In last decade, there is a large increase in installed capacity of wind power. Asmore wind power is integrated into utility networks, related technologychallenges draw much attention. The doubly fed induction generator (DFIG) isthe mainstream choice for wind turbine generator (WTG) in current market andthe object of this thesis. It is very sensitive to voltage dips. The enhancement oflow voltage ride through (LVRT) is one of the most important issues for DFIG,and many works have already been done to provide solutions.In current works, the voltage dip waveforms that are applied in LVRTrelated works are largely different from waveforms in reality, because they failto consider the the effect of realistic wind farm configurations on waveforms ofvoltage dips and significant influences of additional characteristics of voltagedips. The true impact of the voltage dip needs to be assessed in performanceevaluation and development of LVRT methods. To support the development ofpractical LVRT capacity enhancement solutions, the application of voltage dipknowledge is definitely demanded.In this thesis, the characteristics of realistic waveform voltage dips in windfarm are analyized based on voltage dip knowldege from power quality field,measured voltage dip from industry and realistic wind farm configurations.Classical analysis theory is applied to explain the principles of the impact ofvoltage dip characteristics on dynamic behavior of DFIG. The impacts of manywidely neglected characteristics such as phase angle jump (PAJ), point on wave(POW) of initiation and recovery, voltage recovery process, transformerconfigurations, load effect are revealed and verified by simulations. The impactof many voltage dip characteristics on DFIG are studied for the first time. / De senaste tio åren har sett en stor ökning av installerad effekt av vindkraft.Mer vindkraft i elnäten har lett till större uppmärksamhet om dess tekniskautmaningar. Den dubbelmatad asynkrongenerator (DFIG) är idag denvanligaste förekommande typen i vindkraftverk. Den är mycket känslig förspänningssänkningar. Förbättring av tålighet för spänningssänkningar (LVRT)är en av de viktigaste frågorna för DFIG, och många studier har redan söktlösningar.I befintliga studier om LVRT har spänningssänkningarna skiljt sig väsentligtfrån verkliga vågformer, då de inte har tagit hänsyn till realistiskavindparkkonfigurationer och betydande påverkan av ytterligare egenskaper hosspänningssänkningar. För att stödja utvecklingen av praktiska LVRT lösningarbehövs mer kunskap om spänningssänkningar för att bedöma dess verkligainverkan.Detta examensarbete förbättrar LVRT analysen av DFIG genom att tillämpakunskap om spänningssänkningar från elkvalitetsområdet, tillsammans medrealistiska vindparkskonfigurationer. Inflytandet av ändringar i fasvinkel(PAJ), fasvinkeln vid sänkning och återhämtning (POW), spänningsåterhämtning, transformatorkonfigurationer, last och många andra egenskaperav spänningssänkningar ingår också. Inflytandet av många egenskaper avspänningssänkningar studeras här akademiskt för första gången. Denkaraktäristik av realistiska spänningssänkningar som inträffar vid generatornspoler, och de effekter dessa har, studeras och förklaras genom teoretisk analysoch intensiva simuleringar.

<p> This study reports on karren forms on limestone dip slopes, which were recently exposed by deforestation on the Quatsino Formation and observable relationships of the karren features of a specific sl~pe are represented as a detailed map. Also, many relationships of gravitomorphic runnel characteristics are analyzed for significance. Runnel types being considered are Hortonian, decantation and composite forms. Solution runnel width, depth and width/depth ratio are studied in association with length. These relationships determine whether the runnel types conform to a theoretical model. Typical aeas·ares of the karren in this area were also recorded. Composite forms are the most abundant because Hortonian and decantation runnels amalgamate beyond about 3m to form composites. All the runnel types, excluding the decanters, illustrate the perfect minimum friction open-channel cross-section. </p> / Thesis / Bachelor of Arts (BA)

Implementation of solar power by photovoltaic modules in cold climates, such as northern Sweden, implies several challenges. Ice and snow coverage not only leads to reduction in energy production due to shading, but it also puts equipment at risk from additional weight. The goal of this thesis was to formulate a passive ice shedding coating for photovoltaics that could handle the demands of both high optical transmittance and durability. In addition, the coating should be environmentally friendly and low cost. For that purpose, a state-of-the-art, superhydrophobic sol-gel silica-based coating was selected with the focus on optimizing its transparency, wettability, and durability. Different concentrations of binder, tetraethyl orthosilicate (TEOS), and catalyst (HCl) in the sol were explored, as well as post-treatment temperatures and sol aging, Hydrophobization was done by self-assembly of a silane and plasma polymerization of a siloxane. The coatings were characterized by UV-Vis spectroscopy, contact angle measurements, Scanning Electron Microscopy (SEM), X-ray Photoelectron Spectroscopy (XPS), tape peel strength, freeze-thaw cycling, ice adhesion force and a field test. Superhydrophobic, anti-reflective coatings with high transmittance (88.5±1.9%) were achieved, with some of them retaining their superhydrophobic properties after 15 freeze-thaw cycles between room temperature and -20°C. The main findings were that the amount of TEOS in the sol has the largest influence on transmittance and strength, with more TEOS leading to less transparent but stronger coatings, and that calcination of the coatings greatly improves their durability.

Third-generation advanced high-strength steels (3G AHSS) are being developed to assist in vehicle light weighting so that fuel efficiency may be improved without sacrificing passenger safety. 3G-AHSS have received significant interest from the automotive industry as a critical candidate for their unique combination of high strength and ductility. However, due to selective oxidation of the principal alloying elements such as Mn, Si, Al, and Cr at the steel surface during the annealing stage prior to immersion in the galvanizing Zn(Al, Fe) bath, the process of continuous hot-dip galvanizing of these steel is challenging. This thesis determined the influence of annealing process parameters such as oxygen partial pressure and annealing time, on the selective oxidation and reactive wetting of an Fe-0.15C-5.56Mn-1.17Si-1Al (wt%) prototype 3G AHSS during intercritical annealing as well as continuous galvanizing. Simulated annealing and galvanizing were conducted on the prototype Fe-0.15C-5.56Mn-0117Si-1Al (wt%) 3G steel; Intercritical annealing heat treatments were carried out at 690˚C in a N2-5 vol pct H2 process atmosphere under dew points of 223 K (–50 °C), 243 (–30 °C) and 268 K (–5 °C). MnO was the major oxide formed at the outmost layer of the external oxides on all annealed samples. The experimental parameters, on the other hand, had a substantial impact on the morphology, distribution, thickness, and surface oxide coverage. The greatest Mn surface concentration as well as maximum surface oxide coverage and thickness was obtained by annealing the panels under the 223 K (–50 °C) and 243 (–30 °C) dp process atmospheres. The oxides formed under these process atmospheres largely comprised coarse, compact, and continuous film nodules. In contrast, MnO nodules formed under the 268 K (–5 °C) dewpoint process, exhibited wider spacing between finer and thinner nodules, which was consistent with the internal oxidation mode, while under 223 K (–50 °C) dp process atmosphere, generally external oxidation took place. Poor reactive wetting was obtained for the panels annealed under the 223 K (–50 °C) dp process atmosphere for both the 60 s and 120 s holding times as well as the 243 K (–30 °C) dp process atmosphere for 120 s. This was attributed to the formation of a thick, compact oxide layer on the steel surface, which acted as a barrier between the substrate and Zn bath, preventing Fe dissolution from the substrate surface for the formation of the desired Fe2Al5Znx interfacial layer. However, a well-developed interfacial Fe-Al intermetallic layer was formed under the 268 K (–5 °C) and 243 (–30 °C) dp process atmospheres for intercritical annealing times of 60 s, which is indicative of a good reactive wetting since the thinner and nodule-like oxides on the steel surface after annealing encourage the reactive wetting. External oxides morphology plays a dominant role in facilitating the contact between Zn-alloy bath and the substrate via different mechanisms such as aluminothermic reduction which occurred for the sample annealed under the 268 K (–5 °C) dp process atmosphere. / Thesis / Master of Applied Science (MASc)

Polymer coatings are thin films of polymer deposited on different substrates for various applications. Such surface coatings can serve a functional purpose (adhesives, photographic films), protective purpose (anticorrosion), or decorative purpose (paint). Additionally, their composite coatings containing ceramic, or metal particles are often used to enhance durability, functionality, or aesthetics. Electrophoretic deposition (EPD) and dip coating are two promising methods for the fabrication of polymer and composite coatings due to the ease of fabrication, low cost, and high-volume production. EPD involves the electrophoresis of charged particles and their deposition on the electrode surface, which requires the colloidal particles to be charged in a stable suspension as a precursor solution for deposition. Many polymers cannot be deposited by EPD directly because of their charge neutrality and poor dispersion. Therefore, it is critical to develop efficient charging dispersants to modify electrically neutral polymers for their EPD. The approach was inspired by the strong solubilization power of bile acids in the human body. Two types of bile salts, cholic acid sodium salt and sodium chenodeoxycholate, and three types of biosurfactants, carbenoxolone sodium salt, glycyrrhizic acid, and 18β-glycyrrhetinic acid, which share similar structures with bile salts, were discovered for charging, dispersion, and EPD of different materials. The electrically neutral polymers (PTFE and PVDF), chemically inert materials (diamond, nanodiamond, graphene, carbon dots, carbon nanotubes and Zr-doped hydrotalcite (MHT)), and their composites can be well dispersed in suspension and deposited using these bio-surfactants as dispersants. It was found that the unique chemical structures of these biomolecules play vital roles in the surface modification and EPD of different materials. Moreover, the deposited polymer (PVDF, PTFE) and composite (PTFE-MHT) coatings can provide outstanding corrosion protection for stainless steel. The biomimetic and versatile strategy opens a way for the deposition of other electrically neutral materials through EPD. These findings also provide a promising strategy for selecting new dispersants for EPD. The deposition of high molecular weight (MW) polymers such as poly(ethyl methacrylate) (PEMA) at high concentrations in non-toxic solvents continues to be a challenge for dip coating. In this work, we firstly proposed using water-isopropanol as a co-solvent to dissolve high MW PEMA at high concentrations. It was found that water molecules can solvate carbonyl groups of PEMA and facilitate their dissolution. This method avoided the usage of toxic solvents and a long-time heating procedure for their removal. Moreover, it allows the fabrication of high-quality PEMA and composite coatings containing different flame retardant materials (FRMs), including double hydroxide LiAl2(OH)7.2H2O (LiAlDH), huntite, halloysite and hydrotalcite, through the dip coating method. A novel solid state synthesis method was proposed to fabricate LiAlDH, which is promising for the fabrication of other advanced DHs. Such composite coatings combined advanced properties of PEMA and functional properties of FRMs, such as corrosion inhibition and FR properties. / Thesis / Doctor of Engineering (DEng) / Polymer and composite coatings have been utilized for a wide range of applications due to their barrier properties, scratch and abrasion resistance, chemical resistance, and biocompatibility. Various techniques have been developed to fabricate polymer and composite coatings, such as electrophoretic deposition (EPD) and the dip coating method. However, limitations remain. EPD unitizes an electrical field to drive charged particles in a suspension toward conductive substrates to achieve film deposition. This process requires a stable suspension with charged particles, therefore, the electroneutral polymers present difficulties in their EPD. In addition, dissolving high molecular weight polymers at high concentrations in a non-toxic solvent is currently challenging, which is vital to utilize dip coating technique. The objective of this work was to develop advanced charging dispersants for EPD of electroneutral polymers and non-toxic solvents for dip coating of high molecular weight polymers. New biomimetic and versatile approaches have been developed for EPD of different electrically neutral polymers, chemically inert materials, and their composite coatings. A non-toxic co-solvent was proposed to dissolve high molecular weight polymer at high concentration for dip coating of the polymer and its composite coatings containing flame retardant materials. The results presented in this work showed the formation of high-quality films with multifunctionality and paved new strategies for further developments.

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<p> Intercritically annealed steels, such as dual-phase steels, have found widespread use in automotive structural components due to their high strength and ductility. Elements such as Mn, Al and Si, added to improve the mechanical properties are selectively oxidized during heat treatment and limit the ability of the alloy to be reactively wet during continuous hot-dip galvanizing. Subsequently, a limit has been placed on the amount of alloy which can be used if the steel is to be subsequently galvanized. The specifics of this limit have not been explored in detail, nor has the mechanism of decreased wettability been well demonstrated in the literature other than to say that the galvanizing reaction is limited by oxides on the surface.</p> <p> Using a force balance, it is shown that the presence of MnO on the surface of steels greatly reduces the wettability with a typical galvanizing bath (Zn-0.2wt%Al, Fe-saturated, 460°C). Furthermore, it was determined that this is caused by the additional and rate-limiting step of aluminothermic reduction of the oxide layer with the bath Al, required for subsequent inhibition layer formation. By using a low pO2 during annealing, the wettability was improved by reducing the thickness of the MnO layer when compared to intermediate and industrially common values of pO2. Using a high pO2 also resulted in improved wettability since the internal oxide which was formed did not reduce the wettability since it was not exposed to the bath alloy.</p> <p> Improvements in hardenability were also explored via dilatometry showing that the formation of bainite is delayed with increasing Mn content, as well as a decrease in transformation temperatures from γ during cooling (i.e. Ms and Bs). At ~5wt% Mn, only the the transformation to αM could be observed. This opens the door to higher strength, galvanized steels - as well as possibly galvanized martensitic steels.</p> / Thesis / Master of Applied Science (MASc)

<p> Aluminum is usually added to the zinc bath to form an Fe-Al interfacial layer which retards the formation of a series of Fe-Zn intermetallic compounds during the hot-dip galvanizing process. However, experimentally exploring the inhibition layer formation and obtaining useful experimental data to understand the mechanisms is quite challenging due to short times involved in this process. In this study, a galvanizing simulator was used to perform dipping times as short as O.ls and rapid spot cooling techniques have been applied to stop the reaction between the molten zinc coating and steel substrate as quickly as possible. In addition, the actual reaction time has been precisely calculated through the logged sample time and temperature during the hot-dipping process. The kinetics and formation mechanism of the inhibition layer was characterized using SEM, ICP and EBSD based on the total reaction time. For bath containing 0.2wt% dissolved AI, the results show that FeA13 nucleates and grows during the initial stage of the inhibition layer formation and then Fe2Als forms by a diffusive transformation. The evolution of the interfacial layer formed in a zinc bath with 0.13wt% dissolved AI, including Fe-Aland Fe-Zn intermetallic compounds, was a result of competing reactions. In the initial period, the Fe-Al reaction dominated due to high thermodynamic driving forces. After the zinc concentration reached a critical composition in the substrate grain boundaries, formation of Fe-Zn intermetallic compounds was kinetically favoured. Fe-Zn intermetallic compounds formed due to zinc diffusing to the substrate via short circuit paths and continuously grew by consuming Fe-Al interfacial layer after samples exited the zinc bath due to the limited Al supply. A mathematical model to describe the formation kinetics as a function of temperature for the 0.2wt% Al zinc bath was proposed. It indicated that the development of microstructure of the interfacial layer had significant influence on the effective diffusion coefficient and growth of this layer. However, the model underestimates the AI uptake by the interfacial layer, particularly at higher temperatures. This is thought to be due to the effect of the larger number of triple junctions in the inhibition layer leading to an underestimation of the effective diffusivity. </p> / Thesis / Master of Science (MSc)