The reactions of organomagnesium akoxides EtMgOR (R= Me, Et) with dialkynyl magnesium complexes Mg(CoCR¢F) (R¢F= tBu, SiMe3) give a series of the tetranuclear magnesium complexes [Mg4(OR)2Et2(CoCR¢F)4(THF)4] (R= Me, Et; R¢F= tBu, SiMe3). The reactions of diethyl magnesium complexes MgEt2 with alkynes HCoCR (R= tBu, SiMe3) give two different kinds magnesium complexes. One kind is [Mg4(OEt)2-Et2(CoCR)4(THF)4] (R= tBu, SiMe3); another kind is [Mg4O(CoCR)6(THF)4] (R= tBu, SiMe3). Besides, the reaction of diisopropylamide magnesium complex Mg(NiPr2)2 with alkyne HCoCtBu give first example including two different kind bridge ligands trinuclear magnesium complex Mg3(NiPr2)2(CoCtBu)4(THF)2.

Due to the high electron mobility compared with Si, much attention has been focused on III-V compound semiconductors (gallium arsenide (GaAs) and indium phosphide (InP)) high-speed devices. The high-k material TiO2 not only has high dielectric constant (k = 35-100) but has well lattice match with GaAs and InP substrate. Therefore, titanium oxide (TiO2) was chosen to be the gate oxide in this study. The major problem of III-V compound semiconductors is known to have poor native oxide on it and leading to the Fermi level pinning at the interface of oxide and semiconductor. The C-V stretch-out phenomenon can be observed and the leakage current is high. The higher dielectric constant of poly-crystalline TiO2 film grown on GaAs can be obtained by metal organic chemical vapor deposition (MOCVD). But the high leakage current also occurred due to the grain boundary and defects in the poly-crystalline TiO2 film. The surface passivation of GaAs with (NH4)2Sx treatment (S-GaAs) could prevent it from oxidizing after cleaning and improve the interface properties of MOSFET. The fluorine from liquid phase deposited SiO2 solution can passivate the grain boundary of poly-crystalline MOCVD-TiO2 film and interface state. The high dielectric constant and low leakage current of fluorine passivated MOCVD-TiO2/S-GaAs can be obtained. The leakage current densities are 3.41 x 10-7 A/cm2 and 1.13 x 10-6A/cm2 at ¡Ó1.5 MV/cm, respectively. The Dit is 4.6 x 1011 cm-2eV-1 at the midgap. The dielectric constant can reach 71. In addition, the post-metallization annealing (PMA) is another efficiency way to improve the MOCVD-TiO2 quality. The mechanism of PMA process is from the reaction between the aluminum contact and hydroxyl groups existed on TiO2 film surface. Then the active hydrogen is produced to diffuse through the oxide and passivate the oxide traps. For PMA (350oC)-MOCVD-TiO2 on S-GaAs MOS structure, the leakage current densities can reach 2.5 x 10-7 and 5 x 10-7 A/cm2 at ¡Ó1.5 MV/cm, respectively. The dielectric constant and the Dit are 66 and 5.96 x 1011 cm-2eV-1, respectively. In order to avoid the leakage current from grain boundary of poly-crystalline TiO2, and liquid phase deposited TiO2 (LPD-TiO2) at low temperature can preserve the function of sulfur passivation. Therefore, the amorphous LPD-TiO2 was deposited on S-GaAs. The leakage current densities are 1.04 x 10-7 and 1.91 x 10-7 A/cm2 at ¡Ó0.5 MV/cm, respectively. The Dit is 3.2 x 1011 cm-2eV-1 and the dielectric constant is 48. The LPD-TiO2 film was deposited on (NH4)2Sx treated InP (S-InP), and the 4 x 100 £gm2 enhancement mode N channel InP MOSFET with LPD-TiO2 as gate oxide was fabricated, which showed the good characteristic. The normalized maximum gm is 43 mS/mm at VG = 1.3 V for VDS fixed at 1 V. The maximum calculated £gFE of 348 cm2/V¡Es at VDS = 1 V is obtained.

Thesis (Ph. D.)--University of Hong Kong, 2002. / Includes bibliographical references (leaves 219-222).

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Heteroblasty defines a dramatic change in leaf form and function along a shoot and is a prominent feature of the genus Acacia (Mimosaceae). Function of different leaf types in Acacia (i.e. compound leaf versus phyllode) is well established yet it is unknown whether heteroblasty is a plastic trait. A fully factorial designed experiment established the light environment, and not nutrients or water, had a significant influence on heteroblastic development. Compound leaves, which have higher specific leaf area (SLA), are retained for longer under low irradiance and, specifically, under a low Red:Far Red light environment. Plants grown in high intraspecific density environments also retained compound leaves for longer. Blue light signals and greater ultraviolet radiation had no effect on heteroblastic development. Heteroblasty is thought to aid in seedling establishment however across all experiments there was no consistent evidence of improved plant performance. Rather, there was an optimal allocation of biomass to organs where resources were most limiting and this was more influential in assisting seedling establishment. Lastly, a meta-analysis of a global dataset of leaf traits found compound leaves to be similar to simple leaves but offset towards the cheap to construct with fast returns region of the leaf economics spectrum.

Heteroblasty defines a dramatic change in leaf form and function along a shoot and is a prominent feature of the genus Acacia (Mimosaceae). Function of different leaf types in Acacia (i.e. compound leaf versus phyllode) is well established yet it is unknown whether heteroblasty is a plastic trait. A fully factorial designed experiment established the light environment, and not nutrients or water, had a significant influence on heteroblastic development. Compound leaves, which have higher specific leaf area (SLA), are retained for longer under low irradiance and, specifically, under a low Red:Far Red light environment. Plants grown in high intraspecific density environments also retained compound leaves for longer. Blue light signals and greater ultraviolet radiation had no effect on heteroblastic development. Heteroblasty is thought to aid in seedling establishment however across all experiments there was no consistent evidence of improved plant performance. Rather, there was an optimal allocation of biomass to organs where resources were most limiting and this was more influential in assisting seedling establishment. Lastly, a meta-analysis of a global dataset of leaf traits found compound leaves to be similar to simple leaves but offset towards the cheap to construct with fast returns region of the leaf economics spectrum.

Thesis (Ph.D.)--University of Adelaide, School of Molecular and Biomedical Sciences, Discipline of Genetics, 2005? / "September, 2004" Bibliography: p. 119-136.

Thesis (Ph. D.)--University of Texas at Austin, 2008. / Vita. Includes bibliographical references.