Há décadas a energia solar atrai pesquisadores de todo o planeta devido ao seu enorme potencial de aplicações como fonte de energia térmica. Com a crescente preocupação com o Meio Ambiente e a busca por fontes renováveis de energia, o interesse pelo aproveitamento da energia proveniente do Sol cresceu ainda mais. Apesar de desafios como a intermitência e a sazonalidade solares, e a dificuldade de transporte desta forma de energia, a busca por técnicas de armazenamento visa mitigar estes problemas. Uma alternativa termoquímica é a produção de combustíveis solares, ou seja, combustíveis obtidos por meio do uso da energia concentrada do Sol que possam ser estocados e transportados para onde e quando houver demanda de energia. Uma aplicação de destaque neste tema é a gaseificação de biomassa para a produção de gás de síntese (CO + H2). A gaseificação visa aumentar o potencial energético da biomassa sólida ou líquida ao realizar uma reação endotérmica que transfere a energia acumulada do Sol (por meio de concentradores) para as ligações químicas, com a recombinação dos átomos na forma de gás de síntese. Este gás, além do seu maior poder calorífico, é matéria-prima para muitos processos da indústria química. Desta forma, o objetivo desta reação é obter um combustível mais homogêneo e de fácil manuseio. A gaseificação é uma alternativa importante para o aproveitamento energético da biomassa, pois esta é normalmente bastante heterogênea. Sendo assim, o uso de gaseificadores viabiliza o uso de madeira, resíduos urbanos e agrícolas e outras matérias orgânicas como fontes de energia. Assim, este trabalho apresenta um estudo da utilização de concentradores solares para o processo de gaseificação de biomassa e a concepção de um reator químico solar para operação em escala laboratorial para a sequência dos estudos neste campo de pesquisa. Por meio de uma modelagem térmica, o trabalho destaca a viabilidade técnica da gaseificação solar de biomassa, comprovando um ganho energético e uma redução das emissões de gás carbônico em comparação com a queima direta da biomassa. Por fim, são apresentados os parâmetros de construção e operação de um gaseificador de pequena escala. / From decades, solar energy has instigated researchers worldwide due to its enormous potential. With raising concern for the environment and the search for renewable energy sources, the interest in using the Sun as a power supply grew even more. Despite challenges as the solar seasonality and intermittence, and difficulties transport its energy, innovative storage techniques aim to mitigate those issues. A thermochemical alternative is the production of solar fuels - fuels obtained from concentrated solar power (CSP) - which can be stocked and transported to the time and place there is demand. A forthcoming application in this field is biomass steam-gasification for syngas production (CO + H2). Gasification increases the thermal potential of liquid and solid biomass by means of an endothermic reaction that transfers solar energy (via radiation concentrators) to chemical bonds, re-combining the atoms as syngas (hydrogen and carbon monoxide). This gas mixture, besides its thermal potential, is a raw material for numerous processes in chemical industry. The purpose of this process is to obtain a fuel more homogenous and easy to manipulate. The gasification is an important alternative to biomass energy use, once it is generally heterogeneous. Thus, gasifiers enable the use of wood, algae, solid waste, agricultural byproducts, and other organic matter as power supplies. Therefore, this project presents the study of solar concentrators use in the steamgasification of biomass and the conception of a solar chemical reactor for laboratoryscale tests for the future steps of the research in this field. Models and bibliographic references points to the technical feasibility of solar steam-gasification of biomass, verifying a significant energy gain and carbon emission reduction comparing to direct burn of biomass. Ultimately, the dissertation presents the constructive and operational parameters of a small-scale gasifier.

Concentrating solar power (CSP) plant is a promising technology that exploits direct normal irradiation (DNI) from the sun to be converted into thermal energy in the solar field. One of the advantages of CSP technology is the possibility to store thermal energy in thermal energy storage (TES) for later production of electricity. The integration of thermal storage allows the CSP plant to be a dispatchable system which is defined as having a capability to schedule its operation using an innovative dispatch planning tool. Considering weather forecast and electricity price profile in the market, dispatch planning tool uses an optimization algorithm. It aims to shift the schedule of electricity delivery to the hours with high electricity price. These hours are usually reflected by the high demand periods. The implementation of dispatch optimizer can benefit the CSP plants economically from the received financial revenues. This study proposes an optimization of dispatch planning strategies for the parabolic trough CSP plant under two dispatch approaches: solar driven and storage driven. The performed simulation improves the generation of electricity which reflects to the increase of financial revenue from the electricity sale in both solar and storage driven approaches. Moreover, the optimization also proves to reduce the amount of dumped thermal energy from the solar field.

Direct absorption solar collectors offer possible improvement in efficiency over traditional surface absorbing collectors, because they have fewer heat transfer steps and has the ability to utilise higher radiation fluxes. Carbon black based nanofluids, in a base fluid of salt water, were synthesised by a two-step method where the carbon black nanoparticles were treated with a surfactant, TWEEN-20, in a 1:2 mass ratio and sonicated for 60 minutes to break up agglomerates. The synthesised nanofluids showed stability for over 31 days. The different carbon black concentration nanofluids' solar irradiation absorption properties were compared with each other and with the base fluid of salt water in a concentrating, as well as non-concentration scenario. It was found that the carbon black nanofluids showed excellent absorption properties over the entire solar radiation spectrum. A 1 m2 concentrating unit using a two-axis tracking system, with two mirrors and a 1 m diameter circular Fresnel lens, was used to concentrate solar radiation on a direct absorption solar collector flow cell with a 10 cm2 collection area. An optimum concentration of 0.001 volume % carbon black was found to show a 42 % increase in heating rate, compared to that of salt water. The collector was, however, hampered by high energy losses and the maximum collector efficiency achieved was only 46 %, 23 % higher than that of salt water. The overall system efficiency was only 22 %. This low efficiency can be attributed to the high optical concentration losses (50 % - 70 %) present in the concentrating unit. / Dissertation (MEng)--University of Pretoria, 2016. / Chemical Engineering / MEng / Unrestricted

The durability of two solar-selective aluminium titanium oxynitride multilayer coatings was studied under conditions simulating realistic operation of central receiver power plants. The coatings were deposited by cathodic vacuum arc applying an optimized design concept for complete solar-selective coating (SSC) stacks. Compositional, structural and optical characterization of initial and final stacks was performed by scanning electron microscopy, elastic recoil detection, UV-Vis-NIR-IR spectrophotometry and X-Ray diffraction. The design concept of the solar selective coatings was validated by an excellent agreement between simulated and initial experimental stacking order, composition and optical properties. Both SSC stacks were stable in single stage tests of 12 hours at 650°C. At 800°C, they underwent a structural transformation by full oxidation and they lost their solar selectivity. During cyclic durability tests, multilayer 1, comprised of TiN, Al0.64Ti0.36N and an Al1.37Ti0.54O top layer, fulfilled the performance criterion (PC) ≤ 5% for 300 symmetric, 3 hours long cycles at 600°C in air. Multilayer 2, which was constituted of four AlyTi1-y(OxN1-x) layers, met the performance criterion for 250 cycles (750 hours), but was more sensitive to these harsh conditions. With regard to the degradation mechanisms, the coarser microstructure of multilayer 1 is more resistant against oxidation than multilayer 2 with its graded oxygen content. These results confirm that the designed SSCs based on AlyTi1-y(OxN1-x) materials withstand breakdown at 600ºC in air. Therefore, they can be an exciting candidate material for concentrated solar power applications at high temperature.

The transparent conductive oxide (TCO) SnO2:Ta is developed as a selectively solar-transmitting coating for concentrated solar power (CSP) absorbers. Upon covering with an antireflective layer, a calculated absorptivity of 95% and an emissivity of 30% are achieved for the model configuration of SnO2:Ta on top of a perfect black body (BB). High-temperature stability of the developed TCO up to 1073 K is shown in situ by spectroscopic ellipsometry and Rutherford backscattering spectrometry. The universality of the concept is demonstrated by transforming silicon and glassy carbon from non-selective into solar-selective absorbers by depositing the TCO on top of them. Finally, the energy conversion efficiencies of SnO2:Ta on top of a BB and an ideal non-selective BB absorber are extensively compared as a function of solar concentration factor C and absorber temperature TH. Equal CSP efficiencies can be achieved by the TCO on BB configuration with approximately 50% lower solar concentration. This improvement could be used to reduce the number of mirrors in a solar plant, and thus, the levelized costs of electricity for CSP technology.

>Magister Scientiae - MSc / Phase change material (PCM) through latent heat of molten salt, is a convincing way for thermal energy storage in CSP applications due to its high volume density. Molten salt, with (60% NaNO3 and 40% KNO3) has been used extensively for energy storage however; the low thermal conductivity and specific heat have limited its large implementation in solar applications. For that, molten salt with the additive of silver nanowires (AgNWs) was synthesized and characterized. This research project aims to investigate the thermophysical properties enhancement of nanosalt (Mixture of molten salt and silver nanowires). The results obtained showed that by simply adjusting the temperature, Silver nanowires with high aspect ratio have been synthesized through the enhanced PVP polyol process method. SEM results revealed a network of silver nanowires and TEM results confirmed the presence of silver nanowires with an average diameter of 129 nm and 16 μm in length.

This master thesis report presents a prefeasibility analysis for a Saudi Company to enter the solar industry.Section one of this report illustrates the value chain analysis and opportunity identification and evaluation process applied to CSP technology. Section two offers an example of a potential business case in hybrid-powered commercial irrigation.

No description available.

The cooperation between large scale Concentrated Solar Power plants (CSP) and Solar Photovoltaic (PV) parks can offer stability in power supply and enhance the capacity factor of the CSP plant intended to cover a common demand on the power system. Moreover, it can offer an investment option with lower risk. This Master thesis project presents optimum plant configurations for both technologies under the same meteorological and market conditions. The study is based in the South African electricity market and the Renewable Energy Independent Power Producer Program currently in place in the country. Using MATLAB and TRNSYS softwares, a series of detailed codes were designed in order to model both technologies energy transformation process. The main approach was to design the nominal operation point of both technologies for a given typical meteorological year data and respective technical conditions for each case. Then, a transient simulation was done in order to obtain the electricity yield. The intention was to measure the internal rate of return, levelized cost of electricity and capacity factor for each technology and the combined configuration (CSP-PV plant) under different scenarios and operation modes while a firm capacity was maintained. It was found that the plants can be economically feasible by sizing a storage unit capable of just covering the peak hours. The solar multiple sizes can vary depending on the scenario and plant configuration. Moreover, the internal rate of return increases with the capacity of the CSP in all cases. After the results were obtained, a comparison with a single CSP plant and the optimum CSP-PV plant was done in order to evaluate the performance of the proposed cooperation. Even though the internal rate of return of the CSP-PV plant was found to be within a good range for investment, the CSP-alone alternative offered always higher internal rate of return and lower levelized cost of electricity values. Nonetheless, it was found that the capacity factor of the combined configuration was favored by the integration of PV. The PV alone configuration hold the lowest levelized cost of electricity, thus considered the best option for and investment in South Africa due to its independence towards incentives. Combined PV-CSP systems were also found to be an attractive investment under the South African scheme if the CSP capacity is similar to the PV power plant.

This dissertation addresses the flow control problem in hyperbolic heat transfer mechanisms. It raises in concentrated distributed solar collectors to enhance their production efficiency under the unpredictable variations of the solar energy and the external disturbances. These factors which are either locally measured (the solar irradiance) or inaccessible for measurement (the collectors’ cleanliness) affect the source term of the distributed model and represent a major difficulty for the control design. Moreover, the temperature in the collector can only be measured at the boundaries. In this dissertation, we propose new adaptive control approaches to provide the adequate level of heat while coping with the unpredictable varying disturbances. First, we design model based control strategies for a better efficiency, in terms of accuracy and response time, with a relatively reduced complexity. Second, we enhance the controllers with on-line adaptation laws to continuously update the efficient value of the external conditions. In this study, we approach the control problem using both, the infinite dimensional model (late lumping) and a finite dimensional approximate representation (early lumping). For the early lumping approach, we introduce a new reduced order bilinear approximate model for system analysis and control design. This approximate state representation is then used to derive a nonlinear state feedback resorting to Lyapunov stability theory. To compensate for the external disturbances and the approximation uncertainties, an adaptive controller is developed based on a phenomenological representation of the system dynamics. For the late lumping approach, we propose two PDE based controllers by stabilization of the reference tracking error distributed profile. The control laws are explicitly defined as functions of the available measurement. The first one is obtained using a direct approach for error stabilization while the second one is derived through a nonlinear mapping. Furthermore, we endow the nonlinear controllers with an adaptation law to cope with the unpredictable unmeasured disturbances. The proposed adaptation law is based on a Proportional plus Integral correction feedback. We show that the control objectives with the required performance can be achieved following both approaches, but yet are conditioned with the physical limitations of the system.