Made available in DSpace on 2014-12-17T14:57:49Z (GMT). No. of bitstreams: 1 ReginaldoDS.pdf: 1111406 bytes, checksum: d55968c3491b3eb05981971626b26f4e (MD5) Previous issue date: 2008-07-28 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior / A housing unit was built to study the thermal performance, and of material using a composite made of gypsum and EPS ground. We used two techniques of construction, using blocks, and filling on the spot. Two compositions of the composite were studied. The blocks were fixed using conventional mortar. In the technical of filling on the spot were used PET bottles up inside the walls to provide mechanical and thermal resistance. Compression tests were realized according to the ABNT standard of sealing bricks. It is going to be shown an analysis of the thermal comfort through the use of thermocouples placed on the walls of the building, internally and externally. The manufacturing viability of houses, using recyclable materials, through the use of composite materials proposed will be demonstrated. The constructive aspects showing the advantages and disadvantages of the technique used also will be broached. The block used presents structural functions and thermal insulating, is low cost and represents an alternative to the use of EPS and PET bottles which are materials that end up occupying much space in the landfills, giving than an ecologically correct use. The results of thermal analysis shows the thermal comfort provided by the composite by the obtainment of a difference between the internal and external surfaces of the walls more exposed to the sun around 7? C. The average temperature of the air inside the building, around 28.0 ? C was below the zone of thermal comfort recommended for countries with hot weather / Foi constru?da uma unidade habitacional para estudo de desempenho t?rmico, e de materiais utilizando um comp?sito ? base de gesso e EPS triturado. Foram utilizadas duas t?cnicas de constru??o, usando blocos, e enchimento in loco. Duas composi??es do comp?sito foram estudadas. Os blocos foram assentados utilizando argamassa convencional. Na t?cnica do enchimento in loco utilizou-se garrafas PET no interior das paredes para proporcionar resist?ncias t?rmica e mec?nica. Foram realizados ensaios de compress?o m?nima segundo as normas da ABNT para blocos de veda??o. Foi realizada uma an?lise de conforto t?rmico, atrav?s do uso de termopares colocados nas paredes da edifica??o, interna e externamente. Demonstrar-se-? as viabilidades de fabrica??o de casas, utilizando materiais recicl?veis, atrav?s do uso do material comp?sito proposto. Abordar-se-? tamb?m os aspectos construtivos mostrando as vantagens e desvantagens da t?cnica utilizada. O bloco utilizado apresenta fun??es estruturais e de isolante t?rmico, tem baixo custo e representa uma alternativa para o aproveitamento do EPS e garrafas PET que s?o materiais que acabam ocupando muito espa?o nos aterros sanit?rios, dando-lhe um fim ecologicamente correto. Os resultados da an?lise t?rmica demonstram o conforto t?rmico proporcionado pelo comp?sito pela obten??o de uma diferen?a de temperatura entre as superf?cies interna e externa das paredes mais expostas ao sol em torno de 7? C. A temperatura m?dia do ar no interior da edifica??o, em torno de 28,0? C ficou dentro da zona de conforto t?rmico recomendada para pa?ses de clima quente

Made available in DSpace on 2014-12-17T14:57:51Z (GMT). No. of bitstreams: 1 MarcoASR_TESE.pdf: 5586767 bytes, checksum: d92d904a4f89177a814a13f5f7230b94 (MD5) Previous issue date: 2011-07-11 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior / In this study were conducted experimental procedures for determination of variation of the expandability of rigid polyurethane foam (PUR) from a natural oil polyol (NOP), specifically the Castor oil plant, Ricinus communis, pure and additions of the vermiculite in phase dispersed in different percentage within a range from 0% to 20%, mass replacement. From the information acquired, were defined the parameters for production of bodies of test, plates obtained through controlled expansion, with the final volume fixed. Initially, the plates were subjected to thermal performance tests and evaluated the temperature profiles, to later be extracted samples duly prepared in accordance with the conditions required for each test. Was proceeded then the measurement of the coefficient of thermal conductivity, volumetric capacity heat and thermal diffusivity. The findings values were compared with the results obtained in the tests of thermal performance, contributing to validation of the same. Ultimately, it was investigated the influence that changes in physical-chemical structure of the material had exerted on the variation of thermophysical quantities through gas pycnometry, scanning electron microscopy (SEM) combined with energy dispersive X-ray fluorescence spectroscopy (EDXRF), infrared spectroscopy using Fourier transform (FTIR), thermogravimetric analysis (TGA) and differential thermal analysis (DTA). Based on the results obtained was possible to demonstrate that all load percentage analyzed promoted an increase in the potential expansion (PE) of the resin. In production of the plates, the composites with density near at the free expansion presented high contraction during the cure, being the of higher density adopted as definitive standard. In the thermal performance tests, the heating and cooling curves of the different composites had presented symmetry and values very close for lines of the temperature. The results obtained for the thermophysical properties of composites, showed little difference in respect of pure foam. The percentage of open pores and irregularities in the morphology of the composites were proportionate to the increment of vermiculite. In the interaction between the matrix and dispersed phase, there were no chemical transformations in the region of interface and new compounds were not generated. The composites of PUR-NOP and vermiculite presented thermal insulating properties near the foam pure and percentage significantly less plastic in its composition, to the formulation with 10% of load / Neste estudo, foram realizados procedimentos experimentais para determina??o da varia??o da expansibilidade da espuma r?gida de poliuretano (PUR) de um poliol de ?leo natural (NOP), especificamente o de mamona, Ricinus communis, puro e acrescido de vermiculita na fase dispersa, em distintos percentuais, dentro de uma faixa de 0% a 20%, de substitui??o em massa. A partir das informa??es adquiridas, foram definidos os par?metros para produ??o dos corpos de prova, placas obtidas atrav?s de expans?o controlada, com volume final fixo. Inicialmente, as placas foram submetidas a testes de desempenho t?rmico, sendo avaliados os perfis de temperatura, para posteriormente serem extra?das amostras, devidamente preparadas conforme as condi??es exigidas para cada ensaio. Procedeu-se ent?o a medi??o do coeficiente de condutividade t?rmica, capacidade t?rmica volum?trica e difusividade t?rmica. Os valores encontrados foram comparados com os resultados obtidos nos testes de desempenho t?rmico, contribuindo para valida??o dos mesmos. Por fim, foi investigada a influ?ncia que as altera??es na estrutura f?sico-qu?mica do material, exerceram sobre a varia??o das grandezas termof?sicas, por meio de picnometria a g?s, microscopia eletr?nica de varredura (MEV) combinada com espectroscopia de fluoresc?ncia de raios-X por energia dispersiva (EDXRF), espectroscopia de infravermelho com transformada de Fourier (FTIR), an?lise termogravim?trica (TGA) e an?lise t?rmica diferencial (DTA). Com base nos resultados obtidos foi poss?vel demonstrar que todos os percentuais de carga analisados promoveram um aumento do potencial de expans?o (PE) da resina. Na produ??o das placas, os comp?sitos com densidade pr?xima ? expans?o livre apresentaram grande contra??o na cura, sendo adotados os de maior densidade como padr?o definitivo. Nos ensaios de desempenho t?rmico, as curvas de aquecimento e resfriamento dos diferentes comp?sitos apresentaram simetria e valores muito pr?ximos para as linhas de temperatura. Os resultados obtidos para as propriedades termof?sicas dos comp?sitos, demonstraram pouca diferen?a em rela??o aos da espuma pura. O percentual de poros abertos e irregularidades na morfologia dos comp?sitos foram proporcionais ao incremento da vermiculita. Na intera??o entre matriz e fase dispersa n?o ocorreram transforma??es qu?micas na regi?o de interface e n?o foram gerados novos compostos. Os comp?sitos de PUR-NOP e vermiculita apresentaram propriedades isolantes t?rmicas pr?ximas as da espuma pura e percentual significativamente menor de pl?stico em sua composi??o, para a formula??o com 10% de carga

Made available in DSpace on 2014-12-17T14:58:14Z (GMT). No. of bitstreams: 1 SayonaraMR_DISSERT.pdf: 4952879 bytes, checksum: ae4330b4ec27931c6779586f70b9d134 (MD5) Previous issue date: 2012-05-09 / With a view to revitalizing public environments through criteria that include economy, tourism, aesthetics and respect for the environment, this paper proposes a model of kiosk manufactured with composite material blocks, to be employed as a public instrument. . The model consists of a structure composed of planned blocks and manufactured in cement-based composite, gypsum, ground and water, having the styrofoam inside filled with pet bottles of 500 ml dose. The social and environmental issue is the critical point of the work when it can, through the reuse of environmentally harmful materials such as polyethylene terephthalate PET, using such modules for the construction of various areas of Commerce, promoting the protection of the environment combined with the improvement of the quality of life of the population. The tourism factor, which is significant in the economy of the North, is also considered as the modulated kiosk has a visual aspect innovative and differentiated. The environmental issue is addressed by encouraging the reuse of PET material and EPS (polystyrene) / Apresenta-se um bloco fabricado em comp?sito ? base de cimento, gesso, isopor triturado, raspa de pneu e ?gua, tendo seu interior preenchido com doze garrafas pet de 500 ml, destinados ? constru??o de um quiosque. Foi confeccionada uma forma em madeira que permitiu a fabrica??o de cinco blocos por vez com as dimens?es: L = 800 mm, H = 260 mm e B = 100 mm. No interior dos blocos podem ser colocados v?rios tipos de materiais, dentre eles: garrafas pet, latas de cerveja e/ou refrigerante, placas de isopor, etc. O comp?sito tamb?m pode ser formulado para v?rias propor??es de misturae pode ser utilizado para a constru??o de alvenarias para casas populares, quiosques, divis?rias e at? para m?veis fixos planejados. Foram realizados testes de resist?ncia ? compress?o para v?rias formula??es do comp?sito que atendeu ? norma espec?fica para blocos utilizados na constru??o civil. Foi tamb?m avaliada a condutividade t?rmica do comp?sito para posterior estudo de conforto t?rmico gerado em uma alvenaria constru?da com o comp?sito proposto. Os testes de conforto t?rmico foram realizados num espa?o constru?do na Escola Estadual Raimundo Soares, transformado em Espa?o Ci?ncia dessa escola. Foi tamb?m constru?do um quiosque modulado que contempla economia, est?tica e respeito ao meio ambiente

Made available in DSpace on 2014-12-17T14:58:14Z (GMT). No. of bitstreams: 1 JoseOO_DISSERT.pdf: 1240113 bytes, checksum: dbf41a478040a880c57e2dbf04e10cda (MD5) Previous issue date: 2012-03-30 / The objective of this research is the fabrication of a composite reinforced with dyed sisal fiber and polyester matrix for application in the fields such as, fashion, clothing, interior textiles; fashion accessories are some of the examples. For the fabrication of the composite, the sisal fibers were subjected to processes such as: chemical treatment with sodium hydroxide (NaOH) in the removal of impurities; bleaching for removing the yellowish color of the natural fiber and dyeing with direct dyes to confer the colors blue, green and orange. The search for new technologies ecologically correct has become a major concern in recent decades. Studies show that composite polymer reinforced by natural fibers is suitable for a large number of applications, and its use is advantageous in terms of economic and ecological. The dyed fibers were cut to a length of 30 mm, is used in the confection of webs. For this purpose, a web preparer by immersion, developed in the Laboratory of Chemical Textile of UFRN. The composite sheets measuring 300 x 300 x3 mm were molded by compression, with unsaturated orthophthalic polyester as matrix, and the samples in sizes 150 x 25 x 3 mm were cut with the aid of a laser machine, to be subjected to traction and flexion. The mechanical properties of traction and flexion in three points were performed in the Laboratory of metal and mechanical tests of Materials Engineering of UFRN. The resulting samples from the tests were evaluated in scanning electron microscope (SEM) at CTGas RN. On the basis of the analysis of the results from the mechanical tests, it was observed that the composite had good mechanical behavior, both in traction as in flexion. Furthermore, it was observed that in the water absorption test, the samples had a different percentage among themselves, this occurred due to the variation of density found in the fibre webs. The images of the SEM showed the failures from the manufacturing process and the adhesion of fibre/matrix. When the samples were prepared with the dyed fibers to be applied in fashion, the results were positive, and it can be concluded that the main objective of this work was achieved / A busca por novas tecnologias ecologicamente corretas tem se tornado uma grande preocupa??o nas ?ltimas d?cadas. Estudos comprovam que comp?sitos polim?ricos refor?ados por fibras naturais s?o adequadas a um grande n?mero de aplica??es e seu uso ? vantajoso em termos econ?micos e ecol?gicos. O objetivo desta pesquisa ? a fabrica??o de um comp?sito refor?ado com fibra de sisal tingida e matriz de poli?ster para aplica??o na moda: vestu?rio, t?xteis lar, acess?rios de moda etc. Para o seu beneficiamento, as fibras de sisal foram submetidas aos diversos processos: tratamento qu?mico com hidr?xido de s?dio (NaOH) na retirada das impurezas; alvejamento para remo??o da cor amarelada natural da fibra e tingimento com corantes diretos para conferir as cores azul, verde e alaranjado. As fibras tingidas foram cortadas com comprimento de 30 mm e utilizadas na confec??o das mantas. Para isso utilizou-se um preparador de manta por imers?o, desenvolvido no Laborat?rio de Qu?mico T?xtil da UFRN. Os comp?sitos medindo 300 x 300 x 3 mm foram moldados por compress?o, com poli?ster insaturado ortoft?lico como matriz, e as amostras nos tamanhos 150 x25 x3 mm foram cortadas com aux?lio de uma m?quina ? laser, para serem submetidas ? an?lise mec?nica de tra??o e flex?o. As propriedades mec?nicas de tra??o e flex?o em tr?s pontos foram realizadas no Laborat?rio de Metais e Ensaios Mec?nicos de Engenharia de Materiais da UFRN. As amostras resultantes das propriedades mec?nicas foram avaliadas no Microscopio Eletronico de Varredura (MEV) no CTG?s RN. Com base nas an?lises dos resultados dos ensaios mec?nicos, observou-se que os compositos tiveram bom comportamento mec?nico, tanto na tra??o como na flex?o. Tamb?m observou-se que no ensaio de absor??o de ?gua, as amostras tiveram um percentual diferente entre si, isso ocorreu devido ? varia??o da densidade encontrada nas mantas. As imagens do MEV mostraram as falhas provenientes do processo de fabrica??o e a ades?o fibra/matriz. Quando foram preparadas as amostras com as fibras tingidas para serem aplicadas na moda, os resultados foram positivos e pode-se concluir que o objetivo principal do presente trabalho foi atingido

Made available in DSpace on 2014-12-17T14:58:15Z (GMT). No. of bitstreams: 1 JoseJBS_DISSERT.pdf: 2506780 bytes, checksum: d6a8e17babc22c04b62e29971d6d4c29 (MD5) Previous issue date: 2011-06-06 / It presents a new type of insulation for ductwork hot water, which can be used in solar systems for heating water, which consists of a composite of different compositions based on plaster, cement and EPS ground, palm and water. This composite has as its main features easy assembly and manufacturing processes and low cost. Comparative results will be presented on the tests of materials and thermal tubes proposed. Four formulations were used to manufacture tubes with three diameters 70, 65 and 42mm. It was also tested conventionally used for elastomeric foam insulation to 110 ? C, for a comparative analysis with the composite pipe insulator proposed. It will demonstrate that the cost of manufacturing of such tubes is competitive with alternative elastomeric foam tested, but results of the composite tube to the temperature range studied, are lower. Another drawback of the composite insulator tube is its large mass. It would be important to test such a composite for greater levels of temperature to a diagnostic technique competitive with conventionally used insulators. A positive factor of using the proposed composite-tube would be the recycling of EPS so damaging to the environment, representing an environmentally friendly application of science / Apresenta-se um novo tipo de isolamento t?rmico para tubos condutores de ?gua quente, que pode ser utilizado em sistemas solares para aquecimento de ?gua, que consiste de um comp?sito, de diferentes formula??es, ? base de gesso, cimento , EPS triturado, dend? e ?gua. Tal comp?sito tem como principais caracter?sticas seus f?ceis processos de fabrica??o e montagem de baixo custo. Ser?o apresentados resultados comparativos relativos aos ensaios t?rmicos e de materiais dos tubos propostos. Foram utilizadas quatro formula??es para a fabrica??o dos tubos, com tr?s di?metros 70, 65 e 42mm. Foi tamb?m testada a espuma elastom?rica convencionalmente utilizada para isolamento t?rmico at? 110?C, para uma an?lise comparativa com o tubo comp?sito isolante t?rmico proposto. Demonstrar-se-? que o custo de fabrica??o de tais tubos alternativos ? competitivo com a espuma elastom?rica ensaiada, por?m os resultados do teste de resist?ncia t?rmica do tubo comp?sito, para a faixa de temperatura analisada, s?o inferiores. Um fator positivo da utiliza??o do tubo-comp?sito proposto seria a reciclagem do EPS t?o danoso ao ambiente, representando uma aplica??o cient?fica ambientalmente correta

Made available in DSpace on 2014-12-17T14:58:21Z (GMT). No. of bitstreams: 1 ElisangelaBNH_DISSERT.pdf: 5500408 bytes, checksum: 312e914c2b5560a38c07ef6f6b3c70be (MD5) Previous issue date: 2013-01-14 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior / The composites manufactured with long fibres aligned in a single direction, and overlay has been shown to have better performance than the short fibers randomly distributed. In particular, the lignocellulosic fibers extracted from the sisal leaves, used in conjunction with the epoxy resin has attracted the attention of many researchers because the final properties of the system formed. In this work composites based on epoxy resin reinforced with sisal fibers were manufactured. The sisal fibres were treated with an alkaline solution of 0.06 mol/l NaOH. The treated, and untreated fibres were subjected to tension x extension tests. The composites were manufactured in the "Lossy" mold with the specifications of the samples to be produced (300x20x4 mm). The tension tests were carried out in accordance with the ASTM standards 3039 (for the composite aligned in a single direction) and ASTM D5573 (for composites in overlay), three point bending tests were performed according to ASTM D790. Analyzing the results of the tests of tension and three point bending tests, it was observed that the composites with the configuration of overlapping had the better elastic module in both tests. As to the maximum resistance to tension, the best result was the composites aligned in a single direction. Tests of absorption of water and micrographs are in progress / Os comp?sitos fabricados com fibras longas alinhadas unidirecionalmente e em sobreposi??o tem demonstrado que possuem melhor desempenho do que as fibras cortadas aleatoriamente distribu?das. Em especial, as fibras lignocelul?sicas extra?das do sisal, utilizadas em conjunto com a resina ep?xi tem atra?do a aten??o de muitos pesquisadores devido ?s propriedades finais do sistema formado. No presente trabalho foram fabricados comp?sitos ? base de resina ep?xi refor?ado com fibras de sisal. As fibras de sisal foram submetidas ao tratamento alcalino com NaOH a 0,06 mol/l, em seguida submetidas ao ensaio de tra??o na fibra tratada e n?o tratada. Os comp?sitos foram fabricados no molde denominado de Lossy (molde com perdas) usinado de acordo com as especifica??es das amostras a serem produzidas (300x20x4 mm). Os ensaios de tra??o foram realizados de acordo com as normas ASTM 3039 (Para os comp?sitos alinhados unidirecionalmente) e ASTM D5573 (Para os comp?sitos em sobreposi??o), os ensaios de flex?o em tr?s pontos foram realizados de acordo com as normas ASTM D 790. Analisando os resultados dos ensaios de tra??o e flex?o em tr?s pontos, foram observados que os comp?sitos com a configura??o de sobreposi??o teve melhor m?dulo de elasticidade em ambos os ensaios. Quanto a resist?ncia m?xima a tra??o o melhor resultado foi do comp?sito alinhado unidirecionalmente. No ensaio de absor??o de ?gua foi observado que os comp?sitos possuem um n?vel muito baixo de absor??o e o comp?sito alinhado unidirecionalmente obteve percentual de satura??o de 1,97 %. Nas micrografias, se observa as regi?es de ruptura/trincas do comp?sito e seu comportamento (fibra/matriz)

Submitted by Automa??o e Estat?stica (sst@bczm.ufrn.br) on 2018-01-23T14:20:40Z No. of bitstreams: 1 ZulmarJofliDosSantosJunior_TESE.pdf: 3964236 bytes, checksum: 3b3bfc71a2c718ffc333877fed25c592 (MD5) / Approved for entry into archive by Arlan Eloi Leite Silva (eloihistoriador@yahoo.com.br) on 2018-01-25T11:00:02Z (GMT) No. of bitstreams: 1 ZulmarJofliDosSantosJunior_TESE.pdf: 3964236 bytes, checksum: 3b3bfc71a2c718ffc333877fed25c592 (MD5) / Made available in DSpace on 2018-01-25T11:00:03Z (GMT). No. of bitstreams: 1 ZulmarJofliDosSantosJunior_TESE.pdf: 3964236 bytes, checksum: 3b3bfc71a2c718ffc333877fed25c592 (MD5) Previous issue date: 2017-08-31 / As quest?es ambientais v?m provocando discuss?es entre v?rios atores sociais compostos por grupos de ativistas, ambientalistas, pol?ticos, cientistas, pesquisadores, discentes, institui??es p?blicas e privadas. Dentro deste universo o presente trabalho prop?ese a obter e caracterizar um comp?sito de matriz de resina Poli?ster Ortoft?lica com carga de refor?o/ enchimento de fibra vegetal da esp?cie Agave Angustifolia Haw na propor??o de 5%, 7,5% e 10% em massa em rela??o ? matriz. Foram fabricadas mantas de fibra da agave para tr?s formula??es e, para a obten??o do comp?sito, utilizou-se o processo de prensagem a frio. As mantas de agave, intercaladas com a resina, foram colocadas no molde com orienta??es defasadas de 90? entre as mesmas e pesando 5g cada. Os corpos de prova das formula??es dos comp?sitos foram fabricados em molde fechado, baseados em normas espec?ficas e foram submetidos a ciclos de ensaios mec?nicos, t?rmicos, f?sicos e qu?micos. Sendo determinadas as resist?ncias mec?nicas a tra??o, flex?o, impacto, propriedades termof?sicas, a densidade, a absor??o de ?gua doce e salgada, e a composi??o qu?mica atrav?s da Espectrometria de Fluoresc?ncia de Raios X (FRX). Provou-se a viabilidade de obten??o do comp?sito para todas as formula??es estudadas. A formula??o mecanicamente mais vi?vel foi a de 10% de fibra de Agave Angustifolia Haw. Todas as formula??es apresentaram resist?ncias mec?nicas ? tra??o e ao impacto superiores ? da resina matriz, traduzindo uma fun??o de carga de refor?o da fibra de Agave utilizada. As fibras comportaram-se como carga de enchimento quando todas as suas formula??es apresentaram resist?ncias mec?nicas a flex?o inferior ? da resina matriz. / Environmental issues have raised discussions among several social agents such as activists, ambietalists, politicians, scientists, professors and both private and public institutions. Within this scope, this paper aims to develop and carachterize an Orthophthalic Polyester resin matrix composite with reinforcing / filling load of vegetable fiber of the species Agave Angustifolia Haw in the proportion of 5%, 7.5% and 10% in mass comparing to the matrix. Agave fiber blankets were made for three formulations and, to obtain the composite, the cold pressing process was used. The agave blankets, intercalated with the resin, were placed in the template with 90? lagged orientations between them and weighing 5g each. The test specimens of the composite formulations were fabricated in a closed mould, based on specific standards and subjected to mechanical, thermal, physical and chemical test cycles. The tensile strength, flexural strength, impact, thermophysical properties, density, freshwater and saltwater absorption, and chemical composition are determined by X-Ray Fluorescence Spectrometry (FRX). The feasibility of obtaining the composite was tested for all formulations studied. The mechanically most viable formulation was the one composed by 10% Agave Angustifolia Haw fiber. All the formulations had higher tensile and impact strength than the matrix resin, leading to a reinforcing load function of the Agave fiber used. The fibers behaved as fillers when all of their formulations presented mechanical strength at lower flexion than the matrix resin.

Submitted by Automa??o e Estat?stica (sst@bczm.ufrn.br) on 2017-01-12T14:20:00Z No. of bitstreams: 1 RodolfoAlbuquerqueBuarqueDeAssuncao_DISSERT.pdf: 3341925 bytes, checksum: 95332904ffdde1cc83db64f825ee63fe (MD5) / Approved for entry into archive by Arlan Eloi Leite Silva (eloihistoriador@yahoo.com.br) on 2017-01-18T14:22:16Z (GMT) No. of bitstreams: 1 RodolfoAlbuquerqueBuarqueDeAssuncao_DISSERT.pdf: 3341925 bytes, checksum: 95332904ffdde1cc83db64f825ee63fe (MD5) / Made available in DSpace on 2017-01-18T14:22:16Z (GMT). No. of bitstreams: 1 RodolfoAlbuquerqueBuarqueDeAssuncao_DISSERT.pdf: 3341925 bytes, checksum: 95332904ffdde1cc83db64f825ee63fe (MD5) Previous issue date: 2016-06-30 / O comp?sito Mo-Cu ? muito usado como material para contatos el?tricos e dissipadores de calor devido ?s excelentes propriedades do cobre de condutividade t?rmica e el?trica e boa trabalhabilidade, aliada ? alta resist?ncia a solda e eros?o por arco el?trico do molibd?nio. No primeiro caso, formas bastante simples s?o exigidas e a infiltra??o de cobre l?quido em um esqueleto de molibd?nio pr?-sinterizado ? a t?cnica de consolida??o normalmente utilizada. Diferentemente, geometrias mais complexas e densidades iguais ou pr?ximas da te?rica s?o necess?rias para aplica??o como dissipadores de calor. A metalurgia do p? atrav?s das t?cnicas de prepara??o de p?s com processamento por moagem de alta energia, compacta??o ou moldagem de p? por inje??o e sinteriza??o ? uma rota bastante vi?vel para produ??o desses componentes. Entretanto, a baixa solubilidade entre cobre e molibd?nio dificulta a obten??o de densidade igual ou pr?xima da densidade te?rica. Este trabalho investiga a obten??o do comp?sito Mo-27,82%?Cu preparado por moagem de alta energia e mistura mec?nica dos p?s de cobre e heptamolibdato de am?nio (HMA) de f?rmula qu?mica (NH4)6Mo7O24 .4H2O, decomposto e reduzido por H2, antes e durante a sinteriza??o, evidenciando duas rotas de fabrica??o diferentes para o material. A influ?ncia da press?o de compacta??o na densifica??o e microestrutura do comp?sito Mo-27,82%?Cu tamb?m foi investigada. Para isto, os p?s mo?dos por 50 horas foram prensados a 200, 400 e 600 MPa. Para se entender o efeito da temperatura na densidade e microestrutura do comp?sito Mo-27,82%?Cu, amostras foram sinterizadas a 1000, 1100 e 1200 oC. Os corpos prensados a 200 e 400 MPa e sinterizados a 1200 oC alcan?aram a maior densidade entre as amostras produzidas, no valor de 94?0,4 % da densidade te?rica. Por?m, aqueles que foram decompostos e reduzidos durante a sinteriza??o apresentaram trincas de fabrica??o. J? os corpos sinterizados a 1100 oC atingiram o maior valor de microdureza (571,70?78,82 HV), apesar de uma baixa densidade em rela??o a te?rica (79,17?1,78%). / The Mo-Cu composite is a material used for electrical contact and heat sinks due its excellent properties of thermal and electrical conductivity and cooper good workability allied to its great resistance welding and electrical arc erosion of molybdenum. In the first case, simple shapes are required and the infiltration of the pre-sintered molybdenum skeleton with liquid copper is the technique of consolidation normally used. On the second case, more complex geometries and a density near or equal the theoretical density are required for the application as heat sink. The powder metallurgy is a very viable route for the production of these components, through the techniques of powder preparation processed by mechanical alloying, compaction or casting. However, the low dissolution of one component in the other and the liquid copper high contact angle on the molybdenum phase difficult the obtainment of a density near or equal the theoretical density. This research investigates the obtainment of the Mo-27,82%?Cu composite prepared by mechanical alloying and mechanical mix of the copper powders and ammonium heptamolybdate (HMA) of chemical formula (NH4)6Mo7O24 .4H2O, decomposed and reduced by ?2 before and during the sintering, showing two different fabrication routes for the material. The compaction pressure influence at the densification and microstructure of the Mo-27,82%?Cu composite were also investigated. For this, the powder milled for 50 hours and the mixed powder were pressed at 200, 400 and 600 MPa. In order to understand the temperature effect at the density and microstructure were sintered at 1000, 1100 and 1200 ?C. The bodies pressed at 200 and 400 MPa and sintered at 1200?C reached 94?0,4 % of the theoretical density. However, those which were decomposed and reduced during sintering showed manufacturing cracks. On the other hand, the bodies sintered at 1100 ?C reached the highest microhardness value (571,70?78,82 HV), despite a low theory density (79.17 ? 1.78%).

Submitted by Automa??o e Estat?stica (sst@bczm.ufrn.br) on 2017-02-02T11:57:41Z No. of bitstreams: 1 MarcellaJordannaSilvaMontorilAraujo_DISSERT.pdf: 3443985 bytes, checksum: 367c6ae398c4c1ef8054fbb595d56752 (MD5) / Approved for entry into archive by Arlan Eloi Leite Silva (eloihistoriador@yahoo.com.br) on 2017-02-06T20:29:13Z (GMT) No. of bitstreams: 1 MarcellaJordannaSilvaMontorilAraujo_DISSERT.pdf: 3443985 bytes, checksum: 367c6ae398c4c1ef8054fbb595d56752 (MD5) / Made available in DSpace on 2017-02-06T20:29:13Z (GMT). No. of bitstreams: 1 MarcellaJordannaSilvaMontorilAraujo_DISSERT.pdf: 3443985 bytes, checksum: 367c6ae398c4c1ef8054fbb595d56752 (MD5) Previous issue date: 2016-07-25 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior (CAPES) / A ind?stria t?xtil gera um grande volume de efluentes que, muitas vezes, s?o descartados no meio ambiente sem estarem devidamente tratados. Esses efluentes s?o formados de mol?culas org?nicas e caracterizam-se por apresentar cor, que alteram as propriedades da ?gua deixando-a impr?pria para o consumo. Para o tratamento desses efluentes, a utiliza??o de processos catal?ticos heterog?neos de custo baixo pode ser vantajoso. As argilas v?m sendo bastante estudadas como suportes catal?ticos em raz?o de sua abund?ncia na crosta terrestre e seu baixo custo. Portanto, neste trabalho as argilas vermiculita e bentonita foram usadas como suporte para o catalisador oxihidr?xido de ni?bio e pelo m?todo de deposi??o-precipita??o foram obtidos comp?sitos formados por esses materiais. Os comp?sitos Nb/argila foram caracterizados e as principais t?cnicas mostraram que ocorreu uma modifica??o em cada argila. Os resultados de difratrometria de raios X (DRX) indicaram que ocorreu uma diminui??o da intensidade da reflex?o e um deslocamento do pico principal de ambas as argilas quando o oxihidr?xido de ni?bio ? adicionado na estrutura. As an?lises de espectroscopia na regi?o do infravermelho mostram bandas de adsor??o de ambos os materiais nos comp?sitos Nb/argila, dando a indicativa de que o comp?sito foi realmente formado. As imagens de microscopia eletr?nica de varredura tamb?m confirmaram essa modifica??o de estrutura. Foram realizados testes de oxida??o e oxida??o fotocatal?tica com os comp?sitos obtidos e o teste de oxida??o fotocatal?tica foi o que apresentou melhores resultados, pois o comp?sito de vermiculita (Nb/V0) apresentou uma maior atividade fotocatal?tica removendo 98% da cor do corante alaranjado de metila em 90 minutos de rea??o enquanto que o material comp?sito de bentonita (Nb/B0) removeu apenas 63% durante o mesmo tempo de rea??o. Essa atividade ? devido o comp?sito Nb/V0 ter apresentado um menor valor de band gap (3,08eV) que o comp?sito Nb/B0 (3,33eV). / The textile industry produces a large volume of waste that often is discarded into the environment without being properly treated. These effluents are made of organic molecules and are characterized by their color that alter the properties of water which leave it unfit for consumption. For the treatment of these effluents, the use of heterogeneous catalytic processes of low cost can be advantageous. Clays have been widely studied as catalyst supports because of their abundance in the Earth's crust and its low cost. Therefore, in this study the clays vermiculite and bentonite were used as support for the catalyst oxyhydroxide niobium and by the method of deposition-precipitation it was obtained composites formed from these materials. The composite Nb/clay were characterized and the main techniques showed that was changes in each clay. The results X-ray diffractometer (XRD) showed that there was a decrease in reflection intensity and a shift of the main peak of both clays when oxyhydroxide niobium is added to the structure. The spectroscopic analyzes show infrared adsorption bands of in both materials composite Nb/clay which indicates that the composite was actually formed. The scanning electron microscopy images also confirmed that structure modification. Oxidation and photocatalytic oxidation tests were performed with the obtained composite and photocatalytic oxidation test showed the best results, because the vermiculite composite (Nb/V0) showed higher photocatalytic activity by removing 98% of the color orange dye methyl in 90 minutes of reaction while the composite material of bentonite (Nb/B0) removed only 63% over the same reaction time. This activity is due to the composite Nb/V0 have presented a smaller value of band gap (3,08eV) than the composite Nb/B0 (3,33eV).

Submitted by Automa??o e Estat?stica (sst@bczm.ufrn.br) on 2017-02-02T12:02:51Z No. of bitstreams: 1 AldoPaulinoDeMedeirosJunior_DISSERT.pdf: 2830589 bytes, checksum: e838c6a3026b5cd9757588fa10c784cf (MD5) / Approved for entry into archive by Arlan Eloi Leite Silva (eloihistoriador@yahoo.com.br) on 2017-02-06T21:02:12Z (GMT) No. of bitstreams: 1 AldoPaulinoDeMedeirosJunior_DISSERT.pdf: 2830589 bytes, checksum: e838c6a3026b5cd9757588fa10c784cf (MD5) / Made available in DSpace on 2017-02-06T21:02:12Z (GMT). No. of bitstreams: 1 AldoPaulinoDeMedeirosJunior_DISSERT.pdf: 2830589 bytes, checksum: e838c6a3026b5cd9757588fa10c784cf (MD5) Previous issue date: 2016-10-10 / A utiliza??o de materiais comp?sitos tem sido tema de in?meros trabalhos cient?ficos no Brasil e no mundo. A energia solar ? a fonte energ?tica prim?ria e representa a op??o mais ecologicamente vi?vel e a mais social de todas as fontes energ?ticas. Fabricou-se e estudou-se a capacidades e viabilidade de cozimento de um fog?o solar ? concentra??o multifocal com par?bolas refletoras fabricadas em material comp?sito destinado ao cozimento de alimento para fins residenciais, urbanos e rurais. Foi constitu?do de quatro par?bolas fabricadas com materiais comp?sitos, formados por resina ortoft?lica adicionados aos elementos: cortina de tecido, tecido de malha, saco de algod?o e saco de aniagem (juta). A principal caracter?stica do fog?o solar proposto foi a capacidade de coc??o de quatro alimentos simultaneamente, que lhe deu um car?ter de ineditismo tecnol?gico na coc??o de alimentos. Ser?o apresentados os processos de fabrica??o e montagem. A estrutura do fog?o tenha mobilidade de movimento aparente do sol. Representa uma op??o ecol?gica, limpa e renov?vel j? que ? uma alternativa para o uso em larga escala da lenha para o cozimento de alimentos, sendo um grande ajuda para as popula??es menos favorecidas economicamente que n?o param de crescer. Foram demonstradas as viabilidades t?rmicas e econ?micas do fog?o solar proposto para obten??o do cozimento de alimentos. Para demonstrar a viabilidade de utiliza??o do fog?o solar proposto foram cozidos v?rios alimentos da comida t?pica nordestina. Foi comprovada sua capacidade de produzir a coc??o de alimentos de uma refei??o t?pica, arroz, feij?o, macarr?o e carne em apenas uma hora. / The use of composite materials has been the subject of numerous scientific papers in Brazil and worldwide. Solar energy is the primary energy source and the option is more environmentally sustainable and more social of all energy sources. It is manufactured and studied the capabilities and baking feasibility of a solar cooker will multifocal concentration with reflective parabolas made of composite material for the cooking food for residential, urban and rural purposes. It consisted of four parabolas made of composite materials, formed by orthophthalic resin added to the elements: curtain fabric, knitted fabric, cotton bag, burlap sack (jute). The main feature of the proposed solar stove was cooking capacity of four foods simultaneously, which gave him a technological novelty character in cooking. The manufacturing and assembly processes will be presented. The solar cook structure has mobility apparent movement of the sun. It is an environmentally friendly, clean, renewable option since it is an alternative to the large-scale use of firewood for cooking food, and a great help to the disadvantaged populations that do not stop growing. Thermal and economic feasibility of solar cooker proposed for obtaining cooking and baking food have been demonstrated. To demonstrate the feasibility of using solar cooker proposed were cooked various foods of Northeastern typical food. It has proven its ability to produce the cooking of food in a typical meal, rice, beans, pasta and meat in just one hour.