Salient contour detection is an important lowlevel visual process in the human visual system, and has significance towards understanding higher visual and cognitive processes. Salience detection can be investigated by examining the visual cortical response to visual input. Visual response activity in the early stages of visual processing can be approximated by a sequence of convolutions of the input scene with the difference-of-Gaussian (DoG) and the oriented Gabor filters. The filtered responses are unusually high for prominent edge locations in the image, and are uniformly similar across different natural image inputs. Furthermore, such a response follows a power law distribution. The aim of this thesis is to examine how these response properties could be utilized to the problem of salience detection. First, I identify a method to find the best threshold on the response activity (orientation energy) toward the detection of salient contours: compare the response distribution to a Gaussian distribution of equal variance. Second, I justify this comparison by providing an explanation under the framework of Suspicious Coincidence proposed by Barlow [1]. A connection is provided between perceived salience of contours and the neuronal goal of detecting suspiciousness, where salient contours are seen as affording suspicious coincidences by the visual system. Finally, the neural plausibility of such a salience detection mechanism is investigated, and the representational effciency is shown which could potentially explain why the human visual system can effortlessly detect salience.

This thesis presents experimental studies of gas phasemolecular relaxation after excitation with synchrotron photonsin the 15-35 eV and in the 70-350 eV regions. In the 15-35 eV region, molecular relaxation by neutraldissociation processes and non Franck-Condon effects in N2 and O2 molecules have beenstudied by means of dispersed fluorescence and photoelectronspectroscopy experimental techniques, respectively. From thedispersed fluorescence data, excitation functions for themeasured atomic fluorescence spectra have been obtained. Fromthe recorded photoelectron spectra vibrational branching ratioshave been produced. The results obtained reveal that Rydbergseries and singly and doubly excited valence states of theappropriate symmetry energetically accessible in the studiedregion and interactions between themaccount for most of theobserved effects in these two type of experiments. In the 70-350 eV range, molecular relaxation processesresulting in fragmentation of CD4 and SF6 after absorption ofsynchrotron light have been studied by energy resolved electronion coincidence technique using a multicoincidence experimentalstation developed by our group during the last five years forsuch type of experiments. The coincidence measurements yieldedmass spectra from which information about the kinematics of thedetected fragments has been deduced by means of Monte Carlosimulations of the experimental peak shapes. The obtainedresults show completely different dissociation patternsdepending on the molecular electronic states studied. Thesepatterns reflect the bonding properties of the excited orbitalsand they permit the description and in some cases theidentification of the different molecular relaxation pathwaysobserved. The achievements presented in this thesis exemplifythe potential of the multicoincidence station used in thereported experiments.

It has been shown that neutrons emitted from the same 252Cf fission event are preferentially detected within small angles of each other and at angles around 180 degrees. The distribution of this angular anisotropy is dependent upon the nuclide emitting the neutrons. Coincident neutrons can be detected from a shielded source, so a study of the angular anisotropy between coincident neutrons is useful for this context. This could allow for the dynamic determination of the ratio of the rate of (alpha,n) neutron production to the spontaneous fission neutron production (designated alpha) used in neutron coincidence counting for safeguards. This could also be used to identify neutron emitting isotopes in a homeland security application. An angular frequency distribution for coincident neutrons was produced via experiments using an array of cylindrical liquid scintillators and a 252Cf source. It was found, in accordance with previous experiments, that the angular frequency distribution peaks at small angles and at angles around 180 degrees. A Monte Carlo, physics-based simulation program was created to simulate the distribution of angles between neutrons from the same fission event from 252Cf and 240Pu sources. The resulting distributions were clearly distinguishable from each other. The code was benchmarked to measured results from a 252Cf source at Lawrence Livermore National Laboratory. Knowledge of the unique angular distributions of coincident neutrons from various fissioning sources is useful for identification and verification purposes. Another practical application of angular anisotropy information for coincident neutrons from a given source is determining the ratio of the (alpha,n) to spontaneous fission rates for a source undergoing neutron coincidence counting. The utility of this was verified by using measurements made by faculty and students of the University of Michigan Nuclear Engineering Department for a MOX fuel pin at the Joint Research Center in Ispra, Italy. Good agreement between the predicted and declared values for alpha was found.

An algorithm for extracting event information from a Coulomb Explosion Imaging (CEI) position sensitive detector (PSD) is developed and compared with previously employed schemes. The PSD is calibrated using a newly designed grid overlay and validates the quality of the described algorithm. Precision calculations are performed to determine how best the CEI apparatus at The University of Waterloo can be improved. An algorithm for optimizing coincidence measurements of polyatomic molecules in CEI experiments is developed. Predictions of improved efficiency based on this algorithm are performed and compared with experiments using a triatomic molecule. Analysis of an OCS targeted CEI experiment using highly charged Argon ions to initiate ionization is performed. The resulting measurements are presented using a variety of visualization tools to reveal asynchronous and sequential fragmentation channels of OCS3+.

Salient contour detection is an important lowlevel visual process in the human visual system, and has significance towards understanding higher visual and cognitive processes. Salience detection can be investigated by examining the visual cortical response to visual input. Visual response activity in the early stages of visual processing can be approximated by a sequence of convolutions of the input scene with the difference-of-Gaussian (DoG) and the oriented Gabor filters. The filtered responses are unusually high for prominent edge locations in the image, and are uniformly similar across different natural image inputs. Furthermore, such a response follows a power law distribution. The aim of this thesis is to examine how these response properties could be utilized to the problem of salience detection. First, I identify a method to find the best threshold on the response activity (orientation energy) toward the detection of salient contours: compare the response distribution to a Gaussian distribution of equal variance. Second, I justify this comparison by providing an explanation under the framework of Suspicious Coincidence proposed by Barlow [1]. A connection is provided between perceived salience of contours and the neuronal goal of detecting suspiciousness, where salient contours are seen as affording suspicious coincidences by the visual system. Finally, the neural plausibility of such a salience detection mechanism is investigated, and the representational effciency is shown which could potentially explain why the human visual system can effortlessly detect salience.

<p>This thesis presents experimental studies of gas phasemolecular relaxation after excitation with synchrotron photonsin the 15-35 eV and in the 70-350 eV regions.</p><p>In the 15-35 eV region, molecular relaxation by neutraldissociation processes and non</p><p>Franck-Condon effects in N2 and O2 molecules have beenstudied by means of dispersed fluorescence and photoelectronspectroscopy experimental techniques, respectively. From thedispersed fluorescence data, excitation functions for themeasured atomic fluorescence spectra have been obtained. Fromthe recorded photoelectron spectra vibrational branching ratioshave been produced. The results obtained reveal that Rydbergseries and singly and doubly excited valence states of theappropriate symmetry energetically accessible in the studiedregion and interactions between themaccount for most of theobserved effects in these two type of experiments.</p><p>In the 70-350 eV range, molecular relaxation processesresulting in fragmentation of CD4 and SF6 after absorption ofsynchrotron light have been studied by energy resolved electronion coincidence technique using a multicoincidence experimentalstation developed by our group during the last five years forsuch type of experiments. The coincidence measurements yieldedmass spectra from which information about the kinematics of thedetected fragments has been deduced by means of Monte Carlosimulations of the experimental peak shapes. The obtainedresults show completely different dissociation patternsdepending on the molecular electronic states studied. Thesepatterns reflect the bonding properties of the excited orbitalsand they permit the description and in some cases theidentification of the different molecular relaxation pathwaysobserved. The achievements presented in this thesis exemplifythe potential of the multicoincidence station used in thereported experiments.</p>

This project aims to improve research in gamma-ray spectroscopy by using advanced detector systems. These systems are designed to reduce interference inherent in gamma-ray spectroscopy by rejecting Compton scattering events from high-energy gamma-rays, as well as look at cascading decays of gamma-rays through gamma-gamma coincidence counting. By combining these methods, one is able to lower detection limits for many elements than would otherwise be possible. This work also takes advantage of neutron activation analysis, which allows stable elements to be analyzed by activating them with neutrons, causing them to become unstable and decay with radioactive signatures. By analyzing these signatures, one is able to detect trace levels of elements with relatively small samples sizes (< 1g) and in a nondestructive manner. / text

The treaty verification field is of renewed importance as continued nuclear weapons disarmament is prioritized nationally in partnership with other nuclear weapons states. This interest has led to research and development on technologies that could support future U.S. verification missions. A technology employing pulses of high-energy photons from an electron linear accelerator is one technique under consideration. High-energy photons are advantageous as an interrogation source because they penetrate thick shielding and can generate neutrons inside a measurement object. The neutrons would then multiply when presented with an object containing fissile material and allow for detection in a time domain immediately after the pulse. The purpose of this work was to develop an understanding of neutron behavior following a high-energy photon pulse and then develop a tool set to analyze data from this region to determine if a measurement object contains multiplying material, the mass of that material if present, and the moderation in the measurement object. Results indicate the tool sets developed were able to determine multiplication was present accurately in 3 out of 4 realistic verification objects. Additionally the state of the moderation in each object was able to be determined, and the mass could potentially be determined by calibrating to representative samples.

This thesis is based on experimental results from measurements on methyl halides at a photon energy corresponding to the He IIβ emission line. Double ionization processes involving the valence electrons of the molecules CH3F, CH3Cl and CH3I are studied by means of a magnetic bottle TOF-PEPECO spectrometer. Resulting double ionization data of these molecules suggest that mainly direct double photoionization is observed as a continuous energy sharing between the ejected electron pairs. As a mean to further understand the double ionization processes, a "rule of thumb", for double ionization in molecules, is applied to the data presented in the double ionization spectra. This is done in order to quantify the effective distance between the two vacancies created in the dications. It is found that the distance between the vacancies may be related to the bond distance between the carbon and halogen atoms. Further investigations call for quantum chemical calculations to scrutinize this hypothesis. / Det här examensarbetet är baserat på experimentella fotojonisations studier av metyl halider vid en fotonenergi motsvarande He IIβ emissionslinjen. Valenselektronerna i dubbeljonisations processerna för CH3F, CH3Cl och CH3I har studerats under användning av en så-kallad magnetisk flask TOF-PEPECO spektrometer. Resultaten av dessa mätningar visar att mestadels direkt dubbeljonisation processer före- kommer, där elektronerna delar kontinuerligt på energin som friges vid jonisationen. Den dubbla jonisa- tions processen är ytterligare studerad genom att tillämpa en tumregel för dubbeljonisation i molekyler, vilket ger en indikation av hur stort avståndet är mellan de två vakanserna som skapades när molekylerna joniserade. Resultaten från tumregeln visar att avståndet mellan vakanserna kan vara relaterade till bind- ningsavståndet mellan kol-atomen och halogen-atomen, i respektive metyl halogen. För att ytterligare bekräfta dubbeljonisations processerna i dessa molekyler, krävs kvantmekaniska beräkningar.

An algorithm for extracting event information from a Coulomb Explosion Imaging (CEI) position sensitive detector (PSD) is developed and compared with previously employed schemes. The PSD is calibrated using a newly designed grid overlay and validates the quality of the described algorithm. Precision calculations are performed to determine how best the CEI apparatus at The University of Waterloo can be improved. An algorithm for optimizing coincidence measurements of polyatomic molecules in CEI experiments is developed. Predictions of improved efficiency based on this algorithm are performed and compared with experiments using a triatomic molecule. Analysis of an OCS targeted CEI experiment using highly charged Argon ions to initiate ionization is performed. The resulting measurements are presented using a variety of visualization tools to reveal asynchronous and sequential fragmentation channels of OCS3+.