Due to the fast expansion and development in the optical communication industry, the demand for the broad-band laser light source as used to the optical transmission network system has correspondingly increased. Cr4+ doped YAG crystal fibers, with its broad-band spectral property, is thus becoming more and more indispensable to the growth of the industry. However, the Cr4+:YAG crystal fiber in its own repetitive growth process brings with itself one problem: after each re-growth, the concentration of Cr2O3 and Cr4+ ions would reduce appreciatively. Hence, finding sound solutions for effectively raising the concentration of Cr4+ is now becoming an essential issue in the field. The thesis mainly focuses on the development of using Cr4+:YAG as the laser gain medium. Thin layers of CaO, MgO, and Cr2O3 was coated on the circumference of the Cr:YAG crystal fiber. The LHPG method was then employed to re-grow the coated samples, during which the doped concentration of CaO, MgO and Cr2O3 can in-diffuse. And the effect of charge compensation would go further to simultaneously raise the concentration of Cr4+ ions. Now we have successfully enhance the concentration of Cr4+ ions to 4.86x10-3 wt.%. This study, with the use of the E-Gun coating machine and the IAD (ion-beam assisted deposition) system, also probes the technical side of how to better improve the quality of the crystal fiber laser. Both end faces of the Cr4+:YAG crystal fiber were coated with optical thin films by TiO2 and SiO2 targets. In addition to raise the quality of the thin films, the IAD system also functions to create a laser cavity in which both the anti-reflectance (AR) effect (for pumping the light source) and the high reflectance (HR) effect (for stimulating the light source) are achieved. The accompanied benefits would be the reduction of transmission loss, the increased laser efficiency, and thus a more successful and more stable crystal fiber laser.

In the past three decades, Nd:YAG has been the dominating high power solid-state laser gain medium. Compared with Nd:YAG, Yb:YAG has lower quantum defects which produces less heat so that it can reduce thermo-optical deformation. In addition, the achieved doping concentration can be 100%, and the absorption FWHM at 941 nm is 18 nm. Based on above listed advantages, Yb:YAG has the potential to replace Nd:YAG. Using Yb:YAG as the laser gain medium in reentrant two-mirror laser cavity, we have succeeded in Yb:YAG ring laser and all the intracavity elements are coated by our electron gun deposition system. The main purpose of my research is to continue the previous result (slope efficiency: 20.1%), and further increasing the slope efficiency of our ring cavity with different round-trip transmittance of couplers. Besides, we measured and analyzed the polarization of the planar and non-planar ring cavities. At present, the highest slope efficiency we achieved is 38.9% with a round-trip transmittance of 16.4%.

In this study, the wastewater from oxide chemical mechanical polishing (oxide-CMP) process of semiconductor wafer fabrication was treated by crossflow electro-ultrafiltration with self-prepared tubular inorganic membranes. First of all, a recipe of alumina (72 wt%), bentonite (8 wt%) and water (20 wt%) was determined for the extrusion of green tubes. The porous ceramic green tubes of 200 mm in length thus obtained were subjected to further curing, drying, and sintering processes. The inner and outer radii of the porous ceramic supports were 6.0 mm and 10.0 mm, respectively. Then, nanoscale TiO2 (i.e., the slip) was prepared by sol-gel method. On the tops of porous ceramic supports thin layers of nanoscale TiO2 were applied by the dip-coating method. To analyze the microstructures of tubular inorganic membranes and confirm the nanoscale TiO2 films, a scanning electron microscope equipped with energy-dispersive X-ray analyzer (SEM-EDS) and X-ray diffractometer (XRD) were employed. The self-prepared tubular inorganic composite membranes (TICMs) were futher characterized by permporometry and Kelvin equation to determine their pore size distributions and nominal pore sizes. In addition, through the employment of polyethylene glycol (PEG) of different molecular weights and total organic carbon analysis method, the molecular weight cut-off (MWCO) and tightness coefficient of each TICM was determined. It was found that the self-prepared TICMs were suitable for ultrafiltration applications. In this work, wastewater from the oxide-CMP process of semiconductor wafer fabrication was treated by crossflow electro-ultrafiltration with self- prepared TICMs. The permeate qualities were evaluated. Experimental results have shown that permeate of a higher filtration rate, a turbidity of below 1 NTU, 90% removal of total suspended solids, and a removal efficiency of greater than 80% for soluable silica could be obtained under the conditions of an electric filed strength of 30 V/cm and transmembrane pressure of 5 kgf/cm2. For permeate to meet the feed water requirements for the ultrapure water system, it has to be further treated to lower its silica content to ¡Ø 6 mg/L. Overall speaking, by incorporation of the tubular inorganic composite membranes prepared in this work into the novel electrofiltration treatment module for the treatment of oxide-CMP wastewater would yield permeate suitable for the purpose of reclamation.

A series of novel metallic nanoparticle and suspension were developed and synthesized for ink-jet printing and spin coating applications. Organic components, such as alkanethiols and amines, were used as new capping agent design. The suspension was characterized by NMR, ESCA, TEM, SEM, EDS, TGA, DTG, DSC, TA-MS for chemical composition and three-dimension SAMs desorption.

In this thesis, the contact behavior of the conduct particles in the anisotropic conductive film (ACF) packaging process is investigated. The thermal elastic-plastic finite element (FE) model is employed to simulate the contact process. The commercial MARC finite element method package is used in this work. Two contact models of the ACF packaging are studied : the single particle and the multiple-particles models. In the single particle model a simple axial symmetric FE model is used to simulate the variation of elastic-plastic deformations during packaging process. The effect of coating thickness on the contact deformation is discussed. To explore the effect of particle distribution on the contact deformation and the conduct behavior in the ACF packaging, the multiple-particles 3D model has also been studied. However, to overcome the computing difficulties introduced from huge degrees of freedom, the equivalent nonlinear springs are employed to stand for some conductive particles. The effect of particle distribution and particle parameters on the conductive behavior are studied. Results indicate that the conductive particle parameters may affect the conductive characteristics significantly in the ACF packaging process.

The aim of this study is to develop a software which calculates reflection, transmission and absorption of multilayered thin films by using complex indices of refraction, as a function of both wavelength and thickness. For these calculations matrix methods will be considered and this software is programmed with the matrix method. Outputs of the program will be compared with the theoretical and experimental results studied in the scientific papers.

This thesis describes the works done during the design and deposition process of the antireflection coating for the materials commonly used as refractive optical elements in thermal imaging systems. These coatings are quite necessary to reduce reflection losses from the surface of the optics and stray light that directly affects the image quality. Germanium, zinc sulfide and zinc selenide were used as substrate material and their optical properties were investigated with infrared ellipsometry and FTIR. Antireflection coatings for each material operating in 8-12 &amp / #956 / m range were designed with Needle Synthesis Technique. In order to shorten the optimization time, commercial software / &ldquo / The Essential Macleod&rdquo / was used. In order to reduce the reflectance losses multilayer structure was used in the coating design, and zinc selenide and lead telluride were used as low and high index materials. In this study the necessary theoretical background and common deposition techniques are reviewed. Samples were produced using the magnetron sputtering. To optimize the v thicknesses of the deposited layers, growth period and rate was controlled. Thicknesses of the samples, following to the deposition were also measured by thickness profilometer. A 3-layer coating, PbTe/ZnSe/PbTe, on ZnS and 2-layer coating PbTe/ZnS on Ge having more than 90% transmittance in 9.7-10.3 &amp / #956 / m wavelength region have been successfully produced. Although, the measured range for 3 and 2- layer coating is narrower than the aimed one, it has been shown that, the method developed in this thesis would yield AR-coatings with broader spectral response if a system having better control on deposition parameters is used. For example, our design and optimization work has suggested that a 7-layer AR coating on germanium, with alternating high and low index layers is expected to give transmittance value greater than 93% in the studied wavelength region.

Magnetic nanoparticles have been used in many areas owing to their variable characteristic behaviors. Among these iron oxide nanoparticles are one of the mostly preferred type of nanoparticles. In this study Fe3O4, namely magnetite, which is one type of magnetic iron oxide nanoparticles was used. Magnetite nanoparticles with a narrow size distribution were prepared in aqueous solution using the controlled coprecipitation method. They were characterized by electron microscopic methods (SEM and TEM), crystal structure analysis (XRD), particle size analyzer, vibrating sample magnetometer (VSM) and Raman spectrometry. The nanoparticles were coated with a thin (ca 20 nm) silica shell utilizing the hydrolysis and the polycondensation of tetraethoxysilane (TEOS) under alkaline conditions in ethanol. The presence of silica coating was investigated by energy dispersive X-ray spectrometer (EDX) measurement. After surface modification with an amino silane coupling agent, (3-Aminopropyl)triethoxysilane, histidine was covalently linked to the amine group using glutaraldehyde as cross-linker. Carbonyl complexes of rhenium [Re(CO)3(H2O)3]+ was prepared through reductive carboxylation utilyzing gaseous carbon monoxide as a source of carbonyl and amine borane (BH3NH3) as the reducing agent. The complex formation was followed by HPLC- ICP-MS system and 95% conversion of perrhanete into the complex was achieved. The magnetic nanoparticles were then labeled with the Re complex with a yield of 86.8% through the replacement of labile H2O groups with imidazolyl groups. Thus prepared particles were showed good stability in vitro. Herein rhenium was selected as a surrogate of radioactive 99mTc. However radioactive isotopes of rhenium (186-Re and 188 Re) is also used for radioactive therapy.

Magnetic nanoparticles find broad applications in biomedical field such as drug delivery, hyperthermia and magnetic resonance imaging (MRI). For these applications magnetic nanoparticles need to be coated with suitable materials which are soluble, biocompatible and nontoxic. Among these materials, silica is the most often used coating material. This thesis is focused on preparation of silica coated iron oxide magnetic nanoparticles. Magnetic iron oxide nanoparticles are synthesized by thermal decomposition method. In the presence of iron acetylacetonate Fe(acac)3, a high boiling point organic solvent and a reducing agent, particle sizes ranging from about 5 nm to 7 nm were obtained. Nanoparticles were characterized by transmission electron microscopy (TEM). The obtained nanoparticles were coated with ultra thin silica shell via reverse microemulsion method. The influence of the amount of Igepal CO-520, NH4OH and TEOS was studied systematically and their amounts were optimized to yield monodisperse and well defined particles. The size of the silica coated magnetic nanoparticles and their agglomerates were determined by TEM images and particle size analyzer (zeta sizer). X-Ray photoelectron spectroscopy (XPS) was used to confirm the presence of silica whenever the coating could not be seen by TEM measurements. Magnetic nanoparticles having 4-6 nm thickness of silica shell were obtained. The results showed that the amount of surfactant Igepal CO-520 played an important role in the reaction system.

The improvement in the impermeability of concrete was studied using different methods. The main aim was to investigate impermeability improvement of concrete and to compare these methods. Two different methods were examined to investigate and compare impermeability and strength improvement of concrete by using two different sets of concrete specimens. These methods included the application of coating materials to concrete and the production of concrete using different constituent amounts and types. The first set of concrete specimens was prepared by applying two different coating materials (a coating material including both powder and liquid components / and a coating material including only a liquid component) on reference concrete specimens separately. The second set of concrete specimens was prepared using different proportions of concrete constituents such as cement, water, steel and plastic fibers, mineral and chemical concrete admixtures. Various tests were conducted on both sets of concrete specimens in order to compare the permeability of concrete specimens. However, some of these tests v were not applied on all of the specimens because of test and material specifications. The tests were used to evaluate compressive strength, water absorption, chloride ion penetration and depth of water penetration under pressure. These test methods were carried out on concrete cube specimens and concrete cores taken from those specimens according to the relevant standards. It was found that the permeability of the concrete specimens decreased significantly when the coating material which was composed of the combination of powder and liquid components was applied on concrete specimens. However, permeability did not decrease significantly for concrete specimens coated with the coating material composed of only a liquid component. Significant improvement in the impermeability of the concrete specimens was observed when the amount of cement was increased, the water-to-cement ratio was decreased, mineral admixtures (silica fume and fly ash) and plasticizers were used. This improvement was associated with densification of the concrete microstructure and reduction in capillary pores as a result of pozzolanic reaction and due to reduction in water-to-cement ratio. Coating materials were determined to be effective for concretes with high permeability prior to coating whereas their effect was less significant for lower-initial permeability concretes. Moreover, the effect of coating materials on permeability differed depending on their chemical compositions. The effect of using steel fibers and plastic fibers for the improvement of concrete impermeability was found to be insignificant.