The thesis "Anlre resolved dielectric response in carbon nanotubes" is dedicated to expounding the the anisotropy in the fundamental dielectric response of carbon nanotubes. While nanotubes are along their axis essentially planar graphene, the rolled up topology gives rise to entirely new features for perpendicular polarizations.

The thesis "Anlre resolved dielectric response in carbon nanotubes" is dedicated to expounding the the anisotropy in the fundamental dielectric response of carbon nanotubes. While nanotubes are along their axis essentially planar graphene, the rolled up topology gives rise to entirely new features for perpendicular polarizations.

In this thesis, power system transients are considered as an opportunity for development of on-line diagnostics of power components and specifically the insulation systems of power transformers and bushings. A new technique for on-line dielectric response measurement of power transformer bushings is proposed which utilizes natural transients in the power system, such as lightning and switching surges, as stimuli. Laboratory investigations are done on implementation of the proposed technique. Measurement considerations, data acquisition and processing involved in achievement of reasonable accuracy in the Dielectric Response (DR) are presented. Capability of the technique in tracking of the degradation signatures such as moisture content in the insulation has been evaluated and it has shown a good level of accuracy by being compared to the Frequency Domain Spectroscopy (FDS).  The proposed technique is tested on the service-aged 150 kV bushings and feasibility of the technique for monitoring of dielectric properties of power transformer bushings has been assessed; the results are promising for the technique to be used in the real application.  Partial Discharges (PD) behavior under transients has been also studied for different materials in this project. PD behavior of different defects, at different insulation condition, responding to the overvoltage transients in form of superimposed impulses on ac voltages was investigated and it was perceived how their distinctive response and the interpretation of  that, can be useful for their identification. Besides the conventional materials, surface ac PD properties of modified paper with silica and zinc oxide nanoparticles under the superimposed impulses have been assessed in this project. Proper type and optimum concentration level of nanoparticles in the paper are the factors that lead to the improvement of PD behavior in the modified paper under overvoltage transients. / <p>QC 20160525</p>

Na condução por saltos dispersiva, os portadores de carga são caracterizados por tempos de residência não exponenciais. Como uma conseqüência, efeitos hereditários aparecem e o problema deve ser conduzido no espaçõ de Laplace. Distribuições dielétricas conhecidas e algumas outras foram usadas como possíveis funções capazes de descrever o meio desordenado. Um estudo cuidadoso de seus espectros de freqüência foi realizado. O método de inversão de Widder truncado foi desenvolvido para possibilitar a volta do espaço de Laplace para o do tempo real. Dois tipos de problemas práticos foram abordados: condução dispersiva na qual o campo elétrico das cargas móveis pode ser desprezado e o caso de carga espacial para o qual essa aproximação não pode ser feita. Duas configurações de interesse foram escolhidas: decaimento do potencial de superfície de amostras carregadas por descarga corona e a subida do potencial no carregamento por corrente constante. / Dispersive conductive process are characterized by non-exponential residence times of the hopping carrier. As a consequence, hereditary effects appear and the problem must be conducted in the Laplace space. A bunch of known dielectric distributions functions and others were used as possible functions describing the disordered medium. A careful study of their frequency spectrum was carried out. The truncate Widder inversion was developed in order to allow returning from the Lapace to the real time space. Two kind of practical problems were studied: dispersive conduction in which the electric field of the mobile charge may be neglected and the space charge ones when that approximation cannot be made. Two configurations of interest were selected: the corona discharge potential decay and the constant current potentinal build-up.

Na condução por saltos dispersiva, os portadores de carga são caracterizados por tempos de residência não exponenciais. Como uma conseqüência, efeitos hereditários aparecem e o problema deve ser conduzido no espaçõ de Laplace. Distribuições dielétricas conhecidas e algumas outras foram usadas como possíveis funções capazes de descrever o meio desordenado. Um estudo cuidadoso de seus espectros de freqüência foi realizado. O método de inversão de Widder truncado foi desenvolvido para possibilitar a volta do espaço de Laplace para o do tempo real. Dois tipos de problemas práticos foram abordados: condução dispersiva na qual o campo elétrico das cargas móveis pode ser desprezado e o caso de carga espacial para o qual essa aproximação não pode ser feita. Duas configurações de interesse foram escolhidas: decaimento do potencial de superfície de amostras carregadas por descarga corona e a subida do potencial no carregamento por corrente constante. / Dispersive conductive process are characterized by non-exponential residence times of the hopping carrier. As a consequence, hereditary effects appear and the problem must be conducted in the Laplace space. A bunch of known dielectric distributions functions and others were used as possible functions describing the disordered medium. A careful study of their frequency spectrum was carried out. The truncate Widder inversion was developed in order to allow returning from the Lapace to the real time space. Two kind of practical problems were studied: dispersive conduction in which the electric field of the mobile charge may be neglected and the space charge ones when that approximation cannot be made. Two configurations of interest were selected: the corona discharge potential decay and the constant current potentinal build-up.

No description available.

No description available.

This thesis concerns partial discharge (PD) diagnostics withvariable frequency of applied voltage in the frequency range 1mHz - 400 Hz. The exploration of a new type of spectroscopythat combines partial discharge analysis and dielectricresponse is demonstrated. A question addressed is if and howthe PD activity varies with the frequency of the appliedvoltage. The nature of an existing frequency dependence couldbe useful in the classification of different defects and tojudge the degree of progressive ageing. A Variable-Frequency Phase Resolved Partial DischargeAnalysis (VF-PRPDA) technique is developed for the appliedvoltage frequency range 1 mHz - 400 Hz. The VF-PRPDA techniqueis combined with a system for high voltage dielectricspectroscopy that allows simultaneous measurements. TheVF-PRPDA technique is used for studying the frequencydependence of PD. The PD activity is for example measured byintegrated measures like total charge per cycle and totalnumber of discharges per cycle. Statistical measures like mean,standard deviation, skewness, kurtosis etc. are applied tomeasure the frequency dependence of the phasedistributions. High voltage dielectric spectroscopy is supplemented withharmonic analysis for studying non-linear dielectric responsecurrents. The VF-PRPDA technique is demonstrated on defined objectslike point-plane gaps and artificial voids, but also on aninsulated stator bar and a paper insulated cable. Surfacedischarges on insulating surfaces are studied in an environmentwith a controlled relative humidity and temperature. Theadsorption of moisture on the insulating surface alters thesurface conductivity of the surface and the frequencydependence of the PD activity. The influence of temperature upon the PD activity is studiedfor a oil paper insulated cable. The results of the measurements show that the partialdischarge activity in general is frequency dependent over thefrequency range 1 mHz - 400 Hz. The reasons behind thefrequency dependence are linked to surface- and bulk-conducting mechanisms, frequency dependent field distributionsand statistical effects of the supply of start electrons. An algorithm is developed that relates the phase resolved PDcurrent measured with the PRPDA technique to the non-linearcurrent measured with dielectric spectroscopy. The algorithm isexperimentally verified by simultaneous measurements of PRPDAand dielectric spectroscopy on defined objects. The resultsexplain the contribution of PD to the apparent capacitance andloss. Moreover, the harmonics of the fundamental currentcomponent yield information about, for example, polaritydependent discharge sources. Keywords:diagnostic methods, partial discharges, phaseresolved, variable frequency, dielectric spectroscopy,dielectric response, harmonics, insulation / QC 20100527

Development of the power gridtowards a more reliable and smarter system requires frequent on-line monitoring of the power components. Power transformers and their bushings are particularly important components in a power transmission system and their insulation degradation may lead to catastrophic failures. Time consuming and costly replacement of these components raise the importance of their frequent monitoring. A fault in a power transformer bushing can also involve in the failure of the transformer. Therefore, on-line diagnostics of power transformers and their bushings is of great interest. Several methods exist for diagnostics of these components. However, some of them can only be done off-line in maintenance periods, and the existing on-line methods generally provide less information, especially on the internal solid insulation parts. In this project, a new technique for on-line diagnostics of the power transformer and the bushing insulation is proposed. In this technique, natural transients happening in the power system such as lightning and switching surges can be used as stimuli for on-line dielectric response measurements. This technique can provide information on insulation close to what Dielectric Spectroscopy offers in off-line measurements. The wide-ranging frequency content of power system transients is their advantage for being usedas stimuli when measuring the Dielectric Response. The response can have particular signatures due to different types of defects in the insulation varying with frequency. Oil-impregnated paper as a major insulation component in power transformer and its bushing has been investigated in this project. Moisture content and temperature, as two important degradation factors in this type of insulation, have been studied to evaluate the performance of the proposed technique in the diagnostics of the oil-impregnated paper. The results are verified with the dielectric response obtained through commercial instruments. The results show that the proposed technique has the ability to track the changes in dielectric response due to the moisture content and temperature. Measurements were done at both highvoltage (40kV) and low voltage (10V) levels, and the corresponding circuit models to achieve reasonable accuracy for the results are discussed. Moving on from the material samples, a further study was done on three service-aged 150 kV bushings to investigate the feasibility of the technique on the diagnostics of power transformer bushings. Their dielectric response measured by the transient stimuli showed good agreement with their response obtained by the commercial instruments. The effect of the transformer winding on the transient response of the bushing is a further aspect of the real conditions for on-line diagnostics. This has been investigated through the simulation of transient models for transformers and bushings, and possible solutions for distinguishing the responses are presented. The proposed new on-line diagnostics technique by utilizing natural transients can provide information about the insulation system in a certain range of frequency without interrupting the operation or requiring an external voltage source. However, the validity range of the results depends on the bandwidth of the applied transients and other measurement considerations. This approach can be valuable in frequent monitoring of dielectric properties of the power transformers and their bushings as a complement to the other available on-line techniques. / <p>QC 20140409</p>

There is great interest in the development of new polar dielectric ceramics and multiferroic materials with new and improved properties. A family of tetragonal tungsten bronze (TTB) relaxors of composition Ba₆M³⁺Nb₉O₃₀ (M³⁺ = Ga³⁺, Sc³⁺ and In³⁺, and also their solid solutions) were studied in an attempt to understand their dielectric properties to enable design of novel polar TTB materials. A combination of electrical measurements (dielectric and impedance spectroscopy) and powder diffraction (X-ray and neutron) studies as a function of temperature was employed for characterising the dynamic dipole response in these materials. The effect of B-site doping on fundamental dipolar relaxation parameters were investigated by independently fitting the dielectric permittivity to the Vogel-Fulcher (VF) model, and the dielectric loss to Universal Dielectric Response (UDR) and Arrhenius models. These studies showed an increase in the characteristic dipole freezing temperature (T[subscript(f)]) with increase B-cation radius. Crystallographic data indicated a corresponding maximum in tetragonal strain at T[subscript(f)], consistent with the slowing and eventual freezing of dipoles. In addition, the B1 crystallographic site was shown to be most active in terms of the dipolar response. A more in-depth analysis of the relaxor behaviour of these materials revealed that, with the stepwise increase in the ionic radius of the M³⁺ cation on the B-site within the Sc-In solid solution series, the Vogel-Fulcher curves (lnf vs. T[subscript(m)]) are displaced to higher temperatures, while the degree of relaxor behaviour (frequency dependence) increases. Unfortunately, additional features appear in the dielectric spectroscopy data, dramatically affecting the Vogel-Fulcher fitting parameters. A parametric study of the reproducibility of acquisition and analysis of dielectric data was therefore carried out. The applicability of the Vogel-Fulcher expression to fit dielectric permittivity data was investigated, from the simple unrestricted (“free”) fit to a wider range of imposed values for the VF relaxation parameters that fit with high accuracy the experimental data. The reproducibility of the dielectric data and the relaxation parameters obtained by VF fitting were shown to be highly sensitive to the thermal history of samples and also the conditions during dielectric data acquisition (i.e., heating/cooling rate). In contrast, UDR analysis of the dielectric loss data provided far more reproducible results, and to an extent was able to partially deconvolute the additional relaxation processes present in these materials. The exact nature of these additional relaxations is not yet fully understood. It was concluded application of the Vogel-Fulcher model should be undertaken with great care. The UDR model may represent a feasible alternative to the evaluation of fundamental relaxation parameters, and a step forward towards the understanding of the dielectric processes in tetragonal tungsten bronzes.