This work is divided in two thematic parts. The first part shows a refurbishment of a Omicron low temperature STM set-up and its utilization for preparation of superconducting-magnetic interfaces. First, a cleaning procedure of suitable metallic substrates, specifically W(110) and Ir(111), is shown. It is followed by results of iron monolayer deposition on Ir(111) (Fe-Ir(111) interface). The last section deals with study of vanadium growth on pure Ir(111) substrate as well as on mentioned Fe-Ir(111) interface. The second thematic part deals with magnetism of cobalt atoms on a monolayer metal dichalcogenide WS2. It focuses primarily on studying their magnetic moment and magnetic anisotropy using X-ray magnetic circular dichroism (XMCD).

Depuis plusieurs années, le département Temps-Fréquence de l’institut FEMTO-ST mène une étude sur le comportement des résonateurs à ondes acoustiques de volume à énergie piégée dans des cristaux à quartz à température cryogénique, typiquement proche de 4 K. Les performances en termes de coefficient de qualité mécanique relevé à ces températures, plusieurs milliards à quelques dizaines de MHz, font des cavités acoustiques en quartz de bons candidats pour des sources de fréquences cryogéniques ultrastables.Les travaux présentés dans ce manuscrit s’inscrivent dans la continuité de ce programme d’étude. Ils visent à consolider l’intérêt du quartz mais aussi à envisager des solutions alternatives à base de matériaux à très faibles pertes acoustiques mais non piézoélectriques pour lesquels l’excitation optique est une alternative crédible. Les présents travaux peuvent être résumés en trois parties majeures :- La première partie a été réalisée dans le but de déterminer une coupe de quartz possédant un point d’inversion sur sa caractéristique fréquence-température aux températures cryogéniques. La seule régulation de température du résonateur d’une source de fréquence ultrastable est en effet insuffisante sans l’existence d’un tel point qui doit servir de point de fonctionnement à la régulation thermique. La recherche d’une coupe compensée a nécessité une campagne préliminaire de mesure des coefficients de température des coefficients élastiques du matériau, inconnus à basses températures. Il a alors été possible, à partir de la connaissance de ces coefficients, d’identifier par le calcul puis de réaliser une coupe remplissant les conditions recherchées.- La seconde partie a pour objectif de faire la preuve de concept consistant à utiliser une cavité acoustique en quartz en cavité optique. Dans sa version de base, le résonateur à quartz à onde de volume piégée est plan-convexe (pour assurer le piégeage) et à électrodes (métalliques pour assurer l’excitation électrique !) déposées sur chacune de ses faces. Il est démontré, théoriquement et expérimentalement, qu’une telle géométrie fonctionne en cavité optique, avec son avantage de simplicité mais avec ses limites. Cette structure de base doit être mise à profit pour le couplage optomécanique abordé en troisième partie et constitue le socle de conception de dispositifs optomécaniques plus performants.- La troisième partie est consacrée à l’évaluation de la pertinence du couplage optomécanique de tels dispositifs fonctionnant à température cryogénique. Une étude portant sur la quantification théorique du couplage optomécanique que peut atteindre une telle cavité a été réalisée. / For a few years, the Time and Frequency department in FEMTO-ST Insitute has been leading research about the behavior of Bulk Acoustic Wave (BAW) trapped in quartz crystal at cryogenic temperatures (near 4K).The measured quality factor are around a few billions at few tens of MHz for such temperatures. Acoustical quartz cavities are therefore good candidates for ultrastable cryogenic frequency sources. The work presented here is in the natural continuation of the research cited above. They aim at strenghtening the interest for quartz crystal, but also to consider alternative solutions with non-piezoelectric material with very-low acoustical losses, for which optical excitation is an option. The following work can be summed up in three main parts:- The first part is about the determination of a quartz crystal cut for which a turnover point exists in the frequency-temperature curve in the cryogenic region. Indeed, it is not enough to barely control the temperature in an ultrastable frequency source. Such a turnover point needs to be the operation point for thermal regulation. Searching a compensated cut arose the need for a preliminary measurements campaign of thermal coefficients of elastics coefficients of the material, which were unknown at low temperature. It was then possible, based on these coefficients, to calculate and even realize a cut fulfilling the required condition.- The second part had the objective to demonstrate conceptually that using a quartz acoustical cavity as an optical cavity was feasible. In its basic scheme, a BAW quartz resonator is plano-convex (to ensure the trapping of the acoustic wave) and has electrodes (metal-made to ensure electrical excitation) deposited on each face. It has been demonstrated, both theoretically and experimentally, that such a geometry works fine as an optical cavity, with its corresponding advantages and limitations. This scheme is used for the optomechanical coupling discussed in the third part and constitutes the very base for more efficient optomechanical devices.- The third part is dedicated to the evaluation of how efficient will such devices be while functioning at cryogenic temperature. A theoretical quantification of the optomechanical coupling that these cavities might reach is also presented.

Sr₃Ru₂O₇ is a quasi-two-dimensional metal and has a paramagnetic ground state that is heavily renormalised by electron-electron correlations and magnetic exchange interactions. Inextricably linked to this renormalisation is the metamagnetism of Sr₃Ru₂O₇ - a rapid rise in uniform magnetisation over a narrow range of applied magnetic field. Knowledge of the zero-field physics is essential to any description of the metamagnetism. Light may be shed on the enigmatic ground state of Sr₃Ru₂O₇ by doping the crystal lattice with foreign cations: this is the primary purpose of the original research referred to in this thesis, in which studies of some of the electronic properties of crystals of cation-doped Sr₃Ru₂O₇ are reported. Single crystals of Sr₃(Ru[subscript(1-x)]Ti[subscript(x)])₂O₇ and Sr₃(Ru[subscript(1-x)]Cr[subscript(x)])₂O₇ have been synthesised in an image furnace and some of the properties of these crystals have been measured. Evidence that indicates the emergence of a spin density wave as a function of Ti-doping in Sr₃(Ru[subscript(1-x)]Ti[subscript(x)])₂O₇ is presented. Time-dependent magnetic irreversibility has been observed in samples of Sr₃(Ru[subscript(1-x)]Cr[subscript(x)])₂O₇, thus hinting at the involvement of the RKKY mechanism in these materials. Regarding cation doping out of the conducting RuO₂ planes, samples of (Sr[subscript(1-y)]La[subscript(y)])₃Ru₂O₇ have been grown and investigated. Both the Sommerfeld coefficient and the Fermi liquid A coefficient of (Sr[subscript(1-y)]La[subscript(y)])₃Ru₂O₇ are found to decrease as a function of y (0 ≤ y ≤ 0.02); these observations point towards a reduction in the thermodynamic mass of the Landau quasiparticles. Results from magnetoresistance and magnetisation measurements indicate that the metamagnetism of the (Sr[subscript(1-y)]La[subscript(y)])₃Ru₂O₇ series probably cannot be explained by a rigid band-shift model. Also, some aspects of these data imply that the metamagnetism cannot be fully accounted for by a spin fluctuation extension to the Ginzburg-Landau theory of uniform magnetisation.

Ce rapport de thèse porte sur une étude expérimentale et théorique de l'ébullition en microgravité. Les expériences furent réalisées en condition de gravité terrestre, en vol parabolique et en fusée-sonde. Les expériences en vol parabolique ont montré l'influence de divers paramètres sur le transfert thermique et ont mis en évidence les mécanismes contrôlant le transfert thermique. De l'écriture des équations gouvernant ces mécanismes et de l'identification des échelles caractéristiques, une corrélation permettant d'estimer le transfert de chaleur lors de l'ébullition en microgravité pour une large gamme de fluide est bâtie. L'expérience en fusée-sonde a permis d'étudier l'influence des gaz incondensables et notamment de la convection Marangoni sur le comportement de l'ébullition et sur le transfert thermique. / Between the different propulsion phases, the Ariane V rocket passes through microgravity periods and solar radiation can induce boiling in its cryogenics tanks. Experiments were performed during 6 parabolic flights and in a sounding rocket to study pool boiling in microgravity. In the parabolic flight experiments, the influence of pressure, subcooling and surface roughness was studied. It is showed that subcooling has a weak effect on microgravity boiling heat transfer, and that roughness is an important factor also in microgravity. Detailed results on the behavior of bubbles and on the superheated liquid layer show that the heat transfer mechanisms can be divided in two groups : the primary mechanisms which directly take energy from the wall and the secondary mechanisms which transport the energy stored in the fluid by the primary mechanisms, from the vicinity of the wall to the bulk liquid. The secondary mechanisms appear not to limit primary mechanism heat transfer which explains the weak influence of gravity on heat transfer. From the study of equations governing primary mechanisms and the definition of new scales, a correlation is built to predict heat transfer in microgravity for a wide variety of fluids. In the sounding rocket experiment, the influence of non-condensable gases was studied. The existence of two regimes of boiling heat transfer with non-condensable gas is established. The temperature in the primary bubble is directly measured and the influences of both Marangoni convection and non-condensable gas on both heat transfer and bubble growth are also considered.

Pulse tube cryocoolers (PTC) are a class of rugged and high-endurance refrigeration systems that operate without moving parts at their low temperature ends, and are capable of reaching temperatures down to and below 123 K. PTCs are particularly suitable for applications in space, guiding systems, cryosurgery, medicine preservation, superconducting electronics, magnetic resonance imaging, weather observation, and liquefaction of gases. Applications of these cryocoolers span across many industries including defense, aerospace, biomedical, energy, and high tech. Among the challenges facing the PTC research community is the improvement of system efficiency, which is a direct function of the regenerator component performance. A PTC implements the theory of oscillatory compression and expansion of the gas within a closed volume to achieve desired refrigeration. An important deficiency with respect to the state of art models dealing with PTCs is the limited understanding of the hydrodynamic and thermal transport parameters associated with periodic flow of a cryogenic fluid in micro-porous structures. In view of the above, the goals of this investigation include: 1) experimentally measuring and correlating the steady and periodic flow Darcy permeability and Forchheimer’s inertial hydrodynamic parameters for available rare-Earth ErPr regenerator filler; 2) employing a CFD-assisted methodology for the unambiguous quantification of the Darcy permeability and Forchheimer’s inertial hydrodynamic parameters, based on experimentally measured steady and periodic flow pressure drops in porous structures representing recently developed regenerator fillers; and 3) performing a direct numerical pore-level investigation for steady and periodic flows in a generic porous medium in order to elucidate the flow and transport processes, and quantify the solid-fluid hydrodynamic and heat transfer parameters. These hydrodynamic resistances parameters were found to be significantly different for steady and oscillatory flows.

Cryocoolers are closed cycle devices which produce cooling below 120 K. Usually, one or two linear motors are used to drive one pulse tube cryocooler. Cryocoolers are used for various applications like, cooling of infra red detectors, cryo surgical knife, cryogen recondenser etc. In this thesis the design development and testing of Twin Pulse Tube Cryocooler (TPTC) are discussed. TPTC consists of two pulse tubes driven by dual piston head linear compressor. This dual piston linear compressor is operated using single linear motor. Using this configuration, cooling power is doubled with reduced cost of compressor. The design, fabrication and testing of Linear Moving Magnet Synchronous Motor (LMMSM) based dual piston head linear compressor are carried out indigenously. Finite Element Method (FEM) analysis is used for estimating eddy current loss and flux distribution pattern in various mover configurations of the linear motor. The developed fabrication and assembly procedure of linear motor are discussed in detail. The mover of linear motor is supported by using a pair of cross armed C – type flexures. These flexures are designed using FEM and are fabricated indigenously. The flexure pairs are tested for 108 cycles with ± 3 mm stroke length of linear motor before assembling compressor. Linear motor is usually required to be operated at different frequencies. Thus, a variable frequency and variable voltage Pulse Width Modulated (PWM) based power supply is designed using analog circuits like Op-Amps. This cost effective power supply is capable of delivering 27 A at 100 V with frequency range of 25 Hz to 80 Hz continuously. Sage software was used to carry out 1-D simulation and obtain dimensions of various Pulse Tube Cryocooler (PTC) components. Various pulse tube configurations like Joint Twin PTC, Twin PTC with buffer volume and single PTC with buffer volume were carried out. A Computational Fluid Dynamics (CFD) Fluent 2-D analysis was carried out for single PTC with buffer volume. The fabrication and assembly procedure of PTC is discussed in detail. A novel method of heat exchanger fabrication was developed and analyzed using FEM and its performance is tested experimentally. The twin PTC is operated at 34 bar and 48 Hz. A light weight High Temperature Superconductor (HTS) based level sensor is developed to monitor the cryogen level. The developed sensor was calibrated against discrete diode array and pre-calibrated continuous capacitance type level sensor. The calibrations were carried out in indigenously designed and fabricated 4-wall cryostat using Liquid Nitrogen (LN2) and LOX as cryogen. LabVIEW software based data acquisition was designed for testing, recording and monitoring the performance of twin PTC and level sensors during experiments.

L'imagerie par résonance magnétique (IRM) est une modalité qui offre de bons contrastes et une bonne résolution spatiale, mais qui souffre d'un important problème de sensibilité. Pour répondre à cette problématique, le paradigme actuel est d'accroitre le champ magnétique des aimants d'IRM. Ceci mène toutefois à une explosion des coûts et à des contraintes accrues vis-à-vis des patients. L'approche que nous présentons est radicalement différente~: il s'agit de travailler à champ faible. Les antennes classiques n'étant pas assez sensibles pour recueillir le signal, l'idée est d'utiliser des SQIF. Ces derniers sont une nouvelle technologie d'antennes supraconductrices ultra-sensibles basées sur les réseaux de SQUID. Le projet vise à optimiser les capteurs SQIF et à les adapter pour la première fois à la RMN afin de mesurer un signal sur un aimant à 0.2~T.Pour ce faire, nous avons développé et étudié les performances de nouvelles architectures d'antennes SQIF afin de définir la géométrie la plus adaptée à la RMN. Nous avons également cherché à mieux comprendre comment le contexte d'utilisation de ces nouvelles antennes pouvait influencer leurs performances. Le jeu d'antennes le plus performant réalisé avait un facteur de transfert de 8.4~kVperT et un seuil de détection de 190~fTperHz. Il fut également observé que la présence d'un champ magnétique pendant le refroidissement de ces capteurs supraconducteurs dégradait leur réponse, phénomène à prendre en compte en RMN.Un Démonstrateur Super-QIF intégrant un SQIF dans l'IRM à 0.2~T fut conçu en tenant compte des contraintes géométriques et de l'environnement magnétique. Après sa fabrication, la température du cryostat était de 50~K, donc suffisante pour le bon fonctionnement des SQIF. Les premiers tests ont montrés que la présence du système ne perturbait pas le signal de RMN.Le démonstrateur est toujours en cours de développement et devrait permettre de mesurer un de RMN dans les mois à venir. À long terme, ces travaux pavent la voie à des applications des SQIF en IRM à champ terrestre. / Magnetic resonance imaging (MRI) is a modality that offers good contrasts and good spatial resolution, but suffers from a significant sensitivity problem. To address this issue, the current paradigm is to increase the magnetic field of MRI magnets. However, this leads to an explosion of costs and to increased constraints on patients. The approach we present is radically different: it involves working in a weak field. As conventional antennas are not sensitive enough to collect the signal, the idea is to use SQIF. These are a new ultra sensitive superconducting antenna technology based on SQUID networks. The project aims to optimize SQIF technology and adapt it to measure an NMR signal in a 0.2~T magnet.To do this, we developed and studied the performance of new SQIF antenna architectures in order to define the geometry most suitable for NMR. We also sought to better understand how the context of use of these new antennas could influence their performance. The best performing antennas set had a transfer factor of 8.4~kVperT and a detection threshold of 190~fTperHz. It was also observed that the presence of a magnetic field during the cooling of these superconducting sensors degraded their response, a phenomenon to be accounted for in NMR.The Super-QIF Demonstrator incorporating a SQIF in the 0.2~T MRI was designed considering the geometric constraints and the magnetic environment. After its assembly, the temperature of the cryostat was 50~K, therefore sufficient for the proper operation of SQIF. The first tests showed that the system presence did not disturb the NMR signal.The demonstrator is still under development and is expected to measure an NMR signal in the forthcoming months. In the long term, this work paves the way for applications of SQIF in Earth's field MRI.

No description available.

The diploma thesis is divided into two main parts. The first part describes the production of chrome and cobalt tips for SP-STM with subsequent testing of chrome tips on the Fe-Ir system (111). Furthermore, the first results from the growth studies of niobium on iridium(111) are presented. In the second part is described in detail the experimental LT-STM microscope of the Faculty of Physical Engineering. The chapter deals with the development of the microscope and its testing on a HOPG sample under atmospheric and vacuum conditions. The chapter describes the biggest problems which were solved when the microscope was puting into operation state. The second part also introduces the design of a new vacuum transport system, which consists of a tip and sample transport pallet. At the end of the second part is described the testing of cooling systems for LT-STM and the design of their modifications.