodide (ICN) in the A continuum was studied by the three-dimensional sliced fluorescence imaging (3DSFI) method. The fourth harmonic of a Nd:YAG laser (266 nm) was used to dissociate a low pressure (5 mTorr) sample of ICN, and the resulting CN photofragments were probed by optical-optical double resonance (OODR) detection scheme. A theoretical framework on the emitted fluorescence intensity has been developed to analyze the experimentally obtained image. The vector correlations among the ICN parent molecule transition dipole moment £g, the CN fragment recoil velocity v and the CN rotational angular moment J can be revealed.
|
67 |
The Interdependence of Business Cycles among G7 CountriesKao, Kuo-Feng 31 January 2005 (has links)
Generally speaking, business cycle could be discussed as a short-term fluctuation of business cycle and long-term economic growth. In this research, we will confer what impact factors might have affected the business cycle of correlations (BCCs) across countries in a period of short time. Many empirical analysis have pointed out the temporary factors to the business cycle mainly come from the transferred factors of economic aspect. This is called ¡§Transmission Mechanisms.¡¨
What is ¡§Transmission Mechanisms?¡¨ Economists often try to substitute it in good markets, financial markets, and the coordination of monetary policies. However, in this duration of the empirical analysis, using only these proxy variables to explain BCCs between two countries seems too limited. According to this situation, we believe if the BCCs can be explained by using proxy factors of non-economic variable, the result can be utilized by making up the defect. We attempt to find new factors in political approach and combine with the ¡§Transmission Mechanisms¡¨ that we have introduced earlier. After that, we expect to comprehend the BCCs among G7 countries from the inputs of the two completed different variables.
To analyze further economic implication in our research, five conclusions have been summarized below:
Firstly, increasing bilateral trade has significantly provided positive effect to BCCs among G7 countries from 1980 to 2002. Because the empirical result of Single Country is insignificant, we then use a two-stage method. First, we estimate ¡§Trade¡¨ from endogenous variable to exogenous one. Secondly, we use Panel method to expand its matrix. Finally, we improve the empirical estimators of insignificant statistics before. In other words, the important variables of the correlation of bilateral trade are whether or not the two countries speak the same language; the border problem, and the distance between the two are the same, etc. So, when we talk about the relations between BCCs and good and service markets, we must consider these exogenous factors. Eventually, we will receive more detailed results.
Secondly, although to trade in financial markets can increase the BCCs between two countries, the statistic report is insignificant -0.0019 (0.0012). About this empirical result, we can obtain reasonable explanations from the researches (for instance: Imbs, 2004 or Kose et al, 2003), they point out that financial markets are bound excessively by globalization. Therefore, this will aggravatingly make each country to focus on its specialization. Finally, this situation will make the BCCs getting collapsed among these countries. This also explains that the specialization among these countries will reduce the positive effect from the BBCs to financial markets.
Thirdly, in this empirical research of Single-Country, we use three proxy estimators of economics to substitute common properties of the monetary policy. At this point, there are no identical correlations of corresponding among other countries except some significantly negative trends shown to the member countries of European Union. According to this situation, we believe it may be the consequence to all the member countries under some ERM restrictions, which is Treaty of Maastricht. Also, because of the rules form this treaty, the monetary policies are getting to be accordant, and the BCCs among the countries will soon appear in obviously positive trend.
Fourthly, in the model, the difference of the inflation rate between two countries is not significant with BCCs; therefore, an identical correlation is hardly shown. Moreover, the coefficient symbol is not in our expecting direction, so we think maybe some policies are neglected to the influence of this variable. After all these, we believe if we can control some relative policy effect to inflation rate when discussing the relationship between this variable and the BCCs, we should be able to find out the real effect of this substitutive variable to BCCs
Lastly, in the research, the statistics effect of the party variables and business cycle of correlations are very significant. This also indicates the political factor will play an important role for many sources of the fluctuation tread of BCCs. In other words, when we discuss the issue of BCCs if miss the contribution of political factors to the BCCs. Then, this might cause the omitted variable biased, and finally cause the whole computation become inefficient. In addition, we can have further discussion by an input of a factor: to conserve the joint benefit of all the member countries in an economic organization, these countries need to be ruled by the same ideal political party. Otherwise, the institute will never reach its essential result.
Combining all the conclusions we have shown above, we can find out the BCCs among G7 countries from 1980-2002. Besides the influence of the ¡§Transmission Mechanisms,¡¨ the result will be varied by the political factors. In conclusion, we need to consider the contribution of the political party variables to the BCCs when talking about this issue, therefore; the original theoretical model can be more persuasive. According to a statistics of IMF, the BCCs among those industrial countries are falling little by little in recent years. Therefore, consolidating trade cooperation is essential for what we believe to improve the BCCs among G7. At the same time, pass through a strong integrate monetary policy can move forward all the incumbent parties from all the countries to agree among themselves, and even reach more substantial effect. From the example like this, we might find evidence from BCCs issues by discussing the integration process in European Monetary Union.
|
68 |
G7 business cycle synchronization and transmission mechanism.Chou, I-Hsiu 22 June 2006 (has links)
Since Bretton Woods System break down in year 1973. Many economists found that there are more similar business cycle between industrial countries. Recently, Doyle and Faust(2002) proposed the correlation of business cycle between two countries becomes weaker.
Therefore in this search, we try to carry out two different aspect factor that effects the countries¡¦ business cycle correlation. The factor is so-called ¡§transmission mechanism.¡¨
Generally specking, Many empirical analysis have pointed out the temporary factors to the business cycle mainly come from the transferred factors of economic aspect.
What is ¡§Transmission Mechanisms?¡¨ Economists often try to substitute it in
good markets, financial markets, and the coordination of monetary policies. However,
in this duration of the empirical analysis, using only these proxy variables to explain
BCCs between two countries seems too limited. According to this situation, we
believe if the BCCs can be explained by using proxy factors of non-economic variable, the result can be utilized by making up the defect.
We attempt to find new factors in political approach and combine with the ¡§Transmission Mechanisms¡¨ that we have introduced earlier.
To analyze further economic implication in our research, five conclusions have
been summarized below:
Firstly, increasing bilateral trade has significantly provided positive effect to
BCCs among G7 countries from 1980 to 2002. Because bilateral trade intensity index is endogenous , we use exogenous variable as instrumental variable to estimate ¡§Trade¡¨. Secondly, we use Panel method to expand its matrix. Finally, we improve the empirical estimators of insignificant statistics before. So, when we talk about
the relations between BCCs and good and service markets, we must consider these
exogenous factors. Eventually, we will receive more detailed results.
Secondly, although to trade in financial markets can increase the BCCs between
two countries, the statistic report is insignificant . About this
empirical result, we can obtain reasonable explanations from the researches (for
instance: Imbs, 2004 or Kose et al, 2003), they point out that financial markets are
bound excessively by globalization. Therefore, this will aggravatingly make each
country to focus on its specialization. Finally, this situation will make the BCCs
getting collapsed among these countries. This also explains that the specialization
among these countries will reduce the positive effect from the BBCs to financial
markets.
Thirdly, in the research, the statistics effect of the trade intensity index and specialization are significant negative. It means that when good in transaction will result in more specialization. Two countries have similar industrial structure.Imbs(2004) consider the problem is the index we use to measure bilateral trade intensity. This index was effected from two countries¡¦ size . If use Clark and van Wincoop¡¦s trade intensity index to measure the effect, we can find that significant specialization by comparative advantage effect.
Fourth, there are high level financial integration between two countries, because international risk sharing result in two countries have different industrial structure.
Lastly, in the research, the statistics effect of the party variables and business
cycle of correlations are very significant. This also indicates the political factor will
play an important role for many sources of the fluctuation tread of BCCs. In other
words, when we discuss the issue of BCCs if miss the contribution of political factors
to the BCCs. Then, this might cause the omitted variable biased, and finally cause
the whole computation become inefficient. In addition, we can have further discussion
by an input of a factor: to conserve the joint benefit of all the member countries in an
economic organization, these countries need to be ruled by the same ideal political
party. Otherwise, the institute will never reach its essential result.
Combining all the conclusions we have shown above, we can find out the BCCs
among G7 countries from 1980-2002. Besides the influence of the ¡§Transmission
Mechanisms,¡¨ the result will be varied by the political factors. In conclusion, we need
to consider the contribution of the political party variables to the BCCs when talking
about this issue, therefore; the original theoretical model can be more persuasive.
According to a statistics of IMF, the BCCs among those industrial countries are
falling little by little in recent years. Therefore, consolidating trade cooperation is
essential for what we believe to improve the BCCs among G7. At the same time, pass
through a strong integrate monetary policy can move forward all the incumbent
parties from all the countries to agree among themselves, and even reach more
substantial effect. From the example like this, we might find evidence from BCCs
issues by discussing the integration process in European Monetary Union.
|
69 |
Analysis of coupled body mooring and fender systemGirija Sasidharan Pillai, Harish 01 November 2005 (has links)
The hydrodynamic excitation and response behavior of multi-body systems with
varying degrees of coupling presents many challenges for designers of offshore
structures. In this study, attention is focused upon the analysis and interpretation of
experimental data obtained for an unmanned deepwater mini-Tension Leg Platform
(mini-TLP) coupled to a tender barge. Each body has its own mooring system and the
bodies are connected by two breast lines extending from central points on the mini-TLP
to central points on the bow and stern of the tender barge. A fender system is located
between the two platforms. Thus the two floating bodies are constrained to move
together in surge and yaw while they are free to move independently in heave, roll and
pitch with some limitations on sway.
The data of the individual records are characterized using statistical moments,
including skewness and kurtosis, to examine the degree of non-Gaussian behavior.
Correlation analysis and cross spectral analysis are used to investigate the relationships
between selected measurements such as the motion of each vessel, tensions in the
mooring lines and tendons and the forces on the fenders. The analysis shows that the
coupling effects reduce the mooring line and tendon tensions significantly and that the
motions of the two vessels influence the line tensions and fender forces. The data
distribution patterns followed by the parameters and the corresponding extreme values
are also investigated.
|
70 |
Smoothed universal correlations in the two-dimensional Anderson modelUski, V., Mehlig, B., Romer, R. A., Schreiber, M. 30 October 1998 (has links) (PDF)
We report on calculations of smoothed spectral correlations in the twodimensional
Anderson model for weak disorder. As pointed out in (M. Wilkinson,
J. Phys. A: Math. Gen. 21, 1173 (1988)), an analysis of the smoothing
dependence of the correlation functions provides a sensitive means of establishing
consistency with random matrix theory. We use a semiclassical approach
to describe these fluctuations and offer a detailed comparison between
numerical and analytical calculations for an exhaustive set of two-point correlation
functions. We consider parametric correlation functions with an external
Aharonov-Bohm flux as a parameter and discuss two cases, namely
broken time-reversal invariance and partial breaking of time-reversal invariance.
Three types of correlation functions are considered: density-of-states,
velocity and matrix element correlation functions. For the values of smoothing
parameter close to the mean level spacing the semiclassical expressions
and the numerical results agree quite well in the whole range of the magnetic
flux.
|
Page generated in 0.0244 seconds