PhD, Faculty of Engineering and the Built Environment, University of the Witwatersrand / In this study the heat transfer and frictional pressure drop performance characteristics of plate heat exchangers (PHE’s) used as refrigerant liquid overfeed evaporators were investigated. PHE’s have been gaining new applications in the refrigeration industry, especially as evaporators, during the last few decades, but the available information in the open literature for operation in this mode is rather limited. This study aims to extend the knowledge of PHE evaporator performance and to develop a model for use in evaluating heat transfer and pressure drop over as wide a range of operating conditions as possible. A laboratory experimental facility was constructed and the thermal-hydraulic characteristics of three middle-size industrial PHE’s were measured. The exchangers all had 24 plates of the same size but with different chevron angle combinations of 28°/28°, 28°/60°, and 60°/60°. Two sets of tests were carried out with the three units: single-phase performance tests with water, and evaporator performance tests with R134a and R507A, for which the exchangers operated as refrigerant liquid over-feed evaporators. The tests with water served to provide accurate water-side heat transfer information for the evaporator performance analysis which is the primary purpose of this study. In the evaporator performance tests, refrigerant flow boiling heat transfer and two-phase pressure drop data were obtained under steady conditions, over a range of heat flux from 1.9 to 6.9 kW/m2, refrigerant mass flux from 5.6 to 31.4 kg/(m2s), outlet vapour quality from 0.2 to 0/95, and saturation temperatures from 5.9 to 13.0 °C. Additional field data of thermal performance were collected on an ammonia and a R12 PHE water chiller, operating as thermo-siphon evaporators at their design working conditions. All experimental data were reduced and analyzed to obtain the refrigerant-side heat transfer coefficients and frictional pressure drops in the PHE evaporators. The heat transfer results showed a strong dependence on heat flux and a weak dependence on mass flux, vapour fraction and the chevron angle. Along with the ii observations from the ammonia and R12 evaporators, it is concluded that the dominating heat transfer mechanism in this type of evaporator is nucleate boiling rather than forced convection. In contrast to the heat transfer characteristics, the refrigerant two-phase frictional pressure drop was found to be strongly influenced by mass flow rate, vapour fraction and also the chevron angle. An almost linear increase of the frictional pressure drop with the homogeneous two-phase kinetic energy per unit volume was observed for both refrigerants. Based on the experimental data, correlations were developed for predicting the refrigerant boiling heat transfer coefficient and two-phase frictional pressure drop in PHE liquid over-feed evaporators. Two correlations were developed for boiling heat transfer, one of these reflecting the h-q relationship in pool boiling, the other with all constants and exponents determined by regression analysis. The mean absolute errors are respectively 7.3% and 6.8% for these correlations. For two-phase frictional pressure drop, data were correlated using two established methods, namely the homogeneous and the Lockhart-Martinelli methods, with means absolute errors of 6.7% and 4.2%, respectively. The homogeneous model showed a slightly higher discrepancy with the experimental data but is likely to be more physically sound for PHE evaporators, and is much simpler to apply. Validation of these correlations with other data has been difficult due to the shortage of published information. For other refrigerants operating at comparable conditions, these correlations should serve as a guide, while more accurate design or evaluation may need to be based on further testing. The performance analysis carried out in this study was based on systematic experimental investigations and field tests on industrial PHE units. Correlations were developed covering a rather extensive range of flow parameters, plate geometry and various refrigerants. Such correlations have not been reported previously for PHE liquid over-feed evaporators. The results simplify the performance analysis of PHE evaporators and provide a reliable thermalhydraulic model of PHE liquid over-feed evaporators, which can be used for system modeling of water-chilling machines employing this type of evaporator.

The transition from fluorinated gases to natural refrigerants could be key to reducing the impacts of climate change. Ice rinks are energy-intensive buildings, with large heating and cooling demands. The pumping power required to move the secondary refrigerant typically accounts for a sizable amount of the energy use of the refrigeration system. The use of aqua ammonia as a secondary fluid shows promising results, with pumping power use of about half that required of ethylene glycol, environmental friendliness, and low corrosivity to steel components. Aquaammonia is still novel but is currently in usein 34 Swedish ice rinks. This thesis addresses questions regarding evaporation rates, performance, material compatibility, safety, and regulations of aqua ammonia in ice rink systems. Laboratory tests were performed to assess aqua ammonia evaporation rates during storage and operations. Long-duration concentration change, in well-sealed and well-stored containers, indicated low levels of evaporation for all tested concentrations samples. Short-term concentration in open-air conditions, indicated rapid rates of evaporation, with nearly full evaporation of all ammonia concentration occurring within only 90seconds of open-air exposure. Testing of sample-mixtures containing contamination by substances aquaammonia was likely to encounter during retrofit replacement situations determined that aquaammonia and calcium chloride produce flakey sedimentation. Additionally, lower concentrations of aquaammonia are slightly more prone to becoming basic when mixed with the tested substances, such as calcium chloride. Historical data of systems operating with aquaammonia were analyzed for energy performance. While pumping requirements typically account for 10-20% of the energy for refrigeration, the pumps of the rinks studied with aqua ammonia accounted for only 1.2 to 4.2%. However, data availability and system configuration anomalies suggest additional analyses are required. Furthermore, best operating, maintenance, and safety practices were analyzed and global regulatory restrictions were examined. Surveying of manufacturer material compatibility information found copper and brass to be incompatible with aqua ammonia, while steel and carbon steel are recommended. Various plastics were addressed by the manufacturers, notably PVC was found to be acceptable for use with aqua ammonia. A cost comparison between aqua ammonia and calcium chloride found aqua ammonia to require less expensive equipment. Finally, aqua ammoniawas determined to fall outside of the classification of refrigerants in several international refrigeration codes. Various additional safety regulations guiding personal protective equipment, exposure times, transportation, storage, and disposal regulations were catalogued as part of this work. In summary, aqua ammoniawas found to be a safe substance with performance that matches theoretical energy savings. Pumping requirements were reduced from 10-20% to approximately 1-5% of overall refrigeration system energy use. Necessary safety precautions were found to be much less stringent than high concentrations of ammonia and aqua ammonia was ascertained to fall outside of refrigeration codes in Europe, Canada, and the United States of America. / Övergången från fluorerade gaser till naturliga köldmedier kan vara nyckeln till att minska effekterna av klimatförändringen. Isbanor är energikrävande byggnader med stora värme-och kylbehov. Den pumpeffekt som krävs för att pumpa köldbärare står vanligtvis för en stor mängd energianvändning i kylsystemet. Användningen av ammoniakvatten som köldbärare visar lovande resultat, med användning av pumpeffekt på ungefär hälften som krävs av etylenglykol, miljövänlighet och låg korrosion för stålkomponenter. Ammoniakvattenär fortfarande ny men används för närvarande i 34 svenska isbanor. Detta exjobb behandlar frågor om avdunstningshastigheter, energiprestanda, materialkompatibilitet, säkerhet och föreskrifter för ammoniakvatten i isbanasystem. Laboratorietester utfördes för att bedöma avdunstningshastigheter för ammoniakvatten under lagring och drift. Långvarig koncentrationsförändring, i väl tillslutna och välförvarade behållare, indikerade låga nivåer av avdunstning för alla testade koncentrationsprover. En kortvarig koncentration under friluftsförhållanden indikerade snabba avdunstningshastigheter, med nästan full avdunstning av all ammoniakkoncentration inom endast 90 sekunder efter exponering. Testning av olika ammoniakvatten lösningar som innehåller föroreningar skulle sannolikt påträffas vid byte av köldbärare. Dessutom är lägre koncentrationer av ammoniakvatten lite mer benägna att bli basiska när de blandas med de testade ämnena. Historiska data för system som arbetar med ammoniakvatten analyserades med avseende på energiprestanda. Medan pumpeffekten vanligtvis står för 10-20% av kylenergin, pumparna för de studerade isbanorna med ammoniakvatten behövde bara för 1,2 till 4,2%av kylenergi. Datatillgänglighet och systemkonfigurationsavvikelser föreslår dock att ytterligare analyser krävs. Dessutom analyserades bästa metoder för drift, underhållning och säkerhet och globala regleringsbegränsningar. Kartläggning av tillverkarens materialkompatibilitetsinformation visade att koppar och mässing var oförenliga med ammoniakvatten, medan stål och kolstål rekommenderas. Olika plast och packning materialbehandlades, särskilt PVC var acceptabelt för användning med ammoniakvatten. En kostnadsjämförelse mellan ammoniakvatten och kalciumklorid köldbärare visade att ammoniakvatten krävde billigare utrustning. Slutligen visades det att ammoniakvatten faller utanför klassificeringen av köldmedier i flera internationella kylnormer. Olika ytterligare säkerhetsreglersom styr personlig skyddsutrustning, exponeringstider, transport, lagring och bortskaffande föreskrifter katalogiserades som en del av detta arbete. Sammanfattningsvis visade ammoniakvatten vara ett säkert ämne med prestanda som matchar teoretiska energibesparingar. Pumpeffekten minskade mellan 10-20% och 1-5% av den totala energianvändningen i kylsystemet. Nödvändiga säkerhetsåtgärder visade sig vara mycket mindre stränga än att höga koncentrationer av ammoniak och ammoniakvatten konstaterades falla utanför kylnormeri Europa, Kanada och USA.

HCFC-22 is the world�s most widely used refrigerant. It serves in both residential and commercial applications, from small window units to large water chillers, and everything in between. Its particular combination of efficiency, capacity and pressure has made it a popular choice for equipment designers. Nevertheless, it does have some ODP, so international law set forth in the Montreal Protocol and its Copenhagen and Vienna amendments have put HCFC-22 on a phase out schedule. In developed countries, production of HCFC-22 will end no later than the year 2030. Zeotropic blend HFC-407C has been established as a drop-in alternative for HCFC-22 in the industry due to their zero Ozone Depletion Potential (ODP) and similarities in thermodynamic properties and performance. However, when a system is charged with a zeotropic mixture, it raises concerns about temperature glide at two-phase state, differential oil solubility and internal composition shift. Not enough research has been done to cover all aspects of alternative refrigerants applications in the systems. This research intended to explore behavior of this alternative refrigerants compare to HCFC-22 and challenges facing the industry in design, operation service and maintenance of these equipments. The purpose of this research is to investigate behavior of R407C refrigerant in chiller systems. This includes performance and efficiency variations when it replaces R22 in an existing system as well as challenges involved maintaining the system charged with R407C. It is a common practice in the industry these days to evacuate and completely recharge when part of the new refrigerant blend was leaked from the system. This has proved to be extremely costly exercise with grave environmental ramifications. This research is intended to address challenges faced in the real world and practical terms. Theoretical and experimental approaches used as a methodology in this work. The system mathematically modeled to predict detailed system performance and effect of the leak at various conditions. To make this feasible and accurate enough, two separate approaches made, first system performance for pure R22 and R407C, and second system subjected to range of leak fractions. The earlier model was relatively straight forward when compared to the latter. Modeling a system charged with R407C ternary mixture and subjected to range of leaks posed enormous challenges. A sophisticated experimental test apparatus was also designed and built. Comprehensive and detailed tests at various conditions were conducted with special attention on instrumental accuracy and correct methodology. The first part has been successfully modeled and predicted all the factors and performance with excellent accuracy when compared to the test results. In these approaches pure refrigerants R22 and R407C were used and simulated the system behavior at range of conditions. However, the second part was the most challenging ever. Comprehensive leak process simulations produced trends of R32/R125/R134a composition change as function of rate of leak. Starting from this point, equations have been created to represent the composition change as function of percentage of the leak. The system thermodynamic cycle was also modeled to calculate capacity, power input and COP at the range of the conditions. Despite many affecting parameters and complexity of the model, the mathematical model successfully predicted the test outcome with a very reasonable accuracy, averaging around 3% with some times reaching to 5 to 6%. On the experimental stage the system charged with the new HFC-407C was deliberately subjected to refrigerant leak at various leak stages. The aim was to objectively determine to what extend the gas leak can be still acceptable without going through the expensive complete gas charge. The effect of leak was tested and verified at 10% steps, from 10% up to 50% mass fraction for the total charge. It has been observed that at the leaks beyond 30%, the adverse effect on the capacity becomes more significant, from 8 to about 15% decrease. While the power input decreased at slower pace, from 3% up to about 8% depending on the test conditions. This translated to COP decrease ranging from 4 to about 7%. This capacity loss and efficiency decrease are significant figures which suggests that the system, here chiller, can not be allowed to degrade the performance to that extend and still continue operating.

El tubo capilar con intercambio de calor líquido-succión (CT-LSHX) es un componente ampliamente utilizado en refrigeradores domésticos. Trabajos recientes han indicado que la entrada del tubo capilar era bifásica, aunque condiciones subenfriadas estaban medidas a la salida del condensador. El objetivo de esta tesis doctoral es examinar las condiciones reales a la entrada del tubo capilar de un refrigerador doméstico mediante el uso de un banco de pruebas innovador. Se instalaron tubos transparentes a la salida del condensador y a la entrada del tubo capilar con el fin de visualizar el flujo. La campaña de visualización experimental revela que el flujo a la entrada del tubo capilar era bifásico a pesar de la medición de un cierto subenfriamiento, independientemente de la posición del filtro instalado a la entrada del capilar (horizontal o vertical), la dirección del flujo (hacia arriba o hacia abajo) y la carga de refrigerante. Este estudio demuestra también que el filtro no estaba actuando como un acumulador ya que el nivel de líquido del capilar siempre siguió la entrada del tubo capilar, independientemente de la longitud del tubo capilar dentro del filtro. Se plantearon dos hipótesis para explicar el fenómeno: una condición de no equilibrio del refrigerante y/o un desequilibrio entre el caudal másico del compresor y del capilar, es decir, el sistema estaría equipado con un capilar no bastante restrictivo en comparación con las necesidades del compresor. El condensador original refrigerante-aire fue reemplazado por un condensador refrigerante-agua para evaluar, a partir del balance de calor en el condensador de agua, las condiciones del refrigerante a la salida del condensador y, por lo tanto, a la entrada del tubo capilar. Las mediciones indican un flujo bifásico no equilibrado compuesto de vapor y líquido subenfriados a la entrada del tubo capilar. Para verificar si la presencia de flujo bifásico se debía a un desequilibrio entre el caudal másico del compresor y del capilar, el diseño del banco de prueba se modificó utilizando un diámetro de tubo capilar más pequeño y aumentando la velocidad del compresor. Con esta nueva configuración, se alcanzó a llenar de líquido el filtro y, por lo tanto, tener condiciones exclusivamente líquidas a la entrada del tubo capilar. Se realizó una comparación de prestaciones entre un flujo bifásico y un flujo únicamente líquido a la entrada del capilar. Los resultados revelan que el COP fue mayor cuando la entrada del capilar era sólo líquida. / El tub capil·lar amb intercanvi de calor líquid-succió (CT-LSHX) és un component àmpliament utilitzat en refrigeradors domèstics. Treballs recents han indicat que l'entrada del tub capil·lar era bifàsica, encara que condicions sub-refredades estaven mesurades a l'eixida del condensador. L'objectiu d'aquesta tesi doctoral és examinar les condicions reals a l'entrada del tub capil·lar d'un refrigerador domèstic mitjançant l'ús d'un banc de proves innovador. Es van instal·lar tubs transparents a l'eixida del condensador i a l'entrada del tub capil·lar amb la finalitat de visualitzar el flux. La campanya de visualització experimental revela que el flux a l'entrada del tub capil·lar era bifàsic malgrat el mesurament d'un cert sub-refredament, independentment de la posició del filtre instal·lat a l'entrada del capil·lar (horitzontal o vertical), la direcció del flux (cap amunt o cap avall) i la càrrega de refrigerant. Aquest estudi demostra també que el filtre no estava actuant com un acumulador ja que el nivell de líquid del capil·lar sempre va seguir l'entrada del tub capil·lar, independentment de la longitud del tub capil·lar dins del filtre. Es van plantejar dues hipòtesis per a explicar el fenomen: una condició de no equilibri del refrigerant i/o un desequilibri entre el cabal màssic del compressor i del capil·lar, és a dir, el sistema estaria equipat amb un capil·lar no bastant restrictiu en comparació amb les necessitats del compressor. El condensador original refrigerant-aire va ser reemplaçat per un condensador refrigerant-aigua per a avaluar, a partir del balanç de calor en el condensador d'aigua, les condicions del refrigerant a l'eixida del condensador i, per tant, a l'entrada del tub capil·lar. Els mesuraments indiquen un flux bifàsic no equilibrat compost de vapor i líquid sub-refredats a l'entrada del tub capil·lar. Per a verificar si la presència de flux bifàsic es devia a un desequilibri entre el cabal màssic del compressor i del capil·lar, el disseny del banc de prova es va modificar utilitzant un diàmetre de tub capil·lar més xicotet i augmentant la velocitat del compressor. Amb aquesta nova configuració, es va aconseguir omplir de líquid el filtre i, per tant, tindre condicions exclusivament líquides a l'entrada del tub capil·lar. Es va realitzar una comparació de prestacions entre un flux bifàsic i un flux únicament líquid a l'entrada del capil·lar. Els resultats revelen que el COP va ser major quan l'entrada del capil·lar era només líquida. / Capillary tube with liquid-to-suction heat exchanger (CT-LSHX) is a component widely used in household refrigerators. Recent works have indicated that even when measuring subcooled conditions at the condenser outlet, the actual capillary tube inlet is two phase-flow. The aim of this PhD thesis is to examine the actual conditions at the capillary tube inlet of a household refrigerator by using an innovative test bench. Transparent tubes were set up at the condenser outlet and capillary tube inlet. The experimental visualisation campaign reveals that the capillary tube inlet was two-phase flow despite the measurement of a certain subcooling, regardless of the filter position (horizontal or vertical), flow direction (upward or downward) and refrigerant charge. This study also demonstrates that the filter was not acting as an accumulator since the liquid level of the capillary always followed the capillary tube entrance, regardless of the capillary tube length inside the filter. Two hypotheses were then posed to explain the phenomenon: a non-equilibrium condition of the refrigerant and/or an unbalanced matching between compressor and capillary tube, that is, the system would be equipped with a capillary tube with a notably large expansion capacity compared to the needs of the compressor. The original refrigerant-to-air condenser was replaced by a refrigerant-to-water condenser to assess, from the heat balance at the water condenser, the refrigerant conditions at the condenser outlet and therefore, at the capillary tube inlet. Measurements indicate a non-equilibrium two-phase flow composed of subcooled vapour and liquid at the capillary tube inlet. To verify if the presence of two-phase flow was due to unbalanced matching between the capillary tube and compressor, the test bench design was modified by using a smaller capillary tube diameter and increasing compressor speed. Fully liquid conditions at the capillary tube inlet were reached with this new configuration. A performance analysis comparison between a capillary tube inlet composed of vapour and liquid and a capillary tube inlet composed of only liquid was also performed. Results reveal that COP were higher in cases of fully liquid conditions at the capillary tube inlet. / Bardoulet, LV. (2018). Non-adiabatic capillary tubes in high efficiency household refrigerator: an experimental study [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/113170 / TESIS

This study aimed to facilitate evaluation of alternative refrigerants for the air conditioner market. In order to achieve this target, two objectives were set. The first being the identification of alternative refrigerant with regard to regulations and trends. The second being enabling of thermodynamic evaluation of refrigerants for single components in air conditioners via design and installation of a test rig. A literature review was conducted to investigate the regulations, standards and trends for nine regions with high market shares. Furthermore, refrigerant substitutes for R410A and R22 where identified. The literature showed strong indications that a global HFC phase down is on the horizon, but that the approach and urge for such a phase down varies between regions where three main priorities could be seen; efficiency, GWP values and safety. Comparing these priorities with simulated refrigerant characteristics such as Carnot efficiency, GWP values, volumetric capacity and the liquid density using RefProp, identified alternatives. Further the literature showed that the lower flammability limit (LFL) and the amount of charge allowed were limiting factors for flammable refrigerant. There are many new refrigerants that could have less charge for the same capacity the LFL however restricts the refrigerants like R290, R441A and R443A only to be used in small systems. A test rig was designed and constructed in order to enable testing of single components in air conditioners. To verify the test rig, tests conducted with an evaporator using two refrigerants: R410A and R32. The reliability and validity of the tests was studied by comparing the results from the air side and refrigerant side, via uncertainty calculations using the GUM method and by a thermodynamic evaluation. The results of the repetition tests showed an expanded uncertainty, with a confidence interval of 95%, of 26 W for a cooling capacity of 2190W for R410A (Q̇evap,R410A=2190±26W). For R32 the expanded uncertainty was 27W for a cooling capacity of 2795W (Q̇evap,R32=2795±27W). Also the test rig was verified to be used for analyzing detailed evaluation of evaporators such as looking at heat transfer and the differential pressure drop. Further the study presented six conclusions: When evaluating refrigerants regional priorities between efficiency, safety and GWP values, refrigerant characteristics and type of unit need to be considered. Safety standards need to be more acceptable towards flammable refrigerants in order to meet low GWP targets. The change in market trends leads to new roles for the refrigerant and compressor suppliers and put higher demand on air conditioner manufacturers to consider refrigerant characteristics in product development. The importance of experimental thermodynamic evaluation on refrigerants effect on single components is increasing. Performance of different refrigerant for single components can be evaluated for optimizing cycle performance. Leapfrogging in the developing world can lead to a faster introduction of low GWP refrigerants.

Diploma thesis deals with the problem of refrigerant cooling needs for air conditioning systems of buildings. Summary focuses on the theoretical basics and the physical nature of refrigeration and air conditioning technology. The consequences of split unite on microclimate in the room was experimentally tested and simultaneously investigated happenings associated to its activity. The aim is to unify the theoretical and experimentally obtained facts and apply them in the designing of air conditioning units. Design of air conditioning systems builds on my bachelor thesis, "Hot-air heating of gym", which subject was the ventilation system of gym.

Master of Science / Department of Architectural Engineering and Construction Science / Julia A. Keen / This report addresses the operation, use, and design of air-to-air variable refrigerant flow systems, also known as VRF. Relatively new to the United States, these HVAC systems have potential to reduce energy consumption and utility costs in the correct applications. Although useful in many applications, the best building types for VRF are those requiring a large number of zones and with low ventilation air requirements. The report explains design and system selection considerations and accordingly presents two flowcharts to help designers implement this system. To show how the system compares to traditional technologies in terms of efficiency and cost, the report presents results from several studies comparing VRF to other systems. In addition, an energy modeling study is conducted to clarify the effect of climate on the system; this study established air-to-air VRF as having highest energy consumption in dry, southern climates, based on energy use and operating costs. With this report, HVAC designers can learn when air-to-air VRF is an acceptable method for providing heating and cooling in a building.

As environmental protection issue become the most hot global issues recently, Air Conditioning Industry has to face not only its own management and marketing problems, but also the responsibilities to environmental pollution. Thus, how to deal with the external pressure, the international regimes, and internal pressure become more and more important toward Air Conditioning Industry. How could Air Conditioning Industry take balance between international regimes and its own growth and profit? In addition, it also briefly discusses how Air Conditioning Industry could use its own resource and the strategy of diversification to create different road, making a high pollution industry transform to a green industry. Thus, this study is divided into external and internal factors which make AC industry have to change by strategy of diversification, and cases studying of how Air Conditioner transform itself to fit in the external rapidly changing world. The transformation relies on the effort and cooperation of stakeholders of government, association, and enterprises. Consequently, how these stakeholders achieve the goals on development of Taiwan's heat pump market might be more and more important on Air Conditioning Industry's future.

With tighter regulations on the use of Hydroflurocarbons (HFCs) due to their high GWP (Global Warming Potential), many supermarket operators are looking for alternative refrigerants. To contribute to this, the objectives of this thesis are to investigate the practicality, environmental benefits and economic viability of an all-CO2 transcritical refrigeration system suitable for small supermarkets. Whilst the environmental benefits of using CO2 as a refrigerant are clear, there is rather limited practical and technical knowledge on the design and operation of these systems. In this work, simulation models of a transcritical ‘booster’ CO2 refrigeration system have been developed to investigate and evaluate its performance against that of a traditional HFC system. The models were verified using test results from an experimental CO2 system built at Brunel University. To evaluate the performance of the CO2 refrigeration system in the field, energy data from a real supermarket employing a HFC refrigeration system was used for energy simulations. The results demonstrate that the annual energy consumption of the CO2 refrigeration system in a small supermarket in Northern Ireland would be equivalent to that of a typical HFC refrigeration system. However, the low GWP of CO2 will result in a 50% reduction in the combined direct and indirect CO2 emissions over the operational life of the system assuming an annual leakage rate of 15%. Northern Ireland has a high number of small supermarkets due to its rural population, approximately 615. The CO2 system presented in this research could replace the existing R404A systems in these small supermarkets resulting in emissions reduction of up to 188,752 tCO2e. This research has developed selection techniques and criteria to be considered by supermarket designers and operators when developing national strategies for the eventual phase-out of HFC refrigerants in all supermarket sizes. The validated simulation models developed in this research combined with the detailed geographical and refrigeration load ratio analysis presented, will provide valuable information that will assist system designers and operators in the efficient design and optimisation of CO2 technology for small supermarkets.

Ethanol is a renewable energy source that could decrease society's dependence on fossil fuels, while reducing greenhouse gas emissions. Producing ethanol on a small scale on South African farms could provide farmers with the capability of increasing their profits by reducing their input cost. Ethanol can be directly used as fuel and could supply alternative products to their market. This study evaluated the feasibility of using an ammonia/water hybrid heat pump in the ethanol production process. A model for the material and energy balance of a small scale ethanol plant was simulated, to obtain the requirements to which the hybrid heat pump had to adhere. A two stage hybrid heat pump (TSHHP) was then modelled. It is capable of operating at high temperatures and it has high temperature lift capabilities, which are suitable in the production of ethanol. The results from the model demonstrated that the TSHHP could operate at an average temperature lift of 106°C with a maximum temperature of heat delivery as high as 142°C and cooling as low as 9°C. Simultaneous heating and cooling demand in the ethanol production process can be met with the TSHHP. For the TSHHP model, 120 kW of heating and 65 kW of cooling is supplied while maintaining a COP of 2.1. The model accuracy was also verified against another simulation program. Implementation of the TSHHP into the ethanol plant was then discussed, as well as methods to optimize production by energy management. When compared to conventional heating and cooling systems, it was found that the TSHHP provides a more cost effective and energy efficient way of producing ethanol. The economic evaluation demonstrated that the installation cost of the TSHHP would only be 63% of the price of a conventional system. The main advantage is that the TSHHP uses only 38% of the energy used in a conventional system. / Thesis (M.Ing. (Mechanical Engineering))--North-West University, Potchefstroom Campus, 2009.