Made available in DSpace on 2014-12-17T15:48:13Z (GMT). No. of bitstreams: 1 LaurindoSBN.pdf: 1520391 bytes, checksum: 86f5072a56e661766a5174bce88b82d5 (MD5) Previous issue date: 2007-09-21 / Conselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico / Non-Photorealisitc Rendering (NPR) is a class of techniques that aims to reproduce artistic techniques, trying to express feelings and moods on the rendered scenes, giving an aspect of that they had been made "by hand". Another way of defining NPR is that it is the processing of scenes, images or videos into artwork, generating scenes, images or videos that can have the visual appeal of pieces of art, expressing the visual and emotional characteristics of artistic styles. This dissertation presents a new method of NPR for stylization of images and videos, based on a typical artistic expression of the Northeast region of Brazil, that uses colored sand to compose landscape images on the inner surface of glass bottles. This method is comprised by one technique for generating 2D procedural textures of sand, and two techniques that mimic effects created by the artists using their tools. It also presents a method for generating 21 2D animations in sandbox from the stylized video. The temporal coherence within these stylized videos can be enforced on individual objects with the aid of a video segmentation algorithm. The present techniques in this work were used on stylization of synthetic and real videos, something close to impossible to be produced by artist in real life / Renderiza??o N?o Fotoreal?stica (NPR) ? uma classe de t?cnicas que almejam reproduzir t?cnicas art?sticas, tentado expressar sentimentos e emo??es nas cenas renderizadas, dando um aspecto de que foram feitas "manualmente". Outra forma de definir a NPR ? como o processamento de cenas, imagens ou v?deos para gera??o de trabalhos de arte, gerando cenas, imagens ou v?deos que podem ter o atrativo visual de pe?as art?sticas, expressando caracter?sticas visuais e emocionais do estilo art?stico. Esta disserta??o apresenta um novo m?todo de NPR para estiliza??o de imagens e v?deos baseado em uma express?o art?stica t?pica da regi?o Nordeste do Brasil, que usa areia colorida para compor imagens de paisagens na superf?cie interna de garrafas de vidro. Este m?todo possui uma t?cnica para gera??o de texturas procedurais de areia 2D, e duas t?cnicas que imitam os efeitos criados pelos artes?es usando sua ferramenta. Al?m disso, essa disserta??o apresenta tamb?m um m?todo para gera??o de anima??es 21 2D em caixas de areia a partir do v?deo estilizado. A coer?ncia temporal nos v?deos estilizados pode ser for?ada nos objetos individuais do v?deo com aux?lio de um algoritmo de segmenta??o de v?deo. As t?cnicas apresentadas neste trabalho s?o usadas na estiliza??o de v?deos reais e sint?ticos, algo quase imposs?vel de ser produzido pelo artes?o na vida real

Ultrafeinkörnige metallische Werkstoffe haben verstärkt wissenschaftliche Bedeutung erlangt. Um dieser neuartigen Werkstoffklasse über die grundlagenorientierte Forschung hinaus einen Einsatz in technischen Anwendungen zu ermöglichen, ist es notwendig, deren Verhalten unter verschiedenen einsatzrelevanten Belastungsbedingungen vorhersagen zu können. In der vorliegenden Arbeit wird das Schädigungsverhalten einer ultrafeinkörnigen Aluminiumlegierung in den Bereichen der hochzyklischen (HCF) und niedrigzyklischen (LCF) Ermüdung sowie des Rissfortschritts untersucht. Im Mittelpunkt steht dabei die Identifikation der mikrostrukturell wirksamen Mechanismen bei der Entstehung und Ausbreitung von Ermüdungsrissen. Es werden ein homogen ultrafeinkörniger und ein bimodaler Zustand sowie verschiedene duktilitätsoptimierte Zustände betrachtet und systematisch der Einfluss der Korngröße, der Korngrößenverteilung, der Ausscheidungscharakteristik sowie der Festigkeit und Duktilität auf das Ermüdungs- und Rissfortschrittsverhalten ermittelt. Die Untersuchungen zeigen, dass das Schädigungsverhalten der ultrafeinkörnigen Aluminiumlegierung insbesondere durch die Korngröße und Korngrößenverteilung sowie den Kohärenzgrad der festigkeitssteigernden Ausscheidungen beeinflusst wird.

This master thesis presents a theoretical investigation of the energy and stability of interfaces in iron-carbide compounds, specifically focusing on the α-Fe/Cr7C3 system. The study aims to fill the gap in knowledge regarding the surface energetics of these interfaces using Density Functional Theory (DFT). Six different α-Fe/Cr7C3 interfaceswere constructed α-Fe(001)/Cr7C3(024), α-Fe(001)/Cr7C3(202), α-Fe(001)/Cr7C3(040),α-Fe(110)/Cr7C3(024), α-Fe(110)/Cr7C3(202) and α-Fe(110)/Cr7C3(040). Due to limited computational resources, only one of them was computationally analyzed to determine its interfacial energy value. The results revealed that the interfacial energy of the α-Fe(001)/Cr7C3(040) interface falls within the range of incoherent interfaces, indicating its stability. The computed interfacial energy values ranged from 0.94 to 3.39 J/m2, consistent with similar studies on other iron interfaces. The simulations also identified minimum and local minimum points in the interface energy curve, representing stable configurations at specific interface separation distances. The presence of a minimum point at an interface separation value of d = 1.3551 Å with an interfacial energy of 0.94 J/m2 indicates the most stable configuration, while a local minimum point at d = 2.27 Å with an interfacial energy of 2.12 J/m2 suggests another stable configuration for the interface. The conclusion that the computations were correctly performed with an interfacial energy value of 0.94 J/m2 for the most stable configuration at a supercell length (aSupercell ) of 22.23 Å is drawn. The findings of this research have significant implications for future investigations and applications. Firstly, this study fills the gap of the unresearched ferrite-carbide interfaces with theoretical data. Secondly, the knowledge gained from studying these interfaces contributes to understanding hydrogen interactions, which is fundamental for the transition towards a hydrogen economy. Additionally, the incoherent nature of the interface introduces challenges in understanding material behavior and properties, necessitating further investigations for designing efficient systems. Future work includes experimental validation of the α-Fe/Cr7C3 interface to compare the theoretical and experimental energies and stability. Investigating the remaining interfaces and examining the effects of introducing hydrogen atoms in these interfaces, along with calculating the corresponding hydrogen trapping energies, are important research areas. Further advancements in understanding these interfaces can be achieved through interface engineering, multiscale modeling, and studying other iron-carbide systems. / Detta examensarbete presenterar en teoretisk undersökning av energin och stabiliteten hos gränssnitt i järnkarbidföreningar och fokuserar specifikt på α-Fe/Cr7C3-systemet. Studien syftar till att fylla kunskaps tomrummet gällande ytegenskaperna hos dessa gränssnitt genom användning av densitetsfunktionalteori (DFT). Sex olika α-Fe/Cr7C3-gränssnitt konstruerades α-Fe(001)/Cr7C3(024), α-Fe(001)/Cr7C3(202), α-Fe(001)/Cr7C3(040), α-Fe(110)/Cr7C3(024), α-Fe(110)/Cr7C3(202) och α-Fe(110)/Cr7C3(040). På grund av begränsade beräkningsresurser analyserades endast ett av dem för att bestämma dess gränssnittsenergivärde. Resultaten visade att gränssnittsenergin för α-Fe(001)/Cr7C3(040)- gränssnittet ligger inom intervallet för inkoherenta gränssnitt, vilket indikerar dess stabilitet. De beräknade gränssnittsenergivärdena varierade mellan 0,94 och 3,39 J/m2 , vilket är i linje med liknande studier där järngränssnitt studeras. Minimi och lokala minimipunkter i gränssnittets energikurva, vilket representerar stabila konfigurationer vid specifika avstånd mellan gränssnittet. Förekomsten av en minimipunkt vid ett gränssnittsavstånd på d = 1,35 Å med en gränssnittsenergi på 0,94 J/m2 indikerar den mest stabila konfigurationen, medan en lokal minimipunkt vid d = 2,27 Å med en gränssnittsenergi på 2,12 J/m2 antyder en annan stabil konfiguration för gränssnittet. Slutsatsen dras att beräkningarna utfördes korrekt med ett gränssnittsenergivärde på 0,94 J/m2 för den mest stabila konfigurationen vid en supercellslängd (aSupercell) på 22,23 Å. Fynden från denna forskning har betydande implikationer för framtida undersökningar och tillämpningar. För det första fyller denna studie kunskapsgapet gällande de otillräckligt utforskade ferrit-karbidgränssnitten med teoretisk data. För det andra bidrar den erhållna kunskapen från studiet av dessa gränssnitt till förståelsen av väteinteraktioner, vilket är grundläggande för övergången till en väteekonomi. Dessutom innebär gränssnittets inkoherenta natur utmaningar när det gäller att förstå materialbeteende och egenskaper, vilket kräver ytterligare undersökningar för att utforma effektiva system. Framtida arbete inkluderar experimentell validering av gränssnittet mellan α-Fe/Cr7C3 för att jämföra teoretiska och experimentella energier och stabilitet. Att undersöka återstående gränssnitt och undersöka effekterna av att introducera väteatomer i dessa gränssnitt och beräkna motsvarande vätefällningsenergier är viktiga forskningsområden. Gränssnittsdesign, flerskalig modellering och studier av andra järnkarbid-system kan ytterligare främja förståelsen av dessa gränssnitt.

Cette thèse vise à étudier expérimentalement, analytiquement et numériquement, les conséquences de variations et d'oscillations hydrodynamiques à forte variabilité temporelle en milieux poreux partiellement saturés. Les problèmes que nous étudions comportent des surfaces libres tant à l'extérieur qu'à l'intérieur des milieux poreux, celles-ci étant définies comme des isosurfaces de pression d'eau égale à la pression atmosphérique (Pwater = Patm). Les différentes études expérimentales réalisées en laboratoire sont, respectivement : une expérience d'imbibition dans une boite à sable avec effets capillaires importants; la transmission d'oscillations de la surface libre à travers un massif sableux intercalaire dans un petit canal à houle (IMFT, Toulouse); l'étude de la dynamique et de la propagation des oscillations des niveaux d'eau dans un grand canal à houle (HYDRALAB, Barcelone), partiellement recouvert d'un fond sableux incliné, avec mesures de niveaux d'eau en pleine eau et sous le sable, et mesures du fond sableux (érosion/dépôts). Pour les études théoriques, nous avons développés des solutions analytiques linéarisées. Un exemple de problème traité analytiquement est: l'équation linéarisée de Dupuit-Boussinesq (D-B) transitoire à surface libre, en hypothèse d'écoulements plans et vidange/remplissage instantané : oscillations forcées, transmission et dissipation d'ondes à travers une boite à sable rectangulaire. Nous avons aussi développé une solution de l'équation faiblement non linéaire de Dupuit- Boussinesq (D-B) pour étudier le problème d'imbibition avec variation abrupte du niveau d'eau amont (suivi temporel du front de saturation). Nous avons pu étudier les différents types de problèmes transitoires liés aux expériences citées plus haut par simulation numérique. En particulier, nous avons simulé des écoulements partiellement saturés et insaturés, en coupe verticale, à l'aide d'un code de calcul (BIGFLOW 3D) qui résoud l'équation de Richards généralisée en régime transitoire. Nous avons ainsi étudié numériquement en régime non saturé, l'expérience d'imbibition dans un sable initialement sec à frontières verticales (IMFT sandbox), puis l'expérience de propagation d'ondes dans le grand canal à houle de Barcelone (laboratoire HYDRALAB) comportant une plage de sable inclinée, avec un couplage complètement intégré entre les zones micro-poreuse (sable) et “macro-poreuse” (pleine eau). Pour analyser les résultats de cette dernière expérience et les comparer aux simulations, nous avons utilisé plusieurs méthodes de traitement et d'analyse des signaux : analyse de Fourier (spectres de fréquences) ; ondelettes discrètes multi-résolution (Daubechies) ; analyses corrélatoires simple et croisée. Ces méthodes sont combinées avec des méthodes de préfiltrage pour estimer dérives et résidus (moyennes mobiles ; ondelettes multi-résolution). Cette analyse des signaux a permis de comprendre et quantifier la propagation à travers une plage de sable. Au total, les différentes approches de modélisation mis en oeuvre, associé à des procédures de calage en situation de couplage transitoire non linéaire ont permis de reproduire globalement les phénomènes de propagation de teneur en eau et de niveau d'eau dans les différentes configurations étudiées. / This thesis aims at investigating experimentally, analytically and numerically, the consequences of hydrodynamic variations and oscillations with high temporal variability in partially saturated porous media. The problems investigated in this work involve “free surfaces” both outside and inside the porous media, the free surface being defined as the “atmospheric” water pressure isosurface (Pwater = Patm). The laboratory experiments studied in this work are, respectively: Lateral imbibition in a dry sand box with significant capillary effects; Transmission of oscillations of the free surface through a vertical sand box placed in a small wave canal (IMFT, Toulouse); Dynamics of free surface oscillations and wave propagation in a large wave canal (HYDRALAB, Barcelona), partially covered with sand, with measurements of both open water and groundwater levels, and of sand topography (erosion / deposition). For theoretical studies, we have developed linearized analytical solutions. Here is a sample problem that was treated analytically in this work: The linearized equation of Dupuit-Boussinesq (DB) for transient free surface flow, assuming horizontal flow and instantaneous wetting/drainage of the unsaturated zone: forced oscillations, wave transmission and dissipation through a rectangular sandbox. We also developed a weakly nonlinear solution of the Dupuit-Boussinesq equation to study the sudden imbibition (temporal monitoring of the wetting front). We have studied the different types of transient flow problems related to the experiments cited above by numerical simulation. In particular, we have simulated unsaturated or partially saturated transient flows in vertical cross-section, using a computer code (BIGFLOW 3D) which solves a generalized version of Richards’ equation. Thus, using the Richards / BIGFLOW 3D model, we have studied numerically the experiment of unsaturated imbibition in a dry sand (IMFT sandbox), and then, with the same model, we have also studied the partially saturated wave propagation experiment in the large Barcelona wave canal (HYDRALAB laboratory), focusing on the sloping sandy beach, with coupling between the micro-porous zone (sand) and the “macro-porous” zone (open water). To interpret the results of the latter experiment and compare them to simulations, we use several methods of signal analyzis and signal processing, such as: Fourier analysis, discrete multi-resolution wavelets (Daubechies), auto and cross-correlation functions. These methods are combined with pre-filtering methods to estimate trends and residuals (moving averages; discrete wavelet analyses). This signal analyzis has allowed us to interpret and quantify water propagation phenomena through a sandy beach. To sum up, different modeling approaches, combined with model calibration procedures, were applied to transient nonlinear coupled flow problems. These approaches have allowed us to reproduce globally the water content distributions and water level propagation in the different configurations studied in this work.