This dissertation presents new Herschel observations at 70 micron, 160 micron, 250 micron, 350 micron, and 500 micron of the Perseus molecular cloud from the Herschel Gould Belt Survey. The Perseus molecular cloud is a nearby star-forming region consisting of seven main star-forming clumps. The Herschel observations are used to characterize and contrast the properties of these clumps, and to study their embedded core populations. First, we probed the exceptionally young clump, B1-E. Using complementary molecular line data, we demonstrate that B1-E is likely fragmenting into a first generation of dense cores in relative isolation. Such a core formation region has never been observed before. Second, we use complementary long wavelength observations at 850 micron to study the dust properties in the larger, more active B1 clump. We find that Herschel data alone cannot constrain well the dust properties of cold dust emission and that long wavelength observations are needed. Additionally, we find evidence of dust grain growth towards the dense cores in B1, where the dust emissivity index, beta, varies from the often assumed value of beta = 2. In the absence of long wavelength observations, however, assuming beta = 2 is preferable over measuring beta with the Herschel-only bands. Finally, we use the source extraction code, getsources, to identify the core populations within each clump from the Herschel data. In addition, we use complementary archival infrared observations to study their populations of young stellar objects (YSOs). We find that the more massive clumps have an excess of older stage YSOs, suggesting that these regions contracted first. Starless cores are typically associated with peaks in the column density, where those found towards regions of higher column density also have higher average densities and colder temperatures. Starless cores associated with a strong, local interstellar radiation field, however, have higher temperatures. We find that the clumps with the most prominent high column density tails also had the highest fractions of early-stage YSOs. This relation suggests that the quantity of high column density material corresponds to recent star formation activity. / Graduate / 0606

Electrostatic precipitators (ESPs) are commonly used to control particulate emissions from recovery boilers in the kraft pulping process. The electrical resistivity of entrained particulates is known to affect the performance of ESPs. There are many factors which influence resistivity of particulate matter, such as field strength, time of exposure, particle size, particle composition, temperature, and flue gas composition. The objective of this study was to identify the ideal operating conditions and dust particle characteristics which lead to an optimum dust resistivity and maximized ESP efficiency. The effect of these factors was examined through a variety of experimental and analytical techniques on kraft recovery boiler ash samples and synthetically prepared samples. It was concluded that particle composition, gas composition, and ambient temperature had the most pronounced effects, while the other factors, such as field strength and exposure time, had a smaller impact on particle resistivity.

Electrostatic precipitators (ESPs) are commonly used to control particulate emissions from recovery boilers in the kraft pulping process. The electrical resistivity of entrained particulates is known to affect the performance of ESPs. There are many factors which influence resistivity of particulate matter, such as field strength, time of exposure, particle size, particle composition, temperature, and flue gas composition. The objective of this study was to identify the ideal operating conditions and dust particle characteristics which lead to an optimum dust resistivity and maximized ESP efficiency. The effect of these factors was examined through a variety of experimental and analytical techniques on kraft recovery boiler ash samples and synthetically prepared samples. It was concluded that particle composition, gas composition, and ambient temperature had the most pronounced effects, while the other factors, such as field strength and exposure time, had a smaller impact on particle resistivity.

Despite increasing concern about the presence of heavy metals, pesticides and other toxins in indoor environments, very little is known about the physical and chemical composition of ordinary household dust. This study represents the first systematic investigation of the mineralogical composition of indoor dust in residential housing in Canada. Specimens of dust were obtained from homes in six geographically separate cities in the Province of Ontario: two located on the metamorphic and igneous rocks of the Precambrian Canadian Shield (Thunder Bay and Sudbury), the other four located on Palaeozoic limestone and shale dominated bedrock (Barrie, Burlington, Cambridge, and Hamilton). Forty samples of household vacuum dust were obtained. The coarse fraction (80 – 300 µm) of this dust was subjected to flotation (using water) to separate the organic components (e.g. insect fragments, dander), natural and synthetic materials (e.g. fibres, plastics) from the mineral residue. The mineral fraction was then analyzed using quantitative point counting, polarizing light microscopy, powder X-ray diffraction and scanning electron microscopy methods. Despite the great distances between the sampling localities and the distinct differences in bedrock geology, the mineral fraction of dust from all six cities is remarkably similar and dominated by quartz and feldspar, followed by lithic fragments, calcite, and amphibole. Some evidence of the influence of local geology can nevertheless be found. For example, a relatively higher proportion of sulphide minerals is observed in the two cities on the Canadian Shield where these minerals are clearly more abundant in the bedrock. Specimens from Sudbury, Canada’s largest mining centre located atop a nickel-sulphide mineral deposit, showed the highest sulphide contents. Quartz is the dominant mineral in all cities. All quartz grains have internal strain features and fluid inclusions that are indicative of a metamorphic-igneous provenance. In all cities, sand is used on the streets as an abrasive for traction during the icy winter season. This sand is obtained in all cases from local glaciofluvial deposits that were ultimately derived principally from the rocks of the Canadian Shield in the last Pleistocene glaciations that affected all of Ontario. Thus, tracking in sand is the most plausible mechanism by which quartz was introduced into these homes since sampling was done, in all cases, in the winter season. The results indicate that glacial deposits dominate the mineral composition of indoor dust in Ontario cities and that nature of the bedrock immediately underlying the sampling sites is relatively of minor importance.

The objective of this dissertation is to apply radiogenic isotopes extracted from marine sediments to investigate aspects of global climate change over the past 25 kyr, especially ocean and atmospheric circulation, continental aridity, and hydrology. By focusing on the geochemical records from marine sediments and authigenic precipitates preserved in these sediments, I aim to better understand climate forcing and feedback mechanisms, which are critical to models of climate change. Firstly, I have investigated the dynamics of the Intertropical Convergence Zone (ITCZ) over the past 25 kyr in the eastern equatorial Pacific by fingerprinting dust provenance using radiogenic isotopes (Nd, Sr, Pb) and trace elements (Fe, Si, Ba) in the detrital fraction of marine sediments along a transect across the equator at 110ºW. Results from this study suggest no glacial-Holocene difference in the mean position of the ITCZ, but a more northerly, possibly stronger, deglacial ITCZ. Secondly, I have applied Nd isotope ratios from authigenic precipitates extracted from marine sediments and those from fish debris to trace past intermediate water circulation changes on glacial-interglacial and millennial timescales. The authigenic Nd isotope record from the Florida Straits suggests a reduced circulation of Antarctic Intermediate Water (AAIW) into the tropical North Atlantic during the Younger Dryas (YD) and Heinrich 1 (H1) events, associated with a significant reduction in AMOC. However, in the Southern Caribbean, apparent deviations in the Nd isotopic compositions between the acid-reductive leachate and the fish debris suggest that the leachate method is not reliable at this location and that it needs to be tested in more detail in various oceanic settings. In the Southern Caribbean, the fish debris Nd isotope results suggest a two-step recovery of the upper North Atlantic Deep Water during the last deglaciation. Comparing our new fish debris Nd isotope data to authigenic Nd isotope data for sediments from the Florida Straits and the Demarara Rise, we propose that glacial and deglacial AAIW does not penetrate beyond the lower depth limit of modern AAIW in the tropical North Atlantic. Both studies suggest a tight connection between Atlantic intermediate water circulation variability and high-latitude North Atlantic climate change.

In this thesis, it is aimed to investigate and analyze the effect of meteorological conditions on airborne dust measured at Ovacik Open Pit Gold Mine. Meteorological data must be sound and reliable which are used mainly to design an air model to predict the effect of industrial sites on air quality during production. Wind speed, wind direction, airtemperature, air pressure, relative humidity, rainfall, evaporation and sunshine. are the parameters investigated in this study. In the thesis, the meteorological data observed are analyzed and discussed together with the airborne dust measured by MP101M Suspended Particulate Beta Gauge Monitor at Ovacik Gold Mine. In this study, the most significant meteorological parameter affecting airborne dust concentration is determined as air temperature. In this study, it is also determined through airborne dust measurements that neither the short-term limit nor the long-term limit has been exceeded. Therefore, the airborne dust concentrations at Ovacik Gold Mine comply with the Turkish Air Quality Control Regulation.

Chlorinated paraffins (CPs) are ubiquitous environmental contaminants. They fulfill all of the criteria (persistent, toxic, and subject to long-range transport) for persistent organic pollutants (POPs) according to the United Nations Economic Commission for Europe (UNECE). CPs are also under consideration for inclusion in the Stockholm Convention on POPs. Their presence has been shown in various environmental matrices in the industrialized parts of the world, as well as in remote regions such as the Arctic. The aim of this thesis was to increase the limited knowledge of the presence of CPs in the environment, their sources to the environment, and the resulting human exposure. An analytical procedure for the determination of CPs in environmental samples based on gas chromatography coupled to electron capture detection (GC-ECD) has been developed. GC-ECD is a relatively inexpensive instrument that is fast and easy to operate. These advantages open up the possibility for a comprehensive screening of the occurrence of CPs in the environment, including developing countries. Furthermore, the occurrence of CPs in ambient air and in indoor air and dust was studied. Elevated CP concentrations in indoor air (<5-210 ng/m3) were observed compared to ambient air (0.7-33 ng/m3), which is indicative of the presence of indoor emission sources. Indoor air and dust concentrations were used to estimate the human exposure to CPs via the indoor environment. Comparison of the estimates to available dietary intake estimates indicated that the indoor exposure pathways are not negligible. CP concentrations in ambient air from urban Stockholm were higher than in rural Aspvreten, Sweden. This indicates the presence of additional (emission) sources in urban areas compared to rural sites. Additionally, a seasonal variation of air concentrations was observed at both locations, suggesting temperature dependent emission sources for CPs. These observations were supported by a substance flow analysis of CPs performed for Stockholm. This study estimated the major emission sources of CPs to the Stockholm environment to be emissions from painted surfaces and in-place sealants. / At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 2: Manuscript. Paper 3: Manuscript. Paper 4: Manuscript.

The IceCube Neutrino Telescope is designed to detect high energy neutrinos with a large array of photomultiplier tubes placed deep within the Antarctic ice. The way that light propagates through the ice needs to be modelled accurately to enable the paths of charged particles to be reconstructed from the distribution of their Cerenkov radiation. Light travelling through even the purest of ice will undergo scattering and absorption processes, however the ice in which IceCube is embedded has optical properties that vary significantly with depth which need to be accurately modelled. Currently, simulation of the muon background using the current ice model is unable to fully replicate experimental data. In this thesis we investigate a potential method of improving on the current generation of ice models. We introduce thin, highly absorbing layers into the current description of the detection medium and investigate the effect on the simulation of muon tracks in IceCube. We find that better agreement between simulation and data can be seen in the occupancy of optical modules, through the introduction of such absorptive layers into the existing ice layers.

ABSTRACT Occupational exposure to wood dust and biohazards associated with wood dust (endotoxins, (1->3)-b-D-glucans, Gram (-)ve bacteria and fungi), their correlation to respiratory function, and symptoms among woodworkers have been investigated in the present study. Wood dust, endotoxins, and allergenic fungi are the main hazards found in woodworking environments. Relatively very few studies have been done on wood dust exposure. The present study was designed to comprehensively investigate the health effects of wood dust exposure, and in particular provide new information regarding: Exposure to (1->3)-b-D-glucans in an occupational environment; Levels of exposure to wood dust and biohazards associated with wood dust in different woodworking environments; Correlations among personal exposures, especially correlations between (1->3)-b-D-glucans and fungi exposures, and endotoxins and Gram (-)ve bacteria exposures; Effects of personal exposure to biohazards on lung function; Effects of personal exposure to biohazards on work-related symptoms; and Determinants of inhalable exposures (provide which factors in the environment influence the personal inhalable exposures). Workers at four different woodworking processes; two logging sites, four sawmills, one major woodchipping operation and five joineries situated in the state of New South Wales in Australia were studied for personal exposure to inhalable dust (n=182) and respirable dust (n=81), fungi (n=120), Gram (-)ve bacteria (n=120), inhalable endotoxin (n=160), respirable endotoxin (n=79), inhalable (1->3)-b-D-glucan (n=105), and respirable (1->3)-b-D-glucan (n=62). The workers (n=168) were also tested for lung function. A questionnaire study (n=195) was carried out to determine the prevalence of work-related symptoms. The geometric mean inhalable exposure at logging sites was 0.56 mg/m3 (n=7), sawmills 1.59 mg/m3 (n=93), the woodchipping mill 1.86 mg/m3 (n=9) and joineries 3.68 mg/m3 (n=66). Overall, sixty two percent of the exposures exceeded the current standards. Among joineries, 95% of the hardwood exposures and 35% of the softwood exposures were above the relevant standards. Compared with green mills, the percentage of samples, which exceeded the hardwood standard was high for dry mills (70% in dry mills, 50% in green mills). The respirable dust exposures were high at the joineries compared with the other worksites. Exposure levels to fungi at logging sites and sawmills were in the range 103-104 cfu/m3, woodchipping 103-105 cfu/m3 and joineries 102-104 cfu/m3. The predominant fungi found at sawmills were Penicillium spp. High exposure levels of Aureobasidium pullulans were also found at two sawmills. At the woodchipping mill the predominant species were Aspergillus fumigatus, Penicillium spp., and Paecilomyces spp. The sawmills, which employed kiln drying processes, had lower exposure levels of fungi compared with the green mills. Those workplaces which had efficient dust control systems showed less exposure to fungi and bacteria. Although mean endotoxin levels were lower than the suggested threshold value of 20 ng/m3, some personal exposures at sawmills and joineries exceeded the threshold limit value. The mean inhalable (1->3)-b-D-glucan level at the woodchipping mill was 2.32 ng/m3, at sawmills 1.37 ng/m3, at logging sites 2.02 ng/m3, and at joineries 0.43 ng/m3. For the respirable size fraction, mean endotoxin and mean (1->3)-b-D-glucan concentrations were much lower, being similar to observed dust concentrations. Significant correlations were found between mean inhalable endotoxin and Gram (-)ve bacteria levels (p<0.0001), and mean airborne inhalable (1->3)-b-D-glucan and fungi levels (p=0.0003). The correlations between mean respirable endotoxin levels vs Gram (-)ve bacteria exposure levels (p=0.005), and respirable (1->3)-b-D-glucan exposure levels vs total fungi levels (p=0.005) were also significant. Significant correlations were found between lung function and personal exposures. Multivariate analyses showed that the effect of all the personal exposures on cross-shift decrements in lung function was more prominent among sawmill and chip mill workers compared with joinery workers. Woodworkers had markedly high prevalence of cough, phlegm, chronic bronchitis, frequent headaches, throat and eye irritations, and nasal symptoms compared with controls. Among the woodworkers, smokers had a high prevalence of chronic bronchitis (20%) compared with non-smokers (10%). Some workers also reported a variety of allergy problems due to exposure to various types of wood dust. Both joinery workers and sawmill and chip mill workers revealed significant correlations between work-related symptoms and personal exposures. Chronic bronchitis was significantly correlated with personal exposure to wood dust, endotoxin, (1->3)-b-D-glucan, fungi, and Gram (-)ve bacteria among joinery workers. Whereas among sawmill workers chronic bronchitis was significantly correlated with personal exposure to endotoxin, (1->3)-b-D-glucan, and fungi. Woodworkers showed significant positive correlations between percentage cross-shift change (decrease) in lung function and respiratory symptoms. Significant inverse correlations were also found among percentage predicted lung function and respiratory symptoms. The elevated inhalable dust exposures observed in this study can be explained by a combination of factors, including: lack of awareness of potential health effects of wood dust exposure among both management and workers, aging equipment, inadequate and ineffective dust extraction systems or usually none especially for hand held tools, poor maintenance of the ventilation system in some, non-segregation of dusty processes, dry sweeping, and the use of compressed air jets. The determinant-of-exposure analysis confirmed the field observations. The significant determinants of personal inhalable dust exposures (n=163) were found to be: local exhaust ventilation, job title, use of hand-held tools, cleaning method used, use of compressed air, and green or dry wood processed. Type of wood processed was not found to be statistically significant. A majority of workers (~90%) did not wear appropriate respirators approved for wood dust, while the workers who did wear them, used them on average less than 50% of the time. Workers should be protected by controlling dust at its source. When exposure to wood dust cannot be avoided, engineering controls should be supplemented with the use of appropriate personal protective equipment.

Thesis (Ph.D.)--University of Wollongong, 2006. / Typescript. Includes bibliographical references: leaf 208-224.