Volatile fatty acids (VFAs) are important building blocks for the chemical industry. These acids can be produced through environmentally friendly processes from a variety of wastes, such as food waste, sludge and cow manure, through anaerobic digestion (AD). The main objective of this thesis was to investigate which operating parameters (e.g. pH, retention time, mix of substrate etc.) are optimal for producing VFAs as efficiently as possible, through AD batch processes. The highest VFA concentration was reached at pH 10 and at day 11 when food waste and sludge were used as substrate to a value of 15.4 g/L, corresponding to 0.77 g VFAs/ g of VSfed. Highest VFA concentration where cow manure was used as substrate was reached on day 10 and with a value of about 10 g/L corresponding to 0.51 g VFAs/ g VSfed. / Flyktiga fettsyror (VFAs) är en viktig byggsten inom den globala kemiindustrin. Dessa fettsyror kan produceras med hjälp av miljövänliga processer där en mängd olika sorters avfall, som t.ex. matavfall, avloppsslam och koavföring kan fungera som substrat, genom anaerobisk rötning. Det huvudsakliga målet med den här kandidatuppsatsen var att utreda vilka de optimala driftförhållanden var för särskilt utvalda driftparametrar (t.ex. pH, retentionstid, mix av substrat etc.) för att producera flyktiga fettsyror så effektivt som möjligt, genom anaerobisk rötning. Högst koncentration av VFAs nåddes vid pH 10 på dag 11 när matavfall och avloppsslam användes tillsammans som substrat till ett värde på 15 g/L, vilket motsvarar en avkastning på 0.77 g VFAs / g VSin. Högst VFAs-koncentration när koavföring användes som substrat nåddes på dag 10 med ett värde på 10 g/L, motsvarande en avkastning på 0.51 g VFA/ g VSin.

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Orientador: Jorge de Lucas Junior / Banca: Beno Wendling / Banca: João Antônio Galbiatti / Banca: Regina Maria Quintão Lana / Banca: Elias Nascentes Borges / Resumo: A necessidade de ampliação de atitudes que levam o meio rural a buscar a sustentabilidade e a implantação do uso da biodigestão anaeróbia tem sido incentivada por se tratar de um mecanismo de desenvolvimento limpo que alia a importância do tratamento dos resíduos agropecuários (dejetos), geração de energia (biogás) e biofertilizante. Desenvolveu-se um estudo em que se focou a hipótese que a implantação de sistema de tratamento de dejetos, com o uso de biodigestor anaeróbio e o aproveitamento dos seus produtos, o biofertilizante, poderia substituir a adubação mineral nitrogenada de cobertura no cultivo de forrageiras e que essa prática poderia reduzir o custo de adubação e promover ganhos adicionais com a geração de energia elétrica e ganhos ambientais, com a redução de emissão de metano e produção do biogás. Utilizou-se como ferramenta para embasar a hipótese três cultivos de forrageira, um de sorgo e dois de milho. Observou-se que a aplicação de biofertilizante e composto bovino não promoveram aumentos significativos na produtividade das culturas. Paralelamente desenvolveu-se a implantação de um biodigestor de manta de PVC flexível que serviu de parâmetros para a simulação da viabilidade econômica de um sistema de criação de bovino para 100 vacas leiteiras e um sistema de criação de suínos de ciclo completo para 500 matrizes. Conclui-se que projetos que contemplam o princípio da interdisciplinaridade podem auxiliar de maneira mais efetiva na tomada de decisão de implantação de soluções ambientalmente corretas que podem ser também economicamente viáveis. / Abstract: Because of the need for expansion of attitudes that lead to rural areas to seek sustainability. The introduction of the use of anaerobic digestion has been encouraged by the case of a clean development mechanism that combines the importance of processing of agricultural waste (manure), generation of energy (biogas) and biofertilizer. Has developed a study that focused on the hypothesis that the deployment system for the treatment of waste using anaerobic biodigest and use products, the biofertilizer, could replace mineral nitrogen fertilization in coverage the cultivation of fodder and that this practice could reduce the cost of fertilizer and promote additional gains in the generation of electric energy and environmental gains, such as reducing the emission of methane. It was used as a tool for the hypothesis based three of forage crops, one the sorghum and two maize. It was observed that the application of biofertilizer and compost cattle did not promote significant increases in productivity of crops. Developed in parallel to implement a blanket biodigest of flexible PVC that served as parameters for the simulation of the economic viability of a system for creating and veal to 100 dairy cows and a pig breeding cycle of full matrix for 500. It is concluded that projects that include the principle of interdisciplinarity can assist more effectively in decision making for the deployment of environmentally correct solutions that can be economically viable. / Doutor

This study was carried out to evaluate the potential of high-rate anaerobic digestion of high-solids organic fraction of municipal solid waste (OFMSW) for the production of organic acids and alcohols in leaching bed reactors (LBRs). For this purpose, two different experimental set-ups, namely Set-1 and Set-2, were operated. In the Set-1, only OFMSW without paper was studied in two identical LBRs, whereas, four identical LBRs, fed with OFMSW with paper and cow manure in different proportions, were operated in the Set-2. In this study, 50-60% of hydrolysis efficiency was achieved in the LBRs of Set-1, whereas this value was decreased to 20-25% in the LBRs of Set-2 / which was resulted from OFMSW containing cellulose and less volume of water addition in the Set-2. The mass of total volatile fatty acids (tVFA) production was found as 7000-9000 mg at the end of 80 days in the LBRs of Set-1, fed with OFMSW without paper, whereas it was 3000 mg at the end of 40 days in the LBR of Set-2, containing only OFMSW with paper. It was also observed that cow manure addition increased the amount of tVFA production in the LBR of Set-2. In conclusion, LBRs were found as alternative reactors for the degradation of OFMSW compared to completely stirred tank reactors (CSTRs) in terms of rapid hydrolysis and acidification, which can result in high hydrolysis yield and tVFA production.

La limitation des ressources énergétiques fossiles et les lourds impacts environnementaux pouvant résulter de leur exploitation, entraînent un regain d’intérêt pour la digestion anaérobie. Face aux enjeux énergétiques et sanitaires, la conduite d’un méthaniseur implique l’optimisation de la production de méthane, mais aussi d’assurer la qualité sanitaire du digestat du point de vue des micropolluants. C’est dans ce cadre que s’inscrit ce projet de thèse réalisé en partenariat avec la ferme expérimentale de la Bouzule. L’optimisation de la co-digestion de substrats a montré que l’ajout d’herbe ensilée durant 36 semaines, améliorait le rendement du procédé de 20%. Le suivi des micropolluants (métaux lourds et HAPs) contenus dans les herbes provenant des bordures de route a montré que la qualité du digestat ne serait pas affectée si elles sont incorporées au digesteur. L’étude en réacteur batch de l’impact des antibiotiques sur la production de méthane a montré que : à 8 mg/L et 16 mg/L de tétracycline on observe une baisse de 23% et 28% respectivement, à 14 mg/L de spiramycine on observe une baisse de 40%, et à 20 mg/L de tylosine on observe une baisse de 30%. En réacteur continu, les faibles concentrations de tétracycline (0,2 mg/L et 2 mg/L) amélioraient d’environ 5% de la production de méthane au bout de 7 jours. A 200 mg/L et 2000 mg/L de tétracycline, on atteint des baisses de 30% et 40%, et le système ne récupère pas au bout de 7 jours. Quant à la spiramycine, à 1,4 mg/L, 14 mg/L et 140 mg/L, les baisses ont été de 14%, 24% et 39% respectivement, et au bout de 7 jours, une baisse résiduelle est toujours observable. Par ailleurs, les digestats issus des tests avec les antibiotiques sont en accord avec la réglementation / The limitation of fossil energy resources and heavy environmental impacts arising from their operation, there is a renewed interest for anaerobic digestion. According to the energy, and health issues, the monitoring of an anaerobic digester involves the maximization of the methane production, but also to ensure a good quality of digestate from the perspective of micropollutants. It is within this framework that this project of thesis is realized in partnership with the experimental farm of “La Bouzule”. The optimization of the co-digestion of substrates, showed that the use of 36 weeks grass silage improved the process yield by 20%. The monitoring of heavy metals and PAHs content in the grasses from roadsides showed that these grasses – if used as co-substrate in the digester – will not affect the digestate quality. The study of the impact of antibiotics on methane production in batch reactor showed that: 8 mg/L and 16 mg/L of tetracycline led to 23% and 48% decrease respectively, 14 mg/L of spiramycin led to 40% decrease, and 20 mg/L tylosin to 30% decrease. The monitoring of the continuous reactor showed that low levels of tetracycline (0.2 mg/L and 2 mg/L) led to an improvement of about 5% of the methane production. At 200 mg/L and 2000 mg/L of tetracycline, reductions of 30% and 40% are achieved, and the system did not recover after 7 days. The addition of spiramycin to the continuous reactor at 1.4 mg/L, 14 mg/L and 140 mg/L resulted in decreases of 14%, 24% and 39% respectively. For the latter, after one week, a residual drop is still observable. Furthermore, the digestate resulting from the monitoring of the continuous reactor during the tests with antibiotics is in accordance with current regulations

Made available in DSpace on 2014-06-11T19:33:33Z (GMT). No. of bitstreams: 0 Previous issue date: 2009-05-06Bitstream added on 2014-06-13T20:45:16Z : No. of bitstreams: 1 silva_aa_dr_jabo.pdf: 637049 bytes, checksum: 5ae6ccd522ca36efab6ebab2ca5ea62e (MD5) / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) / Sansuy S.A. Industria de Plasticos / Universidade Federal de Uberlandia / A necessidade de ampliação de atitudes que levam o meio rural a buscar a sustentabilidade e a implantação do uso da biodigestão anaeróbia tem sido incentivada por se tratar de um mecanismo de desenvolvimento limpo que alia a importância do tratamento dos resíduos agropecuários (dejetos), geração de energia (biogás) e biofertilizante. Desenvolveu-se um estudo em que se focou a hipótese que a implantação de sistema de tratamento de dejetos, com o uso de biodigestor anaeróbio e o aproveitamento dos seus produtos, o biofertilizante, poderia substituir a adubação mineral nitrogenada de cobertura no cultivo de forrageiras e que essa prática poderia reduzir o custo de adubação e promover ganhos adicionais com a geração de energia elétrica e ganhos ambientais, com a redução de emissão de metano e produção do biogás. Utilizou-se como ferramenta para embasar a hipótese três cultivos de forrageira, um de sorgo e dois de milho. Observou-se que a aplicação de biofertilizante e composto bovino não promoveram aumentos significativos na produtividade das culturas. Paralelamente desenvolveu-se a implantação de um biodigestor de manta de PVC flexível que serviu de parâmetros para a simulação da viabilidade econômica de um sistema de criação de bovino para 100 vacas leiteiras e um sistema de criação de suínos de ciclo completo para 500 matrizes. Conclui-se que projetos que contemplam o princípio da interdisciplinaridade podem auxiliar de maneira mais efetiva na tomada de decisão de implantação de soluções ambientalmente corretas que podem ser também economicamente viáveis. / Because of the need for expansion of attitudes that lead to rural areas to seek sustainability. The introduction of the use of anaerobic digestion has been encouraged by the case of a clean development mechanism that combines the importance of processing of agricultural waste (manure), generation of energy (biogas) and biofertilizer. Has developed a study that focused on the hypothesis that the deployment system for the treatment of waste using anaerobic biodigest and use products, the biofertilizer, could replace mineral nitrogen fertilization in coverage the cultivation of fodder and that this practice could reduce the cost of fertilizer and promote additional gains in the generation of electric energy and environmental gains, such as reducing the emission of methane. It was used as a tool for the hypothesis based three of forage crops, one the sorghum and two maize. It was observed that the application of biofertilizer and compost cattle did not promote significant increases in productivity of crops. Developed in parallel to implement a blanket biodigest of flexible PVC that served as parameters for the simulation of the economic viability of a system for creating and veal to 100 dairy cows and a pig breeding cycle of full matrix for 500. It is concluded that projects that include the principle of interdisciplinarity can assist more effectively in decision making for the deployment of environmentally correct solutions that can be economically viable.

The aim of this study was to assess the effect of composting process of cow manure and rice straw with application of cow urine and to evaluate the quality of composting products. There were two treatment piles, in which one pile was applied with cow urine every week and another pile without urine application. Each pile was set up by one tone cow manure and 500kg rice straw. The piles were half-covered by plastic foil to protect from rain and turned one a week. The composting duration lasted 8 weeks. The parameters such as temperature, pH, DM, density and nitrogen were monitored and observed during the 8-week period. The results showed that there was a significant difference in temperature, compost quality and duration between two piles with and without cow urine application. The application of cow urine increased significant nitrogen and phosphorous content and shortened the composting process. This study recommends that cow urine should be applied for composting process of cow manure and rice straw in order to increase the quality of compost. The final product was in the range of matured compost level and can be used directly for agriculture crop. / Mục tiêu của nghiên cứu nhằm đánh giá ảnh hưởng đến chất lượng phân compost của việc bổ sung nước tiểu vào trong quá trình ủ phân từ nguyên liệu phân bò và rơm rạ. Thí nghiệm được thực hiện trên hai đống ủ phân, một đống ủ được bổ sung nước tiểu bò hàng tuần và một đống ủ không bổ sung nước tiểu bò như là một nghiệm thức đối chứng. Mỗi đống ủ được trộn 1 tấn phân bò và 500kg rơm. Đống ủ phân được đậy kín một nửa phía trên nhằm ngăn cản ảnh hưởng của mưa và được đảo trộn một lần mỗi tuần. Quá trình thí nghiệm được tiến hành trong 8 tuần. Các chỉ tiêu như nhiệt độ, pH, DM, mật độ và chất dinh dưỡng Nitơ và Phốt Pho được quan trắc trong thời gian ủ. Kết quả cho thấy có sự khác biệt đáng kể giữa hai đống phân ủ đối với các chỉ tiêu như nhiệt độ, chất lượng phân compost và thời gian ủ. Đống ủ phân có bổ sung nước tiểu có hàm lượng Nitơ và Phốt pho cao hơn và thời gian ủ ngắn hơn. Kết quả nghiên cứu khuyến cáo nên bổ sung nước tiểu bò cho quá trình ủ phân compost nhằm tăng hàm lượng chất dinh dưỡng cho sản phẩm phân compost. Sản phẩm sau quá trình ủ đạt mức độ phân hữu cơ và có thể sử dụng cho cây trồng.